Record Information |
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Version | 2.0 |
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Created at | 2022-09-10 01:06:17 UTC |
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Updated at | 2022-09-10 01:06:17 UTC |
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NP-MRD ID | NP0293210 |
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Secondary Accession Numbers | None |
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Natural Product Identification |
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Common Name | (1r,3r,4s,4as,8r,8as)-3,4,8,8a-tetramethyl-7-oxo-4-{[(2-oxochromen-7-yl)oxy]methyl}-hexahydro-1h-naphthalen-1-yl acetate |
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Description | Microlobin belongs to the class of organic compounds known as coumarins and derivatives. These are polycyclic aromatic compounds containing a 1-benzopyran moiety with a ketone group at the C2 carbon atom (1-benzopyran-2-one). (1r,3r,4s,4as,8r,8as)-3,4,8,8a-tetramethyl-7-oxo-4-{[(2-oxochromen-7-yl)oxy]methyl}-hexahydro-1h-naphthalen-1-yl acetate is found in Ferula assa-foetida and Ferula microloba. (1r,3r,4s,4as,8r,8as)-3,4,8,8a-tetramethyl-7-oxo-4-{[(2-oxochromen-7-yl)oxy]methyl}-hexahydro-1h-naphthalen-1-yl acetate was first documented in 2016 (PMID: 27463028). Based on a literature review very few articles have been published on Microlobin. |
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Structure | C[C@@H]1C[C@@H](OC(C)=O)[C@]2(C)[C@@H](C)C(=O)CC[C@H]2[C@@]1(C)COC1=CC=C2C=CC(=O)OC2=C1 InChI=1S/C26H32O6/c1-15-12-23(31-17(3)27)26(5)16(2)20(28)9-10-22(26)25(15,4)14-30-19-8-6-18-7-11-24(29)32-21(18)13-19/h6-8,11,13,15-16,22-23H,9-10,12,14H2,1-5H3/t15-,16+,22+,23-,25+,26-/m1/s1 |
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Synonyms | Not Available |
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Chemical Formula | C26H32O6 |
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Average Mass | 440.5360 Da |
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Monoisotopic Mass | 440.21989 Da |
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IUPAC Name | (1R,3R,4S,4aS,8R,8aS)-3,4,8,8a-tetramethyl-7-oxo-4-{[(2-oxo-2H-chromen-7-yl)oxy]methyl}-decahydronaphthalen-1-yl acetate |
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Traditional Name | (1R,3R,4S,4aS,8R,8aS)-3,4,8,8a-tetramethyl-7-oxo-4-{[(2-oxochromen-7-yl)oxy]methyl}-hexahydro-1H-naphthalen-1-yl acetate |
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CAS Registry Number | Not Available |
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SMILES | C[C@@H]1C[C@@H](OC(C)=O)[C@]2(C)[C@@H](C)C(=O)CC[C@H]2[C@@]1(C)COC1=CC=C2C=CC(=O)OC2=C1 |
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InChI Identifier | InChI=1S/C26H32O6/c1-15-12-23(31-17(3)27)26(5)16(2)20(28)9-10-22(26)25(15,4)14-30-19-8-6-18-7-11-24(29)32-21(18)13-19/h6-8,11,13,15-16,22-23H,9-10,12,14H2,1-5H3/t15-,16+,22+,23-,25+,26-/m1/s1 |
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InChI Key | PIGAODQEDMJGTF-BXTCTJPFSA-N |
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Experimental Spectra |
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| Not Available | Predicted Spectra |
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| Spectrum Type | Description | Depositor ID | Depositor Organization | Depositor | Deposition Date | View |
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1D NMR | 13C NMR Spectrum (1D, 25 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 100 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 252 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 1000 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 50 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 200 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 75 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 300 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 101 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 400 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 126 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 500 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 151 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 600 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 176 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 700 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 201 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 800 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 226 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 900 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum |
| Chemical Shift Submissions |
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| Not Available | Species |
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Species of Origin | |
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Chemical Taxonomy |
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Description | Belongs to the class of organic compounds known as coumarins and derivatives. These are polycyclic aromatic compounds containing a 1-benzopyran moiety with a ketone group at the C2 carbon atom (1-benzopyran-2-one). |
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Kingdom | Organic compounds |
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Super Class | Phenylpropanoids and polyketides |
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Class | Coumarins and derivatives |
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Sub Class | Not Available |
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Direct Parent | Coumarins and derivatives |
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Alternative Parents | |
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Substituents | - Coumarin
- Benzopyran
- 1-benzopyran
- Alkyl aryl ether
- Pyranone
- Pyran
- Benzenoid
- Heteroaromatic compound
- Carboxylic acid ester
- Ketone
- Lactone
- Cyclic ketone
- Monocarboxylic acid or derivatives
- Ether
- Carboxylic acid derivative
- Oxacycle
- Organoheterocyclic compound
- Organic oxide
- Hydrocarbon derivative
- Organic oxygen compound
- Organooxygen compound
- Carbonyl group
- Aromatic heteropolycyclic compound
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Molecular Framework | Aromatic heteropolycyclic compounds |
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External Descriptors | Not Available |
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Physical Properties |
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State | Not Available |
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Experimental Properties | Property | Value | Reference |
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Melting Point | Not Available | Not Available | Boiling Point | Not Available | Not Available | Water Solubility | Not Available | Not Available | LogP | Not Available | Not Available |
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Predicted Properties | |
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