NP-MRD: Showing NP-Card for 5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(10),11,13-trien-6-yl 3,4,5-trihydroxybenzoate (NP0258076)

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Record Information

Version

2.0

Created at

2022-09-07 23:22:36 UTC

Updated at

2022-09-07 23:22:36 UTC

NP-MRD ID

NP0258076

Secondary Accession Numbers

None

Natural Product Identification

Common Name

5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(10),11,13-trien-6-yl 3,4,5-trihydroxybenzoate

Description

5,12,13,14-Tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]Tetradeca-1(14),10,12-trien-6-yl 3,4,5-trihydroxybenzoate belongs to the class of organic compounds known as steroid lactones. These are sterol lipids containing a lactone moiety linked to the steroid skeleton. 5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(10),11,13-trien-6-yl 3,4,5-trihydroxybenzoate is found in Bergenia purpurascens and Lotus corniculatus. 5,12,13,14-Tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]Tetradeca-1(14),10,12-trien-6-yl 3,4,5-trihydroxybenzoate is an extremely weak basic (essentially neutral) compound (based on its pKa).

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1533004201503052D          

 33 36  0  0  0  0            999 V2000
    4.8395    1.8414    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.0145    1.8414    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.6020    1.1270    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.7770    1.1270    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.3645    0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.7770   -0.3020    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.3645   -1.0164    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.5395   -1.0164    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.1270   -1.7309    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.1270   -0.3020    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.3020   -0.3020    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1105    0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.9355    0.4125    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.3020    1.1270    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1105    1.8414    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.1270    1.1270    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5395    1.8414    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.5395    0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.6020   -0.3020    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.0145   -1.0164    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.8395   -1.0164    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.2520   -0.3020    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.2520   -1.7309    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.0770   -1.7309    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.4895   -2.4454    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.3145   -2.4454    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.0770   -3.1599    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.4895   -3.8743    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.2520   -3.1599    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.8395   -3.8743    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.8395   -2.4454    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.0145    0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.8395    0.4125    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  6  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  2  0  0  0  0
  8 10  1  0  0  0  0
 10 11  2  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 12 14  2  0  0  0  0
 14 15  1  0  0  0  0
 14 16  1  0  0  0  0
 16 17  1  0  0  0  0
 16 18  2  0  0  0  0
  5 18  1  0  0  0  0
 10 18  1  0  0  0  0
  6 19  1  0  0  0  0
 19 20  1  0  0  0  0
 20 21  1  0  0  0  0
 21 22  2  0  0  0  0
 21 23  1  0  0  0  0
 23 24  2  0  0  0  0
 24 25  1  0  0  0  0
 25 26  1  0  0  0  0
 25 27  2  0  0  0  0
 27 28  1  0  0  0  0
 27 29  1  0  0  0  0
 29 30  1  0  0  0  0
 29 31  2  0  0  0  0
 23 31  1  0  0  0  0
 19 32  1  0  0  0  0
  3 32  1  0  0  0  0
 32 33  1  0  0  0  0
M  END

     RDKit          3D

 51 54  0  0  0  0  0  0  0  0999 V2000
    2.4564    1.5339   -2.0930 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.5881    0.8726   -1.0486 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.4950    0.7204   -0.2252 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.2177    1.2722   -0.4910 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.1156    2.2025    0.6473 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.3887    1.6499    1.8239 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.5845    2.4095    0.8150 C   0  0  2  0  0  0  0  0  0  0  0  0
   -1.8438    3.3820    1.9364 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.2190    3.5913    2.1022 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1720    1.1670    1.0520 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1380    0.4912   -0.1653 C   0  0  2  0  0  0  0  0  0  0  0  0
   -3.0052   -0.6944   -0.2000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.7744   -1.6387   -1.1643 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.6032   -2.7546   -1.2332 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.6503   -2.9365   -0.3564 C   0  0  0  0  0  0  0  0  0  0  0  0
   -5.4647   -4.0658   -0.4498 O   0  0  0  0  0  0  0  0  0  0  0  0
   -4.8556   -1.9677    0.6040 C   0  0  0  0  0  0  0  0  0  0  0  0
   -5.9089   -2.1502    1.4872 O   0  0  0  0  0  0  0  0  0  0  0  0
   -4.0506   -0.8488    0.6975 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.2798    0.1281    1.6875 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.6435   -1.4933   -2.1008 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4608   -2.3675   -2.9716 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.8436   -0.3584   -1.9377 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7640    0.1291   -0.6010 C   0  0  1  0  0  0  0  0  0  0  0  0
    3.8535    0.2472   -0.6528 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.9916    0.3585   -1.4309 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.1958   -0.2173   -1.0868 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.3109   -0.0886   -1.8822 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.2761   -0.9371    0.0829 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.4573   -1.5381    0.4814 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.1594   -1.0676    0.8823 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.2669   -1.7950    2.0508 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.9630   -0.4792    0.5129 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.2230    1.8320   -1.4356 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.4036    3.1703    0.4250 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.2976    1.3068    2.4141 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0240    2.8100   -0.1171 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4030    4.3550    1.6815 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4450    3.0106    2.8791 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.6201    4.1162    1.3906 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.5493    1.1978   -0.9406 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3773   -3.4824   -2.0243 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.2714   -4.7455   -1.1715 H   0  0  0  0  0  0  0  0  0  0  0  0
   -6.5162   -2.9506    1.4509 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.0421    0.0044    2.3333 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4124   -0.7121    0.0287 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.9017    0.9385   -2.3604 H   0  0  0  0  0  0  0  0  0  0  0  0
    7.2567    0.4313   -2.7292 H   0  0  0  0  0  0  0  0  0  0  0  0
    8.3148   -1.4990   -0.0295 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.4970   -1.9375    2.6901 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.1187   -0.6022    1.1583 H   0  0  0  0  0  0  0  0  0  0  0  0
  9  8  1  0
  8  7  1  0
  7 10  1  0
 10 11  1  0
 11 24  1  0
 24 23  1  0
 23 21  1  0
 21 22  2  0
 21 13  1  0
 13 14  2  0
 14 15  1  0
 15 16  1  0
 15 17  2  0
 17 18  1  0
 17 19  1  0
 19 20  1  0
 19 12  2  0
 24  4  1  0
  4  3  1  0
  3  2  1  0
  2  1  2  0
  2 25  1  0
 25 26  2  0
 26 27  1  0
 27 28  1  0
 27 29  2  0
 29 30  1  0
 29 31  1  0
 31 32  1  0
 31 33  2  0
  4  5  1  0
  5  6  1  0
  5  7  1  0
 12 11  1  0
 33 25  1  0
 12 13  1  0
  9 40  1  0
  8 38  1  0
  8 39  1  0
  7 37  1  6
 11 41  1  6
 24 46  1  1
 14 42  1  0
 16 43  1  0
 18 44  1  0
 20 45  1  0
  4 34  1  6
 26 47  1  0
 28 48  1  0
 30 49  1  0
 32 50  1  0
 33 51  1  0
  5 35  1  6
  6 36  1  0
M  END


  Mrv1533004201503052D          

 33 36  0  0  0  0            999 V2000
    4.8395    1.8414    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.0145    1.8414    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.6020    1.1270    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.7770    1.1270    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.3645    0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.7770   -0.3020    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.3645   -1.0164    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.5395   -1.0164    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.1270   -1.7309    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.1270   -0.3020    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.3020   -0.3020    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1105    0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.9355    0.4125    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.3020    1.1270    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1105    1.8414    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.1270    1.1270    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5395    1.8414    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.5395    0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.6020   -0.3020    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.0145   -1.0164    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.8395   -1.0164    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.2520   -0.3020    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.2520   -1.7309    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.0770   -1.7309    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.4895   -2.4454    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.3145   -2.4454    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.0770   -3.1599    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.4895   -3.8743    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.2520   -3.1599    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.8395   -3.8743    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.8395   -2.4454    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.0145    0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.8395    0.4125    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  6  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  2  0  0  0  0
  8 10  1  0  0  0  0
 10 11  2  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 12 14  2  0  0  0  0
 14 15  1  0  0  0  0
 14 16  1  0  0  0  0
 16 17  1  0  0  0  0
 16 18  2  0  0  0  0
  5 18  1  0  0  0  0
 10 18  1  0  0  0  0
  6 19  1  0  0  0  0
 19 20  1  0  0  0  0
 20 21  1  0  0  0  0
 21 22  2  0  0  0  0
 21 23  1  0  0  0  0
 23 24  2  0  0  0  0
 24 25  1  0  0  0  0
 25 26  1  0  0  0  0
 25 27  2  0  0  0  0
 27 28  1  0  0  0  0
 27 29  1  0  0  0  0
 29 30  1  0  0  0  0
 29 31  2  0  0  0  0
 23 31  1  0  0  0  0
 19 32  1  0  0  0  0
  3 32  1  0  0  0  0
 32 33  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0258076

> <DATABASE_NAME>
NP-MRD

> <SMILES>
OCC1OC2C(OC(=O)C3=CC(O)=C(O)C(O)=C23)C(OC(=O)C2=CC(O)=C(O)C(O)=C2)C1O

> <INCHI_IDENTIFIER>
InChI=1S/C20H18O13/c21-4-10-14(27)17(32-19(29)5-1-7(22)12(25)8(23)2-5)18-16(31-10)11-6(20(30)33-18)3-9(24)13(26)15(11)28/h1-3,10,14,16-18,21-28H,4H2

> <INCHI_KEY>
SYWMLYSEFOKNQT-UHFFFAOYSA-N

> <FORMULA>
C20H18O13

> <MOLECULAR_WEIGHT>
466.351

> <EXACT_MASS>
466.07474064

> <JCHEM_ACCEPTOR_COUNT>
11

> <JCHEM_ATOM_COUNT>
51

> <JCHEM_AVERAGE_POLARIZABILITY>
42.32949218527305

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
8

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
1

> <JCHEM_IUPAC>
5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(14),10,12-trien-6-yl 3,4,5-trihydroxybenzoate

> <ALOGPS_LOGP>
1.00

> <JCHEM_LOGP>
0.21188686233333343

> <ALOGPS_LOGS>
-2.14

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
8.283290499759648

> <JCHEM_PKA_STRONGEST_ACIDIC>
7.641530545766579

> <JCHEM_PKA_STRONGEST_BASIC>
-2.9792118771763594

> <JCHEM_POLAR_SURFACE_AREA>
223.66999999999996

> <JCHEM_REFRACTIVITY>
104.6477

> <JCHEM_ROTATABLE_BOND_COUNT>
4

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
3.40e+00 g/l

> <JCHEM_TRADITIONAL_IUPAC>
5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(14),10,12-trien-6-yl 3,4,5-trihydroxybenzoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 20-APR-15   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   20-APR-15         0                                  
HETATM    1  O   UNK     0       9.034   3.437   0.000  0.00  0.00           O+0
HETATM    2  C   UNK     0       7.494   3.437   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       6.724   2.104   0.000  0.00  0.00           C+0
HETATM    4  O   UNK     0       5.184   2.104   0.000  0.00  0.00           O+0
HETATM    5  C   UNK     0       4.414   0.770   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       5.184  -0.564   0.000  0.00  0.00           C+0
HETATM    7  O   UNK     0       4.414  -1.897   0.000  0.00  0.00           O+0
HETATM    8  C   UNK     0       2.874  -1.897   0.000  0.00  0.00           C+0
HETATM    9  O   UNK     0       2.104  -3.231   0.000  0.00  0.00           O+0
HETATM   10  C   UNK     0       2.104  -0.564   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       0.564  -0.564   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      -0.206   0.770   0.000  0.00  0.00           C+0
HETATM   13  O   UNK     0      -1.746   0.770   0.000  0.00  0.00           O+0
HETATM   14  C   UNK     0       0.564   2.104   0.000  0.00  0.00           C+0
HETATM   15  O   UNK     0      -0.206   3.437   0.000  0.00  0.00           O+0
HETATM   16  C   UNK     0       2.104   2.104   0.000  0.00  0.00           C+0
HETATM   17  O   UNK     0       2.874   3.437   0.000  0.00  0.00           O+0
HETATM   18  C   UNK     0       2.874   0.770   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       6.724  -0.564   0.000  0.00  0.00           C+0
HETATM   20  O   UNK     0       7.494  -1.897   0.000  0.00  0.00           O+0
HETATM   21  C   UNK     0       9.034  -1.897   0.000  0.00  0.00           C+0
HETATM   22  O   UNK     0       9.804  -0.564   0.000  0.00  0.00           O+0
HETATM   23  C   UNK     0       9.804  -3.231   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0      11.344  -3.231   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0      12.114  -4.565   0.000  0.00  0.00           C+0
HETATM   26  O   UNK     0      13.654  -4.565   0.000  0.00  0.00           O+0
HETATM   27  C   UNK     0      11.344  -5.898   0.000  0.00  0.00           C+0
HETATM   28  O   UNK     0      12.114  -7.232   0.000  0.00  0.00           O+0
HETATM   29  C   UNK     0       9.804  -5.898   0.000  0.00  0.00           C+0
HETATM   30  O   UNK     0       9.034  -7.232   0.000  0.00  0.00           O+0
HETATM   31  C   UNK     0       9.034  -4.565   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0       7.494   0.770   0.000  0.00  0.00           C+0
HETATM   33  O   UNK     0       9.034   0.770   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4   32                                                  
CONECT    4    3    5                                                       
CONECT    5    4    6   18                                                  
CONECT    6    5    7   19                                                  
CONECT    7    6    8                                                       
CONECT    8    7    9   10                                                  
CONECT    9    8                                                            
CONECT   10    8   11   18                                                  
CONECT   11   10   12                                                       
CONECT   12   11   13   14                                                  
CONECT   13   12                                                            
CONECT   14   12   15   16                                                  
CONECT   15   14                                                            
CONECT   16   14   17   18                                                  
CONECT   17   16                                                            
CONECT   18   16    5   10                                                  
CONECT   19    6   20   32                                                  
CONECT   20   19   21                                                       
CONECT   21   20   22   23                                                  
CONECT   22   21                                                            
CONECT   23   21   24   31                                                  
CONECT   24   23   25                                                       
CONECT   25   24   26   27                                                  
CONECT   26   25                                                            
CONECT   27   25   28   29                                                  
CONECT   28   27                                                            
CONECT   29   27   30   31                                                  
CONECT   30   29                                                            
CONECT   31   29   23                                                       
CONECT   32   19    3   33                                                  
CONECT   33   32                                                            
MASTER        0    0    0    0    0    0    0    0   33    0   72    0
END

View in JSmol

Synonyms

Value	Source
5,12,13,14-Tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0,]tetradeca-1(14),10,12-trien-6-yl 3,4,5-trihydroxybenzoic acid	Generator
5,12,13,14-Tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(14),10,12-trien-6-yl 3,4,5-trihydroxybenzoic acid	Generator

Chemical Formula

C₂₀H₁₈O₁₃

Average Mass

466.3510 Da

Monoisotopic Mass

466.07474 Da

IUPAC Name

5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(14),10,12-trien-6-yl 3,4,5-trihydroxybenzoate

Traditional Name

5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(14),10,12-trien-6-yl 3,4,5-trihydroxybenzoate

CAS Registry Number

Not Available

SMILES

OCC1OC2C(OC(=O)C3=CC(O)=C(O)C(O)=C23)C(OC(=O)C2=CC(O)=C(O)C(O)=C2)C1O

InChI Identifier

InChI=1S/C20H18O13/c21-4-10-14(27)17(32-19(29)5-1-7(22)12(25)8(23)2-5)18-16(31-10)11-6(20(30)33-18)3-9(24)13(26)15(11)28/h1-3,10,14,16-18,21-28H,4H2

InChI Key

SYWMLYSEFOKNQT-UHFFFAOYSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Bergenia purpurascens	LOTUS Database	35616633
Lotus corniculatus	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as steroid lactones. These are sterol lipids containing a lactone moiety linked to the steroid skeleton.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Steroids and steroid derivatives

Sub Class

Steroid lactones

Direct Parent

Steroid lactones

Alternative Parents

Substituents

Steroid lactone
2-hydroxysteroid
Hydroxysteroid
3-hydroxysteroid
1-hydroxysteroid
16-oxosteroid
Oxosteroid
Galloyl ester
Gallic acid or derivatives
P-hydroxybenzoic acid alkyl ester
M-hydroxybenzoic acid ester
P-hydroxybenzoic acid ester
Isochromane
Benzopyran
Benzoate ester
2-benzopyran
Pyrogallol derivative
Benzoic acid or derivatives
Benzenetriol
Benzoyl
1-hydroxy-4-unsubstituted benzenoid
Phenol
1-hydroxy-2-unsubstituted benzenoid
Oxane
Dicarboxylic acid or derivatives
Monocyclic benzene moiety
Monosaccharide
Benzenoid
Secondary alcohol
Carboxylic acid ester
Lactone
Dialkyl ether
Carboxylic acid derivative
Polyol
Organoheterocyclic compound
Oxacycle
Ether
Alcohol
Primary alcohol
Organic oxygen compound
Hydrocarbon derivative
Organic oxide
Organooxygen compound
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	1	ALOGPS
logP	0.21	ChemAxon
logS	-2.1	ALOGPS
pKa (Strongest Acidic)	7.64	ChemAxon
pKa (Strongest Basic)	-3	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	11	ChemAxon
Hydrogen Donor Count	8	ChemAxon
Polar Surface Area	223.67 Å²	ChemAxon
Rotatable Bond Count	4	ChemAxon
Refractivity	104.65 m³·mol⁻¹	ChemAxon
Polarizability	42.33 Å³	ChemAxon
Number of Rings	4	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	Yes	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

14464341

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for 5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(10),11,13-trien-6-yl 3,4,5-trihydroxybenzoate (NP0258076)

MOL for NP0258076 (5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(10),11,13-trien-6-yl 3,4,5-trihydroxybenzoate)

3D MOL for NP0258076 (5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(10),11,13-trien-6-yl 3,4,5-trihydroxybenzoate)

3D SDF for NP0258076 (5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(10),11,13-trien-6-yl 3,4,5-trihydroxybenzoate)

3D-SDF for NP0258076 (5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(10),11,13-trien-6-yl 3,4,5-trihydroxybenzoate)

PDB for NP0258076 (5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(10),11,13-trien-6-yl 3,4,5-trihydroxybenzoate)

3D PDB for NP0258076 (5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(10),11,13-trien-6-yl 3,4,5-trihydroxybenzoate)

SMILES for NP0258076 (5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(10),11,13-trien-6-yl 3,4,5-trihydroxybenzoate)

INCHI for NP0258076 (5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(10),11,13-trien-6-yl 3,4,5-trihydroxybenzoate)

Structure for NP0258076 (5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(10),11,13-trien-6-yl 3,4,5-trihydroxybenzoate)

3D Structure for NP0258076 (5,12,13,14-tetrahydroxy-4-(hydroxymethyl)-9-oxo-3,8-dioxatricyclo[8.4.0.0²,⁷]tetradeca-1(10),11,13-trien-6-yl 3,4,5-trihydroxybenzoate)