NP-MRD: Showing NP-Card for (2r,6s)-2-{[(1r,3as,3br,7s,9ar,9bs,11as)-1-[(1s)-1-{[(2r,4s,5s,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-1-hydroxy-9a,11a-dimethyl-2h,3h,3ah,3bh,4h,6h,7h,8h,9h,9bh,10h,11h-cyclopenta[a]phenanthren-7-yl]oxy}-4-methoxy-6-methyl-2,6-dihydropyran-3-one (NP0285895)

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Record Information

Version

2.0

Created at

2022-09-09 14:15:28 UTC

Updated at

2022-09-09 14:15:28 UTC

NP-MRD ID

NP0285895

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(2r,6s)-2-{[(1r,3as,3br,7s,9ar,9bs,11as)-1-[(1s)-1-{[(2r,4s,5s,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-1-hydroxy-9a,11a-dimethyl-2h,3h,3ah,3bh,4h,6h,7h,8h,9h,9bh,10h,11h-cyclopenta[a]phenanthren-7-yl]oxy}-4-methoxy-6-methyl-2,6-dihydropyran-3-one

Description

Periplocoside M belongs to the class of organic compounds known as steroidal glycosides. These are sterol lipids containing a carbohydrate moiety glycosidically linked to the steroid skeleton. (2r,6s)-2-{[(1r,3as,3br,7s,9ar,9bs,11as)-1-[(1s)-1-{[(2r,4s,5s,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-1-hydroxy-9a,11a-dimethyl-2h,3h,3ah,3bh,4h,6h,7h,8h,9h,9bh,10h,11h-cyclopenta[a]phenanthren-7-yl]oxy}-4-methoxy-6-methyl-2,6-dihydropyran-3-one is found in Periploca sepium. (2r,6s)-2-{[(1r,3as,3br,7s,9ar,9bs,11as)-1-[(1s)-1-{[(2r,4s,5s,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-1-hydroxy-9a,11a-dimethyl-2h,3h,3ah,3bh,4h,6h,7h,8h,9h,9bh,10h,11h-cyclopenta[a]phenanthren-7-yl]oxy}-4-methoxy-6-methyl-2,6-dihydropyran-3-one was first documented in 2012 (PMID: 23189735). Based on a literature review a small amount of articles have been published on Periplocoside M (PMID: 34816469) (PMID: 30466613).

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309092216152D          

 43 48  0  0  1  0            999 V2000
    0.1988   -3.9785    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7306   -3.3478    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.4503   -2.5719    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3618   -2.4267    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6421   -1.6508    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -1.4542   -1.5056    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1103   -1.0201    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7018   -1.1653    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.2336   -0.5346    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.0458   -0.6798    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.3261   -1.4557    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.1382   -1.6009    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.6700   -0.9702    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    3.9503   -1.7461    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.3897   -0.1943    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.9215    0.4364    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.7336    0.2912    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.0139   -0.4847    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    5.8261   -0.6299    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    6.4774   -0.1236    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.1602   -0.5866    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.9309   -1.3791    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    6.8714   -2.2019    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    7.7430   -1.5243    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    8.0233   -2.3002    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.2749   -0.8936    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    9.0870   -1.0388    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    9.6188   -0.4081    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   10.4309   -0.5533    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   10.9627    0.0774    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   10.7112   -1.3292    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   11.5233   -1.4744    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   10.1794   -1.9599    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   10.4597   -2.7358    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.3673   -1.8147    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.1064   -1.4059    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    6.4662   -2.1482    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.5745   -2.0366    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.7624   -1.8914    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.4821   -1.1154    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.5776   -0.0491    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.9821   -1.9412    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.7942   -2.0864    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  2  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  6  0  0  0
  5  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  1  1  0  0  0
 10  9  1  6  0  0  0
 10 11  1  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  6  0  0  0
 13 15  1  0  0  0  0
 15 16  2  0  0  0  0
 16 17  1  0  0  0  0
 18 17  1  1  0  0  0
 18 19  1  0  0  0  0
 19 20  1  6  0  0  0
 20 21  1  0  0  0  0
 21 22  1  0  0  0  0
 22 23  1  1  0  0  0
 22 24  1  6  0  0  0
 24 25  1  1  0  0  0
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 27 26  1  6  0  0  0
 27 28  1  0  0  0  0
 28 29  1  0  0  0  0
 29 30  1  6  0  0  0
 29 31  1  0  0  0  0
 31 32  1  6  0  0  0
 31 33  1  0  0  0  0
 33 34  1  6  0  0  0
 33 35  1  0  0  0  0
 27 35  1  0  0  0  0
 22 36  1  0  0  0  0
 19 36  1  0  0  0  0
 36 37  1  6  0  0  0
 36 38  1  0  0  0  0
 38 39  1  0  0  0  0
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 18 40  1  0  0  0  0
 13 40  1  0  0  0  0
 15 41  1  0  0  0  0
 10 41  1  0  0  0  0
  8 42  1  0  0  0  0
  3 42  1  0  0  0  0
 42 43  2  0  0  0  0
M  END

     RDKit          3D

 95100  0  0  0  0  0  0  0  0999 V2000
    9.1384    3.2064   -1.4010 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.3390    2.7392   -0.0837 O   0  0  0  0  0  0  0  0  0  0  0  0
    8.6723    1.6458    0.4578 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.2482    0.8195    1.3163 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.4357   -0.3031    1.8203 C   0  0  2  0  0  0  0  0  0  0  0  0
    9.3908   -1.3733    2.3687 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.5875   -0.8871    0.9330 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.9062   -0.0895    0.0656 C   0  0  1  0  0  0  0  0  0  0  0  0
    5.5411   -0.3044    0.1698 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.0094   -0.8416   -1.0065 C   0  0  1  0  0  0  0  0  0  0  0  0
    4.4084   -2.1699   -0.7111 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8936   -2.2090   -0.8188 C   0  0  0  0  0  0  0  0  0  0  0  0
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    2.1923    1.3316   -0.4381 C   0  0  0  0  0  0  0  0  0  0  0  0
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   -4.5431   -1.0706   -0.0676 C   0  0  2  0  0  0  0  0  0  0  0  0
   -4.5970   -2.5532   -0.3022 C   0  0  0  0  0  0  0  0  0  0  0  0
   -5.5470   -0.4638   -0.8605 O   0  0  0  0  0  0  0  0  0  0  0  0
   -6.5476    0.1141   -0.1409 C   0  0  2  0  0  0  0  0  0  0  0  0
   -7.8551   -0.5180   -0.6397 C   0  0  0  0  0  0  0  0  0  0  0  0
   -8.8539    0.6003   -0.9070 C   0  0  2  0  0  0  0  0  0  0  0  0
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 19 65  1  6
 20 66  1  0
 20 67  1  0
 21 68  1  0
 21 69  1  0
 23 70  1  0
 24 71  1  1
 25 72  1  0
 25 73  1  0
 25 74  1  0
 27 75  1  1
 28 76  1  0
 28 77  1  0
 29 78  1  6
 30 79  1  0
 31 80  1  1
 32 81  1  0
 33 82  1  1
 34 83  1  0
 34 84  1  0
 34 85  1  0
 18 64  1  1
 17 62  1  0
 17 63  1  0
 16 61  1  0
 41 94  1  0
 41 95  1  0
M  END


  Mrv1652309092216152D          

 43 48  0  0  1  0            999 V2000
    0.1988   -3.9785    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7306   -3.3478    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.4503   -2.5719    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3618   -2.4267    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6421   -1.6508    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -1.4542   -1.5056    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1103   -1.0201    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7018   -1.1653    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.2336   -0.5346    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.0458   -0.6798    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.3261   -1.4557    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.1382   -1.6009    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.6700   -0.9702    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    3.9503   -1.7461    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.3897   -0.1943    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.9215    0.4364    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.7336    0.2912    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.0139   -0.4847    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    5.8261   -0.6299    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    6.4774   -0.1236    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.1602   -0.5866    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.9309   -1.3791    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    6.8714   -2.2019    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    7.7430   -1.5243    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    8.0233   -2.3002    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.2749   -0.8936    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    9.0870   -1.0388    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    9.6188   -0.4081    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   10.4309   -0.5533    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   10.9627    0.0774    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   10.7112   -1.3292    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   11.5233   -1.4744    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   10.1794   -1.9599    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   10.4597   -2.7358    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.3673   -1.8147    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.1064   -1.4059    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    6.4662   -2.1482    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.5745   -2.0366    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.7624   -1.8914    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.4821   -1.1154    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.5776   -0.0491    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.9821   -1.9412    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.7942   -2.0864    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  2  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  6  0  0  0
  5  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  1  1  0  0  0
 10  9  1  6  0  0  0
 10 11  1  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  6  0  0  0
 13 15  1  0  0  0  0
 15 16  2  0  0  0  0
 16 17  1  0  0  0  0
 18 17  1  1  0  0  0
 18 19  1  0  0  0  0
 19 20  1  6  0  0  0
 20 21  1  0  0  0  0
 21 22  1  0  0  0  0
 22 23  1  1  0  0  0
 22 24  1  6  0  0  0
 24 25  1  1  0  0  0
 24 26  1  0  0  0  0
 27 26  1  6  0  0  0
 27 28  1  0  0  0  0
 28 29  1  0  0  0  0
 29 30  1  6  0  0  0
 29 31  1  0  0  0  0
 31 32  1  6  0  0  0
 31 33  1  0  0  0  0
 33 34  1  6  0  0  0
 33 35  1  0  0  0  0
 27 35  1  0  0  0  0
 22 36  1  0  0  0  0
 19 36  1  0  0  0  0
 36 37  1  6  0  0  0
 36 38  1  0  0  0  0
 38 39  1  0  0  0  0
 40 39  1  6  0  0  0
 18 40  1  0  0  0  0
 13 40  1  0  0  0  0
 15 41  1  0  0  0  0
 10 41  1  0  0  0  0
  8 42  1  0  0  0  0
  3 42  1  0  0  0  0
 42 43  2  0  0  0  0
M  END
> <DATABASE_ID>
NP0285895

> <DATABASE_NAME>
NP-MRD

> <SMILES>
COC1=C[C@H](C)O[C@@H](O[C@H]2CC[C@]3(C)[C@H]4CC[C@@]5(C)[C@@H](CC[C@]5(O)[C@H](C)O[C@@H]5C[C@H](O)[C@H](O)[C@H](C)O5)[C@@H]4CC=C3C2)C1=O

> <INCHI_IDENTIFIER>
InChI=1S/C34H52O9/c1-18-15-27(39-6)30(37)31(40-18)43-22-9-12-32(4)21(16-22)7-8-23-24(32)10-13-33(5)25(23)11-14-34(33,38)20(3)42-28-17-26(35)29(36)19(2)41-28/h7,15,18-20,22-26,28-29,31,35-36,38H,8-14,16-17H2,1-6H3/t18-,19-,20-,22-,23+,24-,25-,26-,28+,29+,31-,32-,33-,34-/m0/s1

> <INCHI_KEY>
CGUNKFNCRCGQRL-ZECAFWDFSA-N

> <FORMULA>
C34H52O9

> <MOLECULAR_WEIGHT>
604.781

> <EXACT_MASS>
604.361133254

> <JCHEM_ACCEPTOR_COUNT>
9

> <JCHEM_ATOM_COUNT>
95

> <JCHEM_AVERAGE_POLARIZABILITY>
68.2766247530305

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
3

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(2R,6S)-2-{[(1S,2R,5S,10R,11S,14R,15S)-14-[(1S)-1-{[(2R,4S,5S,6S)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-14-hydroxy-2,15-dimethyltetracyclo[8.7.0.0^{2,7}.0^{11,15}]heptadec-7-en-5-yl]oxy}-4-methoxy-6-methyl-3,6-dihydro-2H-pyran-3-one

> <JCHEM_LOGP>
3.8217322576666675

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
6

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
13.625181060121179

> <JCHEM_PKA_STRONGEST_ACIDIC>
12.981862835025336

> <JCHEM_PKA_STRONGEST_BASIC>
-3.2525593911592043

> <JCHEM_POLAR_SURFACE_AREA>
123.91000000000003

> <JCHEM_REFRACTIVITY>
160.7493

> <JCHEM_ROTATABLE_BOND_COUNT>
6

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(2R,6S)-2-{[(1S,2R,5S,10R,11S,14R,15S)-14-[(1S)-1-{[(2R,4S,5S,6S)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-14-hydroxy-2,15-dimethyltetracyclo[8.7.0.0^{2,7}.0^{11,15}]heptadec-7-en-5-yl]oxy}-4-methoxy-6-methyl-2,6-dihydropyran-3-one

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 09-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   09-SEP-22         0                                  
HETATM    1  C   UNK     0       0.371  -7.427   0.000  0.00  0.00           C+0
HETATM    2  O   UNK     0       1.364  -6.249   0.000  0.00  0.00           O+0
HETATM    3  C   UNK     0       0.841  -4.801   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -0.675  -4.530   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -1.199  -3.081   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -2.715  -2.810   0.000  0.00  0.00           C+0
HETATM    7  O   UNK     0      -0.206  -1.904   0.000  0.00  0.00           O+0
HETATM    8  C   UNK     0       1.310  -2.175   0.000  0.00  0.00           C+0
HETATM    9  O   UNK     0       2.303  -0.998   0.000  0.00  0.00           O+0
HETATM   10  C   UNK     0       3.819  -1.269   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       4.342  -2.717   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       5.858  -2.988   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       6.851  -1.811   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       7.374  -3.259   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       6.327  -0.363   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       7.320   0.815   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       8.836   0.544   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       9.359  -0.905   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0      10.875  -1.176   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0      12.091  -0.231   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0      13.366  -1.095   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      12.938  -2.574   0.000  0.00  0.00           C+0
HETATM   23  O   UNK     0      12.827  -4.110   0.000  0.00  0.00           O+0
HETATM   24  C   UNK     0      14.454  -2.845   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0      14.977  -4.294   0.000  0.00  0.00           C+0
HETATM   26  O   UNK     0      15.446  -1.668   0.000  0.00  0.00           O+0
HETATM   27  C   UNK     0      16.962  -1.939   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0      17.955  -0.762   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0      19.471  -1.033   0.000  0.00  0.00           C+0
HETATM   30  O   UNK     0      20.464   0.145   0.000  0.00  0.00           O+0
HETATM   31  C   UNK     0      19.994  -2.481   0.000  0.00  0.00           C+0
HETATM   32  O   UNK     0      21.510  -2.752   0.000  0.00  0.00           O+0
HETATM   33  C   UNK     0      19.002  -3.659   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0      19.525  -5.107   0.000  0.00  0.00           C+0
HETATM   35  O   UNK     0      17.486  -3.387   0.000  0.00  0.00           O+0
HETATM   36  C   UNK     0      11.399  -2.624   0.000  0.00  0.00           C+0
HETATM   37  C   UNK     0      12.070  -4.010   0.000  0.00  0.00           C+0
HETATM   38  C   UNK     0      10.406  -3.802   0.000  0.00  0.00           C+0
HETATM   39  C   UNK     0       8.890  -3.531   0.000  0.00  0.00           C+0
HETATM   40  C   UNK     0       8.367  -2.082   0.000  0.00  0.00           C+0
HETATM   41  C   UNK     0       4.811  -0.092   0.000  0.00  0.00           C+0
HETATM   42  C   UNK     0       1.833  -3.624   0.000  0.00  0.00           C+0
HETATM   43  O   UNK     0       3.349  -3.895   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4   42                                                  
CONECT    4    3    5                                                       
CONECT    5    4    6    7                                                  
CONECT    6    5                                                            
CONECT    7    5    8                                                       
CONECT    8    7    9   42                                                  
CONECT    9    8   10                                                       
CONECT   10    9   11   41                                                  
CONECT   11   10   12                                                       
CONECT   12   11   13                                                       
CONECT   13   12   14   15   40                                             
CONECT   14   13                                                            
CONECT   15   13   16   41                                                  
CONECT   16   15   17                                                       
CONECT   17   16   18                                                       
CONECT   18   17   19   40                                                  
CONECT   19   18   20   36                                                  
CONECT   20   19   21                                                       
CONECT   21   20   22                                                       
CONECT   22   21   23   24   36                                             
CONECT   23   22                                                            
CONECT   24   22   25   26                                                  
CONECT   25   24                                                            
CONECT   26   24   27                                                       
CONECT   27   26   28   35                                                  
CONECT   28   27   29                                                       
CONECT   29   28   30   31                                                  
CONECT   30   29                                                            
CONECT   31   29   32   33                                                  
CONECT   32   31                                                            
CONECT   33   31   34   35                                                  
CONECT   34   33                                                            
CONECT   35   33   27                                                       
CONECT   36   22   19   37   38                                             
CONECT   37   36                                                            
CONECT   38   36   39                                                       
CONECT   39   38   40                                                       
CONECT   40   39   18   13                                                  
CONECT   41   15   10                                                       
CONECT   42    8    3   43                                                  
CONECT   43   42                                                            
MASTER        0    0    0    0    0    0    0    0   43    0   96    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₃₄H₅₂O₉

Average Mass

604.7810 Da

Monoisotopic Mass

604.36113 Da

IUPAC Name

(2R,6S)-2-{[(1S,2R,5S,10R,11S,14R,15S)-14-[(1S)-1-{[(2R,4S,5S,6S)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-14-hydroxy-2,15-dimethyltetracyclo[8.7.0.0^{2,7}.0^{11,15}]heptadec-7-en-5-yl]oxy}-4-methoxy-6-methyl-3,6-dihydro-2H-pyran-3-one

Traditional Name

CAS Registry Number

Not Available

SMILES

COC1=C[C@H](C)O[C@@H](O[C@H]2CC[C@]3(C)[C@H]4CC[C@@]5(C)[C@@H](CC[C@]5(O)[C@H](C)O[C@@H]5C[C@H](O)[C@H](O)[C@H](C)O5)[C@@H]4CC=C3C2)C1=O

InChI Identifier

InChI=1S/C34H52O9/c1-18-15-27(39-6)30(37)31(40-18)43-22-9-12-32(4)21(16-22)7-8-23-24(32)10-13-33(5)25(23)11-14-34(33,38)20(3)42-28-17-26(35)29(36)19(2)41-28/h7,15,18-20,22-26,28-29,31,35-36,38H,8-14,16-17H2,1-6H3/t18-,19-,20-,22-,23+,24-,25-,26-,28+,29+,31-,32-,33-,34-/m0/s1

InChI Key

CGUNKFNCRCGQRL-ZECAFWDFSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Periploca sepium	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as steroidal glycosides. These are sterol lipids containing a carbohydrate moiety glycosidically linked to the steroid skeleton.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Steroids and steroid derivatives

Sub Class

Steroidal glycosides

Direct Parent

Steroidal glycosides

Alternative Parents

Substituents

Steroidal glycoside
Pregnane-skeleton
17-hydroxysteroid
Hydroxysteroid
Delta-5-steroid
O-glycosyl compound
Glycosyl compound
Dihydropyranone
Pyran
Oxane
Monosaccharide
Tertiary alcohol
Cyclic alcohol
Cyclic ketone
Secondary alcohol
Ketone
Oxacycle
Organoheterocyclic compound
Acetal
Organic oxygen compound
Organic oxide
Hydrocarbon derivative
Organooxygen compound
Carbonyl group
Alcohol
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	3.82	ChemAxon
pKa (Strongest Acidic)	12.98	ChemAxon
pKa (Strongest Basic)	-3.3	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	9	ChemAxon
Hydrogen Donor Count	3	ChemAxon
Polar Surface Area	123.91 Å²	ChemAxon
Rotatable Bond Count	6	ChemAxon
Refractivity	160.75 m³·mol⁻¹	ChemAxon
Polarizability	68.28 Å³	ChemAxon
Number of Rings	6	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

C00034115

Chemspider ID

113606395

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

134715182

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

Wang S, Yu X, Wu S, Yang W, Gao Y, Wang W, Wang Q, Wei M, Zhu M, Wu J, Yuan Z, Li Y: Simultaneous determination of periplocin, periplocymarin, periplogenin, periplocoside M and periplocoside N of Cortex Periplocae in rat plasma and its application to a pharmacokinetic study. Biomed Chromatogr. 2022 Mar;36(3):e5283. doi: 10.1002/bmc.5283. Epub 2021 Dec 8. [PubMed:34816469 ]
Lohberger B, Wagner S, Wohlmuther J, Kaltenegger H, Stuendl N, Leithner A, Rinner B, Kunert O, Bauer R, Kretschmer N: Periplocin, the most anti-proliferative constituent of Periploca sepium, specifically kills liposarcoma cells by death receptor mediated apoptosis. Phytomedicine. 2018 Dec 1;51:162-170. doi: 10.1016/j.phymed.2018.10.008. Epub 2018 Oct 11. [PubMed:30466613 ]
Xu R, Du J, Deng L, Yang F, Zhang J, Wang D, Zhang Y: [A new cardiac glycoside from Periploca forrestii]. Zhongguo Zhong Yao Za Zhi. 2012 Aug;37(15):2286-8. [PubMed:23189735 ]
LOTUS database [Link]

Showing NP-Card for (2r,6s)-2-{[(1r,3as,3br,7s,9ar,9bs,11as)-1-[(1s)-1-{[(2r,4s,5s,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-1-hydroxy-9a,11a-dimethyl-2h,3h,3ah,3bh,4h,6h,7h,8h,9h,9bh,10h,11h-cyclopenta[a]phenanthren-7-yl]oxy}-4-methoxy-6-methyl-2,6-dihydropyran-3-one (NP0285895)

MOL for NP0285895 ((2r,6s)-2-{[(1r,3as,3br,7s,9ar,9bs,11as)-1-[(1s)-1-{[(2r,4s,5s,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-1-hydroxy-9a,11a-dimethyl-2h,3h,3ah,3bh,4h,6h,7h,8h,9h,9bh,10h,11h-cyclopenta[a]phenanthren-7-yl]oxy}-4-methoxy-6-methyl-2,6-dihydropyran-3-one)

3D MOL for NP0285895 ((2r,6s)-2-{[(1r,3as,3br,7s,9ar,9bs,11as)-1-[(1s)-1-{[(2r,4s,5s,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-1-hydroxy-9a,11a-dimethyl-2h,3h,3ah,3bh,4h,6h,7h,8h,9h,9bh,10h,11h-cyclopenta[a]phenanthren-7-yl]oxy}-4-methoxy-6-methyl-2,6-dihydropyran-3-one)

3D SDF for NP0285895 ((2r,6s)-2-{[(1r,3as,3br,7s,9ar,9bs,11as)-1-[(1s)-1-{[(2r,4s,5s,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-1-hydroxy-9a,11a-dimethyl-2h,3h,3ah,3bh,4h,6h,7h,8h,9h,9bh,10h,11h-cyclopenta[a]phenanthren-7-yl]oxy}-4-methoxy-6-methyl-2,6-dihydropyran-3-one)

3D-SDF for NP0285895 ((2r,6s)-2-{[(1r,3as,3br,7s,9ar,9bs,11as)-1-[(1s)-1-{[(2r,4s,5s,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-1-hydroxy-9a,11a-dimethyl-2h,3h,3ah,3bh,4h,6h,7h,8h,9h,9bh,10h,11h-cyclopenta[a]phenanthren-7-yl]oxy}-4-methoxy-6-methyl-2,6-dihydropyran-3-one)

PDB for NP0285895 ((2r,6s)-2-{[(1r,3as,3br,7s,9ar,9bs,11as)-1-[(1s)-1-{[(2r,4s,5s,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-1-hydroxy-9a,11a-dimethyl-2h,3h,3ah,3bh,4h,6h,7h,8h,9h,9bh,10h,11h-cyclopenta[a]phenanthren-7-yl]oxy}-4-methoxy-6-methyl-2,6-dihydropyran-3-one)

3D PDB for NP0285895 ((2r,6s)-2-{[(1r,3as,3br,7s,9ar,9bs,11as)-1-[(1s)-1-{[(2r,4s,5s,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-1-hydroxy-9a,11a-dimethyl-2h,3h,3ah,3bh,4h,6h,7h,8h,9h,9bh,10h,11h-cyclopenta[a]phenanthren-7-yl]oxy}-4-methoxy-6-methyl-2,6-dihydropyran-3-one)

SMILES for NP0285895 ((2r,6s)-2-{[(1r,3as,3br,7s,9ar,9bs,11as)-1-[(1s)-1-{[(2r,4s,5s,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-1-hydroxy-9a,11a-dimethyl-2h,3h,3ah,3bh,4h,6h,7h,8h,9h,9bh,10h,11h-cyclopenta[a]phenanthren-7-yl]oxy}-4-methoxy-6-methyl-2,6-dihydropyran-3-one)

INCHI for NP0285895 ((2r,6s)-2-{[(1r,3as,3br,7s,9ar,9bs,11as)-1-[(1s)-1-{[(2r,4s,5s,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-1-hydroxy-9a,11a-dimethyl-2h,3h,3ah,3bh,4h,6h,7h,8h,9h,9bh,10h,11h-cyclopenta[a]phenanthren-7-yl]oxy}-4-methoxy-6-methyl-2,6-dihydropyran-3-one)

Structure for NP0285895 ((2r,6s)-2-{[(1r,3as,3br,7s,9ar,9bs,11as)-1-[(1s)-1-{[(2r,4s,5s,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-1-hydroxy-9a,11a-dimethyl-2h,3h,3ah,3bh,4h,6h,7h,8h,9h,9bh,10h,11h-cyclopenta[a]phenanthren-7-yl]oxy}-4-methoxy-6-methyl-2,6-dihydropyran-3-one)

3D Structure for NP0285895 ((2r,6s)-2-{[(1r,3as,3br,7s,9ar,9bs,11as)-1-[(1s)-1-{[(2r,4s,5s,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}ethyl]-1-hydroxy-9a,11a-dimethyl-2h,3h,3ah,3bh,4h,6h,7h,8h,9h,9bh,10h,11h-cyclopenta[a]phenanthren-7-yl]oxy}-4-methoxy-6-methyl-2,6-dihydropyran-3-one)