Record Information |
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Version | 1.0 |
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Created at | 2022-09-09 22:20:37 UTC |
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Updated at | 2022-09-09 22:20:37 UTC |
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NP-MRD ID | NP0291302 |
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Secondary Accession Numbers | None |
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Natural Product Identification |
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Common Name | (6r)-3,4,5-trihydroxy-6-[(9s)-2,5,9-trihydroxy-7-methyl-10-oxo-4-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}anthracen-9-yl]oxan-2-yl benzoate |
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Description | Mayoside C belongs to the class of organic compounds known as phenolic glycosides. These are organic compounds containing a phenolic structure attached to a glycosyl moiety. Some examples of phenolic structures include lignans, and flavonoids. Among the sugar units found in natural glycosides are D-glucose, L-Fructose, and L rhamnose. (6r)-3,4,5-trihydroxy-6-[(9s)-2,5,9-trihydroxy-7-methyl-10-oxo-4-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}anthracen-9-yl]oxan-2-yl benzoate is found in Picramnia teapensis. It was first documented in 2004 (PMID: 15043409). Based on a literature review a significant number of articles have been published on Mayoside C (PMID: 36115695) (PMID: 36115694) (PMID: 36115693) (PMID: 36115692). |
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Structure | CC1=CC(O)=C2C(=O)C3=C(O[C@@H]4O[C@H](CO)[C@@H](O)[C@H](O)[C@H]4O)C=C(O)C=C3[C@](O)([C@@H]3OC(OC(=O)C4=CC=CC=C4)C(O)C(O)C3O)C2=C1 InChI=1S/C33H34O16/c1-12-7-15-20(17(36)8-12)23(38)21-16(9-14(35)10-18(21)46-31-27(42)24(39)22(37)19(11-34)47-31)33(15,45)29-26(41)25(40)28(43)32(48-29)49-30(44)13-5-3-2-4-6-13/h2-10,19,22,24-29,31-32,34-37,39-43,45H,11H2,1H3/t19-,22-,24+,25?,26?,27-,28?,29-,31-,32?,33+/m1/s1 |
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Synonyms | Not Available |
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Chemical Formula | C33H34O16 |
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Average Mass | 686.6190 Da |
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Monoisotopic Mass | 686.18469 Da |
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IUPAC Name | (6R)-3,4,5-trihydroxy-6-[(9S)-2,5,9-trihydroxy-7-methyl-10-oxo-4-{[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,10-dihydroanthracen-9-yl]oxan-2-yl benzoate |
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Traditional Name | (6R)-3,4,5-trihydroxy-6-[(9S)-2,5,9-trihydroxy-7-methyl-10-oxo-4-{[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}anthracen-9-yl]oxan-2-yl benzoate |
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CAS Registry Number | Not Available |
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SMILES | CC1=CC(O)=C2C(=O)C3=C(O[C@@H]4O[C@H](CO)[C@@H](O)[C@H](O)[C@H]4O)C=C(O)C=C3[C@](O)([C@@H]3OC(OC(=O)C4=CC=CC=C4)C(O)C(O)C3O)C2=C1 |
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InChI Identifier | InChI=1S/C33H34O16/c1-12-7-15-20(17(36)8-12)23(38)21-16(9-14(35)10-18(21)46-31-27(42)24(39)22(37)19(11-34)47-31)33(15,45)29-26(41)25(40)28(43)32(48-29)49-30(44)13-5-3-2-4-6-13/h2-10,19,22,24-29,31-32,34-37,39-43,45H,11H2,1H3/t19-,22-,24+,25?,26?,27-,28?,29-,31-,32?,33+/m1/s1 |
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InChI Key | LONPEFKTZNCYGY-RGSWXRBOSA-N |
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Experimental Spectra |
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| Not Available | Predicted Spectra |
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| Spectrum Type | Description | Depositor ID | Depositor Organization | Depositor | Deposition Date | View |
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1D NMR | 13C NMR Spectrum (1D, 25 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 100 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 252 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 1000 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 50 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 200 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 75 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 300 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 101 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 400 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 126 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 500 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 151 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 600 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 176 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 700 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 201 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 800 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 226 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 900 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum |
| Chemical Shift Submissions |
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| Not Available | Species |
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Species of Origin | |
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Chemical Taxonomy |
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Description | Belongs to the class of organic compounds known as phenolic glycosides. These are organic compounds containing a phenolic structure attached to a glycosyl moiety. Some examples of phenolic structures include lignans, and flavonoids. Among the sugar units found in natural glycosides are D-glucose, L-Fructose, and L rhamnose. |
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Kingdom | Organic compounds |
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Super Class | Organic oxygen compounds |
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Class | Organooxygen compounds |
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Sub Class | Carbohydrates and carbohydrate conjugates |
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Direct Parent | Phenolic glycosides |
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Alternative Parents | |
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Substituents | - Phenolic glycoside
- Anthracene
- O-glycosyl compound
- Benzoate ester
- Benzoic acid or derivatives
- Benzoyl
- Aryl ketone
- 1-hydroxy-4-unsubstituted benzenoid
- 1-hydroxy-2-unsubstituted benzenoid
- Monocyclic benzene moiety
- Monosaccharide
- Oxane
- Benzenoid
- Tertiary alcohol
- Vinylogous acid
- Secondary alcohol
- Carboxylic acid ester
- Ketone
- Polyol
- Acetal
- Oxacycle
- Organoheterocyclic compound
- Carboxylic acid derivative
- Monocarboxylic acid or derivatives
- Hydrocarbon derivative
- Aldehyde
- Primary alcohol
- Alcohol
- Organic oxide
- Aromatic heteropolycyclic compound
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Molecular Framework | Aromatic heteropolycyclic compounds |
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External Descriptors | Not Available |
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Physical Properties |
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State | Not Available |
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Experimental Properties | Property | Value | Reference |
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Melting Point | Not Available | Not Available | Boiling Point | Not Available | Not Available | Water Solubility | Not Available | Not Available | LogP | Not Available | Not Available |
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Predicted Properties | |
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