NP-MRD: Showing NP-Card for (5z)-2-[(2r,3r,3ar,6s,9br)-2-hydroxy-6-(3-methoxy-3-oxopropyl)-3a,6,9b-trimethyl-7-(prop-1-en-2-yl)-1h,2h,3h,4h,7h,8h-cyclopenta[a]naphthalen-3-yl]-7-hydroxy-6-methylhept-5-enoic acid (NP0250626)

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Record Information

Version

2.0

Created at

2022-09-07 13:30:47 UTC

Updated at

2022-09-07 13:30:47 UTC

NP-MRD ID

NP0250626

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(5z)-2-[(2r,3r,3ar,6s,9br)-2-hydroxy-6-(3-methoxy-3-oxopropyl)-3a,6,9b-trimethyl-7-(prop-1-en-2-yl)-1h,2h,3h,4h,7h,8h-cyclopenta[a]naphthalen-3-yl]-7-hydroxy-6-methylhept-5-enoic acid

Description

3-O-Acetyldehydroeburicoic acid belongs to the class of organic compounds known as triterpenoids. These are terpene molecules containing six isoprene units. Based on a literature review very few articles have been published on 3-O-Acetyldehydroeburicoic acid.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309072215302D          

 37 39  0  0  1  0            999 V2000
   -2.5806    1.8016    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.4051    1.7728    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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   -4.6169    1.0156    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -5.0042    0.2871    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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   -3.7425   -0.3837    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3054   -1.0833    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.6927   -1.8118    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.5172   -1.8406    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
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  1  2  2  0  0  0  0
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  2  4  1  0  0  0  0
  4  5  1  0  0  0  0
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  6  7  2  0  0  0  0
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 14 22  1  0  0  0  0
 22 23  2  0  0  0  0
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 13 25  1  0  0  0  0
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  7 28  1  0  0  0  0
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  8 30  1  0  0  0  0
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 36 37  1  0  0  0  0
M  END

     RDKit          3D

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M  END


  Mrv1652309072215302D          

 37 39  0  0  1  0            999 V2000
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   -6.5120   -2.6007    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -5.7548   -1.3405    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.9543   -1.1409    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -5.4623   -0.4908    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3552    0.3447    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -2.6137   -0.0169    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.6408    0.7572    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9263    0.3447    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.2118    0.7572    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.2118    1.5822    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4973    0.3447    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.2171    0.7572    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  2  0  0  0  0
  2  3  1  0  0  0  0
  2  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  6  7  2  0  0  0  0
  7  8  1  0  0  0  0
  8  9  2  0  0  0  0
  9 10  1  0  0  0  0
 10 11  1  0  0  0  0
 11 12  1  1  0  0  0
 11 13  1  0  0  0  0
 13 14  1  1  0  0  0
 14 15  1  0  0  0  0
 15 16  1  0  0  0  0
 16 17  1  0  0  0  0
 17 18  2  0  0  0  0
 18 19  1  0  0  0  0
 18 20  1  0  0  0  0
 20 21  1  0  0  0  0
 14 22  1  0  0  0  0
 22 23  2  0  0  0  0
 22 24  1  0  0  0  0
 13 25  1  0  0  0  0
 25 26  1  6  0  0  0
 25 27  1  0  0  0  0
 27 28  1  0  0  0  0
  7 28  1  0  0  0  0
 11 28  1  0  0  0  0
 28 29  1  6  0  0  0
  8 30  1  0  0  0  0
  4 30  1  0  0  0  0
 30 31  1  1  0  0  0
 30 32  1  6  0  0  0
 32 33  1  0  0  0  0
 33 34  1  0  0  0  0
 34 35  2  0  0  0  0
 34 36  1  0  0  0  0
 36 37  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0250626

> <DATABASE_NAME>
NP-MRD

> <SMILES>
COC(=O)CC[C@@]1(C)C(CC=C2C1=CC[C@]1(C)[C@@H](C(CC\C=C(\C)CO)C(O)=O)[C@H](O)C[C@@]21C)C(C)=C

> <INCHI_IDENTIFIER>
InChI=1S/C31H46O6/c1-19(2)22-11-12-24-23(29(22,4)15-14-26(34)37-7)13-16-30(5)27(25(33)17-31(24,30)6)21(28(35)36)10-8-9-20(3)18-32/h9,12-13,21-22,25,27,32-33H,1,8,10-11,14-18H2,2-7H3,(H,35,36)/b20-9-/t21?,22?,25-,27+,29+,30-,31+/m1/s1

> <INCHI_KEY>
OPDCNCKCFNXEMG-BOCBPPTNSA-N

> <FORMULA>
C31H46O6

> <MOLECULAR_WEIGHT>
514.703

> <EXACT_MASS>
514.329439201

> <JCHEM_ACCEPTOR_COUNT>
5

> <JCHEM_ATOM_COUNT>
83

> <JCHEM_AVERAGE_POLARIZABILITY>
59.60896779367249

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
3

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(5Z)-2-[(2R,3R,3aR,6S,9bR)-2-hydroxy-6-(3-methoxy-3-oxopropyl)-3a,6,9b-trimethyl-7-(prop-1-en-2-yl)-1H,2H,3H,3aH,4H,6H,7H,8H,9bH-cyclopenta[a]naphthalen-3-yl]-7-hydroxy-6-methylhept-5-enoic acid

> <JCHEM_LOGP>
4.008005322333332

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
3

> <JCHEM_PHYSIOLOGICAL_CHARGE>
-1

> <JCHEM_PKA>
14.89272855529073

> <JCHEM_PKA_STRONGEST_ACIDIC>
4.6553124704654625

> <JCHEM_PKA_STRONGEST_BASIC>
-2.0797041161137013

> <JCHEM_POLAR_SURFACE_AREA>
104.06000000000002

> <JCHEM_REFRACTIVITY>
147.34440000000004

> <JCHEM_ROTATABLE_BOND_COUNT>
11

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(5Z)-2-[(2R,3R,3aR,6S,9bR)-2-hydroxy-6-(3-methoxy-3-oxopropyl)-3a,6,9b-trimethyl-7-(prop-1-en-2-yl)-1H,2H,3H,4H,7H,8H-cyclopenta[a]naphthalen-3-yl]-7-hydroxy-6-methylhept-5-enoic acid

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 07-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   07-SEP-22         0                                  
HETATM    1  C   UNK     0      -4.817   3.363   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      -6.356   3.309   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      -7.172   4.615   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -7.079   1.949   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -8.618   1.896   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -9.341   0.536   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0      -8.525  -0.770   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      -6.986  -0.716   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0      -6.170  -2.022   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0      -6.893  -3.382   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0      -8.432  -3.436   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      -7.757  -4.820   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      -9.422  -4.615   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0      -9.049  -6.110   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0     -10.157  -7.179   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0      -9.785  -8.674   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0     -10.892  -9.744   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0     -10.520 -11.238   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0     -11.628 -12.308   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0      -9.039 -11.662   0.000  0.00  0.00           C+0
HETATM   21  O   UNK     0      -8.667 -13.156   0.000  0.00  0.00           O+0
HETATM   22  C   UNK     0      -7.569  -6.534   0.000  0.00  0.00           C+0
HETATM   23  O   UNK     0      -6.461  -5.464   0.000  0.00  0.00           O+0
HETATM   24  O   UNK     0      -7.196  -8.028   0.000  0.00  0.00           O+0
HETATM   25  C   UNK     0     -10.850  -4.039   0.000  0.00  0.00           C+0
HETATM   26  O   UNK     0     -12.156  -4.855   0.000  0.00  0.00           O+0
HETATM   27  C   UNK     0     -10.742  -2.502   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0      -9.248  -2.130   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0     -10.196  -0.916   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0      -6.263   0.643   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0      -4.879  -0.032   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0      -4.929   1.413   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0      -3.596   0.643   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0      -2.262   1.413   0.000  0.00  0.00           C+0
HETATM   35  O   UNK     0      -2.262   2.953   0.000  0.00  0.00           O+0
HETATM   36  O   UNK     0      -0.928   0.643   0.000  0.00  0.00           O+0
HETATM   37  C   UNK     0       0.405   1.413   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3    4                                                  
CONECT    3    2                                                            
CONECT    4    2    5   30                                                  
CONECT    5    4    6                                                       
CONECT    6    5    7                                                       
CONECT    7    6    8   28                                                  
CONECT    8    7    9   30                                                  
CONECT    9    8   10                                                       
CONECT   10    9   11                                                       
CONECT   11   10   12   13   28                                             
CONECT   12   11                                                            
CONECT   13   11   14   25                                                  
CONECT   14   13   15   22                                                  
CONECT   15   14   16                                                       
CONECT   16   15   17                                                       
CONECT   17   16   18                                                       
CONECT   18   17   19   20                                                  
CONECT   19   18                                                            
CONECT   20   18   21                                                       
CONECT   21   20                                                            
CONECT   22   14   23   24                                                  
CONECT   23   22                                                            
CONECT   24   22                                                            
CONECT   25   13   26   27                                                  
CONECT   26   25                                                            
CONECT   27   25   28                                                       
CONECT   28   27    7   11   29                                             
CONECT   29   28                                                            
CONECT   30    8    4   31   32                                             
CONECT   31   30                                                            
CONECT   32   30   33                                                       
CONECT   33   32   34                                                       
CONECT   34   33   35   36                                                  
CONECT   35   34                                                            
CONECT   36   34   37                                                       
CONECT   37   36                                                            
MASTER        0    0    0    0    0    0    0    0   37    0   78    0
END

View in JSmol

Synonyms

Value	Source
3-O-Acetyldehydroeburicoate	Generator

Chemical Formula

C₃₁H₄₆O₆

Average Mass

514.7030 Da

Monoisotopic Mass

514.32944 Da

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

COC(=O)CC[C@@]1(C)C(CC=C2C1=CC[C@]1(C)[C@@H](C(CC\C=C(\C)CO)C(O)=O)[C@H](O)C[C@@]21C)C(C)=C

InChI Identifier

InChI=1S/C31H46O6/c1-19(2)22-11-12-24-23(29(22,4)15-14-26(34)37-7)13-16-30(5)27(25(33)17-31(24,30)6)21(28(35)36)10-8-9-20(3)18-32/h9,12-13,21-22,25,27,32-33H,1,8,10-11,14-18H2,2-7H3,(H,35,36)/b20-9-/t21?,22?,25-,27+,29+,30-,31+/m1/s1

InChI Key

OPDCNCKCFNXEMG-BOCBPPTNSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Not Available

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as triterpenoids. These are terpene molecules containing six isoprene units.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Triterpenoids

Direct Parent

Triterpenoids

Alternative Parents

Substituents

Triterpenoid
Medium-chain hydroxy acid
Medium-chain fatty acid
Branched fatty acid
Methyl-branched fatty acid
Fatty acid ester
Hydroxy fatty acid
Fatty acyl
Unsaturated fatty acid
Dicarboxylic acid or derivatives
Cyclic alcohol
Methyl ester
Carboxylic acid ester
Secondary alcohol
Carboxylic acid derivative
Carboxylic acid
Hydrocarbon derivative
Organic oxide
Alcohol
Carbonyl group
Organic oxygen compound
Primary alcohol
Organooxygen compound
Aliphatic homopolycyclic compound

Molecular Framework

Aliphatic homopolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

78441161

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

139586183

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (5z)-2-[(2r,3r,3ar,6s,9br)-2-hydroxy-6-(3-methoxy-3-oxopropyl)-3a,6,9b-trimethyl-7-(prop-1-en-2-yl)-1h,2h,3h,4h,7h,8h-cyclopenta[a]naphthalen-3-yl]-7-hydroxy-6-methylhept-5-enoic acid (NP0250626)

MOL for NP0250626 ((5z)-2-[(2r,3r,3ar,6s,9br)-2-hydroxy-6-(3-methoxy-3-oxopropyl)-3a,6,9b-trimethyl-7-(prop-1-en-2-yl)-1h,2h,3h,4h,7h,8h-cyclopenta[a]naphthalen-3-yl]-7-hydroxy-6-methylhept-5-enoic acid)

3D MOL for NP0250626 ((5z)-2-[(2r,3r,3ar,6s,9br)-2-hydroxy-6-(3-methoxy-3-oxopropyl)-3a,6,9b-trimethyl-7-(prop-1-en-2-yl)-1h,2h,3h,4h,7h,8h-cyclopenta[a]naphthalen-3-yl]-7-hydroxy-6-methylhept-5-enoic acid)

3D SDF for NP0250626 ((5z)-2-[(2r,3r,3ar,6s,9br)-2-hydroxy-6-(3-methoxy-3-oxopropyl)-3a,6,9b-trimethyl-7-(prop-1-en-2-yl)-1h,2h,3h,4h,7h,8h-cyclopenta[a]naphthalen-3-yl]-7-hydroxy-6-methylhept-5-enoic acid)

3D-SDF for NP0250626 ((5z)-2-[(2r,3r,3ar,6s,9br)-2-hydroxy-6-(3-methoxy-3-oxopropyl)-3a,6,9b-trimethyl-7-(prop-1-en-2-yl)-1h,2h,3h,4h,7h,8h-cyclopenta[a]naphthalen-3-yl]-7-hydroxy-6-methylhept-5-enoic acid)

PDB for NP0250626 ((5z)-2-[(2r,3r,3ar,6s,9br)-2-hydroxy-6-(3-methoxy-3-oxopropyl)-3a,6,9b-trimethyl-7-(prop-1-en-2-yl)-1h,2h,3h,4h,7h,8h-cyclopenta[a]naphthalen-3-yl]-7-hydroxy-6-methylhept-5-enoic acid)

3D PDB for NP0250626 ((5z)-2-[(2r,3r,3ar,6s,9br)-2-hydroxy-6-(3-methoxy-3-oxopropyl)-3a,6,9b-trimethyl-7-(prop-1-en-2-yl)-1h,2h,3h,4h,7h,8h-cyclopenta[a]naphthalen-3-yl]-7-hydroxy-6-methylhept-5-enoic acid)

SMILES for NP0250626 ((5z)-2-[(2r,3r,3ar,6s,9br)-2-hydroxy-6-(3-methoxy-3-oxopropyl)-3a,6,9b-trimethyl-7-(prop-1-en-2-yl)-1h,2h,3h,4h,7h,8h-cyclopenta[a]naphthalen-3-yl]-7-hydroxy-6-methylhept-5-enoic acid)

INCHI for NP0250626 ((5z)-2-[(2r,3r,3ar,6s,9br)-2-hydroxy-6-(3-methoxy-3-oxopropyl)-3a,6,9b-trimethyl-7-(prop-1-en-2-yl)-1h,2h,3h,4h,7h,8h-cyclopenta[a]naphthalen-3-yl]-7-hydroxy-6-methylhept-5-enoic acid)

Structure for NP0250626 ((5z)-2-[(2r,3r,3ar,6s,9br)-2-hydroxy-6-(3-methoxy-3-oxopropyl)-3a,6,9b-trimethyl-7-(prop-1-en-2-yl)-1h,2h,3h,4h,7h,8h-cyclopenta[a]naphthalen-3-yl]-7-hydroxy-6-methylhept-5-enoic acid)

3D Structure for NP0250626 ((5z)-2-[(2r,3r,3ar,6s,9br)-2-hydroxy-6-(3-methoxy-3-oxopropyl)-3a,6,9b-trimethyl-7-(prop-1-en-2-yl)-1h,2h,3h,4h,7h,8h-cyclopenta[a]naphthalen-3-yl]-7-hydroxy-6-methylhept-5-enoic acid)