NP-MRD: Showing NP-Card for (1s,2r,6r,9s,10r,11s,14r,15r,17s,18s,20s,23r,24s)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0²,¹¹.0⁴,⁹.0¹⁵,²⁴.0¹⁸,²³]pentacosane-14,17,20-triol (NP0264071)

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Record Information

Version

2.0

Created at

2022-09-08 07:28:40 UTC

Updated at

2022-09-08 07:28:40 UTC

NP-MRD ID

NP0264071

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1s,2r,6r,9s,10r,11s,14r,15r,17s,18s,20s,23r,24s)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0²,¹¹.0⁴,⁹.0¹⁵,²⁴.0¹⁸,²³]pentacosane-14,17,20-triol

Description

(1s,2r,6r,9s,10r,11s,14r,15r,17s,18s,20s,23r,24s)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0²,¹¹.0⁴,⁹.0¹⁵,²⁴.0¹⁸,²³]pentacosane-14,17,20-triol is found in Fritillaria sewerzowii.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652305021823122D          

 38 43  0  0  0  0            999 V2000
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   -4.7770   -0.4357    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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   -1.3058    0.1162    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -1.6413    0.8699    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
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  1  2  1  0  0  0  0
  1  5  1  0  0  0  0
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  9 12  1  0  0  0  0
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 19 24  1  0  0  0  0
 23 37  1  6  0  0  0
 18 38  1  6  0  0  0
M  END

     RDKit          3D

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M  END


  Mrv1652305021823122D          

 38 43  0  0  0  0            999 V2000
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   -2.0051    0.3847    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0509   -0.6684    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0538    1.5843    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.8208    0.7836    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6713    2.2047    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.9696    2.0323    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.1926    5.1334    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.5218    3.6259    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  1  5  1  0  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  6  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  1  0  0  0  0
  5  9  1  0  0  0  0
  4  6  1  0  0  0  0
 10 11  1  0  0  0  0
 11 12  1  0  0  0  0
  9 12  1  0  0  0  0
  8 10  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  1  0  0  0  0
 15 16  1  0  0  0  0
 11 16  1  0  0  0  0
 10 13  1  0  0  0  0
 17 18  1  0  0  0  0
 16 20  1  0  0  0  0
 15 17  1  0  0  0  0
 21 22  1  0  0  0  0
 22 23  1  0  0  0  0
 23 24  1  0  0  0  0
 18 21  1  0  0  0  0
  4 26  1  6  0  0  0
  5 27  1  1  0  0  0
  6 28  1  6  0  0  0
  9 29  1  6  0  0  0
  2 30  1  0  0  0  0
 30  3  1  0  0  0  0
 30 25  1  1  0  0  0
  8 31  1  1  0  0  0
 10 32  1  6  0  0  0
 11 33  1  6  0  0  0
 16 34  1  1  0  0  0
 17 36  1  6  0  0  0
 15 35  1  6  0  0  0
 18 19  1  0  0  0  0
 19 20  1  0  0  0  0
 19 24  1  0  0  0  0
 23 37  1  6  0  0  0
 18 38  1  6  0  0  0
M  END
> <DATABASE_ID>
NP0264071

> <DATABASE_NAME>
NP-MRD

> <SMILES>
[H][C@]12C[C@@]3([H])[C@]4([H])CN5C[C@H](C)CC[C@@]5([H])[C@H](C)[C@@]4([H])CC[C@@]3(O)[C@]1([H])C[C@H](O)[C@@]1([H])C[C@@H](O)CC[C@]21C

> <INCHI_IDENTIFIER>
InChI=1S/C27H45NO3/c1-15-4-5-24-16(2)18-7-9-27(31)20(19(18)14-28(24)13-15)11-21-22(27)12-25(30)23-10-17(29)6-8-26(21,23)3/h15-25,29-31H,4-14H2,1-3H3/t15-,16-,17+,18-,19-,20+,21+,22-,23-,24+,25+,26-,27+/m1/s1

> <INCHI_KEY>
NQGYOUYEGZOZBN-XBRABRBNSA-N

> <FORMULA>
C27H45NO3

> <MOLECULAR_WEIGHT>
431.661

> <EXACT_MASS>
431.339944313

> <JCHEM_ACCEPTOR_COUNT>
4

> <JCHEM_ATOM_COUNT>
76

> <JCHEM_AVERAGE_POLARIZABILITY>
52.37023350280589

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
3

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(1S,2R,6R,9S,10R,11S,14R,15R,17S,18S,20S,23R,24S)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0^{2,11}.0^{4,9}.0^{15,24}.0^{18,23}]pentacosane-14,17,20-triol

> <ALOGPS_LOGP>
2.93

> <JCHEM_LOGP>
2.7570620276666666

> <ALOGPS_LOGS>
-3.95

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
6

> <JCHEM_PHYSIOLOGICAL_CHARGE>
1

> <JCHEM_PKA>
14.858084266713316

> <JCHEM_PKA_STRONGEST_ACIDIC>
14.1875652573123

> <JCHEM_PKA_STRONGEST_BASIC>
10.543793114197719

> <JCHEM_POLAR_SURFACE_AREA>
63.93000000000001

> <JCHEM_REFRACTIVITY>
123.46069999999999

> <JCHEM_ROTATABLE_BOND_COUNT>
0

> <JCHEM_RULE_OF_FIVE>
1

> <ALOGPS_SOLUBILITY>
4.83e-02 g/l

> <JCHEM_TRADITIONAL_IUPAC>
(1S,2R,6R,9S,10R,11S,14R,15R,17S,18S,20S,23R,24S)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0^{2,11}.0^{4,9}.0^{15,24}.0^{18,23}]pentacosane-14,17,20-triol

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 02-MAY-18   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   02-MAY-18         0                                  
HETATM    1  C   UNK     0      -7.583  -0.043   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      -8.917  -0.813   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      -7.583  -3.123   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -6.250  -2.353   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -6.250  -0.813   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -4.916  -3.123   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0      -3.582  -2.353   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      -3.582  -0.813   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0      -4.916  -0.043   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0      -2.437   0.217   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0      -3.064   1.624   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      -4.595   1.463   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      -0.906   0.056   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0      -0.001   1.302   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      -0.627   2.709   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0      -2.158   2.870   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       0.278   3.955   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0      -0.348   5.361   0.000  0.00  0.00           C+0
HETATM   19  N   UNK     0      -1.879   5.523   0.000  0.00  0.00           N+0
HETATM   20  C   UNK     0      -2.785   4.277   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       0.557   6.607   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      -0.069   8.014   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0      -1.600   8.175   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0      -2.506   6.930   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0     -10.250  -3.123   0.000  0.00  0.00           O+0
HETATM   26  H   UNK     0      -6.250  -3.893   0.000  0.00  0.00           H+0
HETATM   27  C   UNK     0      -6.250   0.727   0.000  0.00  0.00           C+0
HETATM   28  O   UNK     0      -4.915  -4.663   0.000  0.00  0.00           O+0
HETATM   29  H   UNK     0      -4.916  -1.583   0.000  0.00  0.00           H+0
HETATM   30  C   UNK     0      -8.917  -2.353   0.000  0.00  0.00           C+0
HETATM   31  H   UNK     0      -3.743   0.718   0.000  0.00  0.00           H+0
HETATM   32  O   UNK     0      -1.962  -1.248   0.000  0.00  0.00           O+0
HETATM   33  H   UNK     0      -3.834   2.957   0.000  0.00  0.00           H+0
HETATM   34  H   UNK     0      -1.532   1.463   0.000  0.00  0.00           H+0
HETATM   35  H   UNK     0      -1.253   4.115   0.000  0.00  0.00           H+0
HETATM   36  C   UNK     0       1.810   3.794   0.000  0.00  0.00           C+0
HETATM   37  C   UNK     0      -2.226   9.582   0.000  0.00  0.00           C+0
HETATM   38  H   UNK     0      -0.974   6.768   0.000  0.00  0.00           H+0
CONECT    1    2    5                                                       
CONECT    2    1   30                                                       
CONECT    3    4   30                                                       
CONECT    4    3    5    6   26                                             
CONECT    5    1    4    9   27                                             
CONECT    6    7    4   28                                                  
CONECT    7    6    8                                                       
CONECT    8    7    9   10   31                                             
CONECT    9    8    5   12   29                                             
CONECT   10   11    8   13   32                                             
CONECT   11   10   12   16   33                                             
CONECT   12   11    9                                                       
CONECT   13   14   10                                                       
CONECT   14   13   15                                                       
CONECT   15   14   16   17   35                                             
CONECT   16   15   11   20   34                                             
CONECT   17   18   15   36                                                  
CONECT   18   17   21   19   38                                             
CONECT   19   18   20   24                                                  
CONECT   20   16   19                                                       
CONECT   21   22   18                                                       
CONECT   22   21   23                                                       
CONECT   23   22   24   37                                                  
CONECT   24   23   19                                                       
CONECT   25   30                                                            
CONECT   26    4                                                            
CONECT   27    5                                                            
CONECT   28    6                                                            
CONECT   29    9                                                            
CONECT   30    2    3   25                                                  
CONECT   31    8                                                            
CONECT   32   10                                                            
CONECT   33   11                                                            
CONECT   34   16                                                            
CONECT   35   15                                                            
CONECT   36   17                                                            
CONECT   37   23                                                            
CONECT   38   18                                                            
MASTER        0    0    0    0    0    0    0    0   38    0   86    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₇H₄₅NO₃

Average Mass

431.6610 Da

Monoisotopic Mass

431.33994 Da

IUPAC Name

(1S,2R,6R,9S,10R,11S,14R,15R,17S,18S,20S,23R,24S)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0^{2,11}.0^{4,9}.0^{15,24}.0^{18,23}]pentacosane-14,17,20-triol

Traditional Name

(1S,2R,6R,9S,10R,11S,14R,15R,17S,18S,20S,23R,24S)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0^{2,11}.0^{4,9}.0^{15,24}.0^{18,23}]pentacosane-14,17,20-triol

CAS Registry Number

Not Available

SMILES

[H][C@]12C[C@@]3([H])[C@]4([H])CN5C[C@H](C)CC[C@@]5([H])[C@H](C)[C@@]4([H])CC[C@@]3(O)[C@]1([H])C[C@H](O)[C@@]1([H])C[C@@H](O)CC[C@]21C

InChI Identifier

InChI=1S/C27H45NO3/c1-15-4-5-24-16(2)18-7-9-27(31)20(19(18)14-28(24)13-15)11-21-22(27)12-25(30)23-10-17(29)6-8-26(21,23)3/h15-25,29-31H,4-14H2,1-3H3/t15-,16-,17+,18-,19-,20+,21+,22-,23-,24+,25+,26-,27+/m1/s1

InChI Key

NQGYOUYEGZOZBN-XBRABRBNSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Fritillaria sewerzowii	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as cerveratrum-type alkaloids. These are steroidal alkaloids containing the cevane (23-methyl-4- azahexacyclo[12.11.0.0^{2,11}.0^{4,9}.0^{15,24}.0^{18,23}]Pentacosane) moiety, which is a six ring system. Cerveratrum alkaloids have 7-9 oxygen atoms and occur as free alkamines or esters of simple aliphatic or aromatic acids.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Steroids and steroid derivatives

Sub Class

Steroidal alkaloids

Direct Parent

Cerveratrum-type alkaloids

Alternative Parents

Substituents

Cerveratrum-type alkaloid
Azasteroid
Quinolizidine
Alkaloid or derivatives
Piperidine
Cyclic alcohol
Tertiary alcohol
Tertiary aliphatic amine
Tertiary amine
Secondary alcohol
Polyol
Organoheterocyclic compound
Azacycle
Hydrocarbon derivative
Organopnictogen compound
Organooxygen compound
Organonitrogen compound
Alcohol
Organic oxygen compound
Organic nitrogen compound
Amine
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	2.93	ALOGPS
logP	2.76	ChemAxon
logS	-4	ALOGPS
pKa (Strongest Acidic)	14.19	ChemAxon
pKa (Strongest Basic)	10.54	ChemAxon
Physiological Charge	1	ChemAxon
Hydrogen Acceptor Count	4	ChemAxon
Hydrogen Donor Count	3	ChemAxon
Polar Surface Area	63.93 Å²	ChemAxon
Rotatable Bond Count	0	ChemAxon
Refractivity	123.46 m³·mol⁻¹	ChemAxon
Polarizability	52.37 Å³	ChemAxon
Number of Rings	6	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	Yes	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

Not Available

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (1s,2r,6r,9s,10r,11s,14r,15r,17s,18s,20s,23r,24s)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0²,¹¹.0⁴,⁹.0¹⁵,²⁴.0¹⁸,²³]pentacosane-14,17,20-triol (NP0264071)

MOL for NP0264071 ((1s,2r,6r,9s,10r,11s,14r,15r,17s,18s,20s,23r,24s)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0²,¹¹.0⁴,⁹.0¹⁵,²⁴.0¹⁸,²³]pentacosane-14,17,20-triol)

3D MOL for NP0264071 ((1s,2r,6r,9s,10r,11s,14r,15r,17s,18s,20s,23r,24s)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0²,¹¹.0⁴,⁹.0¹⁵,²⁴.0¹⁸,²³]pentacosane-14,17,20-triol)

3D SDF for NP0264071 ((1s,2r,6r,9s,10r,11s,14r,15r,17s,18s,20s,23r,24s)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0²,¹¹.0⁴,⁹.0¹⁵,²⁴.0¹⁸,²³]pentacosane-14,17,20-triol)

3D-SDF for NP0264071 ((1s,2r,6r,9s,10r,11s,14r,15r,17s,18s,20s,23r,24s)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0²,¹¹.0⁴,⁹.0¹⁵,²⁴.0¹⁸,²³]pentacosane-14,17,20-triol)

PDB for NP0264071 ((1s,2r,6r,9s,10r,11s,14r,15r,17s,18s,20s,23r,24s)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0²,¹¹.0⁴,⁹.0¹⁵,²⁴.0¹⁸,²³]pentacosane-14,17,20-triol)

3D PDB for NP0264071 ((1s,2r,6r,9s,10r,11s,14r,15r,17s,18s,20s,23r,24s)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0²,¹¹.0⁴,⁹.0¹⁵,²⁴.0¹⁸,²³]pentacosane-14,17,20-triol)

SMILES for NP0264071 ((1s,2r,6r,9s,10r,11s,14r,15r,17s,18s,20s,23r,24s)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0²,¹¹.0⁴,⁹.0¹⁵,²⁴.0¹⁸,²³]pentacosane-14,17,20-triol)

INCHI for NP0264071 ((1s,2r,6r,9s,10r,11s,14r,15r,17s,18s,20s,23r,24s)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0²,¹¹.0⁴,⁹.0¹⁵,²⁴.0¹⁸,²³]pentacosane-14,17,20-triol)

Structure for NP0264071 ((1s,2r,6r,9s,10r,11s,14r,15r,17s,18s,20s,23r,24s)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0²,¹¹.0⁴,⁹.0¹⁵,²⁴.0¹⁸,²³]pentacosane-14,17,20-triol)

3D Structure for NP0264071 ((1s,2r,6r,9s,10r,11s,14r,15r,17s,18s,20s,23r,24s)-6,10,23-trimethyl-4-azahexacyclo[12.11.0.0²,¹¹.0⁴,⁹.0¹⁵,²⁴.0¹⁸,²³]pentacosane-14,17,20-triol)