NP-MRD: Showing NP-Card for (2s,3r,4s,5r,6r)-2-{[(1s,4as,7r,8as)-1,4a-dimethyl-7-(prop-1-en-2-yl)-octahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2s)-2-methylbutanoate (NP0310803)

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Record Information

Version

2.0

Created at

2022-09-11 06:22:40 UTC

Updated at

2022-09-11 06:22:41 UTC

NP-MRD ID

NP0310803

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(2s,3r,4s,5r,6r)-2-{[(1s,4as,7r,8as)-1,4a-dimethyl-7-(prop-1-en-2-yl)-octahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2s)-2-methylbutanoate

Description

(2S,3R,4S,5R,6R)-2-{[(1S,4aS,7R,8aS)-1,4a-dimethyl-7-(prop-1-en-2-yl)-decahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2S)-2-methylbutanoate belongs to the class of organic compounds known as terpene glycosides. These are prenol lipids containing a carbohydrate moiety glycosidically bound to a terpene backbone. (2s,3r,4s,5r,6r)-2-{[(1s,4as,7r,8as)-1,4a-dimethyl-7-(prop-1-en-2-yl)-octahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2s)-2-methylbutanoate is found in Carthamus lanatus. Based on a literature review very few articles have been published on (2S,3R,4S,5R,6R)-2-{[(1S,4aS,7R,8aS)-1,4a-dimethyl-7-(prop-1-en-2-yl)-decahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2S)-2-methylbutanoate.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309112208222D          

 32 34  0  0  1  0            999 V2000
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M  END

     RDKit          3D

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M  END


  Mrv1652309112208222D          

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 21 22  1  1  0  0  0
 21 23  1  0  0  0  0
 15 23  1  0  0  0  0
 23 24  1  6  0  0  0
 24 25  1  0  0  0  0
 25 26  2  0  0  0  0
 25 27  1  0  0  0  0
 27 28  1  6  0  0  0
 27 29  1  0  0  0  0
 29 30  1  0  0  0  0
 12 31  1  0  0  0  0
  7 31  1  0  0  0  0
 31 32  1  1  0  0  0
  4 32  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0310803

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC[C@H](C)C(=O)O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](C)O[C@H]1O[C@@]1(C)CCC[C@@]2(C)CC[C@H](C[C@H]12)C(C)=C

> <INCHI_IDENTIFIER>
InChI=1S/C26H44O6/c1-8-16(4)23(29)31-22-21(28)20(27)17(5)30-24(22)32-26(7)12-9-11-25(6)13-10-18(15(2)3)14-19(25)26/h16-22,24,27-28H,2,8-14H2,1,3-7H3/t16-,17+,18+,19-,20-,21-,22+,24-,25-,26-/m0/s1

> <INCHI_KEY>
MWIIJKQLNNDGLP-FSEUMVHSSA-N

> <FORMULA>
C26H44O6

> <MOLECULAR_WEIGHT>
452.632

> <EXACT_MASS>
452.313789137

> <JCHEM_ACCEPTOR_COUNT>
5

> <JCHEM_ATOM_COUNT>
76

> <JCHEM_AVERAGE_POLARIZABILITY>
51.05670075489835

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
2

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(2S,3R,4S,5R,6R)-2-{[(1S,4aS,7R,8aS)-1,4a-dimethyl-7-(prop-1-en-2-yl)-decahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2S)-2-methylbutanoate

> <JCHEM_LOGP>
5.0149721696666685

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
3

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
14.182133954514597

> <JCHEM_PKA_STRONGEST_ACIDIC>
12.73885542411131

> <JCHEM_PKA_STRONGEST_BASIC>
-3.612905124205355

> <JCHEM_POLAR_SURFACE_AREA>
85.22

> <JCHEM_REFRACTIVITY>
122.108

> <JCHEM_ROTATABLE_BOND_COUNT>
7

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(2S,3R,4S,5R,6R)-2-{[(1S,4aS,7R,8aS)-1,4a-dimethyl-7-(prop-1-en-2-yl)-octahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2S)-2-methylbutanoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 11-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   11-SEP-22         0                                  
HETATM    1  C   UNK     0      -3.216  14.340   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      -2.689  12.893   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      -3.679  11.713   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -1.173  12.626   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -0.183  13.805   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       1.334  13.538   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       1.860  12.091   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       2.850  13.271   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       3.377  11.823   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       3.904  10.376   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       2.914   9.197   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       1.397   9.464   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      -0.119   9.197   0.000  0.00  0.00           C+0
HETATM   14  O   UNK     0       1.397   7.924   0.000  0.00  0.00           O+0
HETATM   15  C   UNK     0       0.064   7.154   0.000  0.00  0.00           C+0
HETATM   16  O   UNK     0      -1.270   7.924   0.000  0.00  0.00           O+0
HETATM   17  C   UNK     0      -2.604   7.154   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0      -3.938   7.924   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0      -2.604   5.614   0.000  0.00  0.00           C+0
HETATM   20  O   UNK     0      -3.938   4.844   0.000  0.00  0.00           O+0
HETATM   21  C   UNK     0      -1.270   4.844   0.000  0.00  0.00           C+0
HETATM   22  O   UNK     0      -1.270   3.304   0.000  0.00  0.00           O+0
HETATM   23  C   UNK     0       0.064   5.614   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0       1.397   4.844   0.000  0.00  0.00           O+0
HETATM   25  C   UNK     0       2.731   5.614   0.000  0.00  0.00           C+0
HETATM   26  O   UNK     0       2.731   7.154   0.000  0.00  0.00           O+0
HETATM   27  C   UNK     0       4.065   4.844   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       4.065   3.304   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       5.398   5.614   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       5.398   7.154   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0       0.870  10.911   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0      -0.646  11.179   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3    4                                                  
CONECT    3    2                                                            
CONECT    4    2    5   32                                                  
CONECT    5    4    6                                                       
CONECT    6    5    7                                                       
CONECT    7    6    8    9   31                                             
CONECT    8    7                                                            
CONECT    9    7   10                                                       
CONECT   10    9   11                                                       
CONECT   11   10   12                                                       
CONECT   12   11   13   14   31                                             
CONECT   13   12                                                            
CONECT   14   12   15                                                       
CONECT   15   14   16   23                                                  
CONECT   16   15   17                                                       
CONECT   17   16   18   19                                                  
CONECT   18   17                                                            
CONECT   19   17   20   21                                                  
CONECT   20   19                                                            
CONECT   21   19   22   23                                                  
CONECT   22   21                                                            
CONECT   23   21   15   24                                                  
CONECT   24   23   25                                                       
CONECT   25   24   26   27                                                  
CONECT   26   25                                                            
CONECT   27   25   28   29                                                  
CONECT   28   27                                                            
CONECT   29   27   30                                                       
CONECT   30   29                                                            
CONECT   31   12    7   32                                                  
CONECT   32   31    4                                                       
MASTER        0    0    0    0    0    0    0    0   32    0   68    0
END

View in JSmol

Synonyms

Value	Source
(2S,3R,4S,5R,6R)-2-{[(1S,4as,7R,8as)-1,4a-dimethyl-7-(prop-1-en-2-yl)-decahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2S)-2-methylbutanoic acid	Generator

Chemical Formula

C₂₆H₄₄O₆

Average Mass

452.6320 Da

Monoisotopic Mass

452.31379 Da

IUPAC Name

(2S,3R,4S,5R,6R)-2-{[(1S,4aS,7R,8aS)-1,4a-dimethyl-7-(prop-1-en-2-yl)-decahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2S)-2-methylbutanoate

Traditional Name

(2S,3R,4S,5R,6R)-2-{[(1S,4aS,7R,8aS)-1,4a-dimethyl-7-(prop-1-en-2-yl)-octahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2S)-2-methylbutanoate

CAS Registry Number

Not Available

SMILES

CC[C@H](C)C(=O)O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](C)O[C@H]1O[C@@]1(C)CCC[C@@]2(C)CC[C@H](C[C@H]12)C(C)=C

InChI Identifier

InChI=1S/C26H44O6/c1-8-16(4)23(29)31-22-21(28)20(27)17(5)30-24(22)32-26(7)12-9-11-25(6)13-10-18(15(2)3)14-19(25)26/h16-22,24,27-28H,2,8-14H2,1,3-7H3/t16-,17+,18+,19-,20-,21-,22+,24-,25-,26-/m0/s1

InChI Key

MWIIJKQLNNDGLP-FSEUMVHSSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Carthamus lanatus	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as terpene glycosides. These are prenol lipids containing a carbohydrate moiety glycosidically bound to a terpene backbone.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Terpene glycosides

Direct Parent

Terpene glycosides

Alternative Parents

Substituents

Terpene glycoside
Eudesmane, isoeudesmane or cycloeudesmane sesquiterpenoid
Sesquiterpenoid
Hexose monosaccharide
Glycosyl compound
O-glycosyl compound
Fatty acid ester
Monosaccharide
Fatty acyl
Oxane
1,2-diol
Carboxylic acid ester
Secondary alcohol
Acetal
Monocarboxylic acid or derivatives
Oxacycle
Carboxylic acid derivative
Organoheterocyclic compound
Organooxygen compound
Hydrocarbon derivative
Organic oxide
Organic oxygen compound
Carbonyl group
Alcohol
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	5.01	ChemAxon
pKa (Strongest Acidic)	12.74	ChemAxon
pKa (Strongest Basic)	-3.6	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	5	ChemAxon
Hydrogen Donor Count	2	ChemAxon
Polar Surface Area	85.22 Å²	ChemAxon
Rotatable Bond Count	7	ChemAxon
Refractivity	122.11 m³·mol⁻¹	ChemAxon
Polarizability	51.06 Å³	ChemAxon
Number of Rings	3	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

162878658

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (2s,3r,4s,5r,6r)-2-{[(1s,4as,7r,8as)-1,4a-dimethyl-7-(prop-1-en-2-yl)-octahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2s)-2-methylbutanoate (NP0310803)

MOL for NP0310803 ((2s,3r,4s,5r,6r)-2-{[(1s,4as,7r,8as)-1,4a-dimethyl-7-(prop-1-en-2-yl)-octahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2s)-2-methylbutanoate)

3D MOL for NP0310803 ((2s,3r,4s,5r,6r)-2-{[(1s,4as,7r,8as)-1,4a-dimethyl-7-(prop-1-en-2-yl)-octahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2s)-2-methylbutanoate)

3D SDF for NP0310803 ((2s,3r,4s,5r,6r)-2-{[(1s,4as,7r,8as)-1,4a-dimethyl-7-(prop-1-en-2-yl)-octahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2s)-2-methylbutanoate)

3D-SDF for NP0310803 ((2s,3r,4s,5r,6r)-2-{[(1s,4as,7r,8as)-1,4a-dimethyl-7-(prop-1-en-2-yl)-octahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2s)-2-methylbutanoate)

PDB for NP0310803 ((2s,3r,4s,5r,6r)-2-{[(1s,4as,7r,8as)-1,4a-dimethyl-7-(prop-1-en-2-yl)-octahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2s)-2-methylbutanoate)

3D PDB for NP0310803 ((2s,3r,4s,5r,6r)-2-{[(1s,4as,7r,8as)-1,4a-dimethyl-7-(prop-1-en-2-yl)-octahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2s)-2-methylbutanoate)

SMILES for NP0310803 ((2s,3r,4s,5r,6r)-2-{[(1s,4as,7r,8as)-1,4a-dimethyl-7-(prop-1-en-2-yl)-octahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2s)-2-methylbutanoate)

INCHI for NP0310803 ((2s,3r,4s,5r,6r)-2-{[(1s,4as,7r,8as)-1,4a-dimethyl-7-(prop-1-en-2-yl)-octahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2s)-2-methylbutanoate)

Structure for NP0310803 ((2s,3r,4s,5r,6r)-2-{[(1s,4as,7r,8as)-1,4a-dimethyl-7-(prop-1-en-2-yl)-octahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2s)-2-methylbutanoate)

3D Structure for NP0310803 ((2s,3r,4s,5r,6r)-2-{[(1s,4as,7r,8as)-1,4a-dimethyl-7-(prop-1-en-2-yl)-octahydronaphthalen-1-yl]oxy}-4,5-dihydroxy-6-methyloxan-3-yl (2s)-2-methylbutanoate)