NP-MRD: Showing NP-Card for (2s,7r,13s,14s,16r,19r,20r)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0²,⁷.0²,¹⁰.0¹⁴,¹⁶.0¹⁴,²⁰]docosan-11-yl acetate (NP0316576)

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Record Information

Version

2.0

Created at

2022-09-11 15:51:30 UTC

Updated at

2022-09-11 15:51:30 UTC

NP-MRD ID

NP0316576

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(2s,7r,13s,14s,16r,19r,20r)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0²,⁷.0²,¹⁰.0¹⁴,¹⁶.0¹⁴,²⁰]docosan-11-yl acetate

Description

Glaucin B belongs to the class of organic compounds known as limonoids. These are highly oxygenated, modified terpenoids with a prototypical structure either containing or derived from a precursor with a 4,4,8-trimethyl-17-furanylsteroid skeleton. All naturally occurring citrus limonoids contain a furan ring attached to the D-ring, at C-17, as well as oxygen containing functional groups at C-3, C-4, C-7, C-16 and C-17. (2s,7r,13s,14s,16r,19r,20r)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0²,⁷.0²,¹⁰.0¹⁴,¹⁶.0¹⁴,²⁰]docosan-11-yl acetate is found in Tetradium glabrifolium. Based on a literature review very few articles have been published on Glaucin B.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309112217512D          

 38 44  0  0  1  0            999 V2000
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M  END

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M  END


  Mrv1652309112217512D          

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   -0.6751    1.1118    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.1966    1.7894    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.9616    0.9934    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  2  0  0  0  0
  2  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  6  7  2  0  0  0  0
  6  8  1  0  0  0  0
  8  9  1  1  0  0  0
  8 10  1  0  0  0  0
 10 11  1  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  6  0  0  0
 13 15  1  0  0  0  0
 15 16  1  6  0  0  0
 16 17  1  0  0  0  0
 17 18  2  0  0  0  0
 18 19  1  0  0  0  0
 19 20  1  0  0  0  0
 16 20  2  0  0  0  0
 15 21  1  0  0  0  0
 21 22  1  0  0  0  0
 22 23  2  0  0  0  0
 22 24  1  0  0  0  0
 24 25  1  1  0  0  0
 26 25  1  1  0  0  0
 24 26  1  0  0  0  0
  8 26  1  0  0  0  0
 13 26  1  0  0  0  0
 10 27  1  0  0  0  0
 27 28  1  1  0  0  0
 28 29  1  0  0  0  0
 29 30  1  0  0  0  0
 30 31  2  0  0  0  0
 30 32  1  0  0  0  0
 32 33  1  0  0  0  0
 27 33  1  0  0  0  0
 33 34  1  1  0  0  0
 34 35  1  0  0  0  0
 35 36  1  0  0  0  0
 35 37  1  0  0  0  0
 35 38  1  0  0  0  0
  5 38  1  0  0  0  0
 27 38  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0316576

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC(=O)OC1C2C(C)(C)O[C@@H]3CC(=O)OC[C@]23C2CC[C@]3(C)[C@H](OC(=O)[C@@H]4O[C@]34[C@@]2(C)C1=O)C1=COC=C1

> <INCHI_IDENTIFIER>
InChI=1S/C28H32O10/c1-13(29)35-18-19-24(2,3)37-16-10-17(30)34-12-27(16,19)15-6-8-25(4)21(14-7-9-33-11-14)36-23(32)22-28(25,38-22)26(15,5)20(18)31/h7,9,11,15-16,18-19,21-22H,6,8,10,12H2,1-5H3/t15?,16-,18?,19?,21-,22+,25-,26-,27-,28+/m1/s1

> <INCHI_KEY>
IHOHGVDNDQTZGL-MGMGQCLQSA-N

> <FORMULA>
C28H32O10

> <MOLECULAR_WEIGHT>
528.554

> <EXACT_MASS>
528.19954723

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
70

> <JCHEM_AVERAGE_POLARIZABILITY>
52.63829103990049

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
0

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(2S,7R,13S,14S,16R,19S,20R)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0^{2,7}.0^{2,10}.0^{14,16}.0^{14,20}]docosan-11-yl acetate

> <JCHEM_LOGP>
2.0688073576666643

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
7

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA_STRONGEST_ACIDIC>
14.907013528032355

> <JCHEM_PKA_STRONGEST_BASIC>
-2.852567194354381

> <JCHEM_POLAR_SURFACE_AREA>
130.87

> <JCHEM_REFRACTIVITY>
125.2641

> <JCHEM_ROTATABLE_BOND_COUNT>
3

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(2S,7R,13S,14S,16R,19S,20R)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0^{2,7}.0^{2,10}.0^{14,16}.0^{14,20}]docosan-11-yl acetate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 11-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   11-SEP-22         0                                  
HETATM    1  C   UNK     0       4.773   5.386   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       3.257   5.657   0.000  0.00  0.00           C+0
HETATM    3  O   UNK     0       2.734   7.106   0.000  0.00  0.00           O+0
HETATM    4  O   UNK     0       2.264   4.480   0.000  0.00  0.00           O+0
HETATM    5  C   UNK     0       2.788   3.032   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       4.304   2.761   0.000  0.00  0.00           C+0
HETATM    7  O   UNK     0       5.296   3.938   0.000  0.00  0.00           O+0
HETATM    8  C   UNK     0       4.827   1.312   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       4.938   2.848   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       3.793   0.349   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       4.357  -1.314   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       5.873  -1.585   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       6.866  -0.407   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       7.389  -1.856   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       8.382  -0.678   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       8.905  -2.127   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0      10.385  -2.555   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0      10.435  -4.094   0.000  0.00  0.00           C+0
HETATM   19  O   UNK     0       8.986  -4.617   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0       8.041  -3.401   0.000  0.00  0.00           C+0
HETATM   21  O   UNK     0       9.375   0.499   0.000  0.00  0.00           O+0
HETATM   22  C   UNK     0       8.852   1.947   0.000  0.00  0.00           C+0
HETATM   23  O   UNK     0       9.844   3.125   0.000  0.00  0.00           O+0
HETATM   24  C   UNK     0       7.336   2.218   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0       5.820   2.489   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0       6.343   1.041   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       2.318   0.406   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       3.745  -0.174   0.000  0.00  0.00           C+0
HETATM   29  O   UNK     0       3.955  -1.700   0.000  0.00  0.00           O+0
HETATM   30  C   UNK     0       2.740  -2.645   0.000  0.00  0.00           C+0
HETATM   31  O   UNK     0       2.950  -4.171   0.000  0.00  0.00           O+0
HETATM   32  C   UNK     0       1.313  -2.065   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0       1.102  -0.539   0.000  0.00  0.00           C+0
HETATM   34  O   UNK     0      -0.172   0.325   0.000  0.00  0.00           O+0
HETATM   35  C   UNK     0       0.256   1.804   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0      -1.260   2.075   0.000  0.00  0.00           C+0
HETATM   37  C   UNK     0       0.367   3.340   0.000  0.00  0.00           C+0
HETATM   38  C   UNK     0       1.795   1.854   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3    4                                                  
CONECT    3    2                                                            
CONECT    4    2    5                                                       
CONECT    5    4    6   38                                                  
CONECT    6    5    7    8                                                  
CONECT    7    6                                                            
CONECT    8    6    9   10   26                                             
CONECT    9    8                                                            
CONECT   10    8   11   27                                                  
CONECT   11   10   12                                                       
CONECT   12   11   13                                                       
CONECT   13   12   14   15   26                                             
CONECT   14   13                                                            
CONECT   15   13   16   21                                                  
CONECT   16   15   17   20                                                  
CONECT   17   16   18                                                       
CONECT   18   17   19                                                       
CONECT   19   18   20                                                       
CONECT   20   19   16                                                       
CONECT   21   15   22                                                       
CONECT   22   21   23   24                                                  
CONECT   23   22                                                            
CONECT   24   22   25   26                                                  
CONECT   25   24   26                                                       
CONECT   26   25   24    8   13                                             
CONECT   27   10   28   33   38                                             
CONECT   28   27   29                                                       
CONECT   29   28   30                                                       
CONECT   30   29   31   32                                                  
CONECT   31   30                                                            
CONECT   32   30   33                                                       
CONECT   33   32   27   34                                                  
CONECT   34   33   35                                                       
CONECT   35   34   36   37   38                                             
CONECT   36   35                                                            
CONECT   37   35                                                            
CONECT   38   35    5   27                                                  
MASTER        0    0    0    0    0    0    0    0   38    0   88    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₈H₃₂O₁₀

Average Mass

528.5540 Da

Monoisotopic Mass

528.19955 Da

IUPAC Name

(2S,7R,13S,14S,16R,19S,20R)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0^{2,7}.0^{2,10}.0^{14,16}.0^{14,20}]docosan-11-yl acetate

Traditional Name

(2S,7R,13S,14S,16R,19S,20R)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0^{2,7}.0^{2,10}.0^{14,16}.0^{14,20}]docosan-11-yl acetate

CAS Registry Number

Not Available

SMILES

CC(=O)OC1C2C(C)(C)O[C@@H]3CC(=O)OC[C@]23C2CC[C@]3(C)[C@H](OC(=O)[C@@H]4O[C@]34[C@@]2(C)C1=O)C1=COC=C1

InChI Identifier

InChI=1S/C28H32O10/c1-13(29)35-18-19-24(2,3)37-16-10-17(30)34-12-27(16,19)15-6-8-25(4)21(14-7-9-33-11-14)36-23(32)22-28(25,38-22)26(15,5)20(18)31/h7,9,11,15-16,18-19,21-22H,6,8,10,12H2,1-5H3/t15?,16-,18?,19?,21-,22+,25-,26-,27-,28+/m1/s1

InChI Key

IHOHGVDNDQTZGL-MGMGQCLQSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Euodia fargesii	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as limonoids. These are highly oxygenated, modified terpenoids with a prototypical structure either containing or derived from a precursor with a 4,4,8-trimethyl-17-furanylsteroid skeleton. All naturally occurring citrus limonoids contain a furan ring attached to the D-ring, at C-17, as well as oxygen containing functional groups at C-3, C-4, C-7, C-16 and C-17.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Triterpenoids

Direct Parent

Limonoids

Alternative Parents

Substituents

Limonoid skeleton
Steroid lactone
2-oxosteroid
Oxosteroid
11-oxosteroid
Steroid
Naphthopyran
Naphthalene
Tricarboxylic acid or derivatives
Alpha-acyloxy ketone
Delta_valerolactone
Dioxepane
Delta valerolactone
1,4-dioxepane
Pyran
Oxane
Heteroaromatic compound
Tetrahydrofuran
Furan
Lactone
Ketone
Carboxylic acid ester
Oxacycle
Organoheterocyclic compound
Ether
Oxirane
Dialkyl ether
Carboxylic acid derivative
Organic oxygen compound
Organic oxide
Hydrocarbon derivative
Organooxygen compound
Carbonyl group
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	2.07	ChemAxon
pKa (Strongest Acidic)	14.91	ChemAxon
pKa (Strongest Basic)	-2.9	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	6	ChemAxon
Hydrogen Donor Count	0	ChemAxon
Polar Surface Area	130.87 Å²	ChemAxon
Rotatable Bond Count	3	ChemAxon
Refractivity	125.26 m³·mol⁻¹	ChemAxon
Polarizability	52.64 Å³	ChemAxon
Number of Rings	7	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

C00024089

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

133564726

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (2s,7r,13s,14s,16r,19r,20r)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0²,⁷.0²,¹⁰.0¹⁴,¹⁶.0¹⁴,²⁰]docosan-11-yl acetate (NP0316576)

MOL for NP0316576 ((2s,7r,13s,14s,16r,19r,20r)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0²,⁷.0²,¹⁰.0¹⁴,¹⁶.0¹⁴,²⁰]docosan-11-yl acetate)

3D MOL for NP0316576 ((2s,7r,13s,14s,16r,19r,20r)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0²,⁷.0²,¹⁰.0¹⁴,¹⁶.0¹⁴,²⁰]docosan-11-yl acetate)

3D SDF for NP0316576 ((2s,7r,13s,14s,16r,19r,20r)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0²,⁷.0²,¹⁰.0¹⁴,¹⁶.0¹⁴,²⁰]docosan-11-yl acetate)

3D-SDF for NP0316576 ((2s,7r,13s,14s,16r,19r,20r)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0²,⁷.0²,¹⁰.0¹⁴,¹⁶.0¹⁴,²⁰]docosan-11-yl acetate)

PDB for NP0316576 ((2s,7r,13s,14s,16r,19r,20r)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0²,⁷.0²,¹⁰.0¹⁴,¹⁶.0¹⁴,²⁰]docosan-11-yl acetate)

3D PDB for NP0316576 ((2s,7r,13s,14s,16r,19r,20r)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0²,⁷.0²,¹⁰.0¹⁴,¹⁶.0¹⁴,²⁰]docosan-11-yl acetate)

SMILES for NP0316576 ((2s,7r,13s,14s,16r,19r,20r)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0²,⁷.0²,¹⁰.0¹⁴,¹⁶.0¹⁴,²⁰]docosan-11-yl acetate)

INCHI for NP0316576 ((2s,7r,13s,14s,16r,19r,20r)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0²,⁷.0²,¹⁰.0¹⁴,¹⁶.0¹⁴,²⁰]docosan-11-yl acetate)

Structure for NP0316576 ((2s,7r,13s,14s,16r,19r,20r)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0²,⁷.0²,¹⁰.0¹⁴,¹⁶.0¹⁴,²⁰]docosan-11-yl acetate)

3D Structure for NP0316576 ((2s,7r,13s,14s,16r,19r,20r)-19-(furan-3-yl)-9,9,13,20-tetramethyl-5,12,17-trioxo-4,8,15,18-tetraoxahexacyclo[11.9.0.0²,⁷.0²,¹⁰.0¹⁴,¹⁶.0¹⁴,²⁰]docosan-11-yl acetate)