NP-MRD: Showing NP-Card for 2-({4,5-dihydroxy-6-[(2-{4-hydroxy-5a,5b,8,8,11a,13b-hexamethyl-9-[(3,4,5-trihydroxyoxan-2-yl)oxy]-hexadecahydrocyclopenta[a]chrysen-3-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol (NP0298321)

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Record Information

Version

2.0

Created at

2022-09-10 09:29:16 UTC

Updated at

2022-09-10 09:29:16 UTC

NP-MRD ID

NP0298321

Secondary Accession Numbers

None

Natural Product Identification

Common Name

2-({4,5-dihydroxy-6-[(2-{4-hydroxy-5a,5b,8,8,11a,13b-hexamethyl-9-[(3,4,5-trihydroxyoxan-2-yl)oxy]-hexadecahydrocyclopenta[a]chrysen-3-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol

Description

2-({4,5-Dihydroxy-6-[(2-{4-hydroxy-1,2,9,14,18,18-hexamethyl-17-[(3,4,5-trihydroxyoxan-2-yl)oxy]pentacyclo[11.8.0.0²,¹⁰.0⁵,⁹.0¹⁴,¹⁹]Henicosan-6-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol belongs to the class of organic compounds known as triterpene saponins. These are glycosylated derivatives of triterpene sapogenins. The sapogenin moiety backbone is usually based on the oleanane, ursane, taraxastane, bauerane, lanostane, lupeol, lupane, dammarane, cycloartane, friedelane, hopane, 9b,19-cyclo-lanostane, cycloartane, or cycloartanol skeleton. 2-({4,5-dihydroxy-6-[(2-{4-hydroxy-5a,5b,8,8,11a,13b-hexamethyl-9-[(3,4,5-trihydroxyoxan-2-yl)oxy]-hexadecahydrocyclopenta[a]chrysen-3-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol is found in Glinus lotoides. 2-({4,5-Dihydroxy-6-[(2-{4-hydroxy-1,2,9,14,18,18-hexamethyl-17-[(3,4,5-trihydroxyoxan-2-yl)oxy]pentacyclo[11.8.0.0²,¹⁰.0⁵,⁹.0¹⁴,¹⁹]Henicosan-6-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol is an extremely weak basic (essentially neutral) compound (based on its pKa).

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1533004241508402D          

 64 71  0  0  0  0            999 V2000
    6.1454    2.0382    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.6880    1.4167    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.2306    0.7953    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.3094    1.9594    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    8.0901    1.6925    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.7115    2.2352    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    9.4921    1.9684    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   10.1136    2.5110    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   10.8942    2.2442    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    9.6514    1.1589    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   10.4320    0.8920    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   10.5913    0.0825    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.9699   -0.4601    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   10.1291   -1.2696    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.5077   -1.8122    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.6669   -2.6217    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   10.9097   -1.5364    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   11.0690   -2.3459    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   11.5312   -0.9938    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   12.3118   -1.2606    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   11.3719   -0.1843    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   11.9933    0.3583    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    9.0300    0.6162    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.1892   -0.1933    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    8.2493    0.8831    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.6279    0.3404    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.0666    0.8741    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.1403    0.0524    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.3816   -0.2717    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.8390    0.3498    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.4920   -0.3987    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.2623    1.0579    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.8607    1.7785    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.2840    2.4867    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.0358    1.7911    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.6125    1.0830    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.2109    1.8036    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.0141    0.3623    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5908   -0.3458    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.7659   -0.3333    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.3643    0.3874    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5394    0.4000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.9410   -0.3207    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.1161   -0.3082    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.2912   -0.2956    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1104    0.4250    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.9353    0.4376    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3587   -0.2705    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.9571   -0.9912    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3804   -1.6993    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2053   -1.6868    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.6286   -2.3949    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
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   -3.4318   -0.9535    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
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   -2.5851    0.4627    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
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   -0.4580    1.4271    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.4685    1.9434    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.1378    1.1206    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5611    1.8287    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.3860    1.8162    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.7876    1.0955    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.7139    1.9172    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  2  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  6  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  1  0  0  0  0
  7 10  1  0  0  0  0
 10 11  1  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  1  0  0  0  0
 15 16  1  0  0  0  0
 14 17  1  0  0  0  0
 17 18  1  0  0  0  0
 17 19  1  0  0  0  0
 19 20  1  0  0  0  0
 19 21  1  0  0  0  0
 12 21  1  0  0  0  0
 21 22  1  0  0  0  0
 10 23  1  0  0  0  0
 23 24  1  0  0  0  0
 23 25  1  0  0  0  0
  5 25  1  0  0  0  0
 25 26  1  0  0  0  0
  2 27  1  0  0  0  0
 27 28  1  0  0  0  0
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 27 32  1  0  0  0  0
 32 33  1  0  0  0  0
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 48 55  1  0  0  0  0
 55 56  1  0  0  0  0
 46 57  1  0  0  0  0
 57 58  1  0  0  0  0
 57 59  1  0  0  0  0
 57 60  1  0  0  0  0
 42 60  1  0  0  0  0
 60 61  1  0  0  0  0
 61 62  1  0  0  0  0
 62 63  1  0  0  0  0
 36 63  1  0  0  0  0
 41 63  1  0  0  0  0
 63 64  1  0  0  0  0
M  END

     RDKit          3D

144151  0  0  0  0  0  0  0  0999 V2000
    3.6506   -0.0631    1.5607 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5034   -0.4170    0.0946 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.6196   -1.9194   -0.0018 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.4045    0.2459   -0.7022 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.7345    0.0364   -0.4650 C   0  0  1  0  0  0  0  0  0  0  0  0
    6.2982   -0.4420   -1.6385 O   0  0  0  0  0  0  0  0  0  0  0  0
    7.6987   -0.4203   -1.6553 C   0  0  2  0  0  0  0  0  0  0  0  0
    8.0788   -1.7144   -2.3400 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.4225   -1.9010   -2.5168 O   0  0  0  0  0  0  0  0  0  0  0  0
    8.3043   -0.3140   -0.3226 C   0  0  1  0  0  0  0  0  0  0  0  0
    9.6839   -0.1201   -0.3760 O   0  0  0  0  0  0  0  0  0  0  0  0
   10.4068   -1.0161    0.3803 C   0  0  2  0  0  0  0  0  0  0  0  0
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M  END


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M  END
> <DATABASE_ID>
NP0298321

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC(C)(OC1OC(CO)C(OC2OC(CO)C(O)C(O)C2O)C(O)C1O)C1CCC2(C)C1C(O)CC1(C)C2CCC2C3(C)CCC(OC4OCC(O)C(O)C4O)C(C)(C)C3CCC12C

> <INCHI_IDENTIFIER>
InChI=1S/C47H80O17/c1-42(2)26-12-16-46(7)27(44(26,5)15-13-29(42)62-39-35(56)31(52)23(51)20-59-39)9-10-28-45(6)14-11-21(30(45)22(50)17-47(28,46)8)43(3,4)64-41-37(58)34(55)38(25(19-49)61-41)63-40-36(57)33(54)32(53)24(18-48)60-40/h21-41,48-58H,9-20H2,1-8H3

> <INCHI_KEY>
DETMLMKPOGLPGK-UHFFFAOYSA-N

> <FORMULA>
C47H80O17

> <MOLECULAR_WEIGHT>
917.14

> <EXACT_MASS>
916.539551116

> <JCHEM_ACCEPTOR_COUNT>
17

> <JCHEM_ATOM_COUNT>
144

> <JCHEM_AVERAGE_POLARIZABILITY>
101.58117199666438

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
11

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
2-({4,5-dihydroxy-6-[(2-{4-hydroxy-1,2,9,14,18,18-hexamethyl-17-[(3,4,5-trihydroxyoxan-2-yl)oxy]pentacyclo[11.8.0.0²,¹⁰.0⁵,⁹.0¹⁴,¹⁹]henicosan-6-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol

> <ALOGPS_LOGP>
1.09

> <JCHEM_LOGP>
0.41159454500000037

> <ALOGPS_LOGS>
-3.89

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
8

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
12.21588941538851

> <JCHEM_PKA_STRONGEST_ACIDIC>
11.766663281020962

> <JCHEM_PKA_STRONGEST_BASIC>
-3.5265806236668267

> <JCHEM_POLAR_SURFACE_AREA>
277.90999999999997

> <JCHEM_REFRACTIVITY>
225.75980000000007

> <JCHEM_ROTATABLE_BOND_COUNT>
9

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
1.19e-01 g/l

> <JCHEM_TRADITIONAL_IUPAC>
2-({4,5-dihydroxy-6-[(2-{4-hydroxy-1,2,9,14,18,18-hexamethyl-17-[(3,4,5-trihydroxyoxan-2-yl)oxy]pentacyclo[11.8.0.0²,¹⁰.0⁵,⁹.0¹⁴,¹⁹]henicosan-6-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 24-APR-15   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   24-APR-15         0                                  
HETATM    1  C   UNK     0      11.471   3.805   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      12.484   2.645   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      13.497   1.485   0.000  0.00  0.00           C+0
HETATM    4  O   UNK     0      13.644   3.658   0.000  0.00  0.00           O+0
HETATM    5  C   UNK     0      15.101   3.159   0.000  0.00  0.00           C+0
HETATM    6  O   UNK     0      16.261   4.172   0.000  0.00  0.00           O+0
HETATM    7  C   UNK     0      17.719   3.674   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      18.879   4.687   0.000  0.00  0.00           C+0
HETATM    9  O   UNK     0      20.336   4.189   0.000  0.00  0.00           O+0
HETATM   10  C   UNK     0      18.016   2.163   0.000  0.00  0.00           C+0
HETATM   11  O   UNK     0      19.473   1.665   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0      19.770   0.154   0.000  0.00  0.00           C+0
HETATM   13  O   UNK     0      18.610  -0.859   0.000  0.00  0.00           O+0
HETATM   14  C   UNK     0      18.908  -2.370   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      17.748  -3.383   0.000  0.00  0.00           C+0
HETATM   16  O   UNK     0      18.045  -4.894   0.000  0.00  0.00           O+0
HETATM   17  C   UNK     0      20.365  -2.868   0.000  0.00  0.00           C+0
HETATM   18  O   UNK     0      20.662  -4.379   0.000  0.00  0.00           O+0
HETATM   19  C   UNK     0      21.525  -1.855   0.000  0.00  0.00           C+0
HETATM   20  O   UNK     0      22.982  -2.353   0.000  0.00  0.00           O+0
HETATM   21  C   UNK     0      21.228  -0.344   0.000  0.00  0.00           C+0
HETATM   22  O   UNK     0      22.388   0.669   0.000  0.00  0.00           O+0
HETATM   23  C   UNK     0      16.856   1.150   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0      17.153  -0.361   0.000  0.00  0.00           O+0
HETATM   25  C   UNK     0      15.399   1.648   0.000  0.00  0.00           C+0
HETATM   26  O   UNK     0      14.239   0.635   0.000  0.00  0.00           O+0
HETATM   27  C   UNK     0      11.324   1.632   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0      11.462   0.098   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0      10.046  -0.507   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       9.033   0.653   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0       8.385  -0.744   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0       9.823   1.975   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0       9.073   3.320   0.000  0.00  0.00           C+0
HETATM   34  O   UNK     0       9.864   4.642   0.000  0.00  0.00           O+0
HETATM   35  C   UNK     0       7.534   3.343   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0       6.743   2.022   0.000  0.00  0.00           C+0
HETATM   37  C   UNK     0       5.994   3.367   0.000  0.00  0.00           C+0
HETATM   38  C   UNK     0       7.493   0.676   0.000  0.00  0.00           C+0
HETATM   39  C   UNK     0       6.703  -0.645   0.000  0.00  0.00           C+0
HETATM   40  C   UNK     0       5.163  -0.622   0.000  0.00  0.00           C+0
HETATM   41  C   UNK     0       4.413   0.723   0.000  0.00  0.00           C+0
HETATM   42  C   UNK     0       2.874   0.747   0.000  0.00  0.00           C+0
HETATM   43  C   UNK     0       3.623  -0.599   0.000  0.00  0.00           C+0
HETATM   44  C   UNK     0       2.083  -0.575   0.000  0.00  0.00           C+0
HETATM   45  C   UNK     0       0.543  -0.552   0.000  0.00  0.00           C+0
HETATM   46  C   UNK     0      -0.206   0.793   0.000  0.00  0.00           C+0
HETATM   47  O   UNK     0      -1.746   0.817   0.000  0.00  0.00           O+0
HETATM   48  C   UNK     0      -2.536  -0.505   0.000  0.00  0.00           C+0
HETATM   49  O   UNK     0      -1.787  -1.850   0.000  0.00  0.00           O+0
HETATM   50  C   UNK     0      -2.577  -3.172   0.000  0.00  0.00           C+0
HETATM   51  C   UNK     0      -4.117  -3.149   0.000  0.00  0.00           C+0
HETATM   52  O   UNK     0      -4.907  -4.470   0.000  0.00  0.00           O+0
HETATM   53  C   UNK     0      -4.866  -1.803   0.000  0.00  0.00           C+0
HETATM   54  O   UNK     0      -6.406  -1.780   0.000  0.00  0.00           O+0
HETATM   55  C   UNK     0      -4.076  -0.482   0.000  0.00  0.00           C+0
HETATM   56  O   UNK     0      -4.826   0.864   0.000  0.00  0.00           O+0
HETATM   57  C   UNK     0       0.584   2.115   0.000  0.00  0.00           C+0
HETATM   58  C   UNK     0      -0.855   2.664   0.000  0.00  0.00           C+0
HETATM   59  C   UNK     0       0.875   3.628   0.000  0.00  0.00           C+0
HETATM   60  C   UNK     0       2.124   2.092   0.000  0.00  0.00           C+0
HETATM   61  C   UNK     0       2.914   3.414   0.000  0.00  0.00           C+0
HETATM   62  C   UNK     0       4.454   3.390   0.000  0.00  0.00           C+0
HETATM   63  C   UNK     0       5.204   2.045   0.000  0.00  0.00           C+0
HETATM   64  C   UNK     0       5.066   3.579   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3    4   27                                             
CONECT    3    2                                                            
CONECT    4    2    5                                                       
CONECT    5    4    6   25                                                  
CONECT    6    5    7                                                       
CONECT    7    6    8   10                                                  
CONECT    8    7    9                                                       
CONECT    9    8                                                            
CONECT   10    7   11   23                                                  
CONECT   11   10   12                                                       
CONECT   12   11   13   21                                                  
CONECT   13   12   14                                                       
CONECT   14   13   15   17                                                  
CONECT   15   14   16                                                       
CONECT   16   15                                                            
CONECT   17   14   18   19                                                  
CONECT   18   17                                                            
CONECT   19   17   20   21                                                  
CONECT   20   19                                                            
CONECT   21   19   12   22                                                  
CONECT   22   21                                                            
CONECT   23   10   24   25                                                  
CONECT   24   23                                                            
CONECT   25   23    5   26                                                  
CONECT   26   25                                                            
CONECT   27    2   28   32                                                  
CONECT   28   27   29                                                       
CONECT   29   28   30                                                       
CONECT   30   29   31   32   38                                             
CONECT   31   30                                                            
CONECT   32   30   27   33                                                  
CONECT   33   32   34   35                                                  
CONECT   34   33                                                            
CONECT   35   33   36                                                       
CONECT   36   35   37   38   63                                             
CONECT   37   36                                                            
CONECT   38   36   30   39                                                  
CONECT   39   38   40                                                       
CONECT   40   39   41                                                       
CONECT   41   40   42   63                                                  
CONECT   42   41   43   44   60                                             
CONECT   43   42                                                            
CONECT   44   42   45                                                       
CONECT   45   44   46                                                       
CONECT   46   45   47   57                                                  
CONECT   47   46   48                                                       
CONECT   48   47   49   55                                                  
CONECT   49   48   50                                                       
CONECT   50   49   51                                                       
CONECT   51   50   52   53                                                  
CONECT   52   51                                                            
CONECT   53   51   54   55                                                  
CONECT   54   53                                                            
CONECT   55   53   48   56                                                  
CONECT   56   55                                                            
CONECT   57   46   58   59   60                                             
CONECT   58   57                                                            
CONECT   59   57                                                            
CONECT   60   57   42   61                                                  
CONECT   61   60   62                                                       
CONECT   62   61   63                                                       
CONECT   63   62   36   41   64                                             
CONECT   64   63                                                            
MASTER        0    0    0    0    0    0    0    0   64    0  142    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₄₇H₈₀O₁₇

Average Mass

917.1400 Da

Monoisotopic Mass

916.53955 Da

IUPAC Name

2-({4,5-dihydroxy-6-[(2-{4-hydroxy-1,2,9,14,18,18-hexamethyl-17-[(3,4,5-trihydroxyoxan-2-yl)oxy]pentacyclo[11.8.0.0²,¹⁰.0⁵,⁹.0¹⁴,¹⁹]henicosan-6-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol

Traditional Name

CAS Registry Number

Not Available

SMILES

CC(C)(OC1OC(CO)C(OC2OC(CO)C(O)C(O)C2O)C(O)C1O)C1CCC2(C)C1C(O)CC1(C)C2CCC2C3(C)CCC(OC4OCC(O)C(O)C4O)C(C)(C)C3CCC12C

InChI Identifier

InChI=1S/C47H80O17/c1-42(2)26-12-16-46(7)27(44(26,5)15-13-29(42)62-39-35(56)31(52)23(51)20-59-39)9-10-28-45(6)14-11-21(30(45)22(50)17-47(28,46)8)43(3,4)64-41-37(58)34(55)38(25(19-49)61-41)63-40-36(57)33(54)32(53)24(18-48)60-40/h21-41,48-58H,9-20H2,1-8H3

InChI Key

DETMLMKPOGLPGK-UHFFFAOYSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Glinus lotoides	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as triterpene saponins. These are glycosylated derivatives of triterpene sapogenins. The sapogenin moiety backbone is usually based on the oleanane, ursane, taraxastane, bauerane, lanostane, lupeol, lupane, dammarane, cycloartane, friedelane, hopane, 9b,19-cyclo-lanostane, cycloartane, or cycloartanol skeleton.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Terpene glycosides

Direct Parent

Triterpene saponins

Alternative Parents

Substituents

Triterpene saponin
Hopane-skeleton
Triterpenoid
12-hydroxysteroid
Hydroxysteroid
Steroid
Disaccharide
Glycosyl compound
O-glycosyl compound
Oxane
Cyclic alcohol
Secondary alcohol
Polyol
Oxacycle
Acetal
Organoheterocyclic compound
Organooxygen compound
Hydrocarbon derivative
Organic oxygen compound
Alcohol
Primary alcohol
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	1.09	ALOGPS
logP	0.41	ChemAxon
logS	-3.9	ALOGPS
pKa (Strongest Acidic)	11.77	ChemAxon
pKa (Strongest Basic)	-3.5	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	17	ChemAxon
Hydrogen Donor Count	11	ChemAxon
Polar Surface Area	277.91 Å²	ChemAxon
Rotatable Bond Count	9	ChemAxon
Refractivity	225.76 m³·mol⁻¹	ChemAxon
Polarizability	101.58 Å³	ChemAxon
Number of Rings	8	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

Not Available

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for 2-({4,5-dihydroxy-6-[(2-{4-hydroxy-5a,5b,8,8,11a,13b-hexamethyl-9-[(3,4,5-trihydroxyoxan-2-yl)oxy]-hexadecahydrocyclopenta[a]chrysen-3-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol (NP0298321)

MOL for NP0298321 (2-({4,5-dihydroxy-6-[(2-{4-hydroxy-5a,5b,8,8,11a,13b-hexamethyl-9-[(3,4,5-trihydroxyoxan-2-yl)oxy]-hexadecahydrocyclopenta[a]chrysen-3-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol)

3D MOL for NP0298321 (2-({4,5-dihydroxy-6-[(2-{4-hydroxy-5a,5b,8,8,11a,13b-hexamethyl-9-[(3,4,5-trihydroxyoxan-2-yl)oxy]-hexadecahydrocyclopenta[a]chrysen-3-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol)

3D SDF for NP0298321 (2-({4,5-dihydroxy-6-[(2-{4-hydroxy-5a,5b,8,8,11a,13b-hexamethyl-9-[(3,4,5-trihydroxyoxan-2-yl)oxy]-hexadecahydrocyclopenta[a]chrysen-3-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol)

3D-SDF for NP0298321 (2-({4,5-dihydroxy-6-[(2-{4-hydroxy-5a,5b,8,8,11a,13b-hexamethyl-9-[(3,4,5-trihydroxyoxan-2-yl)oxy]-hexadecahydrocyclopenta[a]chrysen-3-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol)

PDB for NP0298321 (2-({4,5-dihydroxy-6-[(2-{4-hydroxy-5a,5b,8,8,11a,13b-hexamethyl-9-[(3,4,5-trihydroxyoxan-2-yl)oxy]-hexadecahydrocyclopenta[a]chrysen-3-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol)

3D PDB for NP0298321 (2-({4,5-dihydroxy-6-[(2-{4-hydroxy-5a,5b,8,8,11a,13b-hexamethyl-9-[(3,4,5-trihydroxyoxan-2-yl)oxy]-hexadecahydrocyclopenta[a]chrysen-3-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol)

SMILES for NP0298321 (2-({4,5-dihydroxy-6-[(2-{4-hydroxy-5a,5b,8,8,11a,13b-hexamethyl-9-[(3,4,5-trihydroxyoxan-2-yl)oxy]-hexadecahydrocyclopenta[a]chrysen-3-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol)

INCHI for NP0298321 (2-({4,5-dihydroxy-6-[(2-{4-hydroxy-5a,5b,8,8,11a,13b-hexamethyl-9-[(3,4,5-trihydroxyoxan-2-yl)oxy]-hexadecahydrocyclopenta[a]chrysen-3-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol)

Structure for NP0298321 (2-({4,5-dihydroxy-6-[(2-{4-hydroxy-5a,5b,8,8,11a,13b-hexamethyl-9-[(3,4,5-trihydroxyoxan-2-yl)oxy]-hexadecahydrocyclopenta[a]chrysen-3-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol)

3D Structure for NP0298321 (2-({4,5-dihydroxy-6-[(2-{4-hydroxy-5a,5b,8,8,11a,13b-hexamethyl-9-[(3,4,5-trihydroxyoxan-2-yl)oxy]-hexadecahydrocyclopenta[a]chrysen-3-yl}propan-2-yl)oxy]-2-(hydroxymethyl)oxan-3-yl}oxy)-6-(hydroxymethyl)oxane-3,4,5-triol)