NP-MRD: Showing NP-Card for (1s,2s,3r,5r,9s,10r)-5-ethenyl-2,3,9,10-tetrahydroxy-5,11,11-trimethyl-16-oxatetracyclo[7.5.2.0¹,¹⁰.0²,⁷]hexadec-6-en-8-one (NP0274636)

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Record Information

Version

2.0

Created at

2022-09-08 22:06:14 UTC

Updated at

2022-09-08 22:06:15 UTC

NP-MRD ID

NP0274636

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1s,2s,3r,5r,9s,10r)-5-ethenyl-2,3,9,10-tetrahydroxy-5,11,11-trimethyl-16-oxatetracyclo[7.5.2.0¹,¹⁰.0²,⁷]hexadec-6-en-8-one

Description

DiaportheinB belongs to the class of organic compounds known as oxepanes. Oxepanes are compounds containing an oxepane ring, which is a seven-member saturated aliphatic heterocycle with one oxygen and six carbon atoms. (1s,2s,3r,5r,9s,10r)-5-ethenyl-2,3,9,10-tetrahydroxy-5,11,11-trimethyl-16-oxatetracyclo[7.5.2.0¹,¹⁰.0²,⁷]hexadec-6-en-8-one is found in Garcinia dulcis and Peroneutypa scoparia. Based on a literature review very few articles have been published on DiaportheinB.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309092200062D          

 26 29  0  0  1  0            999 V2000
    5.0989    2.9071    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.2964    2.1061    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.7015    1.5345    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    5.3677    1.0479    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.2419    2.2197    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.4188    2.1642    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.0665    2.9102    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5857    3.5513    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.2636    3.0999    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.0861    3.9056    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.6147    2.5904    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.6084    1.7654    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.2495    1.2462    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.6521    0.6772    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.8607    0.9101    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.6667    1.7120    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.2641    2.2810    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.6000    2.7705    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.6309    3.0199    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.0555    2.0481    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.8803    2.0654    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.0552    1.4237    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.7480    0.6580    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.5148    0.7385    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.1512   -0.0020    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.3379    0.7940    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  2  0  0  0  0
  3  2  1  1  0  0  0
  3  4  1  6  0  0  0
  3  5  1  0  0  0  0
  5  6  2  0  0  0  0
  6  7  1  0  0  0  0
  7  8  2  0  0  0  0
  7  9  1  0  0  0  0
  9 10  1  1  0  0  0
  9 11  1  0  0  0  0
 11 12  1  0  0  0  0
 13 12  1  6  0  0  0
 13 14  1  0  0  0  0
 14 15  1  0  0  0  0
 15 16  1  0  0  0  0
 16 17  1  0  0  0  0
 17 18  1  0  0  0  0
 17 19  1  0  0  0  0
 17 20  1  0  0  0  0
  9 20  1  0  0  0  0
 13 20  1  0  0  0  0
 20 21  1  1  0  0  0
 13 22  1  0  0  0  0
  6 22  1  0  0  0  0
 22 23  1  1  0  0  0
 22 24  1  0  0  0  0
 24 25  1  1  0  0  0
 24 26  1  0  0  0  0
  3 26  1  0  0  0  0
M  END

     RDKit          3D

 54 57  0  0  0  0  0  0  0  0999 V2000
    5.6838   -0.2340   -0.6581 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.6094   -0.9898   -0.5020 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.4142   -0.3641    0.1220 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.9135    0.3206    1.3957 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.3504   -1.3316    0.4062 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.0608   -1.1428    0.1777 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0283   -2.1259    0.4735 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.3605   -3.3239    0.5168 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3807   -1.7233    0.7181 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.2464   -2.7689    0.6717 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3805   -1.0439    1.9388 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.5803    0.0726    1.7177 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7171    0.4452    0.2555 C   0  0  2  0  0  0  0  0  0  0  0  0
   -1.2110    1.8421    0.1162 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4704    2.0307    0.9062 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3336    0.8200    0.9914 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.1147   -0.1221   -0.1464 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.4229    0.6394   -1.4328 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.1187   -1.2449   -0.0321 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7055   -0.5932   -0.2276 C   0  0  2  0  0  0  0  0  0  0  0  0
   -1.4539   -1.0325   -1.5113 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.5709    0.1543   -0.4247 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.4605   -0.0560   -1.7967 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.6064    1.2365   -0.2264 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.2478    2.3121   -1.0372 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.9039    0.6790   -0.8324 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.6037   -0.6211   -1.1095 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.7252    0.8010   -0.3553 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.6553   -2.0196   -0.8349 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.0429    0.3489    2.0961 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.7173   -0.2646    1.8811 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.2160    1.3665    1.1652 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.6551   -2.2971    0.8463 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1233   -3.3264    1.4752 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.4587   -0.2206    1.9689 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.8768    0.8951    2.3968 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3076    2.1300   -0.9421 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4478    2.5162    0.5578 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2475    2.3508    1.9663 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.0080    2.9162    0.4690 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.4051    1.1707    0.9190 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.2760    0.3225    1.9886 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.6499    1.7026   -1.2430 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.3267    0.2229   -1.9443 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.5970    0.5273   -2.1784 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.2420   -1.5950    1.0121 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.1158   -0.7886   -0.3037 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.9531   -2.0452   -0.7604 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.8428   -1.9409   -1.6333 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.8338   -0.9217   -2.0839 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.7304    1.4931    0.8256 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.4961    3.1811   -0.6841 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.6227    1.4911   -1.0291 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.5873    0.1489   -1.7629 H   0  0  0  0  0  0  0  0  0  0  0  0
 18 17  1  0
 17 19  1  0
 17 16  1  0
 16 15  1  0
 15 14  1  0
 13 14  1  1
 13 12  1  0
 12 11  1  0
 11  9  1  0
  9 10  1  1
  9  7  1  0
  7  8  2  0
  7  6  1  0
  6  5  2  0
  5  3  1  0
  3  4  1  0
  3 26  1  0
 26 24  1  0
 24 25  1  0
 24 22  1  0
 22 23  1  6
  3  2  1  6
  2  1  2  3
  9 20  1  0
 20 21  1  6
 20 17  1  0
 22 13  1  0
 20 13  1  0
 22  6  1  0
 18 43  1  0
 18 44  1  0
 18 45  1  0
 19 46  1  0
 19 47  1  0
 19 48  1  0
 16 41  1  0
 16 42  1  0
 15 39  1  0
 15 40  1  0
 14 37  1  0
 14 38  1  0
 12 35  1  0
 12 36  1  0
 10 34  1  0
  5 33  1  0
  4 30  1  0
  4 31  1  0
  4 32  1  0
 26 53  1  0
 26 54  1  0
 24 51  1  1
 25 52  1  0
 23 50  1  0
  2 29  1  0
  1 27  1  0
  1 28  1  0
 21 49  1  0
M  END


  Mrv1652309092200062D          

 26 29  0  0  1  0            999 V2000
    5.0989    2.9071    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.2964    2.1061    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.7015    1.5345    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    5.3677    1.0479    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.2419    2.2197    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.4188    2.1642    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.0665    2.9102    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5857    3.5513    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.2636    3.0999    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.0861    3.9056    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.6147    2.5904    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.6084    1.7654    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.2495    1.2462    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.6521    0.6772    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.8607    0.9101    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.6667    1.7120    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.2641    2.2810    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.6000    2.7705    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.6309    3.0199    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.0555    2.0481    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.8803    2.0654    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.0552    1.4237    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.7480    0.6580    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.5148    0.7385    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.1512   -0.0020    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.3379    0.7940    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  2  0  0  0  0
  3  2  1  1  0  0  0
  3  4  1  6  0  0  0
  3  5  1  0  0  0  0
  5  6  2  0  0  0  0
  6  7  1  0  0  0  0
  7  8  2  0  0  0  0
  7  9  1  0  0  0  0
  9 10  1  1  0  0  0
  9 11  1  0  0  0  0
 11 12  1  0  0  0  0
 13 12  1  6  0  0  0
 13 14  1  0  0  0  0
 14 15  1  0  0  0  0
 15 16  1  0  0  0  0
 16 17  1  0  0  0  0
 17 18  1  0  0  0  0
 17 19  1  0  0  0  0
 17 20  1  0  0  0  0
  9 20  1  0  0  0  0
 13 20  1  0  0  0  0
 20 21  1  1  0  0  0
 13 22  1  0  0  0  0
  6 22  1  0  0  0  0
 22 23  1  1  0  0  0
 22 24  1  0  0  0  0
 24 25  1  1  0  0  0
 24 26  1  0  0  0  0
  3 26  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0274636

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC1(C)CCC[C@]23CO[C@](O)(C(=O)C4=C[C@](C)(C[C@@H](O)[C@]24O)C=C)[C@@]13O

> <INCHI_IDENTIFIER>
InChI=1S/C20H28O6/c1-5-16(4)9-12-14(22)19(24)20(25)15(2,3)7-6-8-17(20,11-26-19)18(12,23)13(21)10-16/h5,9,13,21,23-25H,1,6-8,10-11H2,2-4H3/t13-,16-,17+,18+,19-,20-/m1/s1

> <INCHI_KEY>
FVYIOIBMUVNZMQ-KNHLKMAJSA-N

> <FORMULA>
C20H28O6

> <MOLECULAR_WEIGHT>
364.438

> <EXACT_MASS>
364.188588622

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
54

> <JCHEM_AVERAGE_POLARIZABILITY>
38.05792458024959

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
4

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
1

> <JCHEM_IUPAC>
(1S,2S,3R,5R,9S,10R)-5-ethenyl-2,3,9,10-tetrahydroxy-5,11,11-trimethyl-16-oxatetracyclo[7.5.2.0^{1,10}.0^{2,7}]hexadec-6-en-8-one

> <JCHEM_LOGP>
1.4107069926666673

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
12.363153807283794

> <JCHEM_PKA_STRONGEST_ACIDIC>
9.260616547491734

> <JCHEM_PKA_STRONGEST_BASIC>
-3.2994762999639766

> <JCHEM_POLAR_SURFACE_AREA>
107.22000000000001

> <JCHEM_REFRACTIVITY>
94.41169999999998

> <JCHEM_ROTATABLE_BOND_COUNT>
1

> <JCHEM_RULE_OF_FIVE>
1

> <JCHEM_TRADITIONAL_IUPAC>
(1S,2S,3R,5R,9S,10R)-5-ethenyl-2,3,9,10-tetrahydroxy-5,11,11-trimethyl-16-oxatetracyclo[7.5.2.0^{1,10}.0^{2,7}]hexadec-6-en-8-one

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 09-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   09-SEP-22         0                                  
HETATM    1  C   UNK     0       9.518   5.427   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       9.887   3.931   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       8.776   2.864   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      10.020   1.956   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       7.918   4.143   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       6.382   4.040   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       5.724   5.432   0.000  0.00  0.00           C+0
HETATM    8  O   UNK     0       6.693   6.629   0.000  0.00  0.00           O+0
HETATM    9  C   UNK     0       4.225   5.786   0.000  0.00  0.00           C+0
HETATM   10  O   UNK     0       3.894   7.290   0.000  0.00  0.00           O+0
HETATM   11  O   UNK     0       3.014   4.835   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0       3.002   3.296   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       4.199   2.326   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       3.084   1.264   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       1.607   1.699   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       1.244   3.196   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       2.360   4.258   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       1.120   5.172   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       3.044   5.637   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       3.837   3.823   0.000  0.00  0.00           C+0
HETATM   21  O   UNK     0       5.377   3.855   0.000  0.00  0.00           O+0
HETATM   22  C   UNK     0       5.703   2.658   0.000  0.00  0.00           C+0
HETATM   23  O   UNK     0       5.130   1.228   0.000  0.00  0.00           O+0
HETATM   24  C   UNK     0       6.561   1.379   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0       5.882  -0.004   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0       8.097   1.482   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4    5   26                                             
CONECT    4    3                                                            
CONECT    5    3    6                                                       
CONECT    6    5    7   22                                                  
CONECT    7    6    8    9                                                  
CONECT    8    7                                                            
CONECT    9    7   10   11   20                                             
CONECT   10    9                                                            
CONECT   11    9   12                                                       
CONECT   12   11   13                                                       
CONECT   13   12   14   20   22                                             
CONECT   14   13   15                                                       
CONECT   15   14   16                                                       
CONECT   16   15   17                                                       
CONECT   17   16   18   19   20                                             
CONECT   18   17                                                            
CONECT   19   17                                                            
CONECT   20   17    9   13   21                                             
CONECT   21   20                                                            
CONECT   22   13    6   23   24                                             
CONECT   23   22                                                            
CONECT   24   22   25   26                                                  
CONECT   25   24                                                            
CONECT   26   24    3                                                       
MASTER        0    0    0    0    0    0    0    0   26    0   58    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₀H₂₈O₆

Average Mass

364.4380 Da

Monoisotopic Mass

364.18859 Da

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

CC1(C)CCC[C@]23CO[C@](O)(C(=O)C4=C[C@](C)(C[C@@H](O)[C@]24O)C=C)[C@@]13O

InChI Identifier

InChI=1S/C20H28O6/c1-5-16(4)9-12-14(22)19(24)20(25)15(2,3)7-6-8-17(20,11-26-19)18(12,23)13(21)10-16/h5,9,13,21,23-25H,1,6-8,10-11H2,2-4H3/t13-,16-,17+,18+,19-,20-/m1/s1

InChI Key

FVYIOIBMUVNZMQ-KNHLKMAJSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Garcinia dulcis	LOTUS Database	35616633
Peroneutypa scoparia	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as oxepanes. Oxepanes are compounds containing an oxepane ring, which is a seven-member saturated aliphatic heterocycle with one oxygen and six carbon atoms.

Kingdom

Organic compounds

Super Class

Organoheterocyclic compounds

Class

Oxepanes

Sub Class

Not Available

Direct Parent

Oxepanes

Alternative Parents

Substituents

Oxepane
Cyclic alcohol
Tetrahydrofuran
Tertiary alcohol
Hemiacetal
Ketone
Secondary alcohol
Oxacycle
Polyol
Organooxygen compound
Hydrocarbon derivative
Organic oxide
Organic oxygen compound
Carbonyl group
Alcohol
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

23076661

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

70695904

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (1s,2s,3r,5r,9s,10r)-5-ethenyl-2,3,9,10-tetrahydroxy-5,11,11-trimethyl-16-oxatetracyclo[7.5.2.0¹,¹⁰.0²,⁷]hexadec-6-en-8-one (NP0274636)

MOL for NP0274636 ((1s,2s,3r,5r,9s,10r)-5-ethenyl-2,3,9,10-tetrahydroxy-5,11,11-trimethyl-16-oxatetracyclo[7.5.2.0¹,¹⁰.0²,⁷]hexadec-6-en-8-one)

3D MOL for NP0274636 ((1s,2s,3r,5r,9s,10r)-5-ethenyl-2,3,9,10-tetrahydroxy-5,11,11-trimethyl-16-oxatetracyclo[7.5.2.0¹,¹⁰.0²,⁷]hexadec-6-en-8-one)

3D SDF for NP0274636 ((1s,2s,3r,5r,9s,10r)-5-ethenyl-2,3,9,10-tetrahydroxy-5,11,11-trimethyl-16-oxatetracyclo[7.5.2.0¹,¹⁰.0²,⁷]hexadec-6-en-8-one)

3D-SDF for NP0274636 ((1s,2s,3r,5r,9s,10r)-5-ethenyl-2,3,9,10-tetrahydroxy-5,11,11-trimethyl-16-oxatetracyclo[7.5.2.0¹,¹⁰.0²,⁷]hexadec-6-en-8-one)

PDB for NP0274636 ((1s,2s,3r,5r,9s,10r)-5-ethenyl-2,3,9,10-tetrahydroxy-5,11,11-trimethyl-16-oxatetracyclo[7.5.2.0¹,¹⁰.0²,⁷]hexadec-6-en-8-one)

3D PDB for NP0274636 ((1s,2s,3r,5r,9s,10r)-5-ethenyl-2,3,9,10-tetrahydroxy-5,11,11-trimethyl-16-oxatetracyclo[7.5.2.0¹,¹⁰.0²,⁷]hexadec-6-en-8-one)

SMILES for NP0274636 ((1s,2s,3r,5r,9s,10r)-5-ethenyl-2,3,9,10-tetrahydroxy-5,11,11-trimethyl-16-oxatetracyclo[7.5.2.0¹,¹⁰.0²,⁷]hexadec-6-en-8-one)

INCHI for NP0274636 ((1s,2s,3r,5r,9s,10r)-5-ethenyl-2,3,9,10-tetrahydroxy-5,11,11-trimethyl-16-oxatetracyclo[7.5.2.0¹,¹⁰.0²,⁷]hexadec-6-en-8-one)

Structure for NP0274636 ((1s,2s,3r,5r,9s,10r)-5-ethenyl-2,3,9,10-tetrahydroxy-5,11,11-trimethyl-16-oxatetracyclo[7.5.2.0¹,¹⁰.0²,⁷]hexadec-6-en-8-one)

3D Structure for NP0274636 ((1s,2s,3r,5r,9s,10r)-5-ethenyl-2,3,9,10-tetrahydroxy-5,11,11-trimethyl-16-oxatetracyclo[7.5.2.0¹,¹⁰.0²,⁷]hexadec-6-en-8-one)