NP-MRD: Showing NP-Card for 5-{1-[(2s,6r)-5-[(3r,3ar,5ar,8r,9ar,9bs)-8-hydroxy-3a,6,6,9a-tetramethyl-7-oxo-octahydro-1h-cyclopenta[a]naphthalen-3-yl]-6-hydroxy-3,6-dihydro-2h-pyran-2-yl]ethenyl}-2,2-dimethylfuran-3-one (NP0312596)

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Record Information

Version

2.0

Created at

2022-09-11 09:30:50 UTC

Updated at

2022-09-11 09:30:50 UTC

NP-MRD ID

NP0312596

Secondary Accession Numbers

None

Natural Product Identification

Common Name

5-{1-[(2s,6r)-5-[(3r,3ar,5ar,8r,9ar,9bs)-8-hydroxy-3a,6,6,9a-tetramethyl-7-oxo-octahydro-1h-cyclopenta[a]naphthalen-3-yl]-6-hydroxy-3,6-dihydro-2h-pyran-2-yl]ethenyl}-2,2-dimethylfuran-3-one

Description

Sodagnitin A belongs to the class of organic compounds known as triterpenoids. These are terpene molecules containing six isoprene units. 5-{1-[(2s,6r)-5-[(3r,3ar,5ar,8r,9ar,9bs)-8-hydroxy-3a,6,6,9a-tetramethyl-7-oxo-octahydro-1h-cyclopenta[a]naphthalen-3-yl]-6-hydroxy-3,6-dihydro-2h-pyran-2-yl]ethenyl}-2,2-dimethylfuran-3-one is found in Cortinarius fulvoincarnatus. Based on a literature review very few articles have been published on Sodagnitin A.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309112211302D          

 36 40  0  0  1  0            999 V2000
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M  END

     RDKit          3D

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M  END


  Mrv1652309112211302D          

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    1.5391    0.4383    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.9291    1.1653    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.0058   -0.2939    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    5.1521    0.5181    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.6358   -0.8265    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  2  0  0  0  0
  2  3  1  0  0  0  0
  3  4  2  0  0  0  0
  4  5  1  0  0  0  0
  5  6  2  0  0  0  0
  5  7  1  0  0  0  0
  7  8  1  0  0  0  0
  7  9  1  0  0  0  0
  7 10  1  0  0  0  0
  3 10  1  0  0  0  0
 11  2  1  6  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  2  0  0  0  0
 15 14  1  1  0  0  0
 15 16  1  0  0  0  0
 16 17  1  0  0  0  0
 18 17  1  1  0  0  0
 18 19  1  0  0  0  0
 15 19  1  0  0  0  0
 19 20  1  1  0  0  0
 19 21  1  0  0  0  0
 21 22  1  0  0  0  0
 23 22  1  1  0  0  0
 23 24  1  0  0  0  0
 24 25  1  0  0  0  0
 24 26  1  0  0  0  0
 24 27  1  0  0  0  0
 27 28  2  0  0  0  0
 27 29  1  0  0  0  0
 29 30  1  6  0  0  0
 29 31  1  0  0  0  0
 31 32  1  0  0  0  0
 18 32  1  0  0  0  0
 23 32  1  0  0  0  0
 32 33  1  1  0  0  0
 14 34  1  0  0  0  0
 34 35  1  6  0  0  0
 34 36  1  0  0  0  0
 11 36  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0312596

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC1(C)OC(=CC1=O)C(=C)[C@@H]1CC=C([C@@H]2CC[C@H]3[C@@]2(C)CC[C@H]2C(C)(C)C(=O)[C@H](O)C[C@]32C)[C@H](O)O1

> <INCHI_IDENTIFIER>
InChI=1S/C30H42O6/c1-16(21-14-24(32)28(4,5)36-21)20-10-8-17(26(34)35-20)18-9-11-23-29(18,6)13-12-22-27(2,3)25(33)19(31)15-30(22,23)7/h8,14,18-20,22-23,26,31,34H,1,9-13,15H2,2-7H3/t18-,19+,20-,22-,23-,26+,29-,30-/m0/s1

> <INCHI_KEY>
RGYVYGAQTJOSEN-OPSOQUJQSA-N

> <FORMULA>
C30H42O6

> <MOLECULAR_WEIGHT>
498.66

> <EXACT_MASS>
498.298139072

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
78

> <JCHEM_AVERAGE_POLARIZABILITY>
56.56131114706301

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
2

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
5-{1-[(2S,6R)-5-[(3R,3aR,5aR,8R,9aR,9bS)-8-hydroxy-3a,6,6,9a-tetramethyl-7-oxo-dodecahydro-1H-cyclopenta[a]naphthalen-3-yl]-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]ethenyl}-2,2-dimethyl-2,3-dihydrofuran-3-one

> <JCHEM_LOGP>
4.528310686666667

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
13.387472832958267

> <JCHEM_PKA_STRONGEST_ACIDIC>
11.818427724948757

> <JCHEM_PKA_STRONGEST_BASIC>
-3.5094642010876997

> <JCHEM_POLAR_SURFACE_AREA>
93.06000000000002

> <JCHEM_REFRACTIVITY>
139.05

> <JCHEM_ROTATABLE_BOND_COUNT>
3

> <JCHEM_RULE_OF_FIVE>
1

> <JCHEM_TRADITIONAL_IUPAC>
5-{1-[(2S,6R)-5-[(3R,3aR,5aR,8R,9aR,9bS)-8-hydroxy-3a,6,6,9a-tetramethyl-7-oxo-octahydro-1H-cyclopenta[a]naphthalen-3-yl]-6-hydroxy-3,6-dihydro-2H-pyran-2-yl]ethenyl}-2,2-dimethylfuran-3-one

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 11-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   11-SEP-22         0                                  
HETATM    1  C   UNK     0      11.150  -5.568   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      11.423  -4.053   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      12.872  -3.531   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      13.302  -2.052   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      14.842  -2.004   0.000  0.00  0.00           C+0
HETATM    6  O   UNK     0      15.707  -0.731   0.000  0.00  0.00           O+0
HETATM    7  C   UNK     0      15.363  -3.453   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      16.750  -2.783   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0      16.174  -4.762   0.000  0.00  0.00           C+0
HETATM   10  O   UNK     0      14.146  -4.397   0.000  0.00  0.00           O+0
HETATM   11  C   UNK     0      10.247  -3.058   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       8.798  -3.580   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       7.622  -2.586   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       7.895  -1.070   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       6.719  -0.076   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       6.832   1.460   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       5.406   2.042   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       4.412   0.866   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       5.223  -0.443   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       6.167  -1.660   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       4.495  -1.800   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       2.956  -1.848   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       2.145  -0.539   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       0.606  -0.587   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0       0.920  -2.095   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0      -0.824  -1.159   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0      -0.206   0.722   0.000  0.00  0.00           C+0
HETATM   28  O   UNK     0      -1.745   0.674   0.000  0.00  0.00           O+0
HETATM   29  C   UNK     0       0.522   2.079   0.000  0.00  0.00           C+0
HETATM   30  O   UNK     0      -0.289   3.388   0.000  0.00  0.00           O+0
HETATM   31  C   UNK     0       2.062   2.127   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0       2.873   0.818   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0       3.601   2.175   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0       9.344  -0.549   0.000  0.00  0.00           C+0
HETATM   35  O   UNK     0       9.617   0.967   0.000  0.00  0.00           O+0
HETATM   36  O   UNK     0      10.520  -1.543   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3   11                                                  
CONECT    3    2    4   10                                                  
CONECT    4    3    5                                                       
CONECT    5    4    6    7                                                  
CONECT    6    5                                                            
CONECT    7    5    8    9   10                                             
CONECT    8    7                                                            
CONECT    9    7                                                            
CONECT   10    7    3                                                       
CONECT   11    2   12   36                                                  
CONECT   12   11   13                                                       
CONECT   13   12   14                                                       
CONECT   14   13   15   34                                                  
CONECT   15   14   16   19                                                  
CONECT   16   15   17                                                       
CONECT   17   16   18                                                       
CONECT   18   17   19   32                                                  
CONECT   19   18   15   20   21                                             
CONECT   20   19                                                            
CONECT   21   19   22                                                       
CONECT   22   21   23                                                       
CONECT   23   22   24   32                                                  
CONECT   24   23   25   26   27                                             
CONECT   25   24                                                            
CONECT   26   24                                                            
CONECT   27   24   28   29                                                  
CONECT   28   27                                                            
CONECT   29   27   30   31                                                  
CONECT   30   29                                                            
CONECT   31   29   32                                                       
CONECT   32   31   18   23   33                                             
CONECT   33   32                                                            
CONECT   34   14   35   36                                                  
CONECT   35   34                                                            
CONECT   36   34   11                                                       
MASTER        0    0    0    0    0    0    0    0   36    0   80    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₃₀H₄₂O₆

Average Mass

498.6600 Da

Monoisotopic Mass

498.29814 Da

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

CC1(C)OC(=CC1=O)C(=C)[C@@H]1CC=C([C@@H]2CC[C@H]3[C@@]2(C)CC[C@H]2C(C)(C)C(=O)[C@H](O)C[C@]32C)[C@H](O)O1

InChI Identifier

InChI=1S/C30H42O6/c1-16(21-14-24(32)28(4,5)36-21)20-10-8-17(26(34)35-20)18-9-11-23-29(18,6)13-12-22-27(2,3)25(33)19(31)15-30(22,23)7/h8,14,18-20,22-23,26,31,34H,1,9-13,15H2,2-7H3/t18-,19+,20-,22-,23-,26+,29-,30-/m0/s1

InChI Key

RGYVYGAQTJOSEN-OPSOQUJQSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Calonarius fulvoincarnatus	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as triterpenoids. These are terpene molecules containing six isoprene units.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Triterpenoids

Direct Parent

Triterpenoids

Alternative Parents

Substituents

Triterpenoid
3-furanone
Pyran
Cyclic alcohol
Dihydrofuran
Vinylogous ester
Cyclic ketone
Secondary alcohol
Ketone
Hemiacetal
Organoheterocyclic compound
Oxacycle
Hydrocarbon derivative
Organic oxide
Organooxygen compound
Organic oxygen compound
Alcohol
Carbonyl group
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

354944

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

400502

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for 5-{1-[(2s,6r)-5-[(3r,3ar,5ar,8r,9ar,9bs)-8-hydroxy-3a,6,6,9a-tetramethyl-7-oxo-octahydro-1h-cyclopenta[a]naphthalen-3-yl]-6-hydroxy-3,6-dihydro-2h-pyran-2-yl]ethenyl}-2,2-dimethylfuran-3-one (NP0312596)

MOL for NP0312596 (5-{1-[(2s,6r)-5-[(3r,3ar,5ar,8r,9ar,9bs)-8-hydroxy-3a,6,6,9a-tetramethyl-7-oxo-octahydro-1h-cyclopenta[a]naphthalen-3-yl]-6-hydroxy-3,6-dihydro-2h-pyran-2-yl]ethenyl}-2,2-dimethylfuran-3-one)

3D MOL for NP0312596 (5-{1-[(2s,6r)-5-[(3r,3ar,5ar,8r,9ar,9bs)-8-hydroxy-3a,6,6,9a-tetramethyl-7-oxo-octahydro-1h-cyclopenta[a]naphthalen-3-yl]-6-hydroxy-3,6-dihydro-2h-pyran-2-yl]ethenyl}-2,2-dimethylfuran-3-one)

3D SDF for NP0312596 (5-{1-[(2s,6r)-5-[(3r,3ar,5ar,8r,9ar,9bs)-8-hydroxy-3a,6,6,9a-tetramethyl-7-oxo-octahydro-1h-cyclopenta[a]naphthalen-3-yl]-6-hydroxy-3,6-dihydro-2h-pyran-2-yl]ethenyl}-2,2-dimethylfuran-3-one)

3D-SDF for NP0312596 (5-{1-[(2s,6r)-5-[(3r,3ar,5ar,8r,9ar,9bs)-8-hydroxy-3a,6,6,9a-tetramethyl-7-oxo-octahydro-1h-cyclopenta[a]naphthalen-3-yl]-6-hydroxy-3,6-dihydro-2h-pyran-2-yl]ethenyl}-2,2-dimethylfuran-3-one)

PDB for NP0312596 (5-{1-[(2s,6r)-5-[(3r,3ar,5ar,8r,9ar,9bs)-8-hydroxy-3a,6,6,9a-tetramethyl-7-oxo-octahydro-1h-cyclopenta[a]naphthalen-3-yl]-6-hydroxy-3,6-dihydro-2h-pyran-2-yl]ethenyl}-2,2-dimethylfuran-3-one)

3D PDB for NP0312596 (5-{1-[(2s,6r)-5-[(3r,3ar,5ar,8r,9ar,9bs)-8-hydroxy-3a,6,6,9a-tetramethyl-7-oxo-octahydro-1h-cyclopenta[a]naphthalen-3-yl]-6-hydroxy-3,6-dihydro-2h-pyran-2-yl]ethenyl}-2,2-dimethylfuran-3-one)

SMILES for NP0312596 (5-{1-[(2s,6r)-5-[(3r,3ar,5ar,8r,9ar,9bs)-8-hydroxy-3a,6,6,9a-tetramethyl-7-oxo-octahydro-1h-cyclopenta[a]naphthalen-3-yl]-6-hydroxy-3,6-dihydro-2h-pyran-2-yl]ethenyl}-2,2-dimethylfuran-3-one)

INCHI for NP0312596 (5-{1-[(2s,6r)-5-[(3r,3ar,5ar,8r,9ar,9bs)-8-hydroxy-3a,6,6,9a-tetramethyl-7-oxo-octahydro-1h-cyclopenta[a]naphthalen-3-yl]-6-hydroxy-3,6-dihydro-2h-pyran-2-yl]ethenyl}-2,2-dimethylfuran-3-one)

Structure for NP0312596 (5-{1-[(2s,6r)-5-[(3r,3ar,5ar,8r,9ar,9bs)-8-hydroxy-3a,6,6,9a-tetramethyl-7-oxo-octahydro-1h-cyclopenta[a]naphthalen-3-yl]-6-hydroxy-3,6-dihydro-2h-pyran-2-yl]ethenyl}-2,2-dimethylfuran-3-one)

3D Structure for NP0312596 (5-{1-[(2s,6r)-5-[(3r,3ar,5ar,8r,9ar,9bs)-8-hydroxy-3a,6,6,9a-tetramethyl-7-oxo-octahydro-1h-cyclopenta[a]naphthalen-3-yl]-6-hydroxy-3,6-dihydro-2h-pyran-2-yl]ethenyl}-2,2-dimethylfuran-3-one)