NP-MRD: Showing NP-Card for 9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0¹,⁶.0¹³,²².0¹⁶,²¹]heptacosa-4,7,11,14,23-pentaene-25,27-dione (NP0287730)

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Record Information

Version

2.0

Created at

2022-09-09 17:03:56 UTC

Updated at

2022-09-09 17:03:56 UTC

NP-MRD ID

NP0287730

Secondary Accession Numbers

None

Natural Product Identification

Common Name

9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0¹,⁶.0¹³,²².0¹⁶,²¹]heptacosa-4,7,11,14,23-pentaene-25,27-dione

Description

9,17,18,23-Tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0¹,⁶.0¹³,²².0¹⁶,²¹]Heptacosa-4,7,11,14,23-pentaene-25,27-dione belongs to the class of organic compounds known as sesterterpenoids. These are terpenes composed of five consecutive isoprene units. 9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0¹,⁶.0¹³,²².0¹⁶,²¹]heptacosa-4,7,11,14,23-pentaene-25,27-dione is found in Micromonospora harpali. Based on a literature review very few articles have been published on 9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0¹,⁶.0¹³,²².0¹⁶,²¹]Heptacosa-4,7,11,14,23-pentaene-25,27-dione.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309092219032D          

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M  END

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M  END


  Mrv1652309092219032D          

 39 43  0  0  0  0            999 V2000
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    4.8198   -1.1876    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.5526   -0.8087    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.2472   -1.2538    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.5909    0.0155    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.3958   -0.1653    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.9086    0.7768    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.8963    0.4606    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.1634    0.0817    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.8632    0.8501    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.1252   -0.7424    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.9134   -2.7209    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.3714   -3.4071    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.0621   -2.8263    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.2854   -2.4652    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.5013   -2.0677    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0413   -2.7526    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.7303    0.6620    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5693    1.4712    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  2  0  0  0  0
  3  4  1  4  0  0  0
  4  5  1  0  0  0  0
  5  6  2  0  0  0  0
  6  7  1  0  0  0  0
  7  8  1  0  0  0  0
  7  9  1  0  0  0  0
  9 10  1  0  0  0  0
  4 10  1  0  0  0  0
 10 11  1  0  0  0  0
 11 12  1  0  0  0  0
 12 13  2  0  0  0  0
 12 14  1  0  0  0  0
 14 15  2  0  0  0  0
 15 16  1  4  0  0  0
 15 17  1  0  0  0  0
 17 18  1  0  0  0  0
 17 19  1  0  0  0  0
 19 20  1  0  0  0  0
 20 21  2  0  0  0  0
 21 22  1  0  0  0  0
 22 23  1  0  0  0  0
 23 24  1  0  0  0  0
 23 25  1  0  0  0  0
 25 26  1  0  0  0  0
 25 27  1  0  0  0  0
 25 28  1  0  0  0  0
 28 29  1  0  0  0  0
 29 30  1  0  0  0  0
 29 31  1  0  0  0  0
 22 31  1  0  0  0  0
 17 31  1  0  0  0  0
 19 32  1  0  0  0  0
 32 33  1  0  0  0  0
 32 34  2  0  0  0  0
 34 35  1  4  0  0  0
 35 36  1  0  0  0  0
  2 36  1  0  0  0  0
 36 37  1  0  0  0  0
 14 38  1  0  0  0  0
 10 38  1  0  0  0  0
 38 39  2  0  0  0  0
M  END
> <DATABASE_ID>
NP0287730

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC1CC23OC(=O)C(C2=O)=C(O)C2(C)C4C(C)CC(C)(O)C(O)C4C=CC2C(C)=CCC(O)C(C)=CC3C=C1

> <INCHI_IDENTIFIER>
InChI=1S/C32H42O7/c1-16-7-9-20-13-18(3)23(33)12-8-17(2)22-11-10-21-25(19(4)15-30(5,38)26(21)34)31(22,6)27(35)24-28(36)32(20,14-16)39-29(24)37/h7-11,13,16,19-23,25-26,33-35,38H,12,14-15H2,1-6H3

> <INCHI_KEY>
DDOSFKMWLJIFOX-UHFFFAOYSA-N

> <FORMULA>
C32H42O7

> <MOLECULAR_WEIGHT>
538.681

> <EXACT_MASS>
538.293053692

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
81

> <JCHEM_AVERAGE_POLARIZABILITY>
58.765588940840075

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
4

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0^{1,6}.0^{13,22}.0^{16,21}]heptacosa-4,7,11,14,23-pentaene-25,27-dione

> <JCHEM_LOGP>
3.420354672333333

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
-1

> <JCHEM_PKA>
13.55854504448492

> <JCHEM_PKA_STRONGEST_ACIDIC>
3.7064198240893087

> <JCHEM_PKA_STRONGEST_BASIC>
-1.3812945046219358

> <JCHEM_POLAR_SURFACE_AREA>
124.29000000000002

> <JCHEM_REFRACTIVITY>
152.72639999999998

> <JCHEM_ROTATABLE_BOND_COUNT>
0

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0^{1,6}.0^{13,22}.0^{16,21}]heptacosa-4,7,11,14,23-pentaene-25,27-dione

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 09-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   09-SEP-22         0                                  
HETATM    1  C   UNK     0      -1.801  -3.227   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      -0.333  -2.761   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       0.114  -0.952   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       0.531   0.688   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -0.918   0.167   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -0.987  -1.403   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       0.524  -2.161   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       1.448  -3.394   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       1.820  -1.462   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       2.055   0.100   0.000  0.00  0.00           C+0
HETATM   11  O   UNK     0       3.070  -1.112   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0       4.532  -0.847   0.000  0.00  0.00           C+0
HETATM   13  O   UNK     0       5.641  -1.916   0.000  0.00  0.00           O+0
HETATM   14  C   UNK     0       4.747   0.638   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       5.989  -0.484   0.000  0.00  0.00           C+0
HETATM   16  O   UNK     0       7.019   0.660   0.000  0.00  0.00           O+0
HETATM   17  C   UNK     0       6.332  -2.093   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       6.991  -0.701   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       6.261  -3.632   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       7.558  -4.463   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       8.926  -3.755   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       8.997  -2.217   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0      10.365  -1.509   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0      11.661  -2.340   0.000  0.00  0.00           O+0
HETATM   25  C   UNK     0      10.436   0.029   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0      11.939  -0.309   0.000  0.00  0.00           C+0
HETATM   27  O   UNK     0      11.029   1.450   0.000  0.00  0.00           O+0
HETATM   28  C   UNK     0       9.140   0.860   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       7.772   0.152   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       7.211   1.587   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0       7.700  -1.386   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0       5.438  -5.079   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0       6.293  -6.360   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0       3.849  -5.276   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0       2.399  -4.602   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0       0.936  -3.860   0.000  0.00  0.00           C+0
HETATM   37  O   UNK     0       0.077  -5.138   0.000  0.00  0.00           O+0
HETATM   38  C   UNK     0       3.230   1.236   0.000  0.00  0.00           C+0
HETATM   39  O   UNK     0       2.929   2.746   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3   36                                                  
CONECT    3    2    4                                                       
CONECT    4    3    5   10                                                  
CONECT    5    4    6                                                       
CONECT    6    5    7                                                       
CONECT    7    6    8    9                                                  
CONECT    8    7                                                            
CONECT    9    7   10                                                       
CONECT   10    9    4   11   38                                             
CONECT   11   10   12                                                       
CONECT   12   11   13   14                                                  
CONECT   13   12                                                            
CONECT   14   12   15   38                                                  
CONECT   15   14   16   17                                                  
CONECT   16   15                                                            
CONECT   17   15   18   19   31                                             
CONECT   18   17                                                            
CONECT   19   17   20   32                                                  
CONECT   20   19   21                                                       
CONECT   21   20   22                                                       
CONECT   22   21   23   31                                                  
CONECT   23   22   24   25                                                  
CONECT   24   23                                                            
CONECT   25   23   26   27   28                                             
CONECT   26   25                                                            
CONECT   27   25                                                            
CONECT   28   25   29                                                       
CONECT   29   28   30   31                                                  
CONECT   30   29                                                            
CONECT   31   29   22   17                                                  
CONECT   32   19   33   34                                                  
CONECT   33   32                                                            
CONECT   34   32   35                                                       
CONECT   35   34   36                                                       
CONECT   36   35    2   37                                                  
CONECT   37   36                                                            
CONECT   38   14   10   39                                                  
CONECT   39   38                                                            
MASTER        0    0    0    0    0    0    0    0   39    0   86    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₃₂H₄₂O₇

Average Mass

538.6810 Da

Monoisotopic Mass

538.29305 Da

IUPAC Name

9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0^{1,6}.0^{13,22}.0^{16,21}]heptacosa-4,7,11,14,23-pentaene-25,27-dione

Traditional Name

9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0^{1,6}.0^{13,22}.0^{16,21}]heptacosa-4,7,11,14,23-pentaene-25,27-dione

CAS Registry Number

Not Available

SMILES

CC1CC23OC(=O)C(C2=O)=C(O)C2(C)C4C(C)CC(C)(O)C(O)C4C=CC2C(C)=CCC(O)C(C)=CC3C=C1

InChI Identifier

InChI=1S/C32H42O7/c1-16-7-9-20-13-18(3)23(33)12-8-17(2)22-11-10-21-25(19(4)15-30(5,38)26(21)34)31(22,6)27(35)24-28(36)32(20,14-16)39-29(24)37/h7-11,13,16,19-23,25-26,33-35,38H,12,14-15H2,1-6H3

InChI Key

DDOSFKMWLJIFOX-UHFFFAOYSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Micromonospora harpali	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as sesterterpenoids. These are terpenes composed of five consecutive isoprene units.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Sesterterpenoids

Direct Parent

Sesterterpenoids

Alternative Parents

Substituents

Sesterterpenoid
Macrolide
Gamma butyrolactone
3-furanone
Vinylogous acid
Alpha,beta-unsaturated carboxylic ester
Enoate ester
Tetrahydrofuran
Tertiary alcohol
Cyclic alcohol
Secondary alcohol
Lactone
Ketone
Carboxylic acid ester
Oxacycle
Organoheterocyclic compound
Polyol
Monocarboxylic acid or derivatives
Enol
Carboxylic acid derivative
Organic oxygen compound
Organic oxide
Hydrocarbon derivative
Organooxygen compound
Carbonyl group
Alcohol
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	3.42	ChemAxon
pKa (Strongest Acidic)	3.71	ChemAxon
pKa (Strongest Basic)	-1.4	ChemAxon
Physiological Charge	-1	ChemAxon
Hydrogen Acceptor Count	6	ChemAxon
Hydrogen Donor Count	4	ChemAxon
Polar Surface Area	124.29 Å²	ChemAxon
Rotatable Bond Count	0	ChemAxon
Refractivity	152.73 m³·mol⁻¹	ChemAxon
Polarizability	58.77 Å³	ChemAxon
Number of Rings	5	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

162815855

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for 9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0¹,⁶.0¹³,²².0¹⁶,²¹]heptacosa-4,7,11,14,23-pentaene-25,27-dione (NP0287730)

MOL for NP0287730 (9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0¹,⁶.0¹³,²².0¹⁶,²¹]heptacosa-4,7,11,14,23-pentaene-25,27-dione)

3D MOL for NP0287730 (9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0¹,⁶.0¹³,²².0¹⁶,²¹]heptacosa-4,7,11,14,23-pentaene-25,27-dione)

3D SDF for NP0287730 (9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0¹,⁶.0¹³,²².0¹⁶,²¹]heptacosa-4,7,11,14,23-pentaene-25,27-dione)

3D-SDF for NP0287730 (9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0¹,⁶.0¹³,²².0¹⁶,²¹]heptacosa-4,7,11,14,23-pentaene-25,27-dione)

PDB for NP0287730 (9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0¹,⁶.0¹³,²².0¹⁶,²¹]heptacosa-4,7,11,14,23-pentaene-25,27-dione)

3D PDB for NP0287730 (9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0¹,⁶.0¹³,²².0¹⁶,²¹]heptacosa-4,7,11,14,23-pentaene-25,27-dione)

SMILES for NP0287730 (9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0¹,⁶.0¹³,²².0¹⁶,²¹]heptacosa-4,7,11,14,23-pentaene-25,27-dione)

INCHI for NP0287730 (9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0¹,⁶.0¹³,²².0¹⁶,²¹]heptacosa-4,7,11,14,23-pentaene-25,27-dione)

Structure for NP0287730 (9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0¹,⁶.0¹³,²².0¹⁶,²¹]heptacosa-4,7,11,14,23-pentaene-25,27-dione)

3D Structure for NP0287730 (9,17,18,23-tetrahydroxy-3,8,12,18,20,22-hexamethyl-26-oxapentacyclo[22.2.1.0¹,⁶.0¹³,²².0¹⁶,²¹]heptacosa-4,7,11,14,23-pentaene-25,27-dione)