NP-MRD: Showing NP-Card for (3s,3as,5s,11as)-3,6,10-trimethyl-2-oxo-3h,3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-5-yl acetate (NP0290821)

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Record Information

Version

2.0

Created at

2022-09-09 21:40:56 UTC

Updated at

2022-09-09 21:40:57 UTC

NP-MRD ID

NP0290821

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(3s,3as,5s,11as)-3,6,10-trimethyl-2-oxo-3h,3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-5-yl acetate

Description

Herbolide A belongs to the class of organic compounds known as germacranolides and derivatives. These are sesquiterpene lactones with a structure based on the germacranolide skeleton, characterized by a gamma lactone fused to a 1,7-dimethylcyclodec-1-ene moiety. (3s,3as,5s,11as)-3,6,10-trimethyl-2-oxo-3h,3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-5-yl acetate is found in Artemisia fragrans, Artemisia herba-alba and Artemisia vallesiaca. Based on a literature review very few articles have been published on Herbolide A.

Structure

MOL 3D MOL SDF PDB SMILES InChI

     RDKit          3D

 45 46  0  0  0  0  0  0  0  0999 V2000
    4.5582    1.5452    1.0722 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.6369    0.4315    0.6604 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.0923   -0.7341    0.6137 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.3132    0.6581    0.3350 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4537   -0.4063   -0.0529 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.3816   -0.6600    0.9704 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.9314   -1.0037    0.4191 C   0  0  2  0  0  0  0  0  0  0  0  0
   -2.1180   -0.3883    1.0624 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.1956    0.9729    1.4061 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0053    1.9982    0.6002 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1211    3.4266    1.1076 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.6765    1.7237   -0.8092 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1589    1.7880   -1.0400 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.2742    0.6916   -1.9249 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.0139   -0.3037   -1.4447 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.3690   -1.3447   -2.4879 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.1373   -0.9569    0.2279 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.7860   -2.3225    0.2021 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5190   -3.2943   -0.1336 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3511   -2.4820    0.6489 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.5570   -3.3408   -0.2728 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.9771    1.2296    2.0625 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.0317    2.4978    1.1071 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.3925    1.5440    0.3425 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.1078   -1.3343   -0.0111 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.2801    0.2285    1.6667 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.6664   -1.4826    1.6964 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.8930   -0.9904   -0.6822 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2759   -0.9987    2.0203 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4398    1.2890    2.4524 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.6153    3.5515    2.0681 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.2276    3.5930    1.1972 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7487    4.0873    0.3079 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1692    0.8855   -1.2753 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0851    2.6223   -1.3780 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.1222    2.7402   -1.5822 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.3734    1.8594   -0.0836 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0451    0.7529   -2.9686 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.7532   -2.2134   -1.9226 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.4637   -1.6819   -3.0324 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.1005   -0.9384   -3.2068 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.2789   -2.7484    1.7081 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.5177   -3.1403   -0.0859 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.8018   -4.3990   -0.2435 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7416   -2.9518   -1.3172 H   0  0  0  0  0  0  0  0  0  0  0  0
 21 20  1  0
 20  7  1  0
  7  6  1  0
  6  5  1  0
  5  4  1  0
  4  2  1  0
  2  1  1  0
  2  3  2  0
  5 15  1  0
 15 16  1  0
 15 14  2  0
 14 13  1  0
 13 12  1  0
 12 10  1  0
 10 11  1  0
 10  9  2  0
  9  8  1  0
  8 17  1  0
 17 18  1  0
 18 19  2  0
 18 20  1  0
  8  7  1  0
 21 43  1  0
 21 44  1  0
 21 45  1  0
 20 42  1  1
  7 28  1  6
  6 26  1  0
  6 27  1  0
  5 25  1  6
  1 22  1  0
  1 23  1  0
  1 24  1  0
 16 39  1  0
 16 40  1  0
 16 41  1  0
 14 38  1  0
 13 36  1  0
 13 37  1  0
 12 34  1  0
 12 35  1  0
 11 31  1  0
 11 32  1  0
 11 33  1  0
  9 30  1  0
  8 29  1  1
M  END


  Mrv1652309092223402D          

 21 22  0  0  1  0            999 V2000
    1.1013   -3.8372    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.6241   -3.1990    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4382   -3.3326    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.3328   -2.4271    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.8556   -1.7889    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.5643   -1.0170    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7502   -0.8834    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.4589   -0.1115    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.9817    0.5267    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.7958    0.3930    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.3186    1.0312    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.0871   -0.3788    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.9012   -0.5125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.1925   -1.2843    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.6697   -1.9226    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.9610   -2.6944    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3652   -0.1501    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.5832   -0.9457    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3551   -1.2370    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.1061   -1.3990    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.1447   -2.2231    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  2  0  0  0  0
  2  4  1  0  0  0  0
  5  4  1  1  0  0  0
  5  6  1  0  0  0  0
  7  6  1  1  0  0  0
  7  8  1  0  0  0  0
  8  9  1  0  0  0  0
  9 10  2  0  0  0  0
 10 11  1  0  0  0  0
 10 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  2  0  0  0  0
  5 15  1  0  0  0  0
 15 16  1  0  0  0  0
  8 17  1  6  0  0  0
 17 18  1  0  0  0  0
 18 19  2  0  0  0  0
 18 20  1  0  0  0  0
  7 20  1  0  0  0  0
 20 21  1  6  0  0  0
M  END
> <DATABASE_ID>
NP0290821

> <DATABASE_NAME>
NP-MRD

> <SMILES>
C[C@H]1[C@@H]2C[C@H](OC(C)=O)\C(C)=C/CC\C(C)=C/[C@H]2OC1=O

> <INCHI_IDENTIFIER>
InChI=1S/C17H24O4/c1-10-6-5-7-11(2)15(20-13(4)18)9-14-12(3)17(19)21-16(14)8-10/h7-8,12,14-16H,5-6,9H2,1-4H3/b10-8-,11-7-/t12-,14-,15-,16+/m0/s1

> <INCHI_KEY>
ALAJEHHXYIGXNY-ZDZYRWLBSA-N

> <FORMULA>
C17H24O4

> <MOLECULAR_WEIGHT>
292.375

> <EXACT_MASS>
292.167459253

> <JCHEM_ACCEPTOR_COUNT>
2

> <JCHEM_ATOM_COUNT>
45

> <JCHEM_AVERAGE_POLARIZABILITY>
31.93433696927359

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
0

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
1

> <JCHEM_IUPAC>
(3S,3aS,5S,11aS)-3,6,10-trimethyl-2-oxo-2H,3H,3aH,4H,5H,8H,9H,11aH-cyclodeca[b]furan-5-yl acetate

> <JCHEM_LOGP>
2.8848262856666667

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
2

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA_STRONGEST_BASIC>
-6.75059714496765

> <JCHEM_POLAR_SURFACE_AREA>
52.6

> <JCHEM_REFRACTIVITY>
80.80999999999999

> <JCHEM_ROTATABLE_BOND_COUNT>
2

> <JCHEM_RULE_OF_FIVE>
1

> <JCHEM_TRADITIONAL_IUPAC>
(3S,3aS,5S,11aS)-3,6,10-trimethyl-2-oxo-3H,3aH,4H,5H,8H,9H,11aH-cyclodeca[b]furan-5-yl acetate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 09-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   09-SEP-22         0                                  
HETATM    1  C   UNK     0       2.056  -7.163   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       3.032  -5.971   0.000  0.00  0.00           C+0
HETATM    3  O   UNK     0       4.551  -6.221   0.000  0.00  0.00           O+0
HETATM    4  O   UNK     0       2.488  -4.531   0.000  0.00  0.00           O+0
HETATM    5  C   UNK     0       3.464  -3.339   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       2.920  -1.898   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       1.400  -1.649   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       0.857  -0.208   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       1.832   0.983   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       3.352   0.734   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       4.328   1.925   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       3.896  -0.707   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       5.416  -0.957   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       5.959  -2.397   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       4.983  -3.589   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       5.527  -5.030   0.000  0.00  0.00           C+0
HETATM   17  O   UNK     0      -0.682  -0.280   0.000  0.00  0.00           O+0
HETATM   18  C   UNK     0      -1.089  -1.765   0.000  0.00  0.00           C+0
HETATM   19  O   UNK     0      -2.529  -2.309   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0       0.198  -2.611   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       0.270  -4.150   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3    4                                                  
CONECT    3    2                                                            
CONECT    4    2    5                                                       
CONECT    5    4    6   15                                                  
CONECT    6    5    7                                                       
CONECT    7    6    8   20                                                  
CONECT    8    7    9   17                                                  
CONECT    9    8   10                                                       
CONECT   10    9   11   12                                                  
CONECT   11   10                                                            
CONECT   12   10   13                                                       
CONECT   13   12   14                                                       
CONECT   14   13   15                                                       
CONECT   15   14    5   16                                                  
CONECT   16   15                                                            
CONECT   17    8   18                                                       
CONECT   18   17   19   20                                                  
CONECT   19   18                                                            
CONECT   20   18    7   21                                                  
CONECT   21   20                                                            
MASTER        0    0    0    0    0    0    0    0   21    0   44    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₁₇H₂₄O₄

Average Mass

292.3750 Da

Monoisotopic Mass

292.16746 Da

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

C[C@H]1[C@@H]2C[C@H](OC(C)=O)\C(C)=C/CC\C(C)=C/[C@H]2OC1=O

InChI Identifier

InChI=1S/C17H24O4/c1-10-6-5-7-11(2)15(20-13(4)18)9-14-12(3)17(19)21-16(14)8-10/h7-8,12,14-16H,5-6,9H2,1-4H3/b10-8-,11-7-/t12-,14-,15-,16+/m0/s1

InChI Key

ALAJEHHXYIGXNY-ZDZYRWLBSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Artemisia fragrans	LOTUS Database	35616633
Artemisia herba-alba	LOTUS Database	35616633
Artemisia vallesiaca	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as germacranolides and derivatives. These are sesquiterpene lactones with a structure based on the germacranolide skeleton, characterized by a gamma lactone fused to a 1,7-dimethylcyclodec-1-ene moiety.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Terpene lactones

Direct Parent

Germacranolides and derivatives

Alternative Parents

Substituents

Germacranolide
Sesquiterpenoid
Germacrane sesquiterpenoid
Gamma butyrolactone
Dicarboxylic acid or derivatives
Tetrahydrofuran
Lactone
Carboxylic acid ester
Oxacycle
Organoheterocyclic compound
Carboxylic acid derivative
Organic oxygen compound
Organic oxide
Hydrocarbon derivative
Organooxygen compound
Carbonyl group
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

C00012198

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

90474440

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (3s,3as,5s,11as)-3,6,10-trimethyl-2-oxo-3h,3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-5-yl acetate (NP0290821)

MOL for NP0290821 ((3s,3as,5s,11as)-3,6,10-trimethyl-2-oxo-3h,3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-5-yl acetate)

3D MOL for NP0290821 ((3s,3as,5s,11as)-3,6,10-trimethyl-2-oxo-3h,3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-5-yl acetate)

3D SDF for NP0290821 ((3s,3as,5s,11as)-3,6,10-trimethyl-2-oxo-3h,3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-5-yl acetate)

3D-SDF for NP0290821 ((3s,3as,5s,11as)-3,6,10-trimethyl-2-oxo-3h,3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-5-yl acetate)

PDB for NP0290821 ((3s,3as,5s,11as)-3,6,10-trimethyl-2-oxo-3h,3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-5-yl acetate)

3D PDB for NP0290821 ((3s,3as,5s,11as)-3,6,10-trimethyl-2-oxo-3h,3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-5-yl acetate)

SMILES for NP0290821 ((3s,3as,5s,11as)-3,6,10-trimethyl-2-oxo-3h,3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-5-yl acetate)

INCHI for NP0290821 ((3s,3as,5s,11as)-3,6,10-trimethyl-2-oxo-3h,3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-5-yl acetate)

Structure for NP0290821 ((3s,3as,5s,11as)-3,6,10-trimethyl-2-oxo-3h,3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-5-yl acetate)

3D Structure for NP0290821 ((3s,3as,5s,11as)-3,6,10-trimethyl-2-oxo-3h,3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-5-yl acetate)