NP-MRD: Showing NP-Card for (2r,2's,2''s,4'as,5'r,5''s,6'r,8's,8'ar)-8'-(acetyloxy)-5''-(furan-3-yl)-2',2''-dihydroxy-6'-methyl-hexahydro-2'h-dispiro[oxirane-2,1'-naphthalene-5',3''-oxolan]-8'a-ylmethyl acetate (NP0323543)

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Record Information

Version

2.0

Created at

2022-09-12 03:01:59 UTC

Updated at

2022-09-12 03:01:59 UTC

NP-MRD ID

NP0323543

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(2r,2's,2''s,4'as,5'r,5''s,6'r,8's,8'ar)-8'-(acetyloxy)-5''-(furan-3-yl)-2',2''-dihydroxy-6'-methyl-hexahydro-2'h-dispiro[oxirane-2,1'-naphthalene-5',3''-oxolan]-8'a-ylmethyl acetate

Description

3,20-Dideacetylteupyreinidine belongs to the class of organic compounds known as dicarboxylic acids and derivatives. These are organic compounds containing exactly two carboxylic acid groups. (2r,2's,2''s,4'as,5'r,5''s,6'r,8's,8'ar)-8'-(acetyloxy)-5''-(furan-3-yl)-2',2''-dihydroxy-6'-methyl-hexahydro-2'h-dispiro[oxirane-2,1'-naphthalene-5',3''-oxolan]-8'a-ylmethyl acetate is found in Teucrium montbretii and Teucrium polium. Based on a literature review very few articles have been published on 3,20-Dideacetylteupyreinidine.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309122205022D          

 33 37  0  0  1  0            999 V2000
    0.5549    1.5471    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.3789    1.5067    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.8259    2.2001    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.7559    0.7729    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.5799    0.7325    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.9569   -0.0013    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.9110    0.8224    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.1746    1.1945    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
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    3.6014    1.2741    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    5.1175    0.4554    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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M  END

     RDKit          3D

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M  END


  Mrv1652309122205022D          

 33 37  0  0  1  0            999 V2000
    0.5549    1.5471    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.3789    1.5067    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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M  END
> <DATABASE_ID>
NP0323543

> <DATABASE_NAME>
NP-MRD

> <SMILES>
C[C@@H]1C[C@H](OC(C)=O)[C@]2(COC(C)=O)[C@H](CC[C@H](O)[C@]22CO2)[C@@]11C[C@H](O[C@@H]1O)C1=COC=C1

> <INCHI_IDENTIFIER>
InChI=1S/C24H32O9/c1-13-8-20(32-15(3)26)23(11-30-14(2)25)18(4-5-19(27)24(23)12-31-24)22(13)9-17(33-21(22)28)16-6-7-29-10-16/h6-7,10,13,17-21,27-28H,4-5,8-9,11-12H2,1-3H3/t13-,17+,18-,19+,20+,21+,22-,23+,24-/m1/s1

> <INCHI_KEY>
QGKJGQDHZIBMKX-MYHZJNNASA-N

> <FORMULA>
C24H32O9

> <MOLECULAR_WEIGHT>
464.511

> <EXACT_MASS>
464.20463261

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
65

> <JCHEM_AVERAGE_POLARIZABILITY>
47.68094418894077

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
2

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
1

> <JCHEM_IUPAC>
[(2R,2'S,2''S,4'aS,5'R,5''S,6'R,8'S,8'aR)-8'-(acetyloxy)-5''-(furan-3-yl)-2',2''-dihydroxy-6'-methyl-octahydrodispiro[oxirane-2,1'-naphthalene-5',3''-oxolane]-8'a-yl]methyl acetate

> <JCHEM_LOGP>
0.7504024696666669

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
13.900197789731717

> <JCHEM_PKA_STRONGEST_ACIDIC>
11.918704656399964

> <JCHEM_PKA_STRONGEST_BASIC>
-2.855538788018883

> <JCHEM_POLAR_SURFACE_AREA>
127.96000000000002

> <JCHEM_REFRACTIVITY>
111.91279999999999

> <JCHEM_ROTATABLE_BOND_COUNT>
6

> <JCHEM_RULE_OF_FIVE>
1

> <JCHEM_TRADITIONAL_IUPAC>
(2R,2'S,2''S,4'aS,5'R,5''S,6'R,8'S,8'aR)-8'-(acetyloxy)-5''-(furan-3-yl)-2',2''-dihydroxy-6'-methyl-hexahydro-2'H-dispiro[oxirane-2,1'-naphthalene-5',3''-oxolane]-8'a-ylmethyl acetate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 12-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   12-SEP-22         0                                  
HETATM    1  C   UNK     0       1.036   2.888   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       2.574   2.813   0.000  0.00  0.00           C+0
HETATM    3  O   UNK     0       3.408   4.107   0.000  0.00  0.00           O+0
HETATM    4  O   UNK     0       3.278   1.443   0.000  0.00  0.00           O+0
HETATM    5  C   UNK     0       4.816   1.367   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       5.520  -0.002   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       5.434   1.535   0.000  0.00  0.00           C+0
HETATM    8  O   UNK     0       4.059   2.230   0.000  0.00  0.00           O+0
HETATM    9  C   UNK     0       3.974   3.767   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       3.270   5.137   0.000  0.00  0.00           C+0
HETATM   11  O   UNK     0       5.262   4.610   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0       6.723   2.378   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       8.097   1.684   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       9.386   2.527   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       8.183   0.146   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       9.553   0.850   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0      10.645  -0.235   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0      12.165   0.011   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0      13.258  -1.074   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0      14.628  -0.371   0.000  0.00  0.00           C+0
HETATM   21  O   UNK     0      14.382   1.150   0.000  0.00  0.00           O+0
HETATM   22  C   UNK     0      12.860   1.385   0.000  0.00  0.00           C+0
HETATM   23  O   UNK     0       9.951  -1.610   0.000  0.00  0.00           O+0
HETATM   24  C   UNK     0       8.429  -1.374   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0       7.734  -2.749   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0       6.894  -0.697   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       6.980  -2.235   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       5.691  -3.078   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       4.317  -2.383   0.000  0.00  0.00           C+0
HETATM   30  O   UNK     0       3.028  -3.226   0.000  0.00  0.00           O+0
HETATM   31  C   UNK     0       4.231  -0.846   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0       2.693  -0.931   0.000  0.00  0.00           C+0
HETATM   33  O   UNK     0       3.388   0.443   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3    4                                                  
CONECT    3    2                                                            
CONECT    4    2    5                                                       
CONECT    5    4    6                                                       
CONECT    6    5    7   26   31                                             
CONECT    7    6    8   12                                                  
CONECT    8    7    9                                                       
CONECT    9    8   10   11                                                  
CONECT   10    9                                                            
CONECT   11    9                                                            
CONECT   12    7   13                                                       
CONECT   13   12   14   15                                                  
CONECT   14   13                                                            
CONECT   15   13   16   24   26                                             
CONECT   16   15   17                                                       
CONECT   17   16   18   23                                                  
CONECT   18   17   19   22                                                  
CONECT   19   18   20                                                       
CONECT   20   19   21                                                       
CONECT   21   20   22                                                       
CONECT   22   21   18                                                       
CONECT   23   17   24                                                       
CONECT   24   23   15   25                                                  
CONECT   25   24                                                            
CONECT   26   15    6   27                                                  
CONECT   27   26   28                                                       
CONECT   28   27   29                                                       
CONECT   29   28   30   31                                                  
CONECT   30   29                                                            
CONECT   31   29    6   32   33                                             
CONECT   32   31   33                                                       
CONECT   33   32   31                                                       
MASTER        0    0    0    0    0    0    0    0   33    0   74    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₄H₃₂O₉

Average Mass

464.5110 Da

Monoisotopic Mass

464.20463 Da

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

C[C@@H]1C[C@H](OC(C)=O)[C@]2(COC(C)=O)[C@H](CC[C@H](O)[C@]22CO2)[C@@]11C[C@H](O[C@@H]1O)C1=COC=C1

InChI Identifier

InChI=1S/C24H32O9/c1-13-8-20(32-15(3)26)23(11-30-14(2)25)18(4-5-19(27)24(23)12-31-24)22(13)9-17(33-21(22)28)16-6-7-29-10-16/h6-7,10,13,17-21,27-28H,4-5,8-9,11-12H2,1-3H3/t13-,17+,18-,19+,20+,21+,22-,23+,24-/m1/s1

InChI Key

QGKJGQDHZIBMKX-MYHZJNNASA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Teucrium montbretii	LOTUS Database	35616633
Teucrium polium	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as dicarboxylic acids and derivatives. These are organic compounds containing exactly two carboxylic acid groups.

Kingdom

Organic compounds

Super Class

Organic acids and derivatives

Class

Carboxylic acids and derivatives

Sub Class

Dicarboxylic acids and derivatives

Direct Parent

Dicarboxylic acids and derivatives

Alternative Parents

Substituents

Dicarboxylic acid or derivatives
Cyclic alcohol
Heteroaromatic compound
Furan
Tetrahydrofuran
Carboxylic acid ester
Hemiacetal
Secondary alcohol
Dialkyl ether
Oxirane
Ether
Oxacycle
Organoheterocyclic compound
Hydrocarbon derivative
Alcohol
Carbonyl group
Organic oxygen compound
Organic oxide
Organooxygen compound
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

10269229

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

21635657

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (2r,2's,2''s,4'as,5'r,5''s,6'r,8's,8'ar)-8'-(acetyloxy)-5''-(furan-3-yl)-2',2''-dihydroxy-6'-methyl-hexahydro-2'h-dispiro[oxirane-2,1'-naphthalene-5',3''-oxolan]-8'a-ylmethyl acetate (NP0323543)

MOL for NP0323543 ((2r,2's,2''s,4'as,5'r,5''s,6'r,8's,8'ar)-8'-(acetyloxy)-5''-(furan-3-yl)-2',2''-dihydroxy-6'-methyl-hexahydro-2'h-dispiro[oxirane-2,1'-naphthalene-5',3''-oxolan]-8'a-ylmethyl acetate)

3D MOL for NP0323543 ((2r,2's,2''s,4'as,5'r,5''s,6'r,8's,8'ar)-8'-(acetyloxy)-5''-(furan-3-yl)-2',2''-dihydroxy-6'-methyl-hexahydro-2'h-dispiro[oxirane-2,1'-naphthalene-5',3''-oxolan]-8'a-ylmethyl acetate)

3D SDF for NP0323543 ((2r,2's,2''s,4'as,5'r,5''s,6'r,8's,8'ar)-8'-(acetyloxy)-5''-(furan-3-yl)-2',2''-dihydroxy-6'-methyl-hexahydro-2'h-dispiro[oxirane-2,1'-naphthalene-5',3''-oxolan]-8'a-ylmethyl acetate)

3D-SDF for NP0323543 ((2r,2's,2''s,4'as,5'r,5''s,6'r,8's,8'ar)-8'-(acetyloxy)-5''-(furan-3-yl)-2',2''-dihydroxy-6'-methyl-hexahydro-2'h-dispiro[oxirane-2,1'-naphthalene-5',3''-oxolan]-8'a-ylmethyl acetate)

PDB for NP0323543 ((2r,2's,2''s,4'as,5'r,5''s,6'r,8's,8'ar)-8'-(acetyloxy)-5''-(furan-3-yl)-2',2''-dihydroxy-6'-methyl-hexahydro-2'h-dispiro[oxirane-2,1'-naphthalene-5',3''-oxolan]-8'a-ylmethyl acetate)

3D PDB for NP0323543 ((2r,2's,2''s,4'as,5'r,5''s,6'r,8's,8'ar)-8'-(acetyloxy)-5''-(furan-3-yl)-2',2''-dihydroxy-6'-methyl-hexahydro-2'h-dispiro[oxirane-2,1'-naphthalene-5',3''-oxolan]-8'a-ylmethyl acetate)

SMILES for NP0323543 ((2r,2's,2''s,4'as,5'r,5''s,6'r,8's,8'ar)-8'-(acetyloxy)-5''-(furan-3-yl)-2',2''-dihydroxy-6'-methyl-hexahydro-2'h-dispiro[oxirane-2,1'-naphthalene-5',3''-oxolan]-8'a-ylmethyl acetate)

INCHI for NP0323543 ((2r,2's,2''s,4'as,5'r,5''s,6'r,8's,8'ar)-8'-(acetyloxy)-5''-(furan-3-yl)-2',2''-dihydroxy-6'-methyl-hexahydro-2'h-dispiro[oxirane-2,1'-naphthalene-5',3''-oxolan]-8'a-ylmethyl acetate)

Structure for NP0323543 ((2r,2's,2''s,4'as,5'r,5''s,6'r,8's,8'ar)-8'-(acetyloxy)-5''-(furan-3-yl)-2',2''-dihydroxy-6'-methyl-hexahydro-2'h-dispiro[oxirane-2,1'-naphthalene-5',3''-oxolan]-8'a-ylmethyl acetate)

3D Structure for NP0323543 ((2r,2's,2''s,4'as,5'r,5''s,6'r,8's,8'ar)-8'-(acetyloxy)-5''-(furan-3-yl)-2',2''-dihydroxy-6'-methyl-hexahydro-2'h-dispiro[oxirane-2,1'-naphthalene-5',3''-oxolan]-8'a-ylmethyl acetate)