NP-MRD: Showing NP-Card for (1s,2s,5s,6s,7s,9r,12r)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl (2e)-3-phenylprop-2-enoate (NP0299553)

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Record Information

Version

2.0

Created at

2022-09-10 11:26:06 UTC

Updated at

2022-09-10 11:26:06 UTC

NP-MRD ID

NP0299553

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1s,2s,5s,6s,7s,9r,12r)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl (2e)-3-phenylprop-2-enoate

Description

(1S,2S,5S,6S,7S,9R,12R)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0¹,⁶]Dodecan-7-yl (2E)-3-phenylprop-2-enoate belongs to the class of organic compounds known as agarofurans. These are organic compounds containing an agarofuran moiety( a three-ring system, with core fragment oxatricyclo[7.2.1.0^{1,6}]Dodec-2-ene). (1s,2s,5s,6s,7s,9r,12r)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl (2e)-3-phenylprop-2-enoate is found in Lydenburgia cassinoides. Based on a literature review very few articles have been published on (1S,2S,5S,6S,7S,9R,12R)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0¹,⁶]Dodecan-7-yl (2E)-3-phenylprop-2-enoate.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309102213262D          

 37 40  0  0  1  0            999 V2000
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M  END

     RDKit          3D

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M  END


  Mrv1652309102213262D          

 37 40  0  0  1  0            999 V2000
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    0.9217   -1.2071    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.1713   -0.7591    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.5083   -1.2889    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7189   -0.6670    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  2  0  0  0  0
  2  4  1  0  0  0  0
  5  4  1  1  0  0  0
  5  6  1  0  0  0  0
  6  7  1  6  0  0  0
  7  8  1  0  0  0  0
  8  9  1  6  0  0  0
  9 10  1  0  0  0  0
 10 11  2  0  0  0  0
 10 12  1  0  0  0  0
 12 13  2  0  0  0  0
 13 14  1  0  0  0  0
 14 15  2  0  0  0  0
 15 16  1  0  0  0  0
 16 17  2  0  0  0  0
 17 18  1  0  0  0  0
 18 19  2  0  0  0  0
 14 19  1  0  0  0  0
  8 20  1  0  0  0  0
 20 21  1  1  0  0  0
 20 22  1  0  0  0  0
 22 23  1  1  0  0  0
 23 24  1  0  0  0  0
 24 25  2  0  0  0  0
 24 26  1  0  0  0  0
 26 27  1  0  0  0  0
 22 28  1  0  0  0  0
 28 29  1  0  0  0  0
 29 30  1  0  0  0  0
 30 31  1  1  0  0  0
 30 32  1  6  0  0  0
 30 33  1  0  0  0  0
  5 33  1  0  0  0  0
 20 33  1  0  0  0  0
 33 34  1  6  0  0  0
 34 35  1  0  0  0  0
  6 35  1  0  0  0  0
 35 36  1  0  0  0  0
 35 37  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0299553

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC(=O)O[C@@H]1[C@H]2C[C@H](OC(=O)\C=C\C3=CC=CC=C3)[C@]3(C)[C@H](CC[C@](C)(O)[C@@]13OC2(C)C)OC(=O)CO

> <INCHI_IDENTIFIER>
InChI=1S/C28H36O9/c1-17(30)34-24-19-15-21(36-22(31)12-11-18-9-7-6-8-10-18)27(5)20(35-23(32)16-29)13-14-26(4,33)28(24,27)37-25(19,2)3/h6-12,19-21,24,29,33H,13-16H2,1-5H3/b12-11+/t19-,20+,21+,24-,26+,27+,28+/m1/s1

> <INCHI_KEY>
ZBLCWCJBUVYIBX-JAZYBIMQSA-N

> <FORMULA>
C28H36O9

> <MOLECULAR_WEIGHT>
516.587

> <EXACT_MASS>
516.235932739

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
73

> <JCHEM_AVERAGE_POLARIZABILITY>
54.21173630005692

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
2

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(1S,2S,5S,6S,7S,9R,12R)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0^{1,6}]dodecan-7-yl (2E)-3-phenylprop-2-enoate

> <JCHEM_LOGP>
2.4043559799999983

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
13.850434363881917

> <JCHEM_PKA_STRONGEST_ACIDIC>
13.03585080779407

> <JCHEM_PKA_STRONGEST_BASIC>
-3.3414055122327886

> <JCHEM_POLAR_SURFACE_AREA>
128.59

> <JCHEM_REFRACTIVITY>
131.9197

> <JCHEM_ROTATABLE_BOND_COUNT>
9

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(1S,2S,5S,6S,7S,9R,12R)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0^{1,6}]dodecan-7-yl (2E)-3-phenylprop-2-enoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 10-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   10-SEP-22         0                                  
HETATM    1  C   UNK     0      -0.075   3.291   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       1.453   2.716   0.000  0.00  0.00           C+0
HETATM    3  O   UNK     0       2.123   4.142   0.000  0.00  0.00           O+0
HETATM    4  O   UNK     0       2.322   1.104   0.000  0.00  0.00           O+0
HETATM    5  C   UNK     0       1.911  -0.474   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       0.681   0.158   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       1.439   1.588   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       3.034   1.662   0.000  0.00  0.00           C+0
HETATM    9  O   UNK     0       3.341   3.489   0.000  0.00  0.00           O+0
HETATM   10  C   UNK     0       2.747   5.281   0.000  0.00  0.00           C+0
HETATM   11  O   UNK     0       1.327   6.093   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0       3.572   6.737   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       3.020   8.220   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       4.002   9.407   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       3.464  10.850   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       4.445  12.037   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       5.964  11.781   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       6.501  10.337   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       5.520   9.150   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       3.812   0.238   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       5.204   1.076   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       5.363   0.374   0.000  0.00  0.00           C+0
HETATM   23  O   UNK     0       7.077   0.817   0.000  0.00  0.00           O+0
HETATM   24  C   UNK     0       8.750   0.853   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0       9.753  -0.392   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0       9.821   2.151   0.000  0.00  0.00           C+0
HETATM   27  O   UNK     0      11.405   2.139   0.000  0.00  0.00           O+0
HETATM   28  C   UNK     0       6.248  -0.893   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       5.606  -2.302   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       4.055  -2.444   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0       4.635  -3.992   0.000  0.00  0.00           C+0
HETATM   32  O   UNK     0       2.922  -3.707   0.000  0.00  0.00           O+0
HETATM   33  C   UNK     0       3.041  -1.217   0.000  0.00  0.00           C+0
HETATM   34  O   UNK     0       1.721  -2.253   0.000  0.00  0.00           O+0
HETATM   35  C   UNK     0       0.320  -1.417   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0      -0.949  -2.406   0.000  0.00  0.00           C+0
HETATM   37  C   UNK     0      -1.342  -1.245   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3    4                                                  
CONECT    3    2                                                            
CONECT    4    2    5                                                       
CONECT    5    4    6   33                                                  
CONECT    6    5    7   35                                                  
CONECT    7    6    8                                                       
CONECT    8    7    9   20                                                  
CONECT    9    8   10                                                       
CONECT   10    9   11   12                                                  
CONECT   11   10                                                            
CONECT   12   10   13                                                       
CONECT   13   12   14                                                       
CONECT   14   13   15   19                                                  
CONECT   15   14   16                                                       
CONECT   16   15   17                                                       
CONECT   17   16   18                                                       
CONECT   18   17   19                                                       
CONECT   19   18   14                                                       
CONECT   20    8   21   22   33                                             
CONECT   21   20                                                            
CONECT   22   20   23   28                                                  
CONECT   23   22   24                                                       
CONECT   24   23   25   26                                                  
CONECT   25   24                                                            
CONECT   26   24   27                                                       
CONECT   27   26                                                            
CONECT   28   22   29                                                       
CONECT   29   28   30                                                       
CONECT   30   29   31   32   33                                             
CONECT   31   30                                                            
CONECT   32   30                                                            
CONECT   33   30    5   20   34                                             
CONECT   34   33   35                                                       
CONECT   35   34    6   36   37                                             
CONECT   36   35                                                            
CONECT   37   35                                                            
MASTER        0    0    0    0    0    0    0    0   37    0   80    0
END

View in JSmol

Synonyms

Value	Source
(1S,2S,5S,6S,7S,9R,12R)-12-(Acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0,]dodecan-7-yl (2E)-3-phenylprop-2-enoic acid	Generator

Chemical Formula

C₂₈H₃₆O₉

Average Mass

516.5870 Da

Monoisotopic Mass

516.23593 Da

IUPAC Name

(1S,2S,5S,6S,7S,9R,12R)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0^{1,6}]dodecan-7-yl (2E)-3-phenylprop-2-enoate

Traditional Name

(1S,2S,5S,6S,7S,9R,12R)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0^{1,6}]dodecan-7-yl (2E)-3-phenylprop-2-enoate

CAS Registry Number

Not Available

SMILES

CC(=O)O[C@@H]1[C@H]2C[C@H](OC(=O)\C=C\C3=CC=CC=C3)[C@]3(C)[C@H](CC[C@](C)(O)[C@@]13OC2(C)C)OC(=O)CO

InChI Identifier

InChI=1S/C28H36O9/c1-17(30)34-24-19-15-21(36-22(31)12-11-18-9-7-6-8-10-18)27(5)20(35-23(32)16-29)13-14-26(4,33)28(24,27)37-25(19,2)3/h6-12,19-21,24,29,33H,13-16H2,1-5H3/b12-11+/t19-,20+,21+,24-,26+,27+,28+/m1/s1

InChI Key

ZBLCWCJBUVYIBX-JAZYBIMQSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Lydenburgia cassinoides	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as agarofurans. These are organic compounds containing an agarofuran moiety( a three-ring system, with core fragment oxatricyclo[7.2.1.0^{1,6}]Dodec-2-ene).

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Sesquiterpenoids

Direct Parent

Agarofurans

Alternative Parents

Substituents

Agarofuran
Cinnamic acid or derivatives
Cinnamic acid ester
Tricarboxylic acid or derivatives
Styrene
Fatty acid ester
Oxepane
Monocyclic benzene moiety
Fatty acyl
Benzenoid
Cyclic alcohol
Alpha,beta-unsaturated carboxylic ester
Tertiary alcohol
Tetrahydrofuran
Enoate ester
Carboxylic acid ester
Organoheterocyclic compound
Oxacycle
Ether
Dialkyl ether
Carboxylic acid derivative
Organooxygen compound
Organic oxygen compound
Hydrocarbon derivative
Primary alcohol
Alcohol
Organic oxide
Carbonyl group
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	2.4	ChemAxon
pKa (Strongest Acidic)	13.04	ChemAxon
pKa (Strongest Basic)	-3.3	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	6	ChemAxon
Hydrogen Donor Count	2	ChemAxon
Polar Surface Area	128.59 Å²	ChemAxon
Rotatable Bond Count	9	ChemAxon
Refractivity	131.92 m³·mol⁻¹	ChemAxon
Polarizability	54.21 Å³	ChemAxon
Number of Rings	4	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

163191393

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (1s,2s,5s,6s,7s,9r,12r)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl (2e)-3-phenylprop-2-enoate (NP0299553)

MOL for NP0299553 ((1s,2s,5s,6s,7s,9r,12r)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl (2e)-3-phenylprop-2-enoate)

3D MOL for NP0299553 ((1s,2s,5s,6s,7s,9r,12r)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl (2e)-3-phenylprop-2-enoate)

3D SDF for NP0299553 ((1s,2s,5s,6s,7s,9r,12r)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl (2e)-3-phenylprop-2-enoate)

3D-SDF for NP0299553 ((1s,2s,5s,6s,7s,9r,12r)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl (2e)-3-phenylprop-2-enoate)

PDB for NP0299553 ((1s,2s,5s,6s,7s,9r,12r)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl (2e)-3-phenylprop-2-enoate)

3D PDB for NP0299553 ((1s,2s,5s,6s,7s,9r,12r)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl (2e)-3-phenylprop-2-enoate)

SMILES for NP0299553 ((1s,2s,5s,6s,7s,9r,12r)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl (2e)-3-phenylprop-2-enoate)

INCHI for NP0299553 ((1s,2s,5s,6s,7s,9r,12r)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl (2e)-3-phenylprop-2-enoate)

Structure for NP0299553 ((1s,2s,5s,6s,7s,9r,12r)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl (2e)-3-phenylprop-2-enoate)

3D Structure for NP0299553 ((1s,2s,5s,6s,7s,9r,12r)-12-(acetyloxy)-2-hydroxy-5-[(2-hydroxyacetyl)oxy]-2,6,10,10-tetramethyl-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl (2e)-3-phenylprop-2-enoate)