NP-MRD: Showing NP-Card for methyl (2z)-3-[(1r,2r,4s,7r,8s,11r,12r,13r,17s)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-5h-furan-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0²,⁴.0²,⁸.0¹³,¹⁷]heptadecan-12-yl]prop-2-enoate (NP0319343)

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Record Information

Version

2.0

Created at

2022-09-11 20:19:09 UTC

Updated at

2022-09-11 20:19:09 UTC

NP-MRD ID

NP0319343

Secondary Accession Numbers

None

Natural Product Identification

Common Name

methyl (2z)-3-[(1r,2r,4s,7r,8s,11r,12r,13r,17s)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-5h-furan-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0²,⁴.0²,⁸.0¹³,¹⁷]heptadecan-12-yl]prop-2-enoate

Description

HARPERFOLIDE belongs to the class of organic compounds known as limonoids. These are highly oxygenated, modified terpenoids with a prototypical structure either containing or derived from a precursor with a 4,4,8-trimethyl-17-furanylsteroid skeleton. All naturally occurring citrus limonoids contain a furan ring attached to the D-ring, at C-17, as well as oxygen containing functional groups at C-3, C-4, C-7, C-16 and C-17. methyl (2z)-3-[(1r,2r,4s,7r,8s,11r,12r,13r,17s)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-5h-furan-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0²,⁴.0²,⁸.0¹³,¹⁷]heptadecan-12-yl]prop-2-enoate is found in Harrisonia perforata. methyl (2z)-3-[(1r,2r,4s,7r,8s,11r,12r,13r,17s)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-5h-furan-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0²,⁴.0²,⁸.0¹³,¹⁷]heptadecan-12-yl]prop-2-enoate was first documented in 2013 (PMID: 23688954). Based on a literature review very few articles have been published on HARPERFOLIDE.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309112222192D          

 39 44  0  0  1  0            999 V2000
    5.8531   -2.4761    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    4.6451   -1.3521    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.6718   -2.3983    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.0678   -1.8363    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.2525   -1.0322    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    4.0328   -1.3000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4335   -0.9326    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
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    1.0311   -1.2068    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.8728   -0.3972    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.2508   -0.9391    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0924   -0.1294    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
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    4.2043   -0.8461    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
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  3  4  2  0  0  0  0
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 36 38  1  0  0  0  0
 30 38  1  0  0  0  0
  7 38  1  0  0  0  0
 38 39  1  1  0  0  0
M  END

     RDKit          3D

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M  END


  Mrv1652309112222192D          

 39 44  0  0  1  0            999 V2000
    5.8531   -2.4761    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    2.2752   -0.1229    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.4599    0.6811    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.9963    0.2778    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.5955    0.9989    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.3441    1.0259    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.1631    0.9263    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.1766    1.7512    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.9849    0.9991    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.3214    0.1166    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.0695   -0.2312    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.6003   -0.2842    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    4.2043   -0.8461    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  2  0  0  0  0
  3  5  1  0  0  0  0
  5  6  2  0  0  0  0
  7  6  1  6  0  0  0
  7  8  1  1  0  0  0
  7  9  1  0  0  0  0
  9 10  1  1  0  0  0
 10 11  1  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  6  0  0  0
 12 14  1  0  0  0  0
 14 15  1  6  0  0  0
 15 16  2  0  0  0  0
 16 17  1  0  0  0  0
 17 18  1  0  0  0  0
 17 19  1  0  0  0  0
 19 20  1  0  0  0  0
 15 20  1  0  0  0  0
 20 21  2  0  0  0  0
 14 22  1  0  0  0  0
 22 23  1  0  0  0  0
 23 24  2  0  0  0  0
 23 25  1  0  0  0  0
 25 26  1  1  0  0  0
 27 26  1  1  0  0  0
 25 27  1  0  0  0  0
 12 27  1  0  0  0  0
 27 28  1  0  0  0  0
  9 28  1  0  0  0  0
 28 29  1  1  0  0  0
 28 30  1  0  0  0  0
 30 31  1  1  0  0  0
 30 32  1  0  0  0  0
 32 33  1  0  0  0  0
 33 34  1  0  0  0  0
 33 35  1  0  0  0  0
 33 36  1  0  0  0  0
 36 37  2  0  0  0  0
 36 38  1  0  0  0  0
 30 38  1  0  0  0  0
  7 38  1  0  0  0  0
 38 39  1  1  0  0  0
M  END
> <DATABASE_ID>
NP0319343

> <DATABASE_NAME>
NP-MRD

> <SMILES>
COC(=O)\C=C/[C@]1(C)[C@H]2CC[C@@]3(C)[C@@H](OC(=O)[C@H]4O[C@@]34[C@]2(C)[C@]2(O)OC(C)(C)C(=O)[C@]12O)C1=CC(O)OC1=O

> <INCHI_IDENTIFIER>
InChI=1S/C27H32O12/c1-21(2)20(32)25(33)22(3,10-8-14(28)35-6)13-7-9-23(4)16(12-11-15(29)36-18(12)30)37-19(31)17-26(23,38-17)24(13,5)27(25,34)39-21/h8,10-11,13,15-17,29,33-34H,7,9H2,1-6H3/b10-8-/t13-,15?,16+,17-,22-,23+,24-,25+,26-,27+/m1/s1

> <INCHI_KEY>
FBSDZWINUANERE-SYFIMXEOSA-N

> <FORMULA>
C27H32O12

> <MOLECULAR_WEIGHT>
548.541

> <EXACT_MASS>
548.18937647

> <JCHEM_ACCEPTOR_COUNT>
9

> <JCHEM_ATOM_COUNT>
71

> <JCHEM_AVERAGE_POLARIZABILITY>
53.323557038868

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
3

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
methyl (2Z)-3-[(1R,2R,4S,7R,8S,11R,12R,13R,17S)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-2,5-dihydrofuran-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0^{2,4}.0^{2,8}.0^{13,17}]heptadecan-12-yl]prop-2-enoate

> <JCHEM_LOGP>
1.944290669999999

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
6

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
11.473847794782712

> <JCHEM_PKA_STRONGEST_ACIDIC>
10.232431177613954

> <JCHEM_PKA_STRONGEST_BASIC>
-4.074819864569766

> <JCHEM_POLAR_SURFACE_AREA>
178.42

> <JCHEM_REFRACTIVITY>
127.98309999999998

> <JCHEM_ROTATABLE_BOND_COUNT>
4

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
methyl (2Z)-3-[(1R,2R,4S,7R,8S,11R,12R,13R,17S)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-5H-furan-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0^{2,4}.0^{2,8}.0^{13,17}]heptadecan-12-yl]prop-2-enoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 11-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   11-SEP-22         0                                  
HETATM    1  C   UNK     0      10.926  -4.622   0.000  0.00  0.00           C+0
HETATM    2  O   UNK     0       9.454  -5.074   0.000  0.00  0.00           O+0
HETATM    3  C   UNK     0       8.326  -4.025   0.000  0.00  0.00           C+0
HETATM    4  O   UNK     0       8.671  -2.524   0.000  0.00  0.00           O+0
HETATM    5  C   UNK     0       6.854  -4.477   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       5.727  -3.428   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       6.071  -1.927   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       7.528  -2.427   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       4.543  -1.741   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       3.381  -2.753   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       1.925  -2.253   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       1.629  -0.741   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       0.468  -1.753   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       0.173  -0.242   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      -0.989  -1.253   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0      -0.853  -2.787   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0      -2.270  -3.391   0.000  0.00  0.00           C+0
HETATM   18  O   UNK     0      -2.614  -4.891   0.000  0.00  0.00           O+0
HETATM   19  O   UNK     0      -3.281  -2.229   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0      -2.489  -0.909   0.000  0.00  0.00           C+0
HETATM   21  O   UNK     0      -3.093   0.508   0.000  0.00  0.00           O+0
HETATM   22  O   UNK     0      -0.123   1.270   0.000  0.00  0.00           O+0
HETATM   23  C   UNK     0       1.038   2.281   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0       0.743   3.793   0.000  0.00  0.00           O+0
HETATM   25  C   UNK     0       2.495   1.782   0.000  0.00  0.00           C+0
HETATM   26  O   UNK     0       3.951   1.282   0.000  0.00  0.00           O+0
HETATM   27  C   UNK     0       2.790   0.270   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       4.247  -0.230   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       4.592   1.271   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       5.593   0.519   0.000  0.00  0.00           C+0
HETATM   31  O   UNK     0       4.845   1.865   0.000  0.00  0.00           O+0
HETATM   32  O   UNK     0       6.242   1.915   0.000  0.00  0.00           O+0
HETATM   33  C   UNK     0       7.771   1.729   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0       7.796   3.269   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0       9.305   1.865   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0       8.067   0.218   0.000  0.00  0.00           C+0
HETATM   37  O   UNK     0       9.463  -0.432   0.000  0.00  0.00           O+0
HETATM   38  C   UNK     0       6.721  -0.530   0.000  0.00  0.00           C+0
HETATM   39  O   UNK     0       7.848  -1.579   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4    5                                                  
CONECT    4    3                                                            
CONECT    5    3    6                                                       
CONECT    6    5    7                                                       
CONECT    7    6    8    9   38                                             
CONECT    8    7                                                            
CONECT    9    7   10   28                                                  
CONECT   10    9   11                                                       
CONECT   11   10   12                                                       
CONECT   12   11   13   14   27                                             
CONECT   13   12                                                            
CONECT   14   12   15   22                                                  
CONECT   15   14   16   20                                                  
CONECT   16   15   17                                                       
CONECT   17   16   18   19                                                  
CONECT   18   17                                                            
CONECT   19   17   20                                                       
CONECT   20   19   15   21                                                  
CONECT   21   20                                                            
CONECT   22   14   23                                                       
CONECT   23   22   24   25                                                  
CONECT   24   23                                                            
CONECT   25   23   26   27                                                  
CONECT   26   25   27                                                       
CONECT   27   26   25   12   28                                             
CONECT   28   27    9   29   30                                             
CONECT   29   28                                                            
CONECT   30   28   31   32   38                                             
CONECT   31   30                                                            
CONECT   32   30   33                                                       
CONECT   33   32   34   35   36                                             
CONECT   34   33                                                            
CONECT   35   33                                                            
CONECT   36   33   37   38                                                  
CONECT   37   36                                                            
CONECT   38   36   30    7   39                                             
CONECT   39   38                                                            
MASTER        0    0    0    0    0    0    0    0   39    0   88    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₇H₃₂O₁₂

Average Mass

548.5410 Da

Monoisotopic Mass

548.18938 Da

IUPAC Name

methyl (2Z)-3-[(1R,2R,4S,7R,8S,11R,12R,13R,17S)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-2,5-dihydrofuran-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0^{2,4}.0^{2,8}.0^{13,17}]heptadecan-12-yl]prop-2-enoate

Traditional Name

methyl (2Z)-3-[(1R,2R,4S,7R,8S,11R,12R,13R,17S)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-5H-furan-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0^{2,4}.0^{2,8}.0^{13,17}]heptadecan-12-yl]prop-2-enoate

CAS Registry Number

Not Available

SMILES

COC(=O)\C=C/[C@]1(C)[C@H]2CC[C@@]3(C)[C@@H](OC(=O)[C@H]4O[C@@]34[C@]2(C)[C@]2(O)OC(C)(C)C(=O)[C@]12O)C1=CC(O)OC1=O

InChI Identifier

InChI=1S/C27H32O12/c1-21(2)20(32)25(33)22(3,10-8-14(28)35-6)13-7-9-23(4)16(12-11-15(29)36-18(12)30)37-19(31)17-26(23,38-17)24(13,5)27(25,34)39-21/h8,10-11,13,15-17,29,33-34H,7,9H2,1-6H3/b10-8-/t13-,15?,16+,17-,22-,23+,24-,25+,26-,27+/m1/s1

InChI Key

FBSDZWINUANERE-SYFIMXEOSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Harrisonia perforata	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as limonoids. These are highly oxygenated, modified terpenoids with a prototypical structure either containing or derived from a precursor with a 4,4,8-trimethyl-17-furanylsteroid skeleton. All naturally occurring citrus limonoids contain a furan ring attached to the D-ring, at C-17, as well as oxygen containing functional groups at C-3, C-4, C-7, C-16 and C-17.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Triterpenoids

Direct Parent

Limonoids

Alternative Parents

Substituents

Limonoid skeleton
Tricarboxylic acid or derivatives
1,4-dioxepane
Delta valerolactone
Dioxepane
Fatty acid ester
Delta_valerolactone
Fatty acyl
2-furanone
3-furanone
Oxane
Enoate ester
Alpha,beta-unsaturated carboxylic ester
Cyclic alcohol
Dihydrofuran
Methyl ester
Tetrahydrofuran
Tertiary alcohol
Hemiacetal
Carboxylic acid ester
Lactone
Ketone
Carboxylic acid derivative
Oxacycle
Ether
Dialkyl ether
Organoheterocyclic compound
Oxirane
Organooxygen compound
Hydrocarbon derivative
Alcohol
Organic oxygen compound
Organic oxide
Carbonyl group
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	1.94	ChemAxon
pKa (Strongest Acidic)	10.23	ChemAxon
pKa (Strongest Basic)	-4.1	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	9	ChemAxon
Hydrogen Donor Count	3	ChemAxon
Polar Surface Area	178.42 Å²	ChemAxon
Rotatable Bond Count	4	ChemAxon
Refractivity	127.98 m³·mol⁻¹	ChemAxon
Polarizability	53.32 Å³	ChemAxon
Number of Rings	6	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

30814495

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

72714904

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

Choodej S, Sommit D, Pudhom K: Rearranged limonoids and chromones from Harrisonia perforata and their anti-inflammatory activity. Bioorg Med Chem Lett. 2013 Jul 1;23(13):3896-900. doi: 10.1016/j.bmcl.2013.04.064. Epub 2013 May 2. [PubMed:23688954 ]
LOTUS database [Link]

Showing NP-Card for methyl (2z)-3-[(1r,2r,4s,7r,8s,11r,12r,13r,17s)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-5h-furan-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0²,⁴.0²,⁸.0¹³,¹⁷]heptadecan-12-yl]prop-2-enoate (NP0319343)

MOL for NP0319343 (methyl (2z)-3-[(1r,2r,4s,7r,8s,11r,12r,13r,17s)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-5h-furan-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0²,⁴.0²,⁸.0¹³,¹⁷]heptadecan-12-yl]prop-2-enoate)

3D MOL for NP0319343 (methyl (2z)-3-[(1r,2r,4s,7r,8s,11r,12r,13r,17s)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-5h-furan-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0²,⁴.0²,⁸.0¹³,¹⁷]heptadecan-12-yl]prop-2-enoate)

3D SDF for NP0319343 (methyl (2z)-3-[(1r,2r,4s,7r,8s,11r,12r,13r,17s)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-5h-furan-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0²,⁴.0²,⁸.0¹³,¹⁷]heptadecan-12-yl]prop-2-enoate)

3D-SDF for NP0319343 (methyl (2z)-3-[(1r,2r,4s,7r,8s,11r,12r,13r,17s)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-5h-furan-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0²,⁴.0²,⁸.0¹³,¹⁷]heptadecan-12-yl]prop-2-enoate)

PDB for NP0319343 (methyl (2z)-3-[(1r,2r,4s,7r,8s,11r,12r,13r,17s)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-5h-furan-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0²,⁴.0²,⁸.0¹³,¹⁷]heptadecan-12-yl]prop-2-enoate)

3D PDB for NP0319343 (methyl (2z)-3-[(1r,2r,4s,7r,8s,11r,12r,13r,17s)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-5h-furan-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0²,⁴.0²,⁸.0¹³,¹⁷]heptadecan-12-yl]prop-2-enoate)

SMILES for NP0319343 (methyl (2z)-3-[(1r,2r,4s,7r,8s,11r,12r,13r,17s)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-5h-furan-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0²,⁴.0²,⁸.0¹³,¹⁷]heptadecan-12-yl]prop-2-enoate)

INCHI for NP0319343 (methyl (2z)-3-[(1r,2r,4s,7r,8s,11r,12r,13r,17s)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-5h-furan-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0²,⁴.0²,⁸.0¹³,¹⁷]heptadecan-12-yl]prop-2-enoate)

Structure for NP0319343 (methyl (2z)-3-[(1r,2r,4s,7r,8s,11r,12r,13r,17s)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-5h-furan-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0²,⁴.0²,⁸.0¹³,¹⁷]heptadecan-12-yl]prop-2-enoate)

3D Structure for NP0319343 (methyl (2z)-3-[(1r,2r,4s,7r,8s,11r,12r,13r,17s)-13,17-dihydroxy-7-(5-hydroxy-2-oxo-5h-furan-3-yl)-1,8,12,15,15-pentamethyl-5,14-dioxo-3,6,16-trioxapentacyclo[9.6.0.0²,⁴.0²,⁸.0¹³,¹⁷]heptadecan-12-yl]prop-2-enoate)