NP-MRD: Showing NP-Card for 7,21-dihydroxy-12-(3-hydroxy-4-methoxyphenyl)-8,16,17,18-tetramethoxy-4-oxa-1-azapentacyclo[11.8.0.0²,¹¹.0⁵,¹⁰.0¹⁴,¹⁹]henicosa-2(11),5(10),6,8,12,14(19),15,17-octaen-3-one (NP0324807)

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Record Information

Version

2.0

Created at

2022-09-12 05:06:11 UTC

Updated at

2022-09-12 05:06:11 UTC

NP-MRD ID

NP0324807

Secondary Accession Numbers

None

Natural Product Identification

Common Name

7,21-dihydroxy-12-(3-hydroxy-4-methoxyphenyl)-8,16,17,18-tetramethoxy-4-oxa-1-azapentacyclo[11.8.0.0²,¹¹.0⁵,¹⁰.0¹⁴,¹⁹]henicosa-2(11),5(10),6,8,12,14(19),15,17-octaen-3-one

Description

Lamellarin V belongs to the class of organic compounds known as phenylpyrroles. These are polycyclic aromatic compounds containing a benzene ring linked to a pyrrole ring through a CC or CN bond. Based on a literature review very few articles have been published on Lamellarin V.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309122207062D          

 41 46  0  0  0  0            999 V2000
    3.7103   -3.4419    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.9959   -3.0294    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
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    2.2814   -0.9669    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.9959   -0.5544    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.9959    0.2706    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.3284    0.7556    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.5834    1.5402    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    3.4084    1.5402    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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M  END

     RDKit          3D

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M  END


  Mrv1652309122207062D          

 41 46  0  0  0  0            999 V2000
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    4.4248   -2.2044    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  2  0  0  0  0
  4  5  1  0  0  0  0
  5  6  2  0  0  0  0
  6  7  1  0  0  0  0
  7  8  2  0  0  0  0
  8  9  1  0  0  0  0
  9 10  1  0  0  0  0
 10 11  1  0  0  0  0
 11 12  2  0  0  0  0
 11 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  2  0  0  0  0
 15 16  1  0  0  0  0
 16 17  1  0  0  0  0
 16 18  2  0  0  0  0
 18 19  1  0  0  0  0
 19 20  1  0  0  0  0
 18 21  1  0  0  0  0
 21 22  2  0  0  0  0
 14 22  1  0  0  0  0
 22 23  1  0  0  0  0
  7 23  1  0  0  0  0
 10 23  2  0  0  0  0
  9 24  1  0  0  0  0
 24 25  1  0  0  0  0
 24 26  1  0  0  0  0
 26 27  1  0  0  0  0
 27 28  2  0  0  0  0
  8 28  1  0  0  0  0
 28 29  1  0  0  0  0
 29 30  2  0  0  0  0
 30 31  1  0  0  0  0
 31 32  1  0  0  0  0
 30 33  1  0  0  0  0
 33 34  1  0  0  0  0
 34 35  1  0  0  0  0
 33 36  2  0  0  0  0
 27 36  1  0  0  0  0
 36 37  1  0  0  0  0
 37 38  1  0  0  0  0
  6 39  1  0  0  0  0
 39 40  2  0  0  0  0
  3 40  1  0  0  0  0
 40 41  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0324807

> <DATABASE_NAME>
NP-MRD

> <SMILES>
COC1=CC=C(C=C1O)C1=C2N(C(O)CC3=C2C=C(OC)C(OC)=C3OC)C2=C1C1=CC(OC)=C(O)C=C1OC2=O

> <INCHI_IDENTIFIER>
InChI=1S/C30H27NO10/c1-36-19-7-6-13(8-17(19)32)24-25-16-10-21(37-2)18(33)12-20(16)41-30(35)27(25)31-23(34)11-15-14(26(24)31)9-22(38-3)29(40-5)28(15)39-4/h6-10,12,23,32-34H,11H2,1-5H3

> <INCHI_KEY>
OXJGJJFCGPYPHD-UHFFFAOYSA-N

> <FORMULA>
C30H27NO10

> <MOLECULAR_WEIGHT>
561.543

> <EXACT_MASS>
561.163496073

> <JCHEM_ACCEPTOR_COUNT>
9

> <JCHEM_ATOM_COUNT>
68

> <JCHEM_AVERAGE_POLARIZABILITY>
57.82646805384046

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
3

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
7,21-dihydroxy-12-(3-hydroxy-4-methoxyphenyl)-8,16,17,18-tetramethoxy-4-oxa-1-azapentacyclo[11.8.0.0^{2,11}.0^{5,10}.0^{14,19}]henicosa-2(11),5,7,9,12,14,16,18-octaen-3-one

> <JCHEM_LOGP>
3.4148167179999986

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
6

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
9.70305707674777

> <JCHEM_PKA_STRONGEST_ACIDIC>
7.94917404354134

> <JCHEM_PKA_STRONGEST_BASIC>
-3.6538920615014634

> <JCHEM_POLAR_SURFACE_AREA>
138.07000000000002

> <JCHEM_REFRACTIVITY>
147.3497

> <JCHEM_ROTATABLE_BOND_COUNT>
6

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
7,21-dihydroxy-12-(3-hydroxy-4-methoxyphenyl)-8,16,17,18-tetramethoxy-4-oxa-1-azapentacyclo[11.8.0.0^{2,11}.0^{5,10}.0^{14,19}]henicosa-2(11),5,7,9,12,14,16,18-octaen-3-one

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 12-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   12-SEP-22         0                                  
HETATM    1  C   UNK     0       6.926  -6.425   0.000  0.00  0.00           C+0
HETATM    2  O   UNK     0       5.592  -5.655   0.000  0.00  0.00           O+0
HETATM    3  C   UNK     0       5.592  -4.115   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       4.259  -3.345   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       4.259  -1.805   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       5.592  -1.035   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       5.592   0.505   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       4.346   1.410   0.000  0.00  0.00           C+0
HETATM    9  N   UNK     0       4.822   2.875   0.000  0.00  0.00           N+0
HETATM   10  C   UNK     0       6.362   2.875   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       7.393   4.019   0.000  0.00  0.00           C+0
HETATM   12  O   UNK     0       6.917   5.484   0.000  0.00  0.00           O+0
HETATM   13  O   UNK     0       8.899   3.699   0.000  0.00  0.00           O+0
HETATM   14  C   UNK     0       9.375   2.235   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      10.881   1.914   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0      11.357   0.450   0.000  0.00  0.00           C+0
HETATM   17  O   UNK     0      12.864   0.130   0.000  0.00  0.00           O+0
HETATM   18  C   UNK     0      10.327  -0.695   0.000  0.00  0.00           C+0
HETATM   19  O   UNK     0      10.803  -2.159   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0       9.772  -3.304   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       8.820  -0.374   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       8.344   1.090   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       6.838   1.410   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       3.792   4.019   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0       4.268   5.484   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0       2.285   3.699   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       1.810   2.235   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       2.840   1.090   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       2.364  -0.374   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       0.858  -0.695   0.000  0.00  0.00           C+0
HETATM   31  O   UNK     0       0.382  -2.159   0.000  0.00  0.00           O+0
HETATM   32  C   UNK     0      -1.124  -2.479   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0      -0.173   0.450   0.000  0.00  0.00           C+0
HETATM   34  O   UNK     0      -1.679   0.130   0.000  0.00  0.00           O+0
HETATM   35  C   UNK     0      -2.155  -1.335   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0       0.303   1.914   0.000  0.00  0.00           C+0
HETATM   37  O   UNK     0      -0.727   3.059   0.000  0.00  0.00           O+0
HETATM   38  C   UNK     0      -0.251   4.524   0.000  0.00  0.00           C+0
HETATM   39  C   UNK     0       6.926  -1.805   0.000  0.00  0.00           C+0
HETATM   40  C   UNK     0       6.926  -3.345   0.000  0.00  0.00           C+0
HETATM   41  O   UNK     0       8.260  -4.115   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4   40                                                  
CONECT    4    3    5                                                       
CONECT    5    4    6                                                       
CONECT    6    5    7   39                                                  
CONECT    7    6    8   23                                                  
CONECT    8    7    9   28                                                  
CONECT    9    8   10   24                                                  
CONECT   10    9   11   23                                                  
CONECT   11   10   12   13                                                  
CONECT   12   11                                                            
CONECT   13   11   14                                                       
CONECT   14   13   15   22                                                  
CONECT   15   14   16                                                       
CONECT   16   15   17   18                                                  
CONECT   17   16                                                            
CONECT   18   16   19   21                                                  
CONECT   19   18   20                                                       
CONECT   20   19                                                            
CONECT   21   18   22                                                       
CONECT   22   21   14   23                                                  
CONECT   23   22    7   10                                                  
CONECT   24    9   25   26                                                  
CONECT   25   24                                                            
CONECT   26   24   27                                                       
CONECT   27   26   28   36                                                  
CONECT   28   27    8   29                                                  
CONECT   29   28   30                                                       
CONECT   30   29   31   33                                                  
CONECT   31   30   32                                                       
CONECT   32   31                                                            
CONECT   33   30   34   36                                                  
CONECT   34   33   35                                                       
CONECT   35   34                                                            
CONECT   36   33   27   37                                                  
CONECT   37   36   38                                                       
CONECT   38   37                                                            
CONECT   39    6   40                                                       
CONECT   40   39    3   41                                                  
CONECT   41   40                                                            
MASTER        0    0    0    0    0    0    0    0   41    0   92    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₃₀H₂₇NO₁₀

Average Mass

561.5430 Da

Monoisotopic Mass

561.16350 Da

IUPAC Name

7,21-dihydroxy-12-(3-hydroxy-4-methoxyphenyl)-8,16,17,18-tetramethoxy-4-oxa-1-azapentacyclo[11.8.0.0^{2,11}.0^{5,10}.0^{14,19}]henicosa-2(11),5,7,9,12,14,16,18-octaen-3-one

Traditional Name

7,21-dihydroxy-12-(3-hydroxy-4-methoxyphenyl)-8,16,17,18-tetramethoxy-4-oxa-1-azapentacyclo[11.8.0.0^{2,11}.0^{5,10}.0^{14,19}]henicosa-2(11),5,7,9,12,14,16,18-octaen-3-one

CAS Registry Number

Not Available

SMILES

COC1=CC=C(C=C1O)C1=C2N(C(O)CC3=C2C=C(OC)C(OC)=C3OC)C2=C1C1=CC(OC)=C(O)C=C1OC2=O

InChI Identifier

InChI=1S/C30H27NO10/c1-36-19-7-6-13(8-17(19)32)24-25-16-10-21(37-2)18(33)12-20(16)41-30(35)27(25)31-23(34)11-15-14(26(24)31)9-22(38-3)29(40-5)28(15)39-4/h6-10,12,23,32-34H,11H2,1-5H3

InChI Key

OXJGJJFCGPYPHD-UHFFFAOYSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Not Available

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as phenylpyrroles. These are polycyclic aromatic compounds containing a benzene ring linked to a pyrrole ring through a CC or CN bond.

Kingdom

Organic compounds

Super Class

Organoheterocyclic compounds

Class

Pyrroles

Sub Class

Substituted pyrroles

Direct Parent

Phenylpyrroles

Alternative Parents

Substituents

3-phenylpyrrole
Coumarin
1-benzopyran
Methoxyphenol
Benzopyran
Phenoxy compound
Phenol ether
Methoxybenzene
Anisole
Pyranone
Alkyl aryl ether
Phenol
1-hydroxy-2-unsubstituted benzenoid
1-hydroxy-4-unsubstituted benzenoid
Monocyclic benzene moiety
Benzenoid
Pyran
Heteroaromatic compound
Lactone
Oxacycle
Ether
Alkanolamine
Azacycle
Organooxygen compound
Organonitrogen compound
Hydrocarbon derivative
Organic oxide
Organic oxygen compound
Organic nitrogen compound
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	3.41	ChemAxon
pKa (Strongest Acidic)	7.95	ChemAxon
pKa (Strongest Basic)	-3.7	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	9	ChemAxon
Hydrogen Donor Count	3	ChemAxon
Polar Surface Area	138.07 Å²	ChemAxon
Rotatable Bond Count	6	ChemAxon
Refractivity	147.35 m³·mol⁻¹	ChemAxon
Polarizability	57.83 Å³	ChemAxon
Number of Rings	6	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

8206304

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

10030733

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for 7,21-dihydroxy-12-(3-hydroxy-4-methoxyphenyl)-8,16,17,18-tetramethoxy-4-oxa-1-azapentacyclo[11.8.0.0²,¹¹.0⁵,¹⁰.0¹⁴,¹⁹]henicosa-2(11),5(10),6,8,12,14(19),15,17-octaen-3-one (NP0324807)

MOL for NP0324807 (7,21-dihydroxy-12-(3-hydroxy-4-methoxyphenyl)-8,16,17,18-tetramethoxy-4-oxa-1-azapentacyclo[11.8.0.0²,¹¹.0⁵,¹⁰.0¹⁴,¹⁹]henicosa-2(11),5(10),6,8,12,14(19),15,17-octaen-3-one)

3D MOL for NP0324807 (7,21-dihydroxy-12-(3-hydroxy-4-methoxyphenyl)-8,16,17,18-tetramethoxy-4-oxa-1-azapentacyclo[11.8.0.0²,¹¹.0⁵,¹⁰.0¹⁴,¹⁹]henicosa-2(11),5(10),6,8,12,14(19),15,17-octaen-3-one)

3D SDF for NP0324807 (7,21-dihydroxy-12-(3-hydroxy-4-methoxyphenyl)-8,16,17,18-tetramethoxy-4-oxa-1-azapentacyclo[11.8.0.0²,¹¹.0⁵,¹⁰.0¹⁴,¹⁹]henicosa-2(11),5(10),6,8,12,14(19),15,17-octaen-3-one)

3D-SDF for NP0324807 (7,21-dihydroxy-12-(3-hydroxy-4-methoxyphenyl)-8,16,17,18-tetramethoxy-4-oxa-1-azapentacyclo[11.8.0.0²,¹¹.0⁵,¹⁰.0¹⁴,¹⁹]henicosa-2(11),5(10),6,8,12,14(19),15,17-octaen-3-one)

PDB for NP0324807 (7,21-dihydroxy-12-(3-hydroxy-4-methoxyphenyl)-8,16,17,18-tetramethoxy-4-oxa-1-azapentacyclo[11.8.0.0²,¹¹.0⁵,¹⁰.0¹⁴,¹⁹]henicosa-2(11),5(10),6,8,12,14(19),15,17-octaen-3-one)

3D PDB for NP0324807 (7,21-dihydroxy-12-(3-hydroxy-4-methoxyphenyl)-8,16,17,18-tetramethoxy-4-oxa-1-azapentacyclo[11.8.0.0²,¹¹.0⁵,¹⁰.0¹⁴,¹⁹]henicosa-2(11),5(10),6,8,12,14(19),15,17-octaen-3-one)

SMILES for NP0324807 (7,21-dihydroxy-12-(3-hydroxy-4-methoxyphenyl)-8,16,17,18-tetramethoxy-4-oxa-1-azapentacyclo[11.8.0.0²,¹¹.0⁵,¹⁰.0¹⁴,¹⁹]henicosa-2(11),5(10),6,8,12,14(19),15,17-octaen-3-one)

INCHI for NP0324807 (7,21-dihydroxy-12-(3-hydroxy-4-methoxyphenyl)-8,16,17,18-tetramethoxy-4-oxa-1-azapentacyclo[11.8.0.0²,¹¹.0⁵,¹⁰.0¹⁴,¹⁹]henicosa-2(11),5(10),6,8,12,14(19),15,17-octaen-3-one)

Structure for NP0324807 (7,21-dihydroxy-12-(3-hydroxy-4-methoxyphenyl)-8,16,17,18-tetramethoxy-4-oxa-1-azapentacyclo[11.8.0.0²,¹¹.0⁵,¹⁰.0¹⁴,¹⁹]henicosa-2(11),5(10),6,8,12,14(19),15,17-octaen-3-one)

3D Structure for NP0324807 (7,21-dihydroxy-12-(3-hydroxy-4-methoxyphenyl)-8,16,17,18-tetramethoxy-4-oxa-1-azapentacyclo[11.8.0.0²,¹¹.0⁵,¹⁰.0¹⁴,¹⁹]henicosa-2(11),5(10),6,8,12,14(19),15,17-octaen-3-one)