NP-MRD: Showing NP-Card for (1s,2s,3s,5s,8s,10s,14s)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0³,⁸]pentadec-11-en-14-yl (2r,3s)-3-hydroxy-2-methylbutanoate (NP0264226)

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Record Information

Version

2.0

Created at

2022-09-08 07:40:39 UTC

Updated at

2022-09-08 07:40:40 UTC

NP-MRD ID

NP0264226

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1s,2s,3s,5s,8s,10s,14s)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0³,⁸]pentadec-11-en-14-yl (2r,3s)-3-hydroxy-2-methylbutanoate

Description

10-Deacetylyunnanxane belongs to the class of organic compounds known as taxanes and derivatives. These are diterpenoids with a structure based either on the taxane skeleton, or a derivative thereof. In term of phytochemistry, several derivatives of the taxane skeleton exist: 2(3->20)-Abeotaxane, 3,11-cyclotaxane, 11(15->1),11(10->9)-abeotaxane, 3,8-seco-taxane, and 11(15->1)-abeotaxane, among others. More complex skeletons have been found recently, which include the taxane-derived [3.3.3] Propellane ring system. (1s,2s,3s,5s,8s,10s,14s)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0³,⁸]pentadec-11-en-14-yl (2r,3s)-3-hydroxy-2-methylbutanoate is found in Taxus media. Based on a literature review very few articles have been published on 10-Deacetylyunnanxane.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309082209402D          

 37 39  0  0  1  0            999 V2000
    0.1752    5.1187    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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 28 35  1  0  0  0  0
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M  END

     RDKit          3D

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M  END


  Mrv1652309082209402D          

 37 39  0  0  1  0            999 V2000
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    4.6149    1.7087    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.0250    2.9970    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.4657    3.6675    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.8743    4.3842    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.6993    4.3886    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1080    5.1053    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1157    3.6764    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3902    3.8064    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.5923    2.3741    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0834    3.0235    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.2256    2.4827    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  2  0  0  0  0
  2  3  1  0  0  0  0
  3  4  1  6  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  5  7  2  0  0  0  0
  3  8  1  0  0  0  0
  8  9  1  0  0  0  0
  9 10  1  0  0  0  0
 10 11  1  1  0  0  0
 10 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  1  0  0  0
 13 15  1  0  0  0  0
 15 16  2  0  0  0  0
 16 17  1  0  0  0  0
 16 18  1  0  0  0  0
 18 19  1  0  0  0  0
 19 20  1  1  0  0  0
 20 21  1  0  0  0  0
 21 22  2  0  0  0  0
 21 23  1  0  0  0  0
 23 24  1  6  0  0  0
 23 25  1  0  0  0  0
 25 26  1  0  0  0  0
 25 27  1  6  0  0  0
 28 19  1  6  0  0  0
 28 29  1  0  0  0  0
 29 30  1  6  0  0  0
 30 31  1  0  0  0  0
 31 32  1  0  0  0  0
 31 33  2  0  0  0  0
 29 34  1  0  0  0  0
 34  2  1  1  0  0  0
 10 34  1  0  0  0  0
 28 35  1  0  0  0  0
 15 35  1  0  0  0  0
 35 36  1  0  0  0  0
 35 37  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0264226

> <DATABASE_NAME>
NP-MRD

> <SMILES>
C[C@H](O)[C@@H](C)C(=O)O[C@H]1CC(C)=C2[C@@H](O)C[C@]3(C)CC[C@H](OC(C)=O)C(=C)[C@H]3[C@H](OC(C)=O)[C@H]1C2(C)C

> <INCHI_IDENTIFIER>
InChI=1S/C29H44O8/c1-14-12-22(37-27(34)15(2)17(4)30)25-26(36-19(6)32)24-16(3)21(35-18(5)31)10-11-29(24,9)13-20(33)23(14)28(25,7)8/h15,17,20-22,24-26,30,33H,3,10-13H2,1-2,4-9H3/t15-,17+,20+,21+,22+,24+,25+,26+,29+/m1/s1

> <INCHI_KEY>
OKVOKMSHJWDUMH-UOIGVGIGSA-N

> <FORMULA>
C29H44O8

> <MOLECULAR_WEIGHT>
520.663

> <EXACT_MASS>
520.303618377

> <JCHEM_ACCEPTOR_COUNT>
5

> <JCHEM_ATOM_COUNT>
81

> <JCHEM_AVERAGE_POLARIZABILITY>
55.53825240007243

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
2

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(1S,2S,3S,5S,8S,10S,14S)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0^{3,8}]pentadec-11-en-14-yl (2R,3S)-3-hydroxy-2-methylbutanoate

> <JCHEM_LOGP>
2.440255530333334

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
3

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA_STRONGEST_ACIDIC>
15.027480528833948

> <JCHEM_PKA_STRONGEST_BASIC>
-0.47865709982328564

> <JCHEM_POLAR_SURFACE_AREA>
119.36000000000001

> <JCHEM_REFRACTIVITY>
137.12450000000004

> <JCHEM_ROTATABLE_BOND_COUNT>
8

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(1S,2S,3S,5S,8S,10S,14S)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0^{3,8}]pentadec-11-en-14-yl (2R,3S)-3-hydroxy-2-methylbutanoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 08-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   08-SEP-22         0                                  
HETATM    1  C   UNK     0       0.327   9.555   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      -0.908   8.635   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      -2.322   9.244   0.000  0.00  0.00           C+0
HETATM    4  O   UNK     0      -2.502  10.774   0.000  0.00  0.00           O+0
HETATM    5  C   UNK     0      -3.916  11.383   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -4.095  12.912   0.000  0.00  0.00           C+0
HETATM    7  O   UNK     0      -5.151  10.463   0.000  0.00  0.00           O+0
HETATM    8  C   UNK     0      -3.557   8.324   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0      -3.378   6.794   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0      -1.963   6.185   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0      -3.293   5.409   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      -2.132   4.624   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      -1.094   3.409   0.000  0.00  0.00           C+0
HETATM   14  O   UNK     0      -1.850   2.068   0.000  0.00  0.00           O+0
HETATM   15  C   UNK     0       0.514   3.145   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       1.953   2.408   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       1.967   0.868   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       3.344   3.153   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       3.280   4.730   0.000  0.00  0.00           C+0
HETATM   20  O   UNK     0       4.613   5.500   0.000  0.00  0.00           O+0
HETATM   21  C   UNK     0       5.947   4.730   0.000  0.00  0.00           C+0
HETATM   22  O   UNK     0       5.947   3.190   0.000  0.00  0.00           O+0
HETATM   23  C   UNK     0       7.281   5.500   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       7.281   7.040   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0       8.614   4.730   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0       9.948   5.500   0.000  0.00  0.00           C+0
HETATM   27  O   UNK     0       8.614   3.190   0.000  0.00  0.00           O+0
HETATM   28  C   UNK     0       1.913   5.594   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       0.869   6.846   0.000  0.00  0.00           C+0
HETATM   30  O   UNK     0       1.632   8.184   0.000  0.00  0.00           O+0
HETATM   31  C   UNK     0       3.172   8.192   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0       3.935   9.530   0.000  0.00  0.00           C+0
HETATM   33  O   UNK     0       3.949   6.863   0.000  0.00  0.00           O+0
HETATM   34  C   UNK     0      -0.728   7.105   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0       1.106   4.432   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0       0.156   5.644   0.000  0.00  0.00           C+0
HETATM   37  C   UNK     0      -0.421   4.634   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3   34                                                  
CONECT    3    2    4    8                                                  
CONECT    4    3    5                                                       
CONECT    5    4    6    7                                                  
CONECT    6    5                                                            
CONECT    7    5                                                            
CONECT    8    3    9                                                       
CONECT    9    8   10                                                       
CONECT   10    9   11   12   34                                             
CONECT   11   10                                                            
CONECT   12   10   13                                                       
CONECT   13   12   14   15                                                  
CONECT   14   13                                                            
CONECT   15   13   16   35                                                  
CONECT   16   15   17   18                                                  
CONECT   17   16                                                            
CONECT   18   16   19                                                       
CONECT   19   18   20   28                                                  
CONECT   20   19   21                                                       
CONECT   21   20   22   23                                                  
CONECT   22   21                                                            
CONECT   23   21   24   25                                                  
CONECT   24   23                                                            
CONECT   25   23   26   27                                                  
CONECT   26   25                                                            
CONECT   27   25                                                            
CONECT   28   19   29   35                                                  
CONECT   29   28   30   34                                                  
CONECT   30   29   31                                                       
CONECT   31   30   32   33                                                  
CONECT   32   31                                                            
CONECT   33   31                                                            
CONECT   34   29    2   10                                                  
CONECT   35   28   15   36   37                                             
CONECT   36   35                                                            
CONECT   37   35                                                            
MASTER        0    0    0    0    0    0    0    0   37    0   78    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₉H₄₄O₈

Average Mass

520.6630 Da

Monoisotopic Mass

520.30362 Da

IUPAC Name

(1S,2S,3S,5S,8S,10S,14S)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0^{3,8}]pentadec-11-en-14-yl (2R,3S)-3-hydroxy-2-methylbutanoate

Traditional Name

(1S,2S,3S,5S,8S,10S,14S)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0^{3,8}]pentadec-11-en-14-yl (2R,3S)-3-hydroxy-2-methylbutanoate

CAS Registry Number

Not Available

SMILES

C[C@H](O)[C@@H](C)C(=O)O[C@H]1CC(C)=C2[C@@H](O)C[C@]3(C)CC[C@H](OC(C)=O)C(=C)[C@H]3[C@H](OC(C)=O)[C@H]1C2(C)C

InChI Identifier

InChI=1S/C29H44O8/c1-14-12-22(37-27(34)15(2)17(4)30)25-26(36-19(6)32)24-16(3)21(35-18(5)31)10-11-29(24,9)13-20(33)23(14)28(25,7)8/h15,17,20-22,24-26,30,33H,3,10-13H2,1-2,4-9H3/t15-,17+,20+,21+,22+,24+,25+,26+,29+/m1/s1

InChI Key

OKVOKMSHJWDUMH-UOIGVGIGSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Taxus media	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as taxanes and derivatives. These are diterpenoids with a structure based either on the taxane skeleton, or a derivative thereof. In term of phytochemistry, several derivatives of the taxane skeleton exist: 2(3->20)-Abeotaxane, 3,11-cyclotaxane, 11(15->1),11(10->9)-abeotaxane, 3,8-seco-taxane, and 11(15->1)-abeotaxane, among others. More complex skeletons have been found recently, which include the taxane-derived [3.3.3] Propellane ring system.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Diterpenoids

Direct Parent

Taxanes and derivatives

Alternative Parents

Substituents

Taxane diterpenoid
Tricarboxylic acid or derivatives
Beta-hydroxy acid
Fatty acid ester
Fatty acyl
Hydroxy acid
Carboxylic acid ester
Secondary alcohol
Carboxylic acid derivative
Hydrocarbon derivative
Organic oxide
Alcohol
Carbonyl group
Organic oxygen compound
Organooxygen compound
Aliphatic homopolycyclic compound

Molecular Framework

Aliphatic homopolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	2.44	ChemAxon
pKa (Strongest Acidic)	15.03	ChemAxon
pKa (Strongest Basic)	-0.48	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	5	ChemAxon
Hydrogen Donor Count	2	ChemAxon
Polar Surface Area	119.36 Å²	ChemAxon
Rotatable Bond Count	8	ChemAxon
Refractivity	137.12 m³·mol⁻¹	ChemAxon
Polarizability	55.54 Å³	ChemAxon
Number of Rings	3	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

62783364

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

101683508

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (1s,2s,3s,5s,8s,10s,14s)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0³,⁸]pentadec-11-en-14-yl (2r,3s)-3-hydroxy-2-methylbutanoate (NP0264226)

MOL for NP0264226 ((1s,2s,3s,5s,8s,10s,14s)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0³,⁸]pentadec-11-en-14-yl (2r,3s)-3-hydroxy-2-methylbutanoate)

3D MOL for NP0264226 ((1s,2s,3s,5s,8s,10s,14s)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0³,⁸]pentadec-11-en-14-yl (2r,3s)-3-hydroxy-2-methylbutanoate)

3D SDF for NP0264226 ((1s,2s,3s,5s,8s,10s,14s)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0³,⁸]pentadec-11-en-14-yl (2r,3s)-3-hydroxy-2-methylbutanoate)

3D-SDF for NP0264226 ((1s,2s,3s,5s,8s,10s,14s)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0³,⁸]pentadec-11-en-14-yl (2r,3s)-3-hydroxy-2-methylbutanoate)

PDB for NP0264226 ((1s,2s,3s,5s,8s,10s,14s)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0³,⁸]pentadec-11-en-14-yl (2r,3s)-3-hydroxy-2-methylbutanoate)

3D PDB for NP0264226 ((1s,2s,3s,5s,8s,10s,14s)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0³,⁸]pentadec-11-en-14-yl (2r,3s)-3-hydroxy-2-methylbutanoate)

SMILES for NP0264226 ((1s,2s,3s,5s,8s,10s,14s)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0³,⁸]pentadec-11-en-14-yl (2r,3s)-3-hydroxy-2-methylbutanoate)

INCHI for NP0264226 ((1s,2s,3s,5s,8s,10s,14s)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0³,⁸]pentadec-11-en-14-yl (2r,3s)-3-hydroxy-2-methylbutanoate)

Structure for NP0264226 ((1s,2s,3s,5s,8s,10s,14s)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0³,⁸]pentadec-11-en-14-yl (2r,3s)-3-hydroxy-2-methylbutanoate)

3D Structure for NP0264226 ((1s,2s,3s,5s,8s,10s,14s)-2,5-bis(acetyloxy)-10-hydroxy-8,12,15,15-tetramethyl-4-methylidenetricyclo[9.3.1.0³,⁸]pentadec-11-en-14-yl (2r,3s)-3-hydroxy-2-methylbutanoate)