NP-MRD: Showing NP-Card for (4e,7s)-n-[(2e)-3-chloro-2-[(1s,2r,3s,5r)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid (NP0319289)

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Record Information

Version

2.0

Created at

2022-09-11 20:14:38 UTC

Updated at

2022-09-11 20:14:38 UTC

NP-MRD ID

NP0319289

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(4e,7s)-n-[(2e)-3-chloro-2-[(1s,2r,3s,5r)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid

Description

(4E,7S)-N-{3-chloro-2-[(1S,2R,3S,5R)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl}-7-methoxytetradec-4-enimidic acid belongs to the class of organic compounds known as monocyclic monoterpenoids. These are monoterpenoids containing 1 ring in the isoprene chain. (4e,7s)-n-[(2e)-3-chloro-2-[(1s,2r,3s,5r)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid is found in Lyngbya sordida. Based on a literature review very few articles have been published on (4E,7S)-N-{3-chloro-2-[(1S,2R,3S,5R)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl}-7-methoxytetradec-4-enimidic acid.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309112222142D          

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M  END

     RDKit          3D

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  Mrv1652309112222142D          

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 21 22  1  0  0  0  0
 22 23  2  0  0  0  0
 22 24  1  0  0  0  0
 24 25  1  6  0  0  0
 24 26  1  0  0  0  0
 26 27  1  0  0  0  0
 27 28  1  6  0  0  0
 27 29  1  0  0  0  0
 21 29  1  0  0  0  0
 29 30  1  1  0  0  0
 29 31  1  6  0  0  0
  8 32  1  6  0  0  0
 32 33  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0319289

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CCCCCCC[C@@H](C\C=C\CCC(O)=NC\C(=C\Cl)[C@@H]1C(=O)[C@H](O)C[C@H](O)[C@]1(C)O)OC

> <INCHI_IDENTIFIER>
InChI=1S/C25H42ClNO6/c1-4-5-6-7-9-12-19(33-3)13-10-8-11-14-22(30)27-17-18(16-26)23-24(31)20(28)15-21(29)25(23,2)32/h8,10,16,19-21,23,28-29,32H,4-7,9,11-15,17H2,1-3H3,(H,27,30)/b10-8+,18-16-/t19-,20+,21-,23+,25-/m0/s1

> <INCHI_KEY>
OEGLIHPBLJQCGW-KFMQOVFWSA-N

> <FORMULA>
C25H42ClNO6

> <MOLECULAR_WEIGHT>
488.06

> <EXACT_MASS>
487.2700658

> <JCHEM_ACCEPTOR_COUNT>
7

> <JCHEM_ATOM_COUNT>
75

> <JCHEM_AVERAGE_POLARIZABILITY>
54.29722538362924

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
4

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(4E,7S)-N-[(2E)-3-chloro-2-[(1S,2R,3S,5R)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid

> <JCHEM_LOGP>
3.499397346666666

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
1

> <JCHEM_PHYSIOLOGICAL_CHARGE>
-1

> <JCHEM_PKA>
6.70246766683331

> <JCHEM_PKA_STRONGEST_ACIDIC>
5.649427354640283

> <JCHEM_PKA_STRONGEST_BASIC>
3.644984503116201

> <JCHEM_POLAR_SURFACE_AREA>
119.58000000000001

> <JCHEM_REFRACTIVITY>
131.68729999999996

> <JCHEM_ROTATABLE_BOND_COUNT>
15

> <JCHEM_RULE_OF_FIVE>
1

> <JCHEM_TRADITIONAL_IUPAC>
(4E,7S)-N-[(2E)-3-chloro-2-[(1S,2R,3S,5R)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 11-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   11-SEP-22         0                                  
HETATM    1  C   UNK     0      -7.855 -17.607   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      -6.343 -17.316   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      -5.335 -18.480   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -3.822 -18.189   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -2.814 -19.353   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -1.302 -19.062   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0      -0.294 -20.226   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       1.218 -19.935   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       2.227 -21.099   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       3.739 -20.808   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       4.747 -21.972   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       6.259 -21.681   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       7.267 -22.845   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       8.780 -22.554   0.000  0.00  0.00           C+0
HETATM   15  O   UNK     0       9.284 -21.099   0.000  0.00  0.00           O+0
HETATM   16  N   UNK     0       9.788 -23.719   0.000  0.00  0.00           N+0
HETATM   17  C   UNK     0      11.300 -23.428   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0      11.804 -21.972   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0      10.796 -20.808   0.000  0.00  0.00           C+0
HETATM   20 Cl   UNK     0      11.300 -19.353   0.000  0.00  0.00          Cl+0
HETATM   21  C   UNK     0      13.316 -21.681   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      13.820 -20.226   0.000  0.00  0.00           C+0
HETATM   23  O   UNK     0      12.812 -19.062   0.000  0.00  0.00           O+0
HETATM   24  C   UNK     0      15.333 -19.935   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0      15.837 -18.480   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0      16.341 -21.099   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0      15.837 -22.554   0.000  0.00  0.00           C+0
HETATM   28  O   UNK     0      16.845 -23.719   0.000  0.00  0.00           O+0
HETATM   29  C   UNK     0      14.325 -22.845   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0      14.563 -24.367   0.000  0.00  0.00           C+0
HETATM   31  O   UNK     0      13.196 -23.894   0.000  0.00  0.00           O+0
HETATM   32  O   UNK     0       1.722 -18.480   0.000  0.00  0.00           O+0
HETATM   33  C   UNK     0       3.235 -18.189   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4                                                       
CONECT    4    3    5                                                       
CONECT    5    4    6                                                       
CONECT    6    5    7                                                       
CONECT    7    6    8                                                       
CONECT    8    7    9   32                                                  
CONECT    9    8   10                                                       
CONECT   10    9   11                                                       
CONECT   11   10   12                                                       
CONECT   12   11   13                                                       
CONECT   13   12   14                                                       
CONECT   14   13   15   16                                                  
CONECT   15   14                                                            
CONECT   16   14   17                                                       
CONECT   17   16   18                                                       
CONECT   18   17   19   21                                                  
CONECT   19   18   20                                                       
CONECT   20   19                                                            
CONECT   21   18   22   29                                                  
CONECT   22   21   23   24                                                  
CONECT   23   22                                                            
CONECT   24   22   25   26                                                  
CONECT   25   24                                                            
CONECT   26   24   27                                                       
CONECT   27   26   28   29                                                  
CONECT   28   27                                                            
CONECT   29   27   21   30   31                                             
CONECT   30   29                                                            
CONECT   31   29                                                            
CONECT   32    8   33                                                       
CONECT   33   32                                                            
MASTER        0    0    0    0    0    0    0    0   33    0   66    0
END

View in JSmol

Synonyms

Value	Source
(4E,7S)-N-{3-chloro-2-[(1S,2R,3S,5R)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl}-7-methoxytetradec-4-enimidate	Generator

Chemical Formula

C₂₅H₄₂ClNO₆

Average Mass

488.0600 Da

Monoisotopic Mass

487.27007 Da

IUPAC Name

(4E,7S)-N-[(2E)-3-chloro-2-[(1S,2R,3S,5R)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid

Traditional Name

(4E,7S)-N-[(2E)-3-chloro-2-[(1S,2R,3S,5R)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid

CAS Registry Number

Not Available

SMILES

CCCCCCC[C@@H](C\C=C\CCC(O)=NC\C(=C\Cl)[C@@H]1C(=O)[C@H](O)C[C@H](O)[C@]1(C)O)OC

InChI Identifier

InChI=1S/C25H42ClNO6/c1-4-5-6-7-9-12-19(33-3)13-10-8-11-14-22(30)27-17-18(16-26)23-24(31)20(28)15-21(29)25(23,2)32/h8,10,16,19-21,23,28-29,32H,4-7,9,11-15,17H2,1-3H3,(H,27,30)/b10-8+,18-16-/t19-,20+,21-,23+,25-/m0/s1

InChI Key

OEGLIHPBLJQCGW-KFMQOVFWSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Lyngbya sordida	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as monocyclic monoterpenoids. These are monoterpenoids containing 1 ring in the isoprene chain.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Monoterpenoids

Direct Parent

Monocyclic monoterpenoids

Alternative Parents

Substituents

Monocyclic monoterpenoid
Cyclitol or derivatives
Cyclic alcohol
Tertiary alcohol
Ketone
Secondary alcohol
Cyclic ketone
Carboximidic acid
Carboximidic acid derivative
Dialkyl ether
Ether
Polyol
Chloroalkene
Vinyl chloride
Vinyl halide
Haloalkene
Propargyl-type 1,3-dipolar organic compound
Organic 1,3-dipolar compound
Organohalogen compound
Organochloride
Organonitrogen compound
Organooxygen compound
Alcohol
Hydrocarbon derivative
Organic oxygen compound
Organic nitrogen compound
Carbonyl group
Organopnictogen compound
Organic oxide
Aliphatic homomonocyclic compound

Molecular Framework

Aliphatic homomonocyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	3.5	ChemAxon
pKa (Strongest Acidic)	5.65	ChemAxon
pKa (Strongest Basic)	3.64	ChemAxon
Physiological Charge	-1	ChemAxon
Hydrogen Acceptor Count	7	ChemAxon
Hydrogen Donor Count	4	ChemAxon
Polar Surface Area	119.58 Å²	ChemAxon
Rotatable Bond Count	15	ChemAxon
Refractivity	131.69 m³·mol⁻¹	ChemAxon
Polarizability	54.3 Å³	ChemAxon
Number of Rings	1	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	Yes	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

162870954

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (4e,7s)-n-[(2e)-3-chloro-2-[(1s,2r,3s,5r)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid (NP0319289)

MOL for NP0319289 ((4e,7s)-n-[(2e)-3-chloro-2-[(1s,2r,3s,5r)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

3D MOL for NP0319289 ((4e,7s)-n-[(2e)-3-chloro-2-[(1s,2r,3s,5r)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

3D SDF for NP0319289 ((4e,7s)-n-[(2e)-3-chloro-2-[(1s,2r,3s,5r)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

3D-SDF for NP0319289 ((4e,7s)-n-[(2e)-3-chloro-2-[(1s,2r,3s,5r)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

PDB for NP0319289 ((4e,7s)-n-[(2e)-3-chloro-2-[(1s,2r,3s,5r)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

3D PDB for NP0319289 ((4e,7s)-n-[(2e)-3-chloro-2-[(1s,2r,3s,5r)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

SMILES for NP0319289 ((4e,7s)-n-[(2e)-3-chloro-2-[(1s,2r,3s,5r)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

INCHI for NP0319289 ((4e,7s)-n-[(2e)-3-chloro-2-[(1s,2r,3s,5r)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

Structure for NP0319289 ((4e,7s)-n-[(2e)-3-chloro-2-[(1s,2r,3s,5r)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

3D Structure for NP0319289 ((4e,7s)-n-[(2e)-3-chloro-2-[(1s,2r,3s,5r)-2,3,5-trihydroxy-2-methyl-6-oxocyclohexyl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)