NP-MRD: Showing NP-Card for 2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate (NP0251249)

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Record Information

Version

2.0

Created at

2022-09-07 14:23:34 UTC

Updated at

2022-09-07 14:23:34 UTC

NP-MRD ID

NP0251249

Secondary Accession Numbers

None

Natural Product Identification

Common Name

2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate

Description

2-{8-Hydroxy-11-methyl-15-[1-(4-methyl-5-oxo-2,5-dihydrofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]Hexadecan-5-yl}propan-2-yl acetate belongs to the class of organic compounds known as tricarboxylic acids and derivatives. These are carboxylic acids containing exactly three carboxyl groups. 2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate is found in Schisandra lancifolia. 2-{8-Hydroxy-11-methyl-15-[1-(4-methyl-5-oxo-2,5-dihydrofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]Hexadecan-5-yl}propan-2-yl acetate is an extremely weak basic (essentially neutral) compound (based on its pKa).

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1533004171520552D          

 37 41  0  0  0  0            999 V2000
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M  END

     RDKit          3D

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M  END


  Mrv1533004171520552D          

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    6.1103   -1.9825    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.0760   -2.6372    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    7.6157   -3.2612    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.4259   -3.1057    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    7.3452   -4.0406    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  3  2  1  4  0  0  0
  3  4  2  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  6  7  2  0  0  0  0
  6  8  1  0  0  0  0
  8  9  2  0  0  0  0
  4  9  1  0  0  0  0
  8 10  1  0  0  0  0
  2 11  1  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  1  0  0  0  0
 15 16  1  0  0  0  0
 16 17  1  0  0  0  0
 17 18  1  0  0  0  0
 18 19  2  0  0  0  0
 18 20  1  0  0  0  0
 20 21  1  0  0  0  0
 14 21  1  0  0  0  0
 21 22  1  0  0  0  0
 21 23  1  0  0  0  0
 23 24  1  0  0  0  0
 13 24  1  0  0  0  0
 24 25  1  0  0  0  0
 11 25  1  0  0  0  0
 25 26  1  0  0  0  0
 25 27  1  0  0  0  0
 27 28  1  0  0  0  0
 28 29  2  0  0  0  0
 28 30  1  0  0  0  0
 11 30  1  0  0  0  0
 17 31  1  0  0  0  0
 31 32  1  0  0  0  0
 31 33  1  0  0  0  0
 31 34  1  0  0  0  0
 34 35  1  0  0  0  0
 35 36  2  0  0  0  0
 35 37  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0251249

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC(C=C1OC(=O)C(C)=C1)C12OC3C(CC4(O)CC(=O)C(CCC34)C(C)(C)OC(C)=O)C1(C)CC(=O)O2

> <INCHI_IDENTIFIER>
InChI=1S/C28H36O9/c1-14-9-17(34-24(14)32)10-15(2)28-26(6,13-22(31)36-28)20-11-27(33)12-21(30)18(25(4,5)35-16(3)29)7-8-19(27)23(20)37-28/h9-10,15,18-20,23,33H,7-8,11-13H2,1-6H3

> <INCHI_KEY>
IQTICRCDMUVTLN-UHFFFAOYSA-N

> <FORMULA>
C28H36O9

> <MOLECULAR_WEIGHT>
516.587

> <EXACT_MASS>
516.235932739

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
73

> <JCHEM_AVERAGE_POLARIZABILITY>
54.88792319850889

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
1

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxo-2,5-dihydrofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate

> <ALOGPS_LOGP>
2.49

> <JCHEM_LOGP>
2.714145555999999

> <ALOGPS_LOGS>
-4.68

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
17.61391768235244

> <JCHEM_PKA_STRONGEST_ACIDIC>
14.260983674273412

> <JCHEM_PKA_STRONGEST_BASIC>
-3.120312115272224

> <JCHEM_POLAR_SURFACE_AREA>
125.43

> <JCHEM_REFRACTIVITY>
131.43239999999997

> <JCHEM_ROTATABLE_BOND_COUNT>
5

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
1.09e-02 g/l

> <JCHEM_TRADITIONAL_IUPAC>
2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 17-APR-15   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   17-APR-15         0                                  
HETATM    1  C   UNK     0       0.980  -2.864   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       2.435  -3.369   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       3.599  -2.362   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       3.309  -0.849   0.000  0.00  0.00           C+0
HETATM    5  O   UNK     0       4.362   0.274   0.000  0.00  0.00           O+0
HETATM    6  C   UNK     0       3.619   1.623   0.000  0.00  0.00           C+0
HETATM    7  O   UNK     0       4.273   3.017   0.000  0.00  0.00           O+0
HETATM    8  C   UNK     0       2.106   1.333   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       1.915  -0.195   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       0.983   2.386   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       2.725  -4.882   0.000  0.00  0.00           C+0
HETATM   12  O   UNK     0       4.074  -4.138   0.000  0.00  0.00           O+0
HETATM   13  C   UNK     0       5.197  -5.191   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       6.725  -5.383   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       7.727  -4.213   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       9.266  -4.266   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0      10.184  -5.503   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       9.789  -6.992   0.000  0.00  0.00           C+0
HETATM   19  O   UNK     0      10.959  -7.993   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0       8.379  -7.611   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       7.016  -6.895   0.000  0.00  0.00           C+0
HETATM   22  O   UNK     0       7.031  -8.435   0.000  0.00  0.00           O+0
HETATM   23  C   UNK     0       5.667  -7.638   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       4.543  -6.585   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0       3.015  -6.394   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0       3.305  -7.907   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       1.666  -7.137   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       0.543  -6.084   0.000  0.00  0.00           C+0
HETATM   29  O   UNK     0      -0.970  -6.375   0.000  0.00  0.00           O+0
HETATM   30  O   UNK     0       1.197  -4.690   0.000  0.00  0.00           O+0
HETATM   31  C   UNK     0      11.696  -5.213   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0      11.986  -6.725   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0      11.406  -3.701   0.000  0.00  0.00           C+0
HETATM   34  O   UNK     0      13.208  -4.923   0.000  0.00  0.00           O+0
HETATM   35  C   UNK     0      14.216  -6.087   0.000  0.00  0.00           C+0
HETATM   36  O   UNK     0      15.728  -5.797   0.000  0.00  0.00           O+0
HETATM   37  C   UNK     0      13.711  -7.542   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3   11                                                  
CONECT    3    2    4                                                       
CONECT    4    3    5    9                                                  
CONECT    5    4    6                                                       
CONECT    6    5    7    8                                                  
CONECT    7    6                                                            
CONECT    8    6    9   10                                                  
CONECT    9    8    4                                                       
CONECT   10    8                                                            
CONECT   11    2   12   25   30                                             
CONECT   12   11   13                                                       
CONECT   13   12   14   24                                                  
CONECT   14   13   15   21                                                  
CONECT   15   14   16                                                       
CONECT   16   15   17                                                       
CONECT   17   16   18   31                                                  
CONECT   18   17   19   20                                                  
CONECT   19   18                                                            
CONECT   20   18   21                                                       
CONECT   21   20   14   22   23                                             
CONECT   22   21                                                            
CONECT   23   21   24                                                       
CONECT   24   23   13   25                                                  
CONECT   25   24   11   26   27                                             
CONECT   26   25                                                            
CONECT   27   25   28                                                       
CONECT   28   27   29   30                                                  
CONECT   29   28                                                            
CONECT   30   28   11                                                       
CONECT   31   17   32   33   34                                             
CONECT   32   31                                                            
CONECT   33   31                                                            
CONECT   34   31   35                                                       
CONECT   35   34   36   37                                                  
CONECT   36   35                                                            
CONECT   37   35                                                            
MASTER        0    0    0    0    0    0    0    0   37    0   82    0
END

View in JSmol

Synonyms

Value	Source
2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxo-2,5-dihydrofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0,.0,]hexadecan-5-yl}propan-2-yl acetic acid	Generator
2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxo-2,5-dihydrofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetic acid	Generator

Chemical Formula

C₂₈H₃₆O₉

Average Mass

516.5870 Da

Monoisotopic Mass

516.23593 Da

IUPAC Name

2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxo-2,5-dihydrofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate

Traditional Name

2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate

CAS Registry Number

Not Available

SMILES

CC(C=C1OC(=O)C(C)=C1)C12OC3C(CC4(O)CC(=O)C(CCC34)C(C)(C)OC(C)=O)C1(C)CC(=O)O2

InChI Identifier

InChI=1S/C28H36O9/c1-14-9-17(34-24(14)32)10-15(2)28-26(6,13-22(31)36-28)20-11-27(33)12-21(30)18(25(4,5)35-16(3)29)7-8-19(27)23(20)37-28/h9-10,15,18-20,23,33H,7-8,11-13H2,1-6H3

InChI Key

IQTICRCDMUVTLN-UHFFFAOYSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Schisandra lancifolia	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as tricarboxylic acids and derivatives. These are carboxylic acids containing exactly three carboxyl groups.

Kingdom

Organic compounds

Super Class

Organic acids and derivatives

Class

Carboxylic acids and derivatives

Sub Class

Tricarboxylic acids and derivatives

Direct Parent

Tricarboxylic acids and derivatives

Alternative Parents

Substituents

Tricarboxylic acid or derivatives
Furofuran
Ketal
2-furanone
Gamma butyrolactone
Cyclic alcohol
Dihydrofuran
Enol ester
Tertiary alcohol
Tetrahydrofuran
Enoate ester
Alpha,beta-unsaturated carboxylic ester
Lactone
Ketone
Cyclic ketone
Carboxylic acid ester
Oxacycle
Acetal
Organoheterocyclic compound
Organooxygen compound
Hydrocarbon derivative
Organic oxide
Alcohol
Organic oxygen compound
Carbonyl group
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	2.49	ALOGPS
logP	2.71	ChemAxon
logS	-4.7	ALOGPS
pKa (Strongest Acidic)	14.26	ChemAxon
pKa (Strongest Basic)	-3.1	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	6	ChemAxon
Hydrogen Donor Count	1	ChemAxon
Polar Surface Area	125.43 Å²	ChemAxon
Rotatable Bond Count	5	ChemAxon
Refractivity	131.43 m³·mol⁻¹	ChemAxon
Polarizability	54.89 Å³	ChemAxon
Number of Rings	5	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

75066725

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for 2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate (NP0251249)

MOL for NP0251249 (2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate)

3D MOL for NP0251249 (2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate)

3D SDF for NP0251249 (2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate)

3D-SDF for NP0251249 (2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate)

PDB for NP0251249 (2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate)

3D PDB for NP0251249 (2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate)

SMILES for NP0251249 (2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate)

INCHI for NP0251249 (2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate)

Structure for NP0251249 (2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate)

3D Structure for NP0251249 (2-{8-hydroxy-11-methyl-15-[1-(4-methyl-5-oxofuran-2-ylidene)propan-2-yl]-6,13-dioxo-14,16-dioxatetracyclo[8.6.0.0²,⁸.0¹¹,¹⁵]hexadecan-5-yl}propan-2-yl acetate)