NP-MRD: Showing NP-Card for 3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one (NP0321603)

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Record Information

Version

2.0

Created at

2022-09-11 23:53:50 UTC

Updated at

2022-09-11 23:53:51 UTC

NP-MRD ID

NP0321603

Secondary Accession Numbers

None

Natural Product Identification

Common Name

3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one

Description

Alpha-Diohobanin, also known as α-diohobanin, belongs to the class of organic compounds known as benzene and substituted derivatives. These are aromatic compounds containing one monocyclic ring system consisting of benzene. 3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one is found in Oreopteris quelpaertensis. Based on a literature review very few articles have been published on alpha-Diohobanin.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309122201532D          

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M  END

     RDKit          3D

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M  END


  Mrv1652309122201532D          

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    0.7145   -4.8792    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145   -4.8792    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145   -5.7042    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289   -4.4667    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289   -3.6417    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2414   -3.7850    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7111   -2.8665    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145   -3.2292    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145   -2.4042    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.1311   -1.8209    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6939   -1.8209    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.1064   -2.5353    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9314   -2.5353    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.3439   -1.8209    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9314   -1.1064    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.1064   -1.1064    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000    0.8250    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145    1.2375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  2  0  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  4  6  1  0  0  0  0
  4  7  1  0  0  0  0
  7  8  2  0  0  0  0
  7  9  1  0  0  0  0
  9 10  1  0  0  0  0
 10 11  2  0  0  0  0
 10 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  2  0  0  0  0
 15 16  1  0  0  0  0
 16 17  2  0  0  0  0
 17 18  1  0  0  0  0
 18 19  2  0  0  0  0
 14 19  1  0  0  0  0
 13 20  1  0  0  0  0
 20 21  1  0  0  0  0
 21 22  2  0  0  0  0
 21 23  1  0  0  0  0
 23 24  2  0  0  0  0
 24 25  1  0  0  0  0
 24 26  1  0  0  0  0
 26 27  1  0  0  0  0
 26 28  2  0  0  0  0
 28 29  1  0  0  0  0
 29 30  1  0  0  0  0
 29 31  1  0  0  0  0
 29 32  1  0  0  0  0
 23 32  1  0  0  0  0
 32 33  2  0  0  0  0
 20 34  1  0  0  0  0
 12 34  1  0  0  0  0
 34 35  1  0  0  0  0
 35 36  2  0  0  0  0
 36 37  1  0  0  0  0
 37 38  2  0  0  0  0
 38 39  1  0  0  0  0
 39 40  2  0  0  0  0
 35 40  1  0  0  0  0
  9 41  2  0  0  0  0
  2 41  1  0  0  0  0
 41 42  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0321603

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC1=CC(C)(C)C(=O)C(C(=O)C2C(C(C2C2=CC=CC=C2)C(=O)C2=C(O)C(C)=CC(C)(C)C2=O)C2=CC=CC=C2)=C1O

> <INCHI_IDENTIFIER>
InChI=1S/C36H36O6/c1-19-17-35(3,4)33(41)27(29(19)37)31(39)25-23(21-13-9-7-10-14-21)26(24(25)22-15-11-8-12-16-22)32(40)28-30(38)20(2)18-36(5,6)34(28)42/h7-18,23-26,37-38H,1-6H3

> <INCHI_KEY>
RWUCIZRRGMDCIH-UHFFFAOYSA-N

> <FORMULA>
C36H36O6

> <MOLECULAR_WEIGHT>
564.678

> <EXACT_MASS>
564.251188879

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
78

> <JCHEM_AVERAGE_POLARIZABILITY>
61.81058442876281

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
2

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one

> <JCHEM_LOGP>
6.937060576666667

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
-2

> <JCHEM_PKA>
5.451806026614801

> <JCHEM_PKA_STRONGEST_ACIDIC>
4.786203054270015

> <JCHEM_PKA_STRONGEST_BASIC>
-7.134644264023099

> <JCHEM_POLAR_SURFACE_AREA>
108.74

> <JCHEM_REFRACTIVITY>
165.54859999999996

> <JCHEM_ROTATABLE_BOND_COUNT>
6

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 12-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   12-SEP-22         0                                  
HETATM    1  C   UNK     0      -1.334   3.850   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      -1.334   2.310   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      -2.667   1.540   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -2.667   0.000   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -4.184   0.267   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -3.194  -1.447   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0      -1.334  -0.770   0.000  0.00  0.00           C+0
HETATM    8  O   UNK     0      -1.334  -2.310   0.000  0.00  0.00           O+0
HETATM    9  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       1.334  -0.770   0.000  0.00  0.00           C+0
HETATM   11  O   UNK     0       2.667  -0.000   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0       1.334  -2.310   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       2.423  -3.399   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       3.963  -3.399   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       4.733  -2.065   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       6.273  -2.065   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       7.043  -3.399   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       6.273  -4.733   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       4.733  -4.733   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       1.334  -4.488   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       1.334  -6.028   0.000  0.00  0.00           C+0
HETATM   22  O   UNK     0       2.667  -6.798   0.000  0.00  0.00           O+0
HETATM   23  C   UNK     0       0.000  -6.798   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       0.000  -8.338   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0       1.334  -9.108   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0      -1.334  -9.108   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0      -1.334 -10.648   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0      -2.667  -8.338   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0      -2.667  -6.798   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0      -4.184  -7.065   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0      -3.194  -5.351   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0      -1.334  -6.028   0.000  0.00  0.00           C+0
HETATM   33  O   UNK     0      -1.334  -4.488   0.000  0.00  0.00           O+0
HETATM   34  C   UNK     0       0.245  -3.399   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0      -1.295  -3.399   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0      -2.065  -4.733   0.000  0.00  0.00           C+0
HETATM   37  C   UNK     0      -3.605  -4.733   0.000  0.00  0.00           C+0
HETATM   38  C   UNK     0      -4.375  -3.399   0.000  0.00  0.00           C+0
HETATM   39  C   UNK     0      -3.605  -2.065   0.000  0.00  0.00           C+0
HETATM   40  C   UNK     0      -2.065  -2.065   0.000  0.00  0.00           C+0
HETATM   41  C   UNK     0       0.000   1.540   0.000  0.00  0.00           C+0
HETATM   42  O   UNK     0       1.334   2.310   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3   41                                                  
CONECT    3    2    4                                                       
CONECT    4    3    5    6    7                                             
CONECT    5    4                                                            
CONECT    6    4                                                            
CONECT    7    4    8    9                                                  
CONECT    8    7                                                            
CONECT    9    7   10   41                                                  
CONECT   10    9   11   12                                                  
CONECT   11   10                                                            
CONECT   12   10   13   34                                                  
CONECT   13   12   14   20                                                  
CONECT   14   13   15   19                                                  
CONECT   15   14   16                                                       
CONECT   16   15   17                                                       
CONECT   17   16   18                                                       
CONECT   18   17   19                                                       
CONECT   19   18   14                                                       
CONECT   20   13   21   34                                                  
CONECT   21   20   22   23                                                  
CONECT   22   21                                                            
CONECT   23   21   24   32                                                  
CONECT   24   23   25   26                                                  
CONECT   25   24                                                            
CONECT   26   24   27   28                                                  
CONECT   27   26                                                            
CONECT   28   26   29                                                       
CONECT   29   28   30   31   32                                             
CONECT   30   29                                                            
CONECT   31   29                                                            
CONECT   32   29   23   33                                                  
CONECT   33   32                                                            
CONECT   34   20   12   35                                                  
CONECT   35   34   36   40                                                  
CONECT   36   35   37                                                       
CONECT   37   36   38                                                       
CONECT   38   37   39                                                       
CONECT   39   38   40                                                       
CONECT   40   39   35                                                       
CONECT   41    9    2   42                                                  
CONECT   42   41                                                            
MASTER        0    0    0    0    0    0    0    0   42    0   92    0
END

View in JSmol

Synonyms

Value	Source
a-Diohobanin	Generator
Α-diohobanin	Generator

Chemical Formula

C₃₆H₃₆O₆

Average Mass

564.6780 Da

Monoisotopic Mass

564.25119 Da

IUPAC Name

3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one

Traditional Name

3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one

CAS Registry Number

Not Available

SMILES

CC1=CC(C)(C)C(=O)C(C(=O)C2C(C(C2C2=CC=CC=C2)C(=O)C2=C(O)C(C)=CC(C)(C)C2=O)C2=CC=CC=C2)=C1O

InChI Identifier

InChI=1S/C36H36O6/c1-19-17-35(3,4)33(41)27(29(19)37)31(39)25-23(21-13-9-7-10-14-21)26(24(25)22-15-11-8-12-16-22)32(40)28-30(38)20(2)18-36(5,6)34(28)42/h7-18,23-26,37-38H,1-6H3

InChI Key

RWUCIZRRGMDCIH-UHFFFAOYSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Oreopteris quelpaertensis	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as benzene and substituted derivatives. These are aromatic compounds containing one monocyclic ring system consisting of benzene.

Kingdom

Organic compounds

Super Class

Benzenoids

Class

Benzene and substituted derivatives

Sub Class

Not Available

Direct Parent

Benzene and substituted derivatives

Alternative Parents

Substituents

Monocyclic benzene moiety
Vinylogous acid
Cyclic ketone
Ketone
Enol
Organic oxygen compound
Organic oxide
Hydrocarbon derivative
Organooxygen compound
Carbonyl group
Aromatic homomonocyclic compound

Molecular Framework

Aromatic homomonocyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	6.94	ChemAxon
pKa (Strongest Acidic)	4.79	ChemAxon
pKa (Strongest Basic)	-7.1	ChemAxon
Physiological Charge	-2	ChemAxon
Hydrogen Acceptor Count	6	ChemAxon
Hydrogen Donor Count	2	ChemAxon
Polar Surface Area	108.74 Å²	ChemAxon
Rotatable Bond Count	6	ChemAxon
Refractivity	165.55 m³·mol⁻¹	ChemAxon
Polarizability	61.81 Å³	ChemAxon
Number of Rings	5	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

C00006606

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

14524437

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for 3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one (NP0321603)

MOL for NP0321603 (3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one)

3D MOL for NP0321603 (3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one)

3D SDF for NP0321603 (3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one)

3D-SDF for NP0321603 (3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one)

PDB for NP0321603 (3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one)

3D PDB for NP0321603 (3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one)

SMILES for NP0321603 (3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one)

INCHI for NP0321603 (3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one)

Structure for NP0321603 (3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one)

3D Structure for NP0321603 (3-hydroxy-2-[3-(2-hydroxy-3,5,5-trimethyl-6-oxocyclohexa-1,3-diene-1-carbonyl)-2,4-diphenylcyclobutanecarbonyl]-4,6,6-trimethylcyclohexa-2,4-dien-1-one)