NP-MRD: Showing NP-Card for (1s,4s,7s,8r,9r,10s,11r,14r)-8-(acetyloxy)-7-[(5s)-5-hydroxy-2-oxo-5h-furan-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0¹,¹⁴.0⁴,⁹]heptadec-12-en-11-yl acetate (NP0322079)

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Record Information

Version

2.0

Created at

2022-09-12 00:39:00 UTC

Updated at

2022-09-12 00:39:01 UTC

NP-MRD ID

NP0322079

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1s,4s,7s,8r,9r,10s,11r,14r)-8-(acetyloxy)-7-[(5s)-5-hydroxy-2-oxo-5h-furan-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0¹,¹⁴.0⁴,⁹]heptadec-12-en-11-yl acetate

Description

(1S,4S,7S,8R,9R,10S,11R,14R)-8-(acetyloxy)-7-[(5S)-5-hydroxy-2-oxo-2,5-dihydrofuran-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0¹,¹⁴.0⁴,⁹]Heptadec-12-en-11-yl acetate belongs to the class of organic compounds known as pentacarboxylic acids and derivatives. These are carboxylic acids containing exactly five carboxyl groups. (1s,4s,7s,8r,9r,10s,11r,14r)-8-(acetyloxy)-7-[(5s)-5-hydroxy-2-oxo-5h-furan-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0¹,¹⁴.0⁴,⁹]heptadec-12-en-11-yl acetate is found in Salvia splendens. Based on a literature review very few articles have been published on (1S,4S,7S,8R,9R,10S,11R,14R)-8-(acetyloxy)-7-[(5S)-5-hydroxy-2-oxo-2,5-dihydrofuran-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0¹,¹⁴.0⁴,⁹]Heptadec-12-en-11-yl acetate.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309122202392D          

 35 39  0  0  1  0            999 V2000
    3.9930   -1.7569    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.2989   -1.3110    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    1.9106   -0.4192    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.2165    0.0266    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.2556    0.8507    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.6693    1.4312    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1449    1.2981    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
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    1.7416    2.0183    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.9888    1.2289    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
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    3.4552    1.9853    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    4.1884    2.3635    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.2275    3.1876    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.8825    1.9176    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.8434    1.0936    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    5.5376    0.6477    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.3063    0.9472    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    2.6829    0.7830    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
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  5 35  1  0  0  0  0
 35 13  1  1  0  0  0
M  END

     RDKit          3D

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M  END


  Mrv1652309122202392D          

 35 39  0  0  1  0            999 V2000
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M  END
> <DATABASE_ID>
NP0322079

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC(=O)O[C@@H]1C=C[C@H]2C(=O)OC[C@]22CC[C@@H]3C(=O)O[C@H]([C@H](OC(C)=O)[C@]3(C)[C@@H]12)C1=C[C@@H](O)OC1=O

> <INCHI_IDENTIFIER>
InChI=1S/C24H26O11/c1-10(25)32-15-5-4-14-21(29)31-9-24(14)7-6-13-22(30)35-17(12-8-16(27)34-20(12)28)19(33-11(2)26)23(13,3)18(15)24/h4-5,8,13-19,27H,6-7,9H2,1-3H3/t13-,14+,15-,16+,17+,18-,19+,23+,24-/m1/s1

> <INCHI_KEY>
FVWSECMXGBTHNX-CSSWALLTSA-N

> <FORMULA>
C24H26O11

> <MOLECULAR_WEIGHT>
490.461

> <EXACT_MASS>
490.147511657

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
61

> <JCHEM_AVERAGE_POLARIZABILITY>
46.43422361134902

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
1

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(1S,4S,7S,8R,9R,10S,11R,14R)-8-(acetyloxy)-7-[(5S)-5-hydroxy-2-oxo-2,5-dihydrofuran-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0^{1,14}.0^{4,9}]heptadec-12-en-11-yl acetate

> <JCHEM_LOGP>
0.3695159123333334

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
15.344141413124486

> <JCHEM_PKA_STRONGEST_ACIDIC>
11.776059376353977

> <JCHEM_PKA_STRONGEST_BASIC>
-4.168491055557481

> <JCHEM_POLAR_SURFACE_AREA>
151.73000000000002

> <JCHEM_REFRACTIVITY>
113.28520000000002

> <JCHEM_ROTATABLE_BOND_COUNT>
5

> <JCHEM_RULE_OF_FIVE>
1

> <JCHEM_TRADITIONAL_IUPAC>
(1S,4S,7S,8R,9R,10S,11R,14R)-8-(acetyloxy)-7-[(5S)-5-hydroxy-2-oxo-5H-furan-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0^{1,14}.0^{4,9}]heptadec-12-en-11-yl acetate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 12-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   12-SEP-22         0                                  
HETATM    1  C   UNK     0       7.454  -3.279   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       6.158  -2.447   0.000  0.00  0.00           C+0
HETATM    3  O   UNK     0       4.789  -3.153   0.000  0.00  0.00           O+0
HETATM    4  O   UNK     0       6.231  -0.909   0.000  0.00  0.00           O+0
HETATM    5  C   UNK     0       4.935  -0.077   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       3.566  -0.783   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       2.271   0.050   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       2.344   1.588   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       1.249   2.672   0.000  0.00  0.00           C+0
HETATM   10  O   UNK     0      -0.270   2.423   0.000  0.00  0.00           O+0
HETATM   11  O   UNK     0       1.942   4.047   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0       3.251   3.767   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       3.712   2.294   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       3.785   3.832   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       5.154   4.538   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       6.450   3.706   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       7.818   4.412   0.000  0.00  0.00           C+0
HETATM   18  O   UNK     0       7.891   5.950   0.000  0.00  0.00           O+0
HETATM   19  O   UNK     0       9.114   3.580   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0       9.041   2.041   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0      10.337   1.209   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      11.772   1.768   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0      12.747   0.576   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0      14.284   0.664   0.000  0.00  0.00           O+0
HETATM   25  O   UNK     0      11.915  -0.720   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0      10.851  -0.236   0.000  0.00  0.00           C+0
HETATM   27  O   UNK     0       9.279  -1.516   0.000  0.00  0.00           O+0
HETATM   28  C   UNK     0       7.672   1.335   0.000  0.00  0.00           C+0
HETATM   29  O   UNK     0       7.599  -0.203   0.000  0.00  0.00           O+0
HETATM   30  C   UNK     0       8.895  -1.035   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0      10.264  -0.329   0.000  0.00  0.00           C+0
HETATM   32  O   UNK     0       8.822  -2.573   0.000  0.00  0.00           O+0
HETATM   33  C   UNK     0       6.377   2.168   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0       6.304   0.629   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0       5.008   1.462   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3    4                                                  
CONECT    3    2                                                            
CONECT    4    2    5                                                       
CONECT    5    4    6   35                                                  
CONECT    6    5    7                                                       
CONECT    7    6    8                                                       
CONECT    8    7    9   13                                                  
CONECT    9    8   10   11                                                  
CONECT   10    9                                                            
CONECT   11    9   12                                                       
CONECT   12   11   13                                                       
CONECT   13   12    8   14   35                                             
CONECT   14   13   15                                                       
CONECT   15   14   16                                                       
CONECT   16   15   17   33                                                  
CONECT   17   16   18   19                                                  
CONECT   18   17                                                            
CONECT   19   17   20                                                       
CONECT   20   19   21   28                                                  
CONECT   21   20   22   26                                                  
CONECT   22   21   23                                                       
CONECT   23   22   24   25                                                  
CONECT   24   23                                                            
CONECT   25   23   26                                                       
CONECT   26   25   21   27                                                  
CONECT   27   26                                                            
CONECT   28   20   29   33                                                  
CONECT   29   28   30                                                       
CONECT   30   29   31   32                                                  
CONECT   31   30                                                            
CONECT   32   30                                                            
CONECT   33   28   16   34   35                                             
CONECT   34   33                                                            
CONECT   35   33    5   13                                                  
MASTER        0    0    0    0    0    0    0    0   35    0   78    0
END

View in JSmol

Synonyms

Value	Source
(1S,4S,7S,8R,9R,10S,11R,14R)-8-(Acetyloxy)-7-[(5S)-5-hydroxy-2-oxo-2,5-dihydrofuran-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0,.0,]heptadec-12-en-11-yl acetic acid	Generator

Chemical Formula

C₂₄H₂₆O₁₁

Average Mass

490.4610 Da

Monoisotopic Mass

490.14751 Da

IUPAC Name

(1S,4S,7S,8R,9R,10S,11R,14R)-8-(acetyloxy)-7-[(5S)-5-hydroxy-2-oxo-2,5-dihydrofuran-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0^{1,14}.0^{4,9}]heptadec-12-en-11-yl acetate

Traditional Name

(1S,4S,7S,8R,9R,10S,11R,14R)-8-(acetyloxy)-7-[(5S)-5-hydroxy-2-oxo-5H-furan-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0^{1,14}.0^{4,9}]heptadec-12-en-11-yl acetate

CAS Registry Number

Not Available

SMILES

CC(=O)O[C@@H]1C=C[C@H]2C(=O)OC[C@]22CC[C@@H]3C(=O)O[C@H]([C@H](OC(C)=O)[C@]3(C)[C@@H]12)C1=C[C@@H](O)OC1=O

InChI Identifier

InChI=1S/C24H26O11/c1-10(25)32-15-5-4-14-21(29)31-9-24(14)7-6-13-22(30)35-17(12-8-16(27)34-20(12)28)19(33-11(2)26)23(13,3)18(15)24/h4-5,8,13-19,27H,6-7,9H2,1-3H3/t13-,14+,15-,16+,17+,18-,19+,23+,24-/m1/s1

InChI Key

FVWSECMXGBTHNX-CSSWALLTSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Salvia splendens	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as pentacarboxylic acids and derivatives. These are carboxylic acids containing exactly five carboxyl groups.

Kingdom

Organic compounds

Super Class

Organic acids and derivatives

Class

Carboxylic acids and derivatives

Sub Class

Pentacarboxylic acids and derivatives

Direct Parent

Pentacarboxylic acids and derivatives

Alternative Parents

Substituents

Pentacarboxylic acid or derivatives
Naphthopyran
Naphthalene
Delta valerolactone
Delta_valerolactone
2-furanone
Gamma butyrolactone
Oxane
Pyran
Dihydrofuran
Alpha,beta-unsaturated carboxylic ester
Enoate ester
Tetrahydrofuran
Lactone
Hemiacetal
Carboxylic acid ester
Organoheterocyclic compound
Oxacycle
Hydrocarbon derivative
Organic oxide
Organic oxygen compound
Organooxygen compound
Carbonyl group
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	0.37	ChemAxon
pKa (Strongest Acidic)	11.78	ChemAxon
pKa (Strongest Basic)	-4.2	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	6	ChemAxon
Hydrogen Donor Count	1	ChemAxon
Polar Surface Area	151.73 Å²	ChemAxon
Rotatable Bond Count	5	ChemAxon
Refractivity	113.29 m³·mol⁻¹	ChemAxon
Polarizability	46.43 Å³	ChemAxon
Number of Rings	5	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	Yes	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

162983118

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (1s,4s,7s,8r,9r,10s,11r,14r)-8-(acetyloxy)-7-[(5s)-5-hydroxy-2-oxo-5h-furan-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0¹,¹⁴.0⁴,⁹]heptadec-12-en-11-yl acetate (NP0322079)

MOL for NP0322079 ((1s,4s,7s,8r,9r,10s,11r,14r)-8-(acetyloxy)-7-[(5s)-5-hydroxy-2-oxo-5h-furan-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0¹,¹⁴.0⁴,⁹]heptadec-12-en-11-yl acetate)

3D MOL for NP0322079 ((1s,4s,7s,8r,9r,10s,11r,14r)-8-(acetyloxy)-7-[(5s)-5-hydroxy-2-oxo-5h-furan-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0¹,¹⁴.0⁴,⁹]heptadec-12-en-11-yl acetate)

3D SDF for NP0322079 ((1s,4s,7s,8r,9r,10s,11r,14r)-8-(acetyloxy)-7-[(5s)-5-hydroxy-2-oxo-5h-furan-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0¹,¹⁴.0⁴,⁹]heptadec-12-en-11-yl acetate)

3D-SDF for NP0322079 ((1s,4s,7s,8r,9r,10s,11r,14r)-8-(acetyloxy)-7-[(5s)-5-hydroxy-2-oxo-5h-furan-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0¹,¹⁴.0⁴,⁹]heptadec-12-en-11-yl acetate)

PDB for NP0322079 ((1s,4s,7s,8r,9r,10s,11r,14r)-8-(acetyloxy)-7-[(5s)-5-hydroxy-2-oxo-5h-furan-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0¹,¹⁴.0⁴,⁹]heptadec-12-en-11-yl acetate)

3D PDB for NP0322079 ((1s,4s,7s,8r,9r,10s,11r,14r)-8-(acetyloxy)-7-[(5s)-5-hydroxy-2-oxo-5h-furan-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0¹,¹⁴.0⁴,⁹]heptadec-12-en-11-yl acetate)

SMILES for NP0322079 ((1s,4s,7s,8r,9r,10s,11r,14r)-8-(acetyloxy)-7-[(5s)-5-hydroxy-2-oxo-5h-furan-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0¹,¹⁴.0⁴,⁹]heptadec-12-en-11-yl acetate)

INCHI for NP0322079 ((1s,4s,7s,8r,9r,10s,11r,14r)-8-(acetyloxy)-7-[(5s)-5-hydroxy-2-oxo-5h-furan-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0¹,¹⁴.0⁴,⁹]heptadec-12-en-11-yl acetate)

Structure for NP0322079 ((1s,4s,7s,8r,9r,10s,11r,14r)-8-(acetyloxy)-7-[(5s)-5-hydroxy-2-oxo-5h-furan-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0¹,¹⁴.0⁴,⁹]heptadec-12-en-11-yl acetate)

3D Structure for NP0322079 ((1s,4s,7s,8r,9r,10s,11r,14r)-8-(acetyloxy)-7-[(5s)-5-hydroxy-2-oxo-5h-furan-3-yl]-9-methyl-5,15-dioxo-6,16-dioxatetracyclo[8.7.0.0¹,¹⁴.0⁴,⁹]heptadec-12-en-11-yl acetate)