NP-MRD: Showing NP-Card for (1r,2e,4s,6z,9z,11r)-4-[(3s)-3,4-dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoate (NP0291929)

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Record Information

Version

2.0

Created at

2022-09-09 23:12:52 UTC

Updated at

2022-09-09 23:12:52 UTC

NP-MRD ID

NP0291929

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1r,2e,4s,6z,9z,11r)-4-[(3s)-3,4-dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoate

Description

(1R,4S,6Z,9Z,11R)-4-[(3S)-3,4-dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoate belongs to the class of organic compounds known as diterpenoids. These are terpene compounds formed by four isoprene units. Based on a literature review very few articles have been published on (1R,4S,6Z,9Z,11R)-4-[(3S)-3,4-dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoate.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309102201122D          

 32 32  0  0  1  0            999 V2000
    1.5477    4.7035    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.7093    3.8944    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4907    3.6299    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.0895    3.3500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.2511    2.5410    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.0325    2.2764    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.6313    1.9965    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7929    1.1875    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.2334    0.5812    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.6371   -0.1383    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.4770   -1.0268    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.2929   -0.7305    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0414   -1.7274    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.4303   -2.4550    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0053   -3.1556    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.8298   -3.1286    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.3836   -3.8831    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7726   -4.6107    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3439   -4.2721    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.1112   -3.4942    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.0833   -1.5863    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.8710   -1.3410    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8401   -0.2909    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5374    0.1500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.2679   -0.2336    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.0524   -0.5362    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    3.0215    0.5140    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4152    1.0735    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    1.8426    1.6111    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.3787    1.6513    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  2  4  2  0  0  0  0
  4  5  1  0  0  0  0
  5  6  2  0  0  0  0
  5  7  1  0  0  0  0
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  8  9  1  0  0  0  0
  9 10  2  0  0  0  0
 10 11  1  0  0  0  0
 11 12  1  1  0  0  0
 11 13  1  6  0  0  0
 13 14  1  0  0  0  0
 14 15  1  0  0  0  0
 15 16  1  1  0  0  0
 15 17  1  0  0  0  0
 17 18  1  0  0  0  0
 17 19  1  0  0  0  0
 17 20  1  0  0  0  0
 11 21  1  0  0  0  0
 21 22  1  0  0  0  0
 22 23  2  0  0  0  0
 23 24  1  0  0  0  0
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 23 26  1  0  0  0  0
 26 27  2  0  0  0  0
 26 28  1  0  0  0  0
 28 29  2  0  0  0  0
 29 30  1  0  0  0  0
  8 30  1  0  0  0  0
 30 31  1  1  0  0  0
 30 32  1  6  0  0  0
M  END

     RDKit          3D

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   -3.1678    0.5325    3.4576 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.3474   -1.4012    2.5255 C   0  0  0  0  0  0  0  0  0  0  0  0
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   -1.3608    2.1910   -2.0488 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.5298    3.1851   -1.7890 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1457    4.0039   -3.0187 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.2300    3.9718   -3.2373 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0458    3.4835   -0.4749 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.3559    4.7445   -0.4134 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.1379    2.8625    0.7846 C   0  0  0  0  0  0  0  0  0  0  0  0
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M  END


  Mrv1652309102201122D          

 32 32  0  0  1  0            999 V2000
    1.5477    4.7035    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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M  END
> <DATABASE_ID>
NP0291929

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC(C)=CC(=O)O[C@@H]1\C=C\[C@@](C)(CC[C@H](O)C(C)(C)O)C\C=C(CO)/C(=O)/C=C\[C@@]1(C)O

> <INCHI_IDENTIFIER>
InChI=1S/C25H38O7/c1-17(2)15-22(29)32-21-10-13-24(5,12-9-20(28)23(3,4)30)11-7-18(16-26)19(27)8-14-25(21,6)31/h7-8,10,13-15,20-21,26,28,30-31H,9,11-12,16H2,1-6H3/b13-10+,14-8-,18-7-/t20-,21+,24+,25+/m0/s1

> <INCHI_KEY>
GFAQUYIQNBAVAL-LFNYBURLSA-N

> <FORMULA>
C25H38O7

> <MOLECULAR_WEIGHT>
450.572

> <EXACT_MASS>
450.261753564

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
70

> <JCHEM_AVERAGE_POLARIZABILITY>
48.75680242679923

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
4

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
1

> <JCHEM_IUPAC>
(1R,2E,4S,6Z,9Z,11R)-4-[(3S)-3,4-dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoate

> <JCHEM_LOGP>
2.7574013970000006

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
1

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
13.980980298499283

> <JCHEM_PKA_STRONGEST_ACIDIC>
13.357688606606303

> <JCHEM_PKA_STRONGEST_BASIC>
-2.8132345124173908

> <JCHEM_POLAR_SURFACE_AREA>
124.29

> <JCHEM_REFRACTIVITY>
126.9772

> <JCHEM_ROTATABLE_BOND_COUNT>
8

> <JCHEM_RULE_OF_FIVE>
1

> <JCHEM_TRADITIONAL_IUPAC>
(1R,2E,4S,6Z,9Z,11R)-4-[(3S)-3,4-dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 10-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   10-SEP-22         0                                  
HETATM    1  C   UNK     0       2.889   8.780   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       3.191   7.270   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       4.649   6.776   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       2.034   6.253   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       2.335   4.743   0.000  0.00  0.00           C+0
HETATM    6  O   UNK     0       3.794   4.249   0.000  0.00  0.00           O+0
HETATM    7  O   UNK     0       1.178   3.727   0.000  0.00  0.00           O+0
HETATM    8  C   UNK     0       1.480   2.217   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       0.436   1.085   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       1.189  -0.258   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       0.890  -1.917   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      -0.547  -1.364   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       0.077  -3.224   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       0.803  -4.583   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      -0.010  -5.890   0.000  0.00  0.00           C+0
HETATM   16  O   UNK     0      -1.549  -5.840   0.000  0.00  0.00           O+0
HETATM   17  C   UNK     0       0.716  -7.249   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       1.442  -8.607   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0      -0.642  -7.975   0.000  0.00  0.00           C+0
HETATM   20  O   UNK     0       2.074  -6.523   0.000  0.00  0.00           O+0
HETATM   21  C   UNK     0       2.022  -2.961   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       3.493  -2.503   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       5.302  -0.543   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       6.603   0.280   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0       7.967  -0.436   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0       3.831  -1.001   0.000  0.00  0.00           C+0
HETATM   27  O   UNK     0       2.529  -1.824   0.000  0.00  0.00           O+0
HETATM   28  C   UNK     0       5.640   0.959   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       4.508   2.004   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       2.879   1.573   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0       3.439   3.007   0.000  0.00  0.00           C+0
HETATM   32  O   UNK     0       2.574   3.082   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3    4                                                  
CONECT    3    2                                                            
CONECT    4    2    5                                                       
CONECT    5    4    6    7                                                  
CONECT    6    5                                                            
CONECT    7    5    8                                                       
CONECT    8    7    9   30                                                  
CONECT    9    8   10                                                       
CONECT   10    9   11                                                       
CONECT   11   10   12   13   21                                             
CONECT   12   11                                                            
CONECT   13   11   14                                                       
CONECT   14   13   15                                                       
CONECT   15   14   16   17                                                  
CONECT   16   15                                                            
CONECT   17   15   18   19   20                                             
CONECT   18   17                                                            
CONECT   19   17                                                            
CONECT   20   17                                                            
CONECT   21   11   22                                                       
CONECT   22   21   23                                                       
CONECT   23   22   24   26                                                  
CONECT   24   23   25                                                       
CONECT   25   24                                                            
CONECT   26   23   27   28                                                  
CONECT   27   26                                                            
CONECT   28   26   29                                                       
CONECT   29   28   30                                                       
CONECT   30   29    8   31   32                                             
CONECT   31   30                                                            
CONECT   32   30                                                            
MASTER        0    0    0    0    0    0    0    0   32    0   64    0
END

View in JSmol

Synonyms

Value	Source
(1R,4S,6Z,9Z,11R)-4-[(3S)-3,4-Dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoic acid	Generator

Chemical Formula

C₂₅H₃₈O₇

Average Mass

450.5720 Da

Monoisotopic Mass

450.26175 Da

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

CC(C)=CC(=O)O[C@@H]1\C=C\[C@@](C)(CC[C@H](O)C(C)(C)O)C\C=C(CO)/C(=O)/C=C\[C@@]1(C)O

InChI Identifier

InChI=1S/C25H38O7/c1-17(2)15-22(29)32-21-10-13-24(5,12-9-20(28)23(3,4)30)11-7-18(16-26)19(27)8-14-25(21,6)31/h7-8,10,13-15,20-21,26,28,30-31H,9,11-12,16H2,1-6H3/b13-10+,14-8-,18-7-/t20-,21+,24+,25+/m0/s1

InChI Key

GFAQUYIQNBAVAL-LFNYBURLSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Not Available

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as diterpenoids. These are terpene compounds formed by four isoprene units.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Diterpenoids

Direct Parent

Diterpenoids

Alternative Parents

Substituents

Diterpenoid
Fatty acid ester
Fatty acyl
Alpha,beta-unsaturated carboxylic ester
Enoate ester
Tertiary alcohol
Cyclic ketone
Secondary alcohol
Ketone
Carboxylic acid ester
Monocarboxylic acid or derivatives
Carboxylic acid derivative
Organic oxygen compound
Organic oxide
Hydrocarbon derivative
Primary alcohol
Organooxygen compound
Carbonyl group
Alcohol
Aliphatic homomonocyclic compound

Molecular Framework

Aliphatic homomonocyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

163008330

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (1r,2e,4s,6z,9z,11r)-4-[(3s)-3,4-dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoate (NP0291929)

MOL for NP0291929 ((1r,2e,4s,6z,9z,11r)-4-[(3s)-3,4-dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoate)

3D MOL for NP0291929 ((1r,2e,4s,6z,9z,11r)-4-[(3s)-3,4-dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoate)

3D SDF for NP0291929 ((1r,2e,4s,6z,9z,11r)-4-[(3s)-3,4-dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoate)

3D-SDF for NP0291929 ((1r,2e,4s,6z,9z,11r)-4-[(3s)-3,4-dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoate)

PDB for NP0291929 ((1r,2e,4s,6z,9z,11r)-4-[(3s)-3,4-dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoate)

3D PDB for NP0291929 ((1r,2e,4s,6z,9z,11r)-4-[(3s)-3,4-dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoate)

SMILES for NP0291929 ((1r,2e,4s,6z,9z,11r)-4-[(3s)-3,4-dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoate)

INCHI for NP0291929 ((1r,2e,4s,6z,9z,11r)-4-[(3s)-3,4-dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoate)

Structure for NP0291929 ((1r,2e,4s,6z,9z,11r)-4-[(3s)-3,4-dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoate)

3D Structure for NP0291929 ((1r,2e,4s,6z,9z,11r)-4-[(3s)-3,4-dihydroxy-4-methylpentyl]-11-hydroxy-7-(hydroxymethyl)-4,11-dimethyl-8-oxocycloundeca-2,6,9-trien-1-yl 3-methylbut-2-enoate)