NP-MRD: Showing NP-Card for (1'r,3s,4's,7'r,8's)-6'-[(2r)-1-[(3s,3as,4r,5s,6as)-4-(hydroxymethyl)-5-methyl-2-oxo-hexahydrocyclopenta[b]furan-3-yl]-2-hydroxypropan-2-yl]-1-methoxy-10'-oxa-5'-azaspiro[indole-3,2'-tricyclo[5.3.1.0⁴,⁸]undecan]-5'-en-2-one (NP0260727)

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Record Information

Version

2.0

Created at

2022-09-08 02:58:30 UTC

Updated at

2022-09-08 02:58:30 UTC

NP-MRD ID

NP0260727

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1'r,3s,4's,7'r,8's)-6'-[(2r)-1-[(3s,3as,4r,5s,6as)-4-(hydroxymethyl)-5-methyl-2-oxo-hexahydrocyclopenta[b]furan-3-yl]-2-hydroxypropan-2-yl]-1-methoxy-10'-oxa-5'-azaspiro[indole-3,2'-tricyclo[5.3.1.0⁴,⁸]undecan]-5'-en-2-one

Description

19Alpha-Hydroxygelsamydine belongs to the class of organic compounds known as terpene lactones. These are prenol lipids containing a lactone ring. (1'r,3s,4's,7'r,8's)-6'-[(2r)-1-[(3s,3as,4r,5s,6as)-4-(hydroxymethyl)-5-methyl-2-oxo-hexahydrocyclopenta[b]furan-3-yl]-2-hydroxypropan-2-yl]-1-methoxy-10'-oxa-5'-azaspiro[indole-3,2'-tricyclo[5.3.1.0⁴,⁸]undecan]-5'-en-2-one is found in Gelsemium elegans. Based on a literature review very few articles have been published on 19alpha-Hydroxygelsamydine.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309082204582D          

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M  END

     RDKit          3D

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M  END


  Mrv1652309082204582D          

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    1.4331    1.8757    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.0029    1.1001    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.4927    0.3372    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.7793    1.1108    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.5926    1.2493    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.1192    0.6143    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.8326   -0.1593    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.0193   -0.2979    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  4  5  2  0  0  0  0
  6  4  1  6  0  0  0
  6  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  1  6  0  0  0
  9 10  2  0  0  0  0
 10 11  1  0  0  0  0
 11 12  1  1  0  0  0
 11 13  1  1  0  0  0
 11 14  1  0  0  0  0
 15 14  1  6  0  0  0
 15 16  1  0  0  0  0
 16 17  2  0  0  0  0
 16 18  1  0  0  0  0
 19 18  1  1  0  0  0
 19 20  1  0  0  0  0
 20 21  1  0  0  0  0
 21 22  1  6  0  0  0
 21 23  1  0  0  0  0
 23 24  1  1  0  0  0
 24 25  1  0  0  0  0
 26 23  1  1  0  0  0
 19 26  1  0  0  0  0
 15 26  1  0  0  0  0
 10 27  1  0  0  0  0
 27 28  1  1  0  0  0
 29 28  1  6  0  0  0
  6 29  1  0  0  0  0
 29 30  1  0  0  0  0
 30 31  1  0  0  0  0
 32 31  1  1  0  0  0
  8 32  1  0  0  0  0
 27 32  1  0  0  0  0
  6 33  1  0  0  0  0
 33 34  2  0  0  0  0
 34 35  1  0  0  0  0
 35 36  2  0  0  0  0
 36 37  1  0  0  0  0
 37 38  2  0  0  0  0
 33 38  1  0  0  0  0
  3 38  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0260727

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CON1C(=O)[C@@]2(C[C@@H]3N=C([C@@H]4C[C@H]2OC[C@H]34)[C@](C)(O)C[C@H]2[C@H]3[C@H](C[C@H](C)[C@H]3CO)OC2=O)C2=CC=CC=C12

> <INCHI_IDENTIFIER>
InChI=1S/C29H36N2O7/c1-14-8-22-24(17(14)12-32)16(26(33)38-22)10-28(2,35)25-15-9-23-29(11-20(30-25)18(15)13-37-23)19-6-4-5-7-21(19)31(36-3)27(29)34/h4-7,14-18,20,22-24,32,35H,8-13H2,1-3H3/t14-,15+,16-,17+,18-,20-,22-,23+,24+,28+,29-/m0/s1

> <INCHI_KEY>
JKNZWTBHBQUFIY-DBEVJBIOSA-N

> <FORMULA>
C29H36N2O7

> <MOLECULAR_WEIGHT>
524.614

> <EXACT_MASS>
524.252251507

> <JCHEM_ACCEPTOR_COUNT>
7

> <JCHEM_ATOM_COUNT>
74

> <JCHEM_AVERAGE_POLARIZABILITY>
55.82360602334984

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
2

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(1'R,3S,4'S,7'R,8'S)-6'-[(2R)-1-[(3S,3aS,4R,5S,6aS)-4-(hydroxymethyl)-5-methyl-2-oxo-hexahydro-2H-cyclopenta[b]furan-3-yl]-2-hydroxypropan-2-yl]-1-methoxy-1,2-dihydro-10'-oxa-5'-azaspiro[indole-3,2'-tricyclo[5.3.1.0^{4,8}]undecan]-5'-en-2-one

> <JCHEM_LOGP>
1.4242145996666649

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
7

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
15.460109676706345

> <JCHEM_PKA_STRONGEST_ACIDIC>
13.867073707824755

> <JCHEM_PKA_STRONGEST_BASIC>
4.983160659048949

> <JCHEM_POLAR_SURFACE_AREA>
117.89

> <JCHEM_REFRACTIVITY>
136.0611

> <JCHEM_ROTATABLE_BOND_COUNT>
5

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(1'R,3S,4'S,7'R,8'S)-6'-[(2R)-1-[(3S,3aS,4R,5S,6aS)-4-(hydroxymethyl)-5-methyl-2-oxo-hexahydrocyclopenta[b]furan-3-yl]-2-hydroxypropan-2-yl]-1-methoxy-10'-oxa-5'-azaspiro[indole-3,2'-tricyclo[5.3.1.0^{4,8}]undecan]-5'-en-2-one

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 08-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   08-SEP-22         0                                  
HETATM    1  C   UNK     0       8.771  -3.512   0.000  0.00  0.00           C+0
HETATM    2  O   UNK     0       7.248  -3.288   0.000  0.00  0.00           O+0
HETATM    3  N   UNK     0       6.679  -1.857   0.000  0.00  0.00           N+0
HETATM    4  C   UNK     0       5.187  -1.476   0.000  0.00  0.00           C+0
HETATM    5  O   UNK     0       4.001  -2.459   0.000  0.00  0.00           O+0
HETATM    6  C   UNK     0       5.088   0.061   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       3.721  -0.796   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       2.308   0.053   0.000  0.00  0.00           C+0
HETATM    9  N   UNK     0       0.858  -0.332   0.000  0.00  0.00           N+0
HETATM   10  C   UNK     0       0.702   1.211   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0      -0.505   2.167   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       0.451   3.374   0.000  0.00  0.00           C+0
HETATM   13  O   UNK     0      -1.461   0.960   0.000  0.00  0.00           O+0
HETATM   14  C   UNK     0      -1.712   3.123   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      -3.144   2.556   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0      -3.526   1.064   0.000  0.00  0.00           C+0
HETATM   17  O   UNK     0      -2.544  -0.122   0.000  0.00  0.00           O+0
HETATM   18  O   UNK     0      -5.063   0.967   0.000  0.00  0.00           O+0
HETATM   19  C   UNK     0      -5.631   2.399   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0      -6.931   3.223   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0      -6.549   4.715   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      -7.531   5.901   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0      -5.012   4.812   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0      -4.187   6.113   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0      -2.648   6.049   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0      -4.445   3.381   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       2.574   1.456   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       4.306   2.334   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       5.207   1.708   0.000  0.00  0.00           C+0
HETATM   30  O   UNK     0       4.443   3.414   0.000  0.00  0.00           O+0
HETATM   31  C   UNK     0       2.675   3.501   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0       1.872   2.053   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0       6.520   0.629   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0       7.055   2.073   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0       8.573   2.332   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0       9.556   1.147   0.000  0.00  0.00           C+0
HETATM   37  C   UNK     0       9.021  -0.297   0.000  0.00  0.00           C+0
HETATM   38  C   UNK     0       7.503  -0.556   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4   38                                                  
CONECT    4    3    5    6                                                  
CONECT    5    4                                                            
CONECT    6    4    7   29   33                                             
CONECT    7    6    8                                                       
CONECT    8    7    9   32                                                  
CONECT    9    8   10                                                       
CONECT   10    9   11   27                                                  
CONECT   11   10   12   13   14                                             
CONECT   12   11                                                            
CONECT   13   11                                                            
CONECT   14   11   15                                                       
CONECT   15   14   16   26                                                  
CONECT   16   15   17   18                                                  
CONECT   17   16                                                            
CONECT   18   16   19                                                       
CONECT   19   18   20   26                                                  
CONECT   20   19   21                                                       
CONECT   21   20   22   23                                                  
CONECT   22   21                                                            
CONECT   23   21   24   26                                                  
CONECT   24   23   25                                                       
CONECT   25   24                                                            
CONECT   26   23   19   15                                                  
CONECT   27   10   28   32                                                  
CONECT   28   27   29                                                       
CONECT   29   28    6   30                                                  
CONECT   30   29   31                                                       
CONECT   31   30   32                                                       
CONECT   32   31    8   27                                                  
CONECT   33    6   34   38                                                  
CONECT   34   33   35                                                       
CONECT   35   34   36                                                       
CONECT   36   35   37                                                       
CONECT   37   36   38                                                       
CONECT   38   37   33    3                                                  
MASTER        0    0    0    0    0    0    0    0   38    0   88    0
END

View in JSmol

Synonyms

Value	Source
19a-Hydroxygelsamydine	Generator
19Α-hydroxygelsamydine	Generator

Chemical Formula

C₂₉H₃₆N₂O₇

Average Mass

524.6140 Da

Monoisotopic Mass

524.25225 Da

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

CON1C(=O)[C@@]2(C[C@@H]3N=C([C@@H]4C[C@H]2OC[C@H]34)[C@](C)(O)C[C@H]2[C@H]3[C@H](C[C@H](C)[C@H]3CO)OC2=O)C2=CC=CC=C12

InChI Identifier

InChI=1S/C29H36N2O7/c1-14-8-22-24(17(14)12-32)16(26(33)38-22)10-28(2,35)25-15-9-23-29(11-20(30-25)18(15)13-37-23)19-6-4-5-7-21(19)31(36-3)27(29)34/h4-7,14-18,20,22-24,32,35H,8-13H2,1-3H3/t14-,15+,16-,17+,18-,20-,22-,23+,24+,28+,29-/m0/s1

InChI Key

JKNZWTBHBQUFIY-DBEVJBIOSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Gelsemium elegans	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as terpene lactones. These are prenol lipids containing a lactone ring.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Terpene lactones

Direct Parent

Terpene lactones

Alternative Parents

Substituents

Terpene lactone
Aromatic monoterpenoid
Monoterpenoid
Indole or derivatives
Oxepane
Gamma butyrolactone
Oxane
Benzenoid
Tertiary alcohol
Pyrroline
Oxolane
Carboxylic acid ester
Ketimine
Lactone
Azacycle
Organoheterocyclic compound
Organic 1,3-dipolar compound
Carboxylic acid derivative
Propargyl-type 1,3-dipolar organic compound
Dialkyl ether
Ether
Oxacycle
Monocarboxylic acid or derivatives
Organic oxygen compound
Imine
Organic nitrogen compound
Carbonyl group
Alcohol
Organic oxide
Organonitrogen compound
Organooxygen compound
Hydrocarbon derivative
Primary alcohol
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

C00027705

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

102003053

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (1'r,3s,4's,7'r,8's)-6'-[(2r)-1-[(3s,3as,4r,5s,6as)-4-(hydroxymethyl)-5-methyl-2-oxo-hexahydrocyclopenta[b]furan-3-yl]-2-hydroxypropan-2-yl]-1-methoxy-10'-oxa-5'-azaspiro[indole-3,2'-tricyclo[5.3.1.0⁴,⁸]undecan]-5'-en-2-one (NP0260727)

MOL for NP0260727 ((1'r,3s,4's,7'r,8's)-6'-[(2r)-1-[(3s,3as,4r,5s,6as)-4-(hydroxymethyl)-5-methyl-2-oxo-hexahydrocyclopenta[b]furan-3-yl]-2-hydroxypropan-2-yl]-1-methoxy-10'-oxa-5'-azaspiro[indole-3,2'-tricyclo[5.3.1.0⁴,⁸]undecan]-5'-en-2-one)

3D MOL for NP0260727 ((1'r,3s,4's,7'r,8's)-6'-[(2r)-1-[(3s,3as,4r,5s,6as)-4-(hydroxymethyl)-5-methyl-2-oxo-hexahydrocyclopenta[b]furan-3-yl]-2-hydroxypropan-2-yl]-1-methoxy-10'-oxa-5'-azaspiro[indole-3,2'-tricyclo[5.3.1.0⁴,⁸]undecan]-5'-en-2-one)

3D SDF for NP0260727 ((1'r,3s,4's,7'r,8's)-6'-[(2r)-1-[(3s,3as,4r,5s,6as)-4-(hydroxymethyl)-5-methyl-2-oxo-hexahydrocyclopenta[b]furan-3-yl]-2-hydroxypropan-2-yl]-1-methoxy-10'-oxa-5'-azaspiro[indole-3,2'-tricyclo[5.3.1.0⁴,⁸]undecan]-5'-en-2-one)

3D-SDF for NP0260727 ((1'r,3s,4's,7'r,8's)-6'-[(2r)-1-[(3s,3as,4r,5s,6as)-4-(hydroxymethyl)-5-methyl-2-oxo-hexahydrocyclopenta[b]furan-3-yl]-2-hydroxypropan-2-yl]-1-methoxy-10'-oxa-5'-azaspiro[indole-3,2'-tricyclo[5.3.1.0⁴,⁸]undecan]-5'-en-2-one)

PDB for NP0260727 ((1'r,3s,4's,7'r,8's)-6'-[(2r)-1-[(3s,3as,4r,5s,6as)-4-(hydroxymethyl)-5-methyl-2-oxo-hexahydrocyclopenta[b]furan-3-yl]-2-hydroxypropan-2-yl]-1-methoxy-10'-oxa-5'-azaspiro[indole-3,2'-tricyclo[5.3.1.0⁴,⁸]undecan]-5'-en-2-one)

3D PDB for NP0260727 ((1'r,3s,4's,7'r,8's)-6'-[(2r)-1-[(3s,3as,4r,5s,6as)-4-(hydroxymethyl)-5-methyl-2-oxo-hexahydrocyclopenta[b]furan-3-yl]-2-hydroxypropan-2-yl]-1-methoxy-10'-oxa-5'-azaspiro[indole-3,2'-tricyclo[5.3.1.0⁴,⁸]undecan]-5'-en-2-one)

SMILES for NP0260727 ((1'r,3s,4's,7'r,8's)-6'-[(2r)-1-[(3s,3as,4r,5s,6as)-4-(hydroxymethyl)-5-methyl-2-oxo-hexahydrocyclopenta[b]furan-3-yl]-2-hydroxypropan-2-yl]-1-methoxy-10'-oxa-5'-azaspiro[indole-3,2'-tricyclo[5.3.1.0⁴,⁸]undecan]-5'-en-2-one)

INCHI for NP0260727 ((1'r,3s,4's,7'r,8's)-6'-[(2r)-1-[(3s,3as,4r,5s,6as)-4-(hydroxymethyl)-5-methyl-2-oxo-hexahydrocyclopenta[b]furan-3-yl]-2-hydroxypropan-2-yl]-1-methoxy-10'-oxa-5'-azaspiro[indole-3,2'-tricyclo[5.3.1.0⁴,⁸]undecan]-5'-en-2-one)

Structure for NP0260727 ((1'r,3s,4's,7'r,8's)-6'-[(2r)-1-[(3s,3as,4r,5s,6as)-4-(hydroxymethyl)-5-methyl-2-oxo-hexahydrocyclopenta[b]furan-3-yl]-2-hydroxypropan-2-yl]-1-methoxy-10'-oxa-5'-azaspiro[indole-3,2'-tricyclo[5.3.1.0⁴,⁸]undecan]-5'-en-2-one)

3D Structure for NP0260727 ((1'r,3s,4's,7'r,8's)-6'-[(2r)-1-[(3s,3as,4r,5s,6as)-4-(hydroxymethyl)-5-methyl-2-oxo-hexahydrocyclopenta[b]furan-3-yl]-2-hydroxypropan-2-yl]-1-methoxy-10'-oxa-5'-azaspiro[indole-3,2'-tricyclo[5.3.1.0⁴,⁸]undecan]-5'-en-2-one)