NP-MRD: Showing NP-Card for 2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0¹,²¹.0³,¹².0⁶,¹¹.0¹⁰,¹⁵.0¹⁴,¹⁹]tetracosa-3,5,8,10,12,14,16,19-octaene-7,18-dione (NP0286634)

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Record Information

Version

2.0

Created at

2022-09-09 15:17:23 UTC

Updated at

2022-09-09 15:17:23 UTC

NP-MRD ID

NP0286634

Secondary Accession Numbers

None

Natural Product Identification

Common Name

2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0¹,²¹.0³,¹².0⁶,¹¹.0¹⁰,¹⁵.0¹⁴,¹⁹]tetracosa-3,5,8,10,12,14,16,19-octaene-7,18-dione

Description

2-Acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0¹,²¹.0³,¹².0⁶,¹¹.0¹⁰,¹⁵.0¹⁴,¹⁹]Tetracosa-3(12),4,6(11),8,10(15),13,16,19-octaene-7,18-dione belongs to the class of organic compounds known as phenanthrols. Phenanthrols are compounds containing a phenanthrene (or its hydrogenated derivative) to which a hydroxyl group is attached. Based on a literature review very few articles have been published on 2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0¹,²¹.0³,¹².0⁶,¹¹.0¹⁰,¹⁵.0¹⁴,¹⁹]Tetracosa-3(12),4,6(11),8,10(15),13,16,19-octaene-7,18-dione.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309092217172D          

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    1.3172   -3.8433    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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M  END

     RDKit          3D

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M  END


  Mrv1652309092217172D          

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   -0.5119   -1.6033    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.1212   -2.1596    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.9441   -2.9653    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9075   -1.9100    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  4  5  2  0  0  0  0
  5  6  1  0  0  0  0
  6  7  2  0  0  0  0
  7  8  1  0  0  0  0
  8  9  1  0  0  0  0
  9 10  2  0  0  0  0
  9 11  1  0  0  0  0
 11 12  2  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 12 15  1  0  0  0  0
  7 15  1  0  0  0  0
 15 16  2  0  0  0  0
 16 17  1  0  0  0  0
 17 18  1  0  0  0  0
 18 19  1  0  0  0  0
 17 20  2  0  0  0  0
 20 21  1  0  0  0  0
 21 22  2  0  0  0  0
 21 23  1  0  0  0  0
 23 24  1  0  0  0  0
  3 24  2  0  0  0  0
 24 25  1  0  0  0  0
 23 26  2  0  0  0  0
  5 26  1  0  0  0  0
 16 26  1  0  0  0  0
  8 27  2  0  0  0  0
 27 28  1  0  0  0  0
 27 29  1  0  0  0  0
 29 30  1  0  0  0  0
 30 31  1  0  0  0  0
 29 32  1  0  0  0  0
 32 33  1  0  0  0  0
 33 34  1  0  0  0  0
 33 35  1  0  0  0  0
 35 36  1  0  0  0  0
  6 36  1  0  0  0  0
 29 36  1  0  0  0  0
 36 37  1  0  0  0  0
  4 37  1  0  0  0  0
 37 38  1  0  0  0  0
 38 39  1  0  0  0  0
 38 40  2  0  0  0  0
M  END
> <DATABASE_ID>
NP0286634

> <DATABASE_NAME>
NP-MRD

> <SMILES>
COC1=CC(=O)C2=C(O)C3(OC)OC(C)CC33C(C(C)=O)C4=C5C3=C2C1=C1C(OC)=CC(=O)C(C(O)=C4OC)=C51

> <INCHI_IDENTIFIER>
InChI=1S/C30H26O10/c1-10-9-29-24(11(2)31)23-22-20-16(26(34)27(23)38-5)12(32)7-14(36-3)18(20)19-15(37-4)8-13(33)17(21(19)25(22)29)28(35)30(29,39-6)40-10/h7-8,10,24,34-35H,9H2,1-6H3

> <INCHI_KEY>
AFOACYDTOFSVOR-UHFFFAOYSA-N

> <FORMULA>
C30H26O10

> <MOLECULAR_WEIGHT>
546.528

> <EXACT_MASS>
546.152597037

> <JCHEM_ACCEPTOR_COUNT>
10

> <JCHEM_ATOM_COUNT>
66

> <JCHEM_AVERAGE_POLARIZABILITY>
54.918221515312425

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
2

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0^{1,21}.0^{3,12}.0^{6,11}.0^{10,15}.0^{14,19}]tetracosa-3(12),4,6(11),8,10(15),13,16,19-octaene-7,18-dione

> <JCHEM_LOGP>
0.9008842896143303

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
7

> <JCHEM_PHYSIOLOGICAL_CHARGE>
-1

> <JCHEM_PKA>
8.582274968035481

> <JCHEM_PKA_STRONGEST_ACIDIC>
1.4366151585119296

> <JCHEM_PKA_STRONGEST_BASIC>
4.131815649203278

> <JCHEM_POLAR_SURFACE_AREA>
137.82000000000002

> <JCHEM_REFRACTIVITY>
145.87099999999995

> <JCHEM_ROTATABLE_BOND_COUNT>
5

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0^{1,21}.0^{3,12}.0^{6,11}.0^{10,15}.0^{14,19}]tetracosa-3(12),4,6(11),8,10(15),13,16,19-octaene-7,18-dione

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 09-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   09-SEP-22         0                                  
HETATM    1  C   UNK     0       2.459  -7.174   0.000  0.00  0.00           C+0
HETATM    2  O   UNK     0       1.420  -6.037   0.000  0.00  0.00           O+0
HETATM    3  C   UNK     0       1.886  -4.569   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       0.848  -3.432   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       1.314  -1.964   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       0.276  -0.826   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       0.741   0.641   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      -0.297   1.779   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       0.169   3.247   0.000  0.00  0.00           C+0
HETATM   10  O   UNK     0      -0.869   4.384   0.000  0.00  0.00           O+0
HETATM   11  C   UNK     0       1.673   3.577   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       2.711   2.440   0.000  0.00  0.00           C+0
HETATM   13  O   UNK     0       4.215   2.770   0.000  0.00  0.00           O+0
HETATM   14  C   UNK     0       4.681   4.238   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       2.246   0.972   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       3.284  -0.165   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       4.788   0.165   0.000  0.00  0.00           C+0
HETATM   18  O   UNK     0       5.254   1.633   0.000  0.00  0.00           O+0
HETATM   19  C   UNK     0       6.758   1.963   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       5.826  -0.972   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       5.360  -2.440   0.000  0.00  0.00           C+0
HETATM   22  O   UNK     0       6.399  -3.578   0.000  0.00  0.00           O+0
HETATM   23  C   UNK     0       3.856  -2.771   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       3.390  -4.239   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0       4.429  -5.376   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0       2.818  -1.633   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0      -1.801   1.448   0.000  0.00  0.00           C+0
HETATM   28  O   UNK     0      -2.839   2.586   0.000  0.00  0.00           O+0
HETATM   29  C   UNK     0      -2.267  -0.020   0.000  0.00  0.00           C+0
HETATM   30  O   UNK     0      -3.418   1.003   0.000  0.00  0.00           O+0
HETATM   31  C   UNK     0      -4.880   0.517   0.000  0.00  0.00           C+0
HETATM   32  O   UNK     0      -3.669  -0.656   0.000  0.00  0.00           O+0
HETATM   33  C   UNK     0      -3.498  -2.186   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0      -4.635  -3.224   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0      -1.989  -2.496   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0      -1.229  -1.157   0.000  0.00  0.00           C+0
HETATM   37  C   UNK     0      -0.956  -2.993   0.000  0.00  0.00           C+0
HETATM   38  C   UNK     0      -2.093  -4.031   0.000  0.00  0.00           C+0
HETATM   39  C   UNK     0      -1.762  -5.535   0.000  0.00  0.00           C+0
HETATM   40  O   UNK     0      -3.561  -3.565   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4   24                                                  
CONECT    4    3    5   37                                                  
CONECT    5    4    6   26                                                  
CONECT    6    5    7   36                                                  
CONECT    7    6    8   15                                                  
CONECT    8    7    9   27                                                  
CONECT    9    8   10   11                                                  
CONECT   10    9                                                            
CONECT   11    9   12                                                       
CONECT   12   11   13   15                                                  
CONECT   13   12   14                                                       
CONECT   14   13                                                            
CONECT   15   12    7   16                                                  
CONECT   16   15   17   26                                                  
CONECT   17   16   18   20                                                  
CONECT   18   17   19                                                       
CONECT   19   18                                                            
CONECT   20   17   21                                                       
CONECT   21   20   22   23                                                  
CONECT   22   21                                                            
CONECT   23   21   24   26                                                  
CONECT   24   23    3   25                                                  
CONECT   25   24                                                            
CONECT   26   23    5   16                                                  
CONECT   27    8   28   29                                                  
CONECT   28   27                                                            
CONECT   29   27   30   32   36                                             
CONECT   30   29   31                                                       
CONECT   31   30                                                            
CONECT   32   29   33                                                       
CONECT   33   32   34   35                                                  
CONECT   34   33                                                            
CONECT   35   33   36                                                       
CONECT   36   35    6   29   37                                             
CONECT   37   36    4   38                                                  
CONECT   38   37   39   40                                                  
CONECT   39   38                                                            
CONECT   40   38                                                            
MASTER        0    0    0    0    0    0    0    0   40    0   92    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₃₀H₂₆O₁₀

Average Mass

546.5280 Da

Monoisotopic Mass

546.15260 Da

IUPAC Name

2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0^{1,21}.0^{3,12}.0^{6,11}.0^{10,15}.0^{14,19}]tetracosa-3(12),4,6(11),8,10(15),13,16,19-octaene-7,18-dione

Traditional Name

2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0^{1,21}.0^{3,12}.0^{6,11}.0^{10,15}.0^{14,19}]tetracosa-3(12),4,6(11),8,10(15),13,16,19-octaene-7,18-dione

CAS Registry Number

Not Available

SMILES

COC1=CC(=O)C2=C(O)C3(OC)OC(C)CC33C(C(C)=O)C4=C5C3=C2C1=C1C(OC)=CC(=O)C(C(O)=C4OC)=C51

InChI Identifier

InChI=1S/C30H26O10/c1-10-9-29-24(11(2)31)23-22-20-16(26(34)27(23)38-5)12(32)7-14(36-3)18(20)19-15(37-4)8-13(33)17(21(19)25(22)29)28(35)30(29,39-6)40-10/h7-8,10,24,34-35H,9H2,1-6H3

InChI Key

AFOACYDTOFSVOR-UHFFFAOYSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Not Available

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as phenanthrols. Phenanthrols are compounds containing a phenanthrene (or its hydrogenated derivative) to which a hydroxyl group is attached.

Kingdom

Organic compounds

Super Class

Benzenoids

Class

Phenanthrenes and derivatives

Sub Class

Phenanthrols

Direct Parent

Phenanthrols

Alternative Parents

Substituents

Phenanthrol
Phenalen-1-one
Phenalen
Naphthofuran
2-naphthol
Naphthalene
Aryl ketone
Anisole
Ketal
Alkyl aryl ether
Vinylogous ester
Vinylogous acid
Tetrahydrofuran
Ketone
Oxacycle
Organoheterocyclic compound
Ether
Enol
Acetal
Organic oxygen compound
Organic oxide
Hydrocarbon derivative
Organooxygen compound
Carbonyl group
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	0.9	ChemAxon
pKa (Strongest Acidic)	1.44	ChemAxon
pKa (Strongest Basic)	4.13	ChemAxon
Physiological Charge	-1	ChemAxon
Hydrogen Acceptor Count	10	ChemAxon
Hydrogen Donor Count	2	ChemAxon
Polar Surface Area	137.82 Å²	ChemAxon
Rotatable Bond Count	5	ChemAxon
Refractivity	145.87 m³·mol⁻¹	ChemAxon
Polarizability	54.92 Å³	ChemAxon
Number of Rings	7	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

136207806

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for 2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0¹,²¹.0³,¹².0⁶,¹¹.0¹⁰,¹⁵.0¹⁴,¹⁹]tetracosa-3,5,8,10,12,14,16,19-octaene-7,18-dione (NP0286634)

MOL for NP0286634 (2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0¹,²¹.0³,¹².0⁶,¹¹.0¹⁰,¹⁵.0¹⁴,¹⁹]tetracosa-3,5,8,10,12,14,16,19-octaene-7,18-dione)

3D MOL for NP0286634 (2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0¹,²¹.0³,¹².0⁶,¹¹.0¹⁰,¹⁵.0¹⁴,¹⁹]tetracosa-3,5,8,10,12,14,16,19-octaene-7,18-dione)

3D SDF for NP0286634 (2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0¹,²¹.0³,¹².0⁶,¹¹.0¹⁰,¹⁵.0¹⁴,¹⁹]tetracosa-3,5,8,10,12,14,16,19-octaene-7,18-dione)

3D-SDF for NP0286634 (2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0¹,²¹.0³,¹².0⁶,¹¹.0¹⁰,¹⁵.0¹⁴,¹⁹]tetracosa-3,5,8,10,12,14,16,19-octaene-7,18-dione)

PDB for NP0286634 (2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0¹,²¹.0³,¹².0⁶,¹¹.0¹⁰,¹⁵.0¹⁴,¹⁹]tetracosa-3,5,8,10,12,14,16,19-octaene-7,18-dione)

3D PDB for NP0286634 (2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0¹,²¹.0³,¹².0⁶,¹¹.0¹⁰,¹⁵.0¹⁴,¹⁹]tetracosa-3,5,8,10,12,14,16,19-octaene-7,18-dione)

SMILES for NP0286634 (2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0¹,²¹.0³,¹².0⁶,¹¹.0¹⁰,¹⁵.0¹⁴,¹⁹]tetracosa-3,5,8,10,12,14,16,19-octaene-7,18-dione)

INCHI for NP0286634 (2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0¹,²¹.0³,¹².0⁶,¹¹.0¹⁰,¹⁵.0¹⁴,¹⁹]tetracosa-3,5,8,10,12,14,16,19-octaene-7,18-dione)

Structure for NP0286634 (2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0¹,²¹.0³,¹².0⁶,¹¹.0¹⁰,¹⁵.0¹⁴,¹⁹]tetracosa-3,5,8,10,12,14,16,19-octaene-7,18-dione)

3D Structure for NP0286634 (2-acetyl-5,20-dihydroxy-4,9,16,21-tetramethoxy-23-methyl-22-oxaheptacyclo[11.11.0.0¹,²¹.0³,¹².0⁶,¹¹.0¹⁰,¹⁵.0¹⁴,¹⁹]tetracosa-3,5,8,10,12,14,16,19-octaene-7,18-dione)