NP-MRD: Showing NP-Card for 8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2h-furan-3-yl)ethyl]-5,6-dimethyl-hexahydro-2h-spiro[naphthalene-1,2'-oxiran]-4-yl 2-methylbut-2-enoate (NP0312910)

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Record Information

Version

2.0

Created at

2022-09-11 10:06:00 UTC

Updated at

2022-09-11 10:06:00 UTC

NP-MRD ID

NP0312910

Secondary Accession Numbers

None

Natural Product Identification

Common Name

8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2h-furan-3-yl)ethyl]-5,6-dimethyl-hexahydro-2h-spiro[naphthalene-1,2'-oxiran]-4-yl 2-methylbut-2-enoate

Description

AC1LATBY belongs to the class of organic compounds known as tetracarboxylic acids and derivatives. These are carboxylic acids containing exactly four carboxyl groups. 8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2h-furan-3-yl)ethyl]-5,6-dimethyl-hexahydro-2h-spiro[naphthalene-1,2'-oxiran]-4-yl 2-methylbut-2-enoate is found in Ajuga ciliata, Ajuga decumbens and Ajuga nipponensis. AC1LATBY is an extremely weak basic (essentially neutral) compound (based on its pKa).

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1533004171501162D          

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M  END

     RDKit          3D

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M  END


  Mrv1533004171501162D          

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   -2.2745    1.8485    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8442    1.2518    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5878    1.6093    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.3140    1.2178    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.4776    2.4269    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.6659    2.5747    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.4801    1.0410    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.3405   -0.9650    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.0900   -1.7510    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.1809   -2.5710    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.2840   -1.9271    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  2  1  1  4  0  0  0
  2  3  2  0  0  0  0
  3  4  1  0  0  0  0
  3  5  1  0  0  0  0
  5  6  2  0  0  0  0
  5  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  1  0  0  0  0
  9 10  1  0  0  0  0
 10 11  1  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 11 13  1  0  0  0  0
 11 14  1  0  0  0  0
 14 15  1  0  0  0  0
 15 16  1  0  0  0  0
 16 17  1  0  0  0  0
 17 18  2  0  0  0  0
 17 19  1  0  0  0  0
 14 20  1  0  0  0  0
 20 21  1  0  0  0  0
 21 22  1  0  0  0  0
 22 23  1  0  0  0  0
 22 24  1  0  0  0  0
 24 25  1  0  0  0  0
 24 26  1  0  0  0  0
 26 27  1  0  0  0  0
 27 28  1  0  0  0  0
 27 29  1  0  0  0  0
 29 30  2  0  0  0  0
 30 31  1  0  0  0  0
 31 32  2  0  0  0  0
 31 33  1  0  0  0  0
 33 34  1  0  0  0  0
 29 34  1  0  0  0  0
 24 35  1  0  0  0  0
  8 35  1  0  0  0  0
 14 35  1  0  0  0  0
 20 36  1  0  0  0  0
 36 37  1  0  0  0  0
 37 38  2  0  0  0  0
 37 39  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0312910

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC=C(C)C(=O)OC1CCC2(CO2)C2(COC(C)=O)C(CC(C)C(C)(CC(O)C3=CC(=O)OC3)C12)OC(C)=O

> <INCHI_IDENTIFIER>
InChI=1S/C29H40O10/c1-7-16(2)26(34)39-22-8-9-28(14-37-28)29(15-36-18(4)30)23(38-19(5)31)10-17(3)27(6,25(22)29)12-21(32)20-11-24(33)35-13-20/h7,11,17,21-23,25,32H,8-10,12-15H2,1-6H3

> <INCHI_KEY>
HZPBAEMQRBYDPW-UHFFFAOYSA-N

> <FORMULA>
C29H40O10

> <MOLECULAR_WEIGHT>
548.629

> <EXACT_MASS>
548.262147488

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
79

> <JCHEM_AVERAGE_POLARIZABILITY>
57.66227473790141

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
1

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2,5-dihydrofuran-3-yl)ethyl]-5,6-dimethyl-octahydro-2H-spiro[naphthalene-1,2'-oxirane]-4-yl 2-methylbut-2-enoate

> <ALOGPS_LOGP>
2.96

> <JCHEM_LOGP>
2.365834175

> <ALOGPS_LOGS>
-4.73

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
-1

> <JCHEM_PKA>
15.042232851860525

> <JCHEM_PKA_STRONGEST_ACIDIC>
5.76697682750473

> <JCHEM_PKA_STRONGEST_BASIC>
-3.0317774432389104

> <JCHEM_POLAR_SURFACE_AREA>
137.96

> <JCHEM_REFRACTIVITY>
138.5959

> <JCHEM_ROTATABLE_BOND_COUNT>
11

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
1.02e-02 g/l

> <JCHEM_TRADITIONAL_IUPAC>
8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2H-furan-3-yl)ethyl]-5,6-dimethyl-hexahydro-2H-spiro[naphthalene-1,2'-oxirane]-4-yl 2-methylbut-2-enoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 17-APR-15   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   17-APR-15         0                                  
HETATM    1  C   UNK     0      -0.812   9.761   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       0.225   8.622   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      -0.243   7.155   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -1.747   6.826   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       0.794   6.016   0.000  0.00  0.00           C+0
HETATM    6  O   UNK     0       2.299   6.345   0.000  0.00  0.00           O+0
HETATM    7  O   UNK     0       0.327   4.549   0.000  0.00  0.00           O+0
HETATM    8  C   UNK     0       1.364   3.410   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       2.868   3.739   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       3.905   2.601   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       3.438   1.133   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       4.905   0.666   0.000  0.00  0.00           C+0
HETATM   13  O   UNK     0       3.766  -0.371   0.000  0.00  0.00           O+0
HETATM   14  C   UNK     0       1.933   0.805   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       2.103  -0.726   0.000  0.00  0.00           C+0
HETATM   16  O   UNK     0       3.513  -1.344   0.000  0.00  0.00           O+0
HETATM   17  C   UNK     0       3.683  -2.875   0.000  0.00  0.00           C+0
HETATM   18  O   UNK     0       5.093  -3.494   0.000  0.00  0.00           O+0
HETATM   19  C   UNK     0       2.442  -3.787   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       1.465  -0.663   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0      -0.039  -0.991   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      -1.076   0.147   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0      -2.581  -0.181   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0      -0.608   1.614   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0      -0.671   3.153   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0      -2.135   1.820   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0      -2.720   3.245   0.000  0.00  0.00           C+0
HETATM   28  O   UNK     0      -1.778   4.464   0.000  0.00  0.00           O+0
HETATM   29  C   UNK     0      -4.246   3.450   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0      -5.309   2.337   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0      -6.697   3.004   0.000  0.00  0.00           C+0
HETATM   32  O   UNK     0      -8.053   2.273   0.000  0.00  0.00           O+0
HETATM   33  O   UNK     0      -6.491   4.530   0.000  0.00  0.00           O+0
HETATM   34  C   UNK     0      -4.976   4.806   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0       0.896   1.943   0.000  0.00  0.00           C+0
HETATM   36  O   UNK     0       2.502  -1.801   0.000  0.00  0.00           O+0
HETATM   37  C   UNK     0       2.035  -3.269   0.000  0.00  0.00           C+0
HETATM   38  O   UNK     0       2.204  -4.799   0.000  0.00  0.00           O+0
HETATM   39  C   UNK     0       0.530  -3.597   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4    5                                                  
CONECT    4    3                                                            
CONECT    5    3    6    7                                                  
CONECT    6    5                                                            
CONECT    7    5    8                                                       
CONECT    8    7    9   35                                                  
CONECT    9    8   10                                                       
CONECT   10    9   11                                                       
CONECT   11   10   12   13   14                                             
CONECT   12   11   13                                                       
CONECT   13   12   11                                                       
CONECT   14   11   15   20   35                                             
CONECT   15   14   16                                                       
CONECT   16   15   17                                                       
CONECT   17   16   18   19                                                  
CONECT   18   17                                                            
CONECT   19   17                                                            
CONECT   20   14   21   36                                                  
CONECT   21   20   22                                                       
CONECT   22   21   23   24                                                  
CONECT   23   22                                                            
CONECT   24   22   25   26   35                                             
CONECT   25   24                                                            
CONECT   26   24   27                                                       
CONECT   27   26   28   29                                                  
CONECT   28   27                                                            
CONECT   29   27   30   34                                                  
CONECT   30   29   31                                                       
CONECT   31   30   32   33                                                  
CONECT   32   31                                                            
CONECT   33   31   34                                                       
CONECT   34   33   29                                                       
CONECT   35   24    8   14                                                  
CONECT   36   20   37                                                       
CONECT   37   36   38   39                                                  
CONECT   38   37                                                            
CONECT   39   37                                                            
MASTER        0    0    0    0    0    0    0    0   39    0   84    0
END

View in JSmol

Synonyms

Value	Source
8-(Acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2,5-dihydrofuran-3-yl)ethyl]-5,6-dimethyl-octahydro-2H-spiro[naphthalene-1,2'-oxirane]-4-yl 2-methylbut-2-enoic acid	Generator

Chemical Formula

C₂₉H₄₀O₁₀

Average Mass

548.6290 Da

Monoisotopic Mass

548.26215 Da

IUPAC Name

8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2,5-dihydrofuran-3-yl)ethyl]-5,6-dimethyl-octahydro-2H-spiro[naphthalene-1,2'-oxirane]-4-yl 2-methylbut-2-enoate

Traditional Name

8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2H-furan-3-yl)ethyl]-5,6-dimethyl-hexahydro-2H-spiro[naphthalene-1,2'-oxirane]-4-yl 2-methylbut-2-enoate

CAS Registry Number

Not Available

SMILES

CC=C(C)C(=O)OC1CCC2(CO2)C2(COC(C)=O)C(CC(C)C(C)(CC(O)C3=CC(=O)OC3)C12)OC(C)=O

InChI Identifier

InChI=1S/C29H40O10/c1-7-16(2)26(34)39-22-8-9-28(14-37-28)29(15-36-18(4)30)23(38-19(5)31)10-17(3)27(6,25(22)29)12-21(32)20-11-24(33)35-13-20/h7,11,17,21-23,25,32H,8-10,12-15H2,1-6H3

InChI Key

HZPBAEMQRBYDPW-UHFFFAOYSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Ajuga ciliata	LOTUS Database	35616633
Ajuga decumbens	LOTUS Database	35616633
Ajuga nipponensis	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as tetracarboxylic acids and derivatives. These are carboxylic acids containing exactly four carboxyl groups.

Kingdom

Organic compounds

Super Class

Organic acids and derivatives

Class

Carboxylic acids and derivatives

Sub Class

Tetracarboxylic acids and derivatives

Direct Parent

Tetracarboxylic acids and derivatives

Alternative Parents

Substituents

Tetracarboxylic acid or derivatives
Fatty acid ester
2-furanone
Fatty acyl
Dihydrofuran
Alpha,beta-unsaturated carboxylic ester
Enoate ester
Carboxylic acid ester
Lactone
Secondary alcohol
Dialkyl ether
Oxirane
Ether
Oxacycle
Organoheterocyclic compound
Hydrocarbon derivative
Alcohol
Organic oxygen compound
Carbonyl group
Organic oxide
Organooxygen compound
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	2.96	ALOGPS
logP	2.37	ChemAxon
logS	-4.7	ALOGPS
pKa (Strongest Acidic)	5.77	ChemAxon
pKa (Strongest Basic)	-3	ChemAxon
Physiological Charge	-1	ChemAxon
Hydrogen Acceptor Count	6	ChemAxon
Hydrogen Donor Count	1	ChemAxon
Polar Surface Area	137.96 Å²	ChemAxon
Rotatable Bond Count	11	ChemAxon
Refractivity	138.6 m³·mol⁻¹	ChemAxon
Polarizability	57.66 Å³	ChemAxon
Number of Rings	4	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

494584

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for 8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2h-furan-3-yl)ethyl]-5,6-dimethyl-hexahydro-2h-spiro[naphthalene-1,2'-oxiran]-4-yl 2-methylbut-2-enoate (NP0312910)

MOL for NP0312910 (8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2h-furan-3-yl)ethyl]-5,6-dimethyl-hexahydro-2h-spiro[naphthalene-1,2'-oxiran]-4-yl 2-methylbut-2-enoate)

3D MOL for NP0312910 (8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2h-furan-3-yl)ethyl]-5,6-dimethyl-hexahydro-2h-spiro[naphthalene-1,2'-oxiran]-4-yl 2-methylbut-2-enoate)

3D SDF for NP0312910 (8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2h-furan-3-yl)ethyl]-5,6-dimethyl-hexahydro-2h-spiro[naphthalene-1,2'-oxiran]-4-yl 2-methylbut-2-enoate)

3D-SDF for NP0312910 (8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2h-furan-3-yl)ethyl]-5,6-dimethyl-hexahydro-2h-spiro[naphthalene-1,2'-oxiran]-4-yl 2-methylbut-2-enoate)

PDB for NP0312910 (8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2h-furan-3-yl)ethyl]-5,6-dimethyl-hexahydro-2h-spiro[naphthalene-1,2'-oxiran]-4-yl 2-methylbut-2-enoate)

3D PDB for NP0312910 (8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2h-furan-3-yl)ethyl]-5,6-dimethyl-hexahydro-2h-spiro[naphthalene-1,2'-oxiran]-4-yl 2-methylbut-2-enoate)

SMILES for NP0312910 (8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2h-furan-3-yl)ethyl]-5,6-dimethyl-hexahydro-2h-spiro[naphthalene-1,2'-oxiran]-4-yl 2-methylbut-2-enoate)

INCHI for NP0312910 (8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2h-furan-3-yl)ethyl]-5,6-dimethyl-hexahydro-2h-spiro[naphthalene-1,2'-oxiran]-4-yl 2-methylbut-2-enoate)

Structure for NP0312910 (8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2h-furan-3-yl)ethyl]-5,6-dimethyl-hexahydro-2h-spiro[naphthalene-1,2'-oxiran]-4-yl 2-methylbut-2-enoate)

3D Structure for NP0312910 (8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[2-hydroxy-2-(5-oxo-2h-furan-3-yl)ethyl]-5,6-dimethyl-hexahydro-2h-spiro[naphthalene-1,2'-oxiran]-4-yl 2-methylbut-2-enoate)