NP-MRD: Showing NP-Card for (2e)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-2,5,5a,8,9,9b-hexahydro-1h-spiro[cyclopenta[a]naphthalene-3,1'-cyclopentan]-2'-yl}-2-methyl-4-oxohept-2-enoic acid (NP0293632)

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Record Information

Version

2.0

Created at

2022-09-10 01:44:32 UTC

Updated at

2022-09-10 01:44:32 UTC

NP-MRD ID

NP0293632

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(2e)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-2,5,5a,8,9,9b-hexahydro-1h-spiro[cyclopenta[a]naphthalene-3,1'-cyclopentan]-2'-yl}-2-methyl-4-oxohept-2-enoic acid

Description

(2e)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-2,5,5a,8,9,9b-hexahydro-1h-spiro[cyclopenta[a]naphthalene-3,1'-cyclopentan]-2'-yl}-2-methyl-4-oxohept-2-enoic acid is found in Abies mariesii.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309102203442D          

 34 37  0  0  0  0            999 V2000
    4.4494    1.9267    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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M  END

     RDKit          3D

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M  END


  Mrv1652309102203442D          

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 19 20  1  0  0  0  0
 20 21  1  0  0  0  0
 21 22  1  0  0  0  0
 18 22  1  0  0  0  0
 22 23  2  0  0  0  0
 23 24  1  0  0  0  0
 24 25  1  0  0  0  0
 25 26  1  0  0  0  0
 26 27  1  0  0  0  0
 26 28  1  0  0  0  0
 26 29  1  0  0  0  0
 29 30  2  0  0  0  0
 29 31  1  0  0  0  0
 31 32  1  0  0  0  0
 32 33  1  0  0  0  0
 21 33  1  0  0  0  0
 25 33  1  0  0  0  0
 33 34  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0293632

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC(CC(=O)\C=C(/C)C(O)=O)C1(C)CCC(=C)C11CCC2C1=CCC1C(C)(C)C(=O)CCC21C

> <INCHI_IDENTIFIER>
InChI=1S/C30H42O4/c1-18(26(33)34)16-21(31)17-20(3)29(7)14-10-19(2)30(29)15-11-22-23(30)8-9-24-27(4,5)25(32)12-13-28(22,24)6/h8,16,20,22,24H,2,9-15,17H2,1,3-7H3,(H,33,34)/b18-16+

> <INCHI_KEY>
DEWPUKVVTOOKSM-FBMGVBCBSA-N

> <FORMULA>
C30H42O4

> <MOLECULAR_WEIGHT>
466.662

> <EXACT_MASS>
466.308309832

> <JCHEM_ACCEPTOR_COUNT>
4

> <JCHEM_ATOM_COUNT>
76

> <JCHEM_AVERAGE_POLARIZABILITY>
53.73392421515462

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
1

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(2E)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-1,2,5,5a,6,7,8,9,9a,9b-decahydrospiro[cyclopenta[a]naphthalene-3,1'-cyclopentane]-2'-yl}-2-methyl-4-oxohept-2-enoic acid

> <JCHEM_LOGP>
6.338432260333335

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
-1

> <JCHEM_PKA>
19.87024693606942

> <JCHEM_PKA_STRONGEST_ACIDIC>
3.7910311938854795

> <JCHEM_PKA_STRONGEST_BASIC>
-6.786203484507554

> <JCHEM_POLAR_SURFACE_AREA>
71.44

> <JCHEM_REFRACTIVITY>
136.10179999999997

> <JCHEM_ROTATABLE_BOND_COUNT>
5

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(2E)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-2,5,5a,8,9,9b-hexahydro-1H-spiro[cyclopenta[a]naphthalene-3,1'-cyclopentane]-2'-yl}-2-methyl-4-oxohept-2-enoic acid

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 10-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   10-SEP-22         0                                  
HETATM    1  C   UNK     0       8.306   3.596   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       8.108   2.069   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       9.227   1.012   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       8.567  -0.380   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       7.040  -0.182   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       5.505  -0.306   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       7.003  -1.722   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       5.651  -2.460   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       8.318  -2.524   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       8.281  -4.063   0.000  0.00  0.00           C+0
HETATM   11  O   UNK     0       6.929  -4.801   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0       9.596  -4.865   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       9.559  -6.404   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       8.207  -7.142   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      10.874  -7.206   0.000  0.00  0.00           C+0
HETATM   16  O   UNK     0      10.837  -8.746   0.000  0.00  0.00           O+0
HETATM   17  O   UNK     0      12.225  -6.468   0.000  0.00  0.00           O+0
HETATM   18  C   UNK     0       6.756   1.331   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       6.472   2.845   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       4.945   3.043   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       4.285   1.651   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       5.404   0.594   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       5.048  -0.905   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       3.572  -1.345   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0       2.453  -0.288   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0       0.977  -0.728   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       1.668  -2.105   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0      -0.258  -1.647   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0      -0.142   0.329   0.000  0.00  0.00           C+0
HETATM   30  O   UNK     0      -1.618  -0.111   0.000  0.00  0.00           O+0
HETATM   31  C   UNK     0       0.214   1.828   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0       1.690   2.268   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0       2.809   1.211   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0       3.166   2.709   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3   18                                                  
CONECT    3    2    4                                                       
CONECT    4    3    5                                                       
CONECT    5    4    6    7   18                                             
CONECT    6    5                                                            
CONECT    7    5    8    9                                                  
CONECT    8    7                                                            
CONECT    9    7   10                                                       
CONECT   10    9   11   12                                                  
CONECT   11   10                                                            
CONECT   12   10   13                                                       
CONECT   13   12   14   15                                                  
CONECT   14   13                                                            
CONECT   15   13   16   17                                                  
CONECT   16   15                                                            
CONECT   17   15                                                            
CONECT   18    5    2   19   22                                             
CONECT   19   18   20                                                       
CONECT   20   19   21                                                       
CONECT   21   20   22   33                                                  
CONECT   22   21   18   23                                                  
CONECT   23   22   24                                                       
CONECT   24   23   25                                                       
CONECT   25   24   26   33                                                  
CONECT   26   25   27   28   29                                             
CONECT   27   26                                                            
CONECT   28   26                                                            
CONECT   29   26   30   31                                                  
CONECT   30   29                                                            
CONECT   31   29   32                                                       
CONECT   32   31   33                                                       
CONECT   33   32   21   25   34                                             
CONECT   34   33                                                            
MASTER        0    0    0    0    0    0    0    0   34    0   74    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₃₀H₄₂O₄

Average Mass

466.6620 Da

Monoisotopic Mass

466.30831 Da

IUPAC Name

(2E)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-1,2,5,5a,6,7,8,9,9a,9b-decahydrospiro[cyclopenta[a]naphthalene-3,1'-cyclopentane]-2'-yl}-2-methyl-4-oxohept-2-enoic acid

Traditional Name

(2E)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-2,5,5a,8,9,9b-hexahydro-1H-spiro[cyclopenta[a]naphthalene-3,1'-cyclopentane]-2'-yl}-2-methyl-4-oxohept-2-enoic acid

CAS Registry Number

Not Available

SMILES

CC(CC(=O)\C=C(/C)C(O)=O)C1(C)CCC(=C)C11CCC2C1=CCC1C(C)(C)C(=O)CCC21C

InChI Identifier

InChI=1S/C30H42O4/c1-18(26(33)34)16-21(31)17-20(3)29(7)14-10-19(2)30(29)15-11-22-23(30)8-9-24-27(4,5)25(32)12-13-28(22,24)6/h8,16,20,22,24H,2,9-15,17H2,1,3-7H3,(H,33,34)/b18-16+

InChI Key

DEWPUKVVTOOKSM-FBMGVBCBSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Abies mariesii	LOTUS Database	35616633

Chemical Taxonomy

Classification

Not classified

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	6.34	ChemAxon
pKa (Strongest Acidic)	3.79	ChemAxon
pKa (Strongest Basic)	-6.8	ChemAxon
Physiological Charge	-1	ChemAxon
Hydrogen Acceptor Count	4	ChemAxon
Hydrogen Donor Count	1	ChemAxon
Polar Surface Area	71.44 Å²	ChemAxon
Rotatable Bond Count	5	ChemAxon
Refractivity	136.1 m³·mol⁻¹	ChemAxon
Polarizability	53.73 Å³	ChemAxon
Number of Rings	4	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (2e)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-2,5,5a,8,9,9b-hexahydro-1h-spiro[cyclopenta[a]naphthalene-3,1'-cyclopentan]-2'-yl}-2-methyl-4-oxohept-2-enoic acid (NP0293632)

MOL for NP0293632 ((2e)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-2,5,5a,8,9,9b-hexahydro-1h-spiro[cyclopenta[a]naphthalene-3,1'-cyclopentan]-2'-yl}-2-methyl-4-oxohept-2-enoic acid)

3D MOL for NP0293632 ((2e)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-2,5,5a,8,9,9b-hexahydro-1h-spiro[cyclopenta[a]naphthalene-3,1'-cyclopentan]-2'-yl}-2-methyl-4-oxohept-2-enoic acid)

3D SDF for NP0293632 ((2e)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-2,5,5a,8,9,9b-hexahydro-1h-spiro[cyclopenta[a]naphthalene-3,1'-cyclopentan]-2'-yl}-2-methyl-4-oxohept-2-enoic acid)

3D-SDF for NP0293632 ((2e)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-2,5,5a,8,9,9b-hexahydro-1h-spiro[cyclopenta[a]naphthalene-3,1'-cyclopentan]-2'-yl}-2-methyl-4-oxohept-2-enoic acid)

PDB for NP0293632 ((2e)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-2,5,5a,8,9,9b-hexahydro-1h-spiro[cyclopenta[a]naphthalene-3,1'-cyclopentan]-2'-yl}-2-methyl-4-oxohept-2-enoic acid)

3D PDB for NP0293632 ((2e)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-2,5,5a,8,9,9b-hexahydro-1h-spiro[cyclopenta[a]naphthalene-3,1'-cyclopentan]-2'-yl}-2-methyl-4-oxohept-2-enoic acid)

SMILES for NP0293632 ((2e)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-2,5,5a,8,9,9b-hexahydro-1h-spiro[cyclopenta[a]naphthalene-3,1'-cyclopentan]-2'-yl}-2-methyl-4-oxohept-2-enoic acid)

INCHI for NP0293632 ((2e)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-2,5,5a,8,9,9b-hexahydro-1h-spiro[cyclopenta[a]naphthalene-3,1'-cyclopentan]-2'-yl}-2-methyl-4-oxohept-2-enoic acid)

Structure for NP0293632 ((2e)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-2,5,5a,8,9,9b-hexahydro-1h-spiro[cyclopenta[a]naphthalene-3,1'-cyclopentan]-2'-yl}-2-methyl-4-oxohept-2-enoic acid)

3D Structure for NP0293632 ((2e)-6-{2',6,6,9a-tetramethyl-5'-methylidene-7-oxo-2,5,5a,8,9,9b-hexahydro-1h-spiro[cyclopenta[a]naphthalene-3,1'-cyclopentan]-2'-yl}-2-methyl-4-oxohept-2-enoic acid)