NP-MRD: Showing NP-Card for (2z)-3-{[(3ar,4r,9r,11ar)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2e)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate (NP0262173)

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Record Information

Version

2.0

Created at

2022-09-08 04:50:02 UTC

Updated at

2022-09-08 04:50:02 UTC

NP-MRD ID

NP0262173

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(2z)-3-{[(3ar,4r,9r,11ar)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2e)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate

Description

3-{[(3AR,4R,9R,11aR)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-2H,3H,3aH,4H,5H,8H,9H,11aH-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2E)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate belongs to the class of organic compounds known as germacranolides and derivatives. These are sesquiterpene lactones with a structure based on the germacranolide skeleton, characterized by a gamma lactone fused to a 1,7-dimethylcyclodec-1-ene moiety. Based on a literature review very few articles have been published on 3-{[(3aR,4R,9R,11aR)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-2H,3H,3aH,4H,5H,8H,9H,11aH-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2E)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309082206502D          

 37 38  0  0  1  0            999 V2000
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M  END

     RDKit          3D

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M  END


  Mrv1652309082206502D          

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  6  7  1  0  0  0  0
  7  8  2  0  0  0  0
  8  9  1  0  0  0  0
  8 10  1  0  0  0  0
 10 11  1  6  0  0  0
 10 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  2  0  0  0  0
 14 15  1  0  0  0  0
 14 16  1  0  0  0  0
 16 17  1  0  0  0  0
 17 18  1  1  0  0  0
 18 19  1  0  0  0  0
 19 20  2  0  0  0  0
 19 21  1  0  0  0  0
 21 22  2  0  0  0  0
 22 23  1  0  0  0  0
 21 24  1  0  0  0  0
 24 25  1  0  0  0  0
 25 26  1  0  0  0  0
 26 27  2  0  0  0  0
 26 28  1  0  0  0  0
 28 29  2  0  0  0  0
 29 30  1  0  0  0  0
 30 31  1  0  0  0  0
 28 32  1  0  0  0  0
 32 33  1  0  0  0  0
 33 34  1  0  0  0  0
 34 35  1  0  0  0  0
 34 36  2  0  0  0  0
 17 37  1  0  0  0  0
 37  2  1  1  0  0  0
  6 37  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0262173

> <DATABASE_NAME>
NP-MRD

> <SMILES>
C\C=C(\COC(=O)C(\COC(C)=O)=C\CO)C(=O)O[C@@H]1C\C(C)=C\C[C@@H](O)\C(C)=C\[C@H]2OC(=O)C(=C)[C@H]12

> <INCHI_IDENTIFIER>
InChI=1S/C27H34O10/c1-6-19(13-35-26(32)20(9-10-28)14-34-18(5)29)27(33)37-22-11-15(2)7-8-21(30)16(3)12-23-24(22)17(4)25(31)36-23/h6-7,9,12,21-24,28,30H,4,8,10-11,13-14H2,1-3,5H3/b15-7+,16-12+,19-6-,20-9+/t21-,22-,23-,24-/m1/s1

> <INCHI_KEY>
DAGQSCAQXPXZRM-GNMIBTGKSA-N

> <FORMULA>
C27H34O10

> <MOLECULAR_WEIGHT>
518.559

> <EXACT_MASS>
518.215197295

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
71

> <JCHEM_AVERAGE_POLARIZABILITY>
52.63345345253109

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
2

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(2Z)-3-{[(3aR,4R,9R,11aR)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-2H,3H,3aH,4H,5H,8H,9H,11aH-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2E)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate

> <JCHEM_LOGP>
2.264880189333333

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
2

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
15.592297743534154

> <JCHEM_PKA_STRONGEST_ACIDIC>
14.513005630064331

> <JCHEM_PKA_STRONGEST_BASIC>
-2.5580048313342765

> <JCHEM_POLAR_SURFACE_AREA>
145.66000000000003

> <JCHEM_REFRACTIVITY>
135.16779999999997

> <JCHEM_ROTATABLE_BOND_COUNT>
11

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(2Z)-3-{[(3aR,4R,9R,11aR)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-3aH,4H,5H,8H,9H,11aH-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2E)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 08-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   08-SEP-22         0                                  
HETATM    1  C   UNK     0       3.417  -3.528   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       4.379  -2.326   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       3.972  -0.840   0.000  0.00  0.00           C+0
HETATM    4  O   UNK     0       2.531  -0.296   0.000  0.00  0.00           O+0
HETATM    5  O   UNK     0       5.259   0.006   0.000  0.00  0.00           O+0
HETATM    6  C   UNK     0       6.461  -0.957   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       7.981  -0.707   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       8.525   0.734   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       7.549   1.925   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0      10.044   0.983   0.000  0.00  0.00           C+0
HETATM   11  O   UNK     0      10.588   2.424   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0      11.020  -0.208   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      10.476  -1.649   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       8.957  -1.898   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       7.467  -1.508   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       8.413  -3.339   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       6.893  -3.589   0.000  0.00  0.00           C+0
HETATM   18  O   UNK     0       6.350  -5.030   0.000  0.00  0.00           O+0
HETATM   19  C   UNK     0       7.325  -6.221   0.000  0.00  0.00           C+0
HETATM   20  O   UNK     0       8.845  -5.971   0.000  0.00  0.00           O+0
HETATM   21  C   UNK     0       6.782  -7.662   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       5.262  -7.911   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       4.286  -6.720   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       7.758  -8.853   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0       9.277  -8.604   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0      10.253  -9.795   0.000  0.00  0.00           C+0
HETATM   27  O   UNK     0       9.709 -11.236   0.000  0.00  0.00           O+0
HETATM   28  C   UNK     0      11.773  -9.545   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0      12.317  -8.105   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0      13.836  -7.855   0.000  0.00  0.00           C+0
HETATM   31  O   UNK     0      14.380  -6.414   0.000  0.00  0.00           O+0
HETATM   32  C   UNK     0      12.749 -10.737   0.000  0.00  0.00           C+0
HETATM   33  O   UNK     0      14.268 -10.487   0.000  0.00  0.00           O+0
HETATM   34  C   UNK     0      15.244 -11.679   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0      16.764 -11.429   0.000  0.00  0.00           C+0
HETATM   36  O   UNK     0      14.700 -13.119   0.000  0.00  0.00           O+0
HETATM   37  C   UNK     0       5.917  -2.397   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3   37                                                  
CONECT    3    2    4    5                                                  
CONECT    4    3                                                            
CONECT    5    3    6                                                       
CONECT    6    5    7   37                                                  
CONECT    7    6    8                                                       
CONECT    8    7    9   10                                                  
CONECT    9    8                                                            
CONECT   10    8   11   12                                                  
CONECT   11   10                                                            
CONECT   12   10   13                                                       
CONECT   13   12   14                                                       
CONECT   14   13   15   16                                                  
CONECT   15   14                                                            
CONECT   16   14   17                                                       
CONECT   17   16   18   37                                                  
CONECT   18   17   19                                                       
CONECT   19   18   20   21                                                  
CONECT   20   19                                                            
CONECT   21   19   22   24                                                  
CONECT   22   21   23                                                       
CONECT   23   22                                                            
CONECT   24   21   25                                                       
CONECT   25   24   26                                                       
CONECT   26   25   27   28                                                  
CONECT   27   26                                                            
CONECT   28   26   29   32                                                  
CONECT   29   28   30                                                       
CONECT   30   29   31                                                       
CONECT   31   30                                                            
CONECT   32   28   33                                                       
CONECT   33   32   34                                                       
CONECT   34   33   35   36                                                  
CONECT   35   34                                                            
CONECT   36   34                                                            
CONECT   37   17    2    6                                                  
MASTER        0    0    0    0    0    0    0    0   37    0   76    0
END

View in JSmol

Synonyms

Value	Source
3-{[(3ar,4R,9R,11ar)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-2H,3H,3ah,4H,5H,8H,9H,11ah-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2E)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoic acid	Generator

Chemical Formula

C₂₇H₃₄O₁₀

Average Mass

518.5590 Da

Monoisotopic Mass

518.21520 Da

IUPAC Name

(2Z)-3-{[(3aR,4R,9R,11aR)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-2H,3H,3aH,4H,5H,8H,9H,11aH-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2E)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate

Traditional Name

(2Z)-3-{[(3aR,4R,9R,11aR)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-3aH,4H,5H,8H,9H,11aH-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2E)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate

CAS Registry Number

Not Available

SMILES

C\C=C(\COC(=O)C(\COC(C)=O)=C\CO)C(=O)O[C@@H]1C\C(C)=C\C[C@@H](O)\C(C)=C\[C@H]2OC(=O)C(=C)[C@H]12

InChI Identifier

InChI=1S/C27H34O10/c1-6-19(13-35-26(32)20(9-10-28)14-34-18(5)29)27(33)37-22-11-15(2)7-8-21(30)16(3)12-23-24(22)17(4)25(31)36-23/h6-7,9,12,21-24,28,30H,4,8,10-11,13-14H2,1-3,5H3/b15-7+,16-12+,19-6-,20-9+/t21-,22-,23-,24-/m1/s1

InChI Key

DAGQSCAQXPXZRM-GNMIBTGKSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Not Available

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as germacranolides and derivatives. These are sesquiterpene lactones with a structure based on the germacranolide skeleton, characterized by a gamma lactone fused to a 1,7-dimethylcyclodec-1-ene moiety.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Terpene lactones

Direct Parent

Germacranolides and derivatives

Alternative Parents

Substituents

Germacranolide
Germacrane sesquiterpenoid
Sesquiterpenoid
Tetracarboxylic acid or derivatives
Fatty acid ester
Gamma butyrolactone
Fatty acyl
Alpha,beta-unsaturated carboxylic ester
Enoate ester
Tetrahydrofuran
Carboxylic acid ester
Lactone
Secondary alcohol
Oxacycle
Carboxylic acid derivative
Organoheterocyclic compound
Organooxygen compound
Hydrocarbon derivative
Organic oxide
Organic oxygen compound
Alcohol
Primary alcohol
Carbonyl group
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	2.26	ChemAxon
pKa (Strongest Acidic)	14.51	ChemAxon
pKa (Strongest Basic)	-2.6	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	6	ChemAxon
Hydrogen Donor Count	2	ChemAxon
Polar Surface Area	145.66 Å²	ChemAxon
Rotatable Bond Count	11	ChemAxon
Refractivity	135.17 m³·mol⁻¹	ChemAxon
Polarizability	52.63 Å³	ChemAxon
Number of Rings	2	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

162997792

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (2z)-3-{[(3ar,4r,9r,11ar)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2e)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate (NP0262173)

MOL for NP0262173 ((2z)-3-{[(3ar,4r,9r,11ar)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2e)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate)

3D MOL for NP0262173 ((2z)-3-{[(3ar,4r,9r,11ar)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2e)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate)

3D SDF for NP0262173 ((2z)-3-{[(3ar,4r,9r,11ar)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2e)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate)

3D-SDF for NP0262173 ((2z)-3-{[(3ar,4r,9r,11ar)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2e)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate)

PDB for NP0262173 ((2z)-3-{[(3ar,4r,9r,11ar)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2e)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate)

3D PDB for NP0262173 ((2z)-3-{[(3ar,4r,9r,11ar)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2e)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate)

SMILES for NP0262173 ((2z)-3-{[(3ar,4r,9r,11ar)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2e)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate)

INCHI for NP0262173 ((2z)-3-{[(3ar,4r,9r,11ar)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2e)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate)

Structure for NP0262173 ((2z)-3-{[(3ar,4r,9r,11ar)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2e)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate)

3D Structure for NP0262173 ((2z)-3-{[(3ar,4r,9r,11ar)-9-hydroxy-6,10-dimethyl-3-methylidene-2-oxo-3ah,4h,5h,8h,9h,11ah-cyclodeca[b]furan-4-yl]oxy}-2-ethylidene-3-oxopropyl (2e)-2-[(acetyloxy)methyl]-4-hydroxybut-2-enoate)