NP-MRD: Showing NP-Card for 6-(4-acetylphenoxymethyl)-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-2-one (NP0301145)

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Record Information

Version

2.0

Created at

2022-09-10 13:55:57 UTC

Updated at

2022-09-10 13:55:57 UTC

NP-MRD ID

NP0301145

Secondary Accession Numbers

None

Natural Product Identification

Common Name

6-(4-acetylphenoxymethyl)-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-2-one

Description

6-[(4-Acetylphenoxy)methyl]-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-2H,3H,3aH,4H,5H,8H,9H,11aH-cyclodeca[b]furan-2-one belongs to the class of organic compounds known as terpene glycosides. These are prenol lipids containing a carbohydrate moiety glycosidically bound to a terpene backbone. 6-(4-acetylphenoxymethyl)-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-2-one is found in Ixeris tamagawaensis. 6-[(4-Acetylphenoxy)methyl]-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-2H,3H,3aH,4H,5H,8H,9H,11aH-cyclodeca[b]furan-2-one is an extremely weak basic (essentially neutral) compound (based on its pKa).

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1533004251509072D          

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M  END

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M  END


  Mrv1533004251509072D          

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    3.0807    7.8833    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.4175    7.3787    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.3642   -1.4826    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.6555   -0.7108    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.8870   -2.1209    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.7011   -1.9872    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.5957   -2.8927    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.1185   -3.5309    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  6  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  2  0  0  0  0
  9 10  1  4  0  0  0
 10 11  1  0  0  0  0
 11 12  1  0  0  0  0
 12 13  2  0  0  0  0
 12 14  1  0  0  0  0
 14 15  2  0  0  0  0
 14 16  1  0  0  0  0
 10 16  1  0  0  0  0
 16 17  1  0  0  0  0
 17 18  1  0  0  0  0
 18 19  1  0  0  0  0
 19 20  2  0  0  0  0
 20 21  1  4  0  0  0
 21 22  1  0  0  0  0
  8 22  1  0  0  0  0
 19 23  1  0  0  0  0
 23 24  1  0  0  0  0
 24 25  1  0  0  0  0
 25 26  2  0  0  0  0
 26 27  1  0  0  0  0
 27 28  2  0  0  0  0
 28 29  1  0  0  0  0
 29 30  2  0  0  0  0
 25 30  1  0  0  0  0
 28 31  1  0  0  0  0
 31 32  2  0  0  0  0
 31 33  1  0  0  0  0
  5 34  1  0  0  0  0
 34 35  1  0  0  0  0
 34 36  1  0  0  0  0
 36 37  1  0  0  0  0
 36 38  1  0  0  0  0
  3 38  1  0  0  0  0
 38 39  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0301145

> <DATABASE_NAME>
NP-MRD

> <SMILES>
COC1OC(OCC2=CC3OC(=O)C(=C)C3CCC(COC3=CC=C(C=C3)C(C)=O)=CCC2)C(O)C(O)C1O

> <INCHI_IDENTIFIER>
InChI=1S/C29H36O10/c1-16-22-12-7-18(14-36-21-10-8-20(9-11-21)17(2)30)5-4-6-19(13-23(22)38-27(16)34)15-37-29-26(33)24(31)25(32)28(35-3)39-29/h5,8-11,13,22-26,28-29,31-33H,1,4,6-7,12,14-15H2,2-3H3

> <INCHI_KEY>
JCBLKMOSECWLKA-UHFFFAOYSA-N

> <FORMULA>
C29H36O10

> <MOLECULAR_WEIGHT>
544.597

> <EXACT_MASS>
544.230847359

> <JCHEM_ACCEPTOR_COUNT>
9

> <JCHEM_ATOM_COUNT>
75

> <JCHEM_AVERAGE_POLARIZABILITY>
55.90362038624361

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
3

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
6-[(4-acetylphenoxy)methyl]-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-2H,3H,3aH,4H,5H,8H,9H,11aH-cyclodeca[b]furan-2-one

> <ALOGPS_LOGP>
1.88

> <JCHEM_LOGP>
2.2848253293333345

> <ALOGPS_LOGS>
-3.79

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
12.778920675136526

> <JCHEM_PKA_STRONGEST_ACIDIC>
12.006297701682728

> <JCHEM_PKA_STRONGEST_BASIC>
-3.7116136885169206

> <JCHEM_POLAR_SURFACE_AREA>
140.98

> <JCHEM_REFRACTIVITY>
140.39040000000003

> <JCHEM_ROTATABLE_BOND_COUNT>
8

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
8.79e-02 g/l

> <JCHEM_TRADITIONAL_IUPAC>
6-(4-acetylphenoxymethyl)-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-3aH,4H,5H,8H,9H,11aH-cyclodeca[b]furan-2-one

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 25-APR-15   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   25-APR-15         0                                  
HETATM    1  C   UNK     0       5.624  -8.281   0.000  0.00  0.00           C+0
HETATM    2  O   UNK     0       4.648  -7.090   0.000  0.00  0.00           O+0
HETATM    3  C   UNK     0       5.192  -5.649   0.000  0.00  0.00           C+0
HETATM    4  O   UNK     0       4.216  -4.458   0.000  0.00  0.00           O+0
HETATM    5  C   UNK     0       4.760  -3.017   0.000  0.00  0.00           C+0
HETATM    6  O   UNK     0       3.784  -1.826   0.000  0.00  0.00           O+0
HETATM    7  C   UNK     0       4.328  -0.385   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       3.352   0.806   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       1.832   0.557   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       0.857   1.748   0.000  0.00  0.00           C+0
HETATM   11  O   UNK     0      -0.682   1.820   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0      -1.089   3.305   0.000  0.00  0.00           C+0
HETATM   13  O   UNK     0      -2.529   3.849   0.000  0.00  0.00           O+0
HETATM   14  C   UNK     0       0.198   4.151   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       0.270   5.690   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       1.400   3.189   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       2.920   3.438   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       3.464   4.879   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       4.983   5.129   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       5.959   3.937   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       5.416   2.497   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       3.896   2.247   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       5.527   6.570   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0       4.551   7.761   0.000  0.00  0.00           O+0
HETATM   25  C   UNK     0       5.095   9.202   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0       4.119  10.393   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       4.663  11.834   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       6.183  12.083   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       7.159  10.892   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       6.615   9.451   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0       6.726  13.524   0.000  0.00  0.00           C+0
HETATM   32  O   UNK     0       5.751  14.715   0.000  0.00  0.00           O+0
HETATM   33  C   UNK     0       8.246  13.774   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0       6.280  -2.768   0.000  0.00  0.00           C+0
HETATM   35  O   UNK     0       6.824  -1.327   0.000  0.00  0.00           O+0
HETATM   36  C   UNK     0       7.256  -3.959   0.000  0.00  0.00           C+0
HETATM   37  O   UNK     0       8.775  -3.709   0.000  0.00  0.00           O+0
HETATM   38  C   UNK     0       6.712  -5.400   0.000  0.00  0.00           C+0
HETATM   39  O   UNK     0       7.688  -6.591   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4   38                                                  
CONECT    4    3    5                                                       
CONECT    5    4    6   34                                                  
CONECT    6    5    7                                                       
CONECT    7    6    8                                                       
CONECT    8    7    9   22                                                  
CONECT    9    8   10                                                       
CONECT   10    9   11   16                                                  
CONECT   11   10   12                                                       
CONECT   12   11   13   14                                                  
CONECT   13   12                                                            
CONECT   14   12   15   16                                                  
CONECT   15   14                                                            
CONECT   16   14   10   17                                                  
CONECT   17   16   18                                                       
CONECT   18   17   19                                                       
CONECT   19   18   20   23                                                  
CONECT   20   19   21                                                       
CONECT   21   20   22                                                       
CONECT   22   21    8                                                       
CONECT   23   19   24                                                       
CONECT   24   23   25                                                       
CONECT   25   24   26   30                                                  
CONECT   26   25   27                                                       
CONECT   27   26   28                                                       
CONECT   28   27   29   31                                                  
CONECT   29   28   30                                                       
CONECT   30   29   25                                                       
CONECT   31   28   32   33                                                  
CONECT   32   31                                                            
CONECT   33   31                                                            
CONECT   34    5   35   36                                                  
CONECT   35   34                                                            
CONECT   36   34   37   38                                                  
CONECT   37   36                                                            
CONECT   38   36    3   39                                                  
CONECT   39   38                                                            
MASTER        0    0    0    0    0    0    0    0   39    0   84    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₉H₃₆O₁₀

Average Mass

544.5970 Da

Monoisotopic Mass

544.23085 Da

IUPAC Name

6-[(4-acetylphenoxy)methyl]-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-2H,3H,3aH,4H,5H,8H,9H,11aH-cyclodeca[b]furan-2-one

Traditional Name

6-(4-acetylphenoxymethyl)-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-3aH,4H,5H,8H,9H,11aH-cyclodeca[b]furan-2-one

CAS Registry Number

Not Available

SMILES

COC1OC(OCC2=CC3OC(=O)C(=C)C3CCC(COC3=CC=C(C=C3)C(C)=O)=CCC2)C(O)C(O)C1O

InChI Identifier

InChI=1S/C29H36O10/c1-16-22-12-7-18(14-36-21-10-8-20(9-11-21)17(2)30)5-4-6-19(13-23(22)38-27(16)34)15-37-29-26(33)24(31)25(32)28(35-3)39-29/h5,8-11,13,22-26,28-29,31-33H,1,4,6-7,12,14-15H2,2-3H3

InChI Key

JCBLKMOSECWLKA-UHFFFAOYSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Ixeris tamagawaensis	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as terpene glycosides. These are prenol lipids containing a carbohydrate moiety glycosidically bound to a terpene backbone.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Terpene glycosides

Direct Parent

Terpene glycosides

Alternative Parents

Substituents

Terpene glycoside
Coumaric acid ester
Hydroxycinnamic acid or derivatives
Cinnamic acid ester
Coumaric acid or derivatives
Cinnamic acid or derivatives
O-glycosyl compound
Iridoid-skeleton
Glycosyl compound
Aromatic monoterpenoid
Monoterpenoid
Bicyclic monoterpenoid
Tricarboxylic acid or derivatives
Styrene
Fatty acid ester
1-hydroxy-2-unsubstituted benzenoid
Phenol
Monocyclic benzene moiety
Monosaccharide
Oxane
Benzenoid
Fatty acyl
Alpha,beta-unsaturated carboxylic ester
Cyclic alcohol
Enoate ester
Tertiary alcohol
Carboxylic acid ester
Secondary alcohol
Acetal
Organoheterocyclic compound
Oxacycle
Carboxylic acid derivative
Polyol
Alcohol
Carbonyl group
Hydrocarbon derivative
Organic oxide
Organic oxygen compound
Organooxygen compound
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	1.88	ALOGPS
logP	2.28	ChemAxon
logS	-3.8	ALOGPS
pKa (Strongest Acidic)	12.01	ChemAxon
pKa (Strongest Basic)	-3.7	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	9	ChemAxon
Hydrogen Donor Count	3	ChemAxon
Polar Surface Area	140.98 Å²	ChemAxon
Rotatable Bond Count	8	ChemAxon
Refractivity	140.39 m³·mol⁻¹	ChemAxon
Polarizability	55.9 Å³	ChemAxon
Number of Rings	4	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

Not Available

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for 6-(4-acetylphenoxymethyl)-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-2-one (NP0301145)

MOL for NP0301145 (6-(4-acetylphenoxymethyl)-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-2-one)

3D MOL for NP0301145 (6-(4-acetylphenoxymethyl)-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-2-one)

3D SDF for NP0301145 (6-(4-acetylphenoxymethyl)-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-2-one)

3D-SDF for NP0301145 (6-(4-acetylphenoxymethyl)-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-2-one)

PDB for NP0301145 (6-(4-acetylphenoxymethyl)-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-2-one)

3D PDB for NP0301145 (6-(4-acetylphenoxymethyl)-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-2-one)

SMILES for NP0301145 (6-(4-acetylphenoxymethyl)-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-2-one)

INCHI for NP0301145 (6-(4-acetylphenoxymethyl)-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-2-one)

Structure for NP0301145 (6-(4-acetylphenoxymethyl)-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-2-one)

3D Structure for NP0301145 (6-(4-acetylphenoxymethyl)-3-methylidene-10-{[(3,4,5-trihydroxy-6-methoxyoxan-2-yl)oxy]methyl}-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-2-one)