NP-MRD: Showing NP-Card for [13-(furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0¹,¹².0³,⁸]heptadecan-7-yl]acetic acid (NP0258459)

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Record Information

Version

2.0

Created at

2022-09-07 23:55:45 UTC

Updated at

2022-09-07 23:55:45 UTC

NP-MRD ID

NP0258459

Secondary Accession Numbers

None

Natural Product Identification

Common Name

[13-(furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0¹,¹².0³,⁸]heptadecan-7-yl]acetic acid

Description

2-[13-(Furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0¹,¹².0³,⁸]Heptadecan-7-yl]acetic acid belongs to the class of organic compounds known as limonoids. These are highly oxygenated, modified terpenoids with a prototypical structure either containing or derived from a precursor with a 4,4,8-trimethyl-17-furanylsteroid skeleton. All naturally occurring citrus limonoids contain a furan ring attached to the D-ring, at C-17, as well as oxygen containing functional groups at C-3, C-4, C-7, C-16 and C-17. [13-(furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0¹,¹².0³,⁸]heptadecan-7-yl]acetic acid is found in Bergia capensis. Based on a literature review very few articles have been published on 2-[13-(furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0¹,¹².0³,⁸]Heptadecan-7-yl]acetic acid.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309082201552D          

 33 37  0  0  0  0            999 V2000
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M  END

     RDKit          3D

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M  END


  Mrv1652309082201552D          

 33 37  0  0  0  0            999 V2000
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M  END
> <DATABASE_ID>
NP0258459

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC1(C)C(CC(O)=O)C2(C)C(CC1=O)OC13CC(=O)OC(C4=COC=C4)C1(C)CCC2C3=C

> <INCHI_IDENTIFIER>
InChI=1S/C26H32O7/c1-14-16-6-8-24(4)22(15-7-9-31-13-15)32-21(30)12-26(14,24)33-19-11-18(27)23(2,3)17(10-20(28)29)25(16,19)5/h7,9,13,16-17,19,22H,1,6,8,10-12H2,2-5H3,(H,28,29)

> <INCHI_KEY>
OQLGEBFKDSZURT-UHFFFAOYSA-N

> <FORMULA>
C26H32O7

> <MOLECULAR_WEIGHT>
456.535

> <EXACT_MASS>
456.21480337

> <JCHEM_ACCEPTOR_COUNT>
5

> <JCHEM_ATOM_COUNT>
65

> <JCHEM_AVERAGE_POLARIZABILITY>
47.30128171023126

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
1

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
1

> <JCHEM_IUPAC>
2-[13-(furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0^{1,12}.0^{3,8}]heptadecan-7-yl]acetic acid

> <JCHEM_LOGP>
3.672461205333331

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
-1

> <JCHEM_PKA>
18.094910949966557

> <JCHEM_PKA_STRONGEST_ACIDIC>
4.287475452203197

> <JCHEM_PKA_STRONGEST_BASIC>
-2.869594286725189

> <JCHEM_POLAR_SURFACE_AREA>
103.03999999999999

> <JCHEM_REFRACTIVITY>
116.627

> <JCHEM_ROTATABLE_BOND_COUNT>
3

> <JCHEM_RULE_OF_FIVE>
1

> <JCHEM_TRADITIONAL_IUPAC>
[13-(furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0^{1,12}.0^{3,8}]heptadecan-7-yl]acetic acid

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 08-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   08-SEP-22         0                                  
HETATM    1  C   UNK     0       7.788   0.513   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       6.694  -0.571   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       7.682  -1.630   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       6.596  -2.798   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       5.056  -2.461   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       4.660  -0.913   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       3.674  -2.097   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       3.121  -0.808   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       2.252  -2.079   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       2.770  -3.529   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       1.551  -4.470   0.000  0.00  0.00           C+0
HETATM   12  O   UNK     0       0.279  -3.601   0.000  0.00  0.00           O+0
HETATM   13  C   UNK     0       0.713  -2.123   0.000  0.00  0.00           C+0
HETATM   14  O   UNK     0       2.467   0.582   0.000  0.00  0.00           O+0
HETATM   15  C   UNK     0       3.333   1.866   0.000  0.00  0.00           C+0
HETATM   16  O   UNK     0       2.666   3.253   0.000  0.00  0.00           O+0
HETATM   17  C   UNK     0       4.890   1.739   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       5.705   0.369   0.000  0.00  0.00           C+0
HETATM   19  O   UNK     0       7.029   1.410   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0       8.592   0.981   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       9.759   1.986   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      11.213   1.477   0.000  0.00  0.00           C+0
HETATM   23  O   UNK     0      12.380   2.481   0.000  0.00  0.00           O+0
HETATM   24  C   UNK     0      11.499  -0.037   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0      12.939   0.508   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0      12.285  -1.361   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0      10.331  -1.041   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0      10.617  -2.554   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       9.449  -3.558   0.000  0.00  0.00           C+0
HETATM   30  O   UNK     0       9.735  -5.072   0.000  0.00  0.00           O+0
HETATM   31  O   UNK     0       7.996  -3.049   0.000  0.00  0.00           O+0
HETATM   32  C   UNK     0       8.878  -0.532   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0       9.188  -2.040   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3   18                                                  
CONECT    3    2    4   32                                                  
CONECT    4    3    5                                                       
CONECT    5    4    6                                                       
CONECT    6    5    7    8   18                                             
CONECT    7    6                                                            
CONECT    8    6    9   14                                                  
CONECT    9    8   10   13                                                  
CONECT   10    9   11                                                       
CONECT   11   10   12                                                       
CONECT   12   11   13                                                       
CONECT   13   12    9                                                       
CONECT   14    8   15                                                       
CONECT   15   14   16   17                                                  
CONECT   16   15                                                            
CONECT   17   15   18                                                       
CONECT   18   17    2    6   19                                             
CONECT   19   18   20                                                       
CONECT   20   19   21   32                                                  
CONECT   21   20   22                                                       
CONECT   22   21   23   24                                                  
CONECT   23   22                                                            
CONECT   24   22   25   26   27                                             
CONECT   25   24                                                            
CONECT   26   24                                                            
CONECT   27   24   28   32                                                  
CONECT   28   27   29                                                       
CONECT   29   28   30   31                                                  
CONECT   30   29                                                            
CONECT   31   29                                                            
CONECT   32   27   20    3   33                                             
CONECT   33   32                                                            
MASTER        0    0    0    0    0    0    0    0   33    0   74    0
END

View in JSmol

Synonyms

Value	Source
2-[13-(Furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0,.0,]heptadecan-7-yl]acetate	Generator

Chemical Formula

C₂₆H₃₂O₇

Average Mass

456.5350 Da

Monoisotopic Mass

456.21480 Da

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

CC1(C)C(CC(O)=O)C2(C)C(CC1=O)OC13CC(=O)OC(C4=COC=C4)C1(C)CCC2C3=C

InChI Identifier

InChI=1S/C26H32O7/c1-14-16-6-8-24(4)22(15-7-9-31-13-15)32-21(30)12-26(14,24)33-19-11-18(27)23(2,3)17(10-20(28)29)25(16,19)5/h7,9,13,16-17,19,22H,1,6,8,10-12H2,2-5H3,(H,28,29)

InChI Key

OQLGEBFKDSZURT-UHFFFAOYSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Bergia capensis	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as limonoids. These are highly oxygenated, modified terpenoids with a prototypical structure either containing or derived from a precursor with a 4,4,8-trimethyl-17-furanylsteroid skeleton. All naturally occurring citrus limonoids contain a furan ring attached to the D-ring, at C-17, as well as oxygen containing functional groups at C-3, C-4, C-7, C-16 and C-17.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Triterpenoids

Direct Parent

Limonoids

Alternative Parents

Substituents

Limonoid skeleton
Delta valerolactone
Delta_valerolactone
Dicarboxylic acid or derivatives
Oxane
Heteroaromatic compound
Furan
Carboxylic acid ester
Ketone
Lactone
Cyclic ketone
Organoheterocyclic compound
Ether
Oxacycle
Dialkyl ether
Carboxylic acid
Carboxylic acid derivative
Carbonyl group
Hydrocarbon derivative
Organic oxygen compound
Organooxygen compound
Organic oxide
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

12306800

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for [13-(furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0¹,¹².0³,⁸]heptadecan-7-yl]acetic acid (NP0258459)

MOL for NP0258459 ([13-(furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0¹,¹².0³,⁸]heptadecan-7-yl]acetic acid)

3D MOL for NP0258459 ([13-(furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0¹,¹².0³,⁸]heptadecan-7-yl]acetic acid)

3D SDF for NP0258459 ([13-(furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0¹,¹².0³,⁸]heptadecan-7-yl]acetic acid)

3D-SDF for NP0258459 ([13-(furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0¹,¹².0³,⁸]heptadecan-7-yl]acetic acid)

PDB for NP0258459 ([13-(furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0¹,¹².0³,⁸]heptadecan-7-yl]acetic acid)

3D PDB for NP0258459 ([13-(furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0¹,¹².0³,⁸]heptadecan-7-yl]acetic acid)

SMILES for NP0258459 ([13-(furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0¹,¹².0³,⁸]heptadecan-7-yl]acetic acid)

INCHI for NP0258459 ([13-(furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0¹,¹².0³,⁸]heptadecan-7-yl]acetic acid)

Structure for NP0258459 ([13-(furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0¹,¹².0³,⁸]heptadecan-7-yl]acetic acid)

3D Structure for NP0258459 ([13-(furan-3-yl)-6,6,8,12-tetramethyl-17-methylidene-5,15-dioxo-2,14-dioxatetracyclo[7.7.1.0¹,¹².0³,⁸]heptadecan-7-yl]acetic acid)