NP-MRD: Showing NP-Card for (1r,2s,6s,7s,8s,9s,12r,13r,14r)-13,14-dihydroxy-6-isopropyl-12-methoxy-9,13-dimethyl-3-methylidene-15-oxatricyclo[6.6.1.0²,⁷]pentadecan-9-yl butanoate (NP0306010)

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Record Information

Version

2.0

Created at

2022-09-10 22:13:52 UTC

Updated at

2022-09-10 22:13:52 UTC

NP-MRD ID

NP0306010

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1r,2s,6s,7s,8s,9s,12r,13r,14r)-13,14-dihydroxy-6-isopropyl-12-methoxy-9,13-dimethyl-3-methylidene-15-oxatricyclo[6.6.1.0²,⁷]pentadecan-9-yl butanoate

Description

(1R,2S,6S,7S,8S,9S,12R,13R,14R)-13,14-dihydroxy-12-methoxy-9,13-dimethyl-3-methylidene-6-(propan-2-yl)-15-oxatricyclo[6.6.1.0²,⁷]Pentadecan-9-yl butanoate belongs to the class of organic compounds known as eunicellane and asbestinane diterpenoids. These are diterpenoids with a structure based on either the eunicellane (5,14-cyclocembrane) or the asbestinane skeleton. (1r,2s,6s,7s,8s,9s,12r,13r,14r)-13,14-dihydroxy-6-isopropyl-12-methoxy-9,13-dimethyl-3-methylidene-15-oxatricyclo[6.6.1.0²,⁷]pentadecan-9-yl butanoate is found in Cladiella krempfi. Based on a literature review very few articles have been published on (1R,2S,6S,7S,8S,9S,12R,13R,14R)-13,14-dihydroxy-12-methoxy-9,13-dimethyl-3-methylidene-6-(propan-2-yl)-15-oxatricyclo[6.6.1.0²,⁷]Pentadecan-9-yl butanoate.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309112200132D          

 31 33  0  0  1  0            999 V2000
   -3.2561    0.8101    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9205    1.5638    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.4055    2.2312    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.0699    2.9849    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2494    3.0711    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -1.9139    3.8248    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0934    3.9110    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.3988    4.4922    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7645    2.4037    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.1001    1.6500    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -1.9285    0.8430    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -1.7359    1.9394    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0500    2.8162    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.2295    2.7299    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.4011    3.5369    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.4849    3.1424    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
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    1.1994    1.9049    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.9139    3.1424    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.6283    2.7299    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.3428    3.1424    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.3835    2.1779    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.5551    1.3709    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.2195    0.6173    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.8326    0.0652    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.6172    0.3202    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4950    0.2048    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.1181   -0.3473    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.8305   -0.5489    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3154    0.2910    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -1.6510   -0.4627    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  2  0  0  0  0
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  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  1  0  0  0
  6  7  1  0  0  0  0
  6  8  1  0  0  0  0
  5  9  1  0  0  0  0
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  9 13  1  0  0  0  0
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 27 29  1  6  0  0  0
 27 30  1  0  0  0  0
 11 30  1  0  0  0  0
 30 31  1  6  0  0  0
M  END

     RDKit          3D

 73 75  0  0  0  0  0  0  0  0999 V2000
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    0.4228    2.3727   -0.2004 C   0  0  0  0  0  0  0  0  0  0  0  0
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M  END


  Mrv1652309112200132D          

 31 33  0  0  1  0            999 V2000
   -3.2561    0.8101    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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M  END
> <DATABASE_ID>
NP0306010

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CCCC(=O)O[C@@]1(C)CC[C@@H](OC)[C@](C)(O)[C@H](O)[C@@H]2O[C@H]1[C@@H]1[C@H]2C(=C)CC[C@H]1C(C)C

> <INCHI_IDENTIFIER>
InChI=1S/C25H42O6/c1-8-9-18(26)31-24(5)13-12-17(29-7)25(6,28)22(27)21-19-15(4)10-11-16(14(2)3)20(19)23(24)30-21/h14,16-17,19-23,27-28H,4,8-13H2,1-3,5-7H3/t16-,17+,19+,20-,21+,22+,23-,24-,25-/m0/s1

> <INCHI_KEY>
FGNNJVLLTPWQFJ-OIGGNUBUSA-N

> <FORMULA>
C25H42O6

> <MOLECULAR_WEIGHT>
438.605

> <EXACT_MASS>
438.298139072

> <JCHEM_ACCEPTOR_COUNT>
5

> <JCHEM_ATOM_COUNT>
73

> <JCHEM_AVERAGE_POLARIZABILITY>
49.7582308168048

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
2

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(1R,2S,6S,7S,8S,9S,12R,13R,14R)-13,14-dihydroxy-12-methoxy-9,13-dimethyl-3-methylidene-6-(propan-2-yl)-15-oxatricyclo[6.6.1.0^{2,7}]pentadecan-9-yl butanoate

> <JCHEM_LOGP>
3.4381857259999995

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
3

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
14.105698706769981

> <JCHEM_PKA_STRONGEST_ACIDIC>
12.704700036340768

> <JCHEM_PKA_STRONGEST_BASIC>
-3.6567542388702137

> <JCHEM_POLAR_SURFACE_AREA>
85.22000000000001

> <JCHEM_REFRACTIVITY>
118.05919999999999

> <JCHEM_ROTATABLE_BOND_COUNT>
6

> <JCHEM_RULE_OF_FIVE>
1

> <JCHEM_TRADITIONAL_IUPAC>
(1R,2S,6S,7S,8S,9S,12R,13R,14R)-13,14-dihydroxy-6-isopropyl-12-methoxy-9,13-dimethyl-3-methylidene-15-oxatricyclo[6.6.1.0^{2,7}]pentadecan-9-yl butanoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 11-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   11-SEP-22         0                                  
HETATM    1  C   UNK     0      -6.078   1.512   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      -5.452   2.919   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      -6.357   4.165   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -5.730   5.572   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -4.199   5.733   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -3.573   7.140   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0      -2.041   7.301   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      -4.478   8.385   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0      -3.294   4.487   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0      -3.920   3.080   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0      -3.600   1.574   0.000  0.00  0.00           C+0
HETATM   12  O   UNK     0      -3.240   3.620   0.000  0.00  0.00           O+0
HETATM   13  C   UNK     0      -1.960   5.257   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0      -0.428   5.096   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      -0.749   6.602   0.000  0.00  0.00           C+0
HETATM   16  O   UNK     0       0.905   5.866   0.000  0.00  0.00           O+0
HETATM   17  C   UNK     0       2.239   5.096   0.000  0.00  0.00           C+0
HETATM   18  O   UNK     0       2.239   3.556   0.000  0.00  0.00           O+0
HETATM   19  C   UNK     0       3.573   5.866   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       4.906   5.096   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       6.240   5.866   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       0.716   4.065   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       1.036   2.559   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       0.410   1.152   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0       1.554   0.122   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0       3.019   0.598   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0      -0.924   0.382   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       0.221  -0.648   0.000  0.00  0.00           C+0
HETATM   29  O   UNK     0      -1.550  -1.025   0.000  0.00  0.00           O+0
HETATM   30  C   UNK     0      -2.455   0.543   0.000  0.00  0.00           C+0
HETATM   31  O   UNK     0      -3.082  -0.864   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3   10                                                  
CONECT    3    2    4                                                       
CONECT    4    3    5                                                       
CONECT    5    4    6    9                                                  
CONECT    6    5    7    8                                                  
CONECT    7    6                                                            
CONECT    8    6                                                            
CONECT    9    5   10   13                                                  
CONECT   10    9    2   11                                                  
CONECT   11   10   12   30                                                  
CONECT   12   11   13                                                       
CONECT   13   12    9   14                                                  
CONECT   14   13   15   16   22                                             
CONECT   15   14                                                            
CONECT   16   14   17                                                       
CONECT   17   16   18   19                                                  
CONECT   18   17                                                            
CONECT   19   17   20                                                       
CONECT   20   19   21                                                       
CONECT   21   20                                                            
CONECT   22   14   23                                                       
CONECT   23   22   24                                                       
CONECT   24   23   25   27                                                  
CONECT   25   24   26                                                       
CONECT   26   25                                                            
CONECT   27   24   28   29   30                                             
CONECT   28   27                                                            
CONECT   29   27                                                            
CONECT   30   27   11   31                                                  
CONECT   31   30                                                            
MASTER        0    0    0    0    0    0    0    0   31    0   66    0
END

View in JSmol

Synonyms

Value	Source
(1R,2S,6S,7S,8S,9S,12R,13R,14R)-13,14-Dihydroxy-12-methoxy-9,13-dimethyl-3-methylidene-6-(propan-2-yl)-15-oxatricyclo[6.6.1.0,]pentadecan-9-yl butanoic acid	Generator

Chemical Formula

C₂₅H₄₂O₆

Average Mass

438.6050 Da

Monoisotopic Mass

438.29814 Da

IUPAC Name

(1R,2S,6S,7S,8S,9S,12R,13R,14R)-13,14-dihydroxy-12-methoxy-9,13-dimethyl-3-methylidene-6-(propan-2-yl)-15-oxatricyclo[6.6.1.0^{2,7}]pentadecan-9-yl butanoate

Traditional Name

(1R,2S,6S,7S,8S,9S,12R,13R,14R)-13,14-dihydroxy-6-isopropyl-12-methoxy-9,13-dimethyl-3-methylidene-15-oxatricyclo[6.6.1.0^{2,7}]pentadecan-9-yl butanoate

CAS Registry Number

Not Available

SMILES

CCCC(=O)O[C@@]1(C)CC[C@@H](OC)[C@](C)(O)[C@H](O)[C@@H]2O[C@H]1[C@@H]1[C@H]2C(=C)CC[C@H]1C(C)C

InChI Identifier

InChI=1S/C25H42O6/c1-8-9-18(26)31-24(5)13-12-17(29-7)25(6,28)22(27)21-19-15(4)10-11-16(14(2)3)20(19)23(24)30-21/h14,16-17,19-23,27-28H,4,8-13H2,1-3,5-7H3/t16-,17+,19+,20-,21+,22+,23-,24-,25-/m0/s1

InChI Key

FGNNJVLLTPWQFJ-OIGGNUBUSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Cladiella krempfi	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as eunicellane and asbestinane diterpenoids. These are diterpenoids with a structure based on either the eunicellane (5,14-cyclocembrane) or the asbestinane skeleton.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Diterpenoids

Direct Parent

Eunicellane and asbestinane diterpenoids

Alternative Parents

Substituents

Cladiellane diterpenoid
Eunicellane-type diterpenoid
Fatty acid ester
Cyclitol or derivatives
Fatty acyl
Tetrahydrofuran
Tertiary alcohol
1,2-diol
Carboxylic acid ester
Secondary alcohol
Carboxylic acid derivative
Dialkyl ether
Ether
Oxacycle
Organoheterocyclic compound
Monocarboxylic acid or derivatives
Hydrocarbon derivative
Alcohol
Organic oxide
Carbonyl group
Organic oxygen compound
Organooxygen compound
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	3.44	ChemAxon
pKa (Strongest Acidic)	12.7	ChemAxon
pKa (Strongest Basic)	-3.7	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	5	ChemAxon
Hydrogen Donor Count	2	ChemAxon
Polar Surface Area	85.22 Å²	ChemAxon
Rotatable Bond Count	6	ChemAxon
Refractivity	118.06 m³·mol⁻¹	ChemAxon
Polarizability	49.76 Å³	ChemAxon
Number of Rings	3	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	Yes	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

162893551

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (1r,2s,6s,7s,8s,9s,12r,13r,14r)-13,14-dihydroxy-6-isopropyl-12-methoxy-9,13-dimethyl-3-methylidene-15-oxatricyclo[6.6.1.0²,⁷]pentadecan-9-yl butanoate (NP0306010)

MOL for NP0306010 ((1r,2s,6s,7s,8s,9s,12r,13r,14r)-13,14-dihydroxy-6-isopropyl-12-methoxy-9,13-dimethyl-3-methylidene-15-oxatricyclo[6.6.1.0²,⁷]pentadecan-9-yl butanoate)

3D MOL for NP0306010 ((1r,2s,6s,7s,8s,9s,12r,13r,14r)-13,14-dihydroxy-6-isopropyl-12-methoxy-9,13-dimethyl-3-methylidene-15-oxatricyclo[6.6.1.0²,⁷]pentadecan-9-yl butanoate)

3D SDF for NP0306010 ((1r,2s,6s,7s,8s,9s,12r,13r,14r)-13,14-dihydroxy-6-isopropyl-12-methoxy-9,13-dimethyl-3-methylidene-15-oxatricyclo[6.6.1.0²,⁷]pentadecan-9-yl butanoate)

3D-SDF for NP0306010 ((1r,2s,6s,7s,8s,9s,12r,13r,14r)-13,14-dihydroxy-6-isopropyl-12-methoxy-9,13-dimethyl-3-methylidene-15-oxatricyclo[6.6.1.0²,⁷]pentadecan-9-yl butanoate)

PDB for NP0306010 ((1r,2s,6s,7s,8s,9s,12r,13r,14r)-13,14-dihydroxy-6-isopropyl-12-methoxy-9,13-dimethyl-3-methylidene-15-oxatricyclo[6.6.1.0²,⁷]pentadecan-9-yl butanoate)

3D PDB for NP0306010 ((1r,2s,6s,7s,8s,9s,12r,13r,14r)-13,14-dihydroxy-6-isopropyl-12-methoxy-9,13-dimethyl-3-methylidene-15-oxatricyclo[6.6.1.0²,⁷]pentadecan-9-yl butanoate)

SMILES for NP0306010 ((1r,2s,6s,7s,8s,9s,12r,13r,14r)-13,14-dihydroxy-6-isopropyl-12-methoxy-9,13-dimethyl-3-methylidene-15-oxatricyclo[6.6.1.0²,⁷]pentadecan-9-yl butanoate)

INCHI for NP0306010 ((1r,2s,6s,7s,8s,9s,12r,13r,14r)-13,14-dihydroxy-6-isopropyl-12-methoxy-9,13-dimethyl-3-methylidene-15-oxatricyclo[6.6.1.0²,⁷]pentadecan-9-yl butanoate)

Structure for NP0306010 ((1r,2s,6s,7s,8s,9s,12r,13r,14r)-13,14-dihydroxy-6-isopropyl-12-methoxy-9,13-dimethyl-3-methylidene-15-oxatricyclo[6.6.1.0²,⁷]pentadecan-9-yl butanoate)

3D Structure for NP0306010 ((1r,2s,6s,7s,8s,9s,12r,13r,14r)-13,14-dihydroxy-6-isopropyl-12-methoxy-9,13-dimethyl-3-methylidene-15-oxatricyclo[6.6.1.0²,⁷]pentadecan-9-yl butanoate)