NP-MRD: Showing NP-Card for (5s,5''s,6r,6''r)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0³,⁷]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol (NP0246673)

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Record Information

Version

2.0

Created at

2022-09-07 08:13:21 UTC

Updated at

2022-09-07 08:13:22 UTC

NP-MRD ID

NP0246673

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(5s,5''s,6r,6''r)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0³,⁷]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol

Description

(5s,5''s,6r,6''r)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0³,⁷]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol is found in Tapinella atrotomentosa.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309072210132D          

 40 46  0  0  1  0            999 V2000
    8.5620    1.4162    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.1495    2.1307    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    7.3245    2.1307    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.9120    2.8452    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    7.3245    3.5596    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.1495    3.5596    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.5620    2.8452    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    9.3870    2.8452    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.4271    3.5126    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.6425    3.2577    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.6425    2.4327    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.9280    2.0202    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.9280    1.1952    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.6425    0.7827    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.6425   -0.0423    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.9280   -0.4548    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    2.9440    2.8452    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
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    6.4271    2.1777    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  2  1  1  1  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  2  0  0  0  0
  6  7  1  0  0  0  0
  2  7  1  0  0  0  0
  7  8  1  6  0  0  0
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 11 40  1  0  0  0  0
  4 40  1  0  0  0  0
M  END

     RDKit          3D

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M  END


  Mrv1652309072210132D          

 40 46  0  0  1  0            999 V2000
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  4  9  1  1  0  0  0
  9 10  1  0  0  0  0
 10 11  2  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  2  0  0  0  0
 14 15  1  0  0  0  0
 15 16  2  0  0  0  0
 16 17  1  0  0  0  0
 16 18  1  0  0  0  0
 18 19  2  0  0  0  0
 13 19  1  0  0  0  0
 12 20  2  0  0  0  0
 20 21  1  0  0  0  0
 21 22  2  0  0  0  0
 10 22  1  0  0  0  0
 22 23  1  0  0  0  0
 23 24  2  0  0  0  0
 24 25  1  0  0  0  0
 25 26  2  0  0  0  0
 26 27  1  0  0  0  0
 26 28  1  0  0  0  0
 28 29  2  0  0  0  0
 23 29  1  0  0  0  0
 21 30  1  0  0  0  0
 31 30  1  1  0  0  0
 31 32  1  0  0  0  0
 32 33  2  0  0  0  0
 33 34  1  0  0  0  0
 34 35  1  6  0  0  0
 34 36  1  0  0  0  0
 36 37  1  1  0  0  0
 36 38  1  0  0  0  0
 31 38  1  0  0  0  0
 31 39  1  0  0  0  0
 20 39  1  0  0  0  0
 11 40  1  0  0  0  0
  4 40  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0246673

> <DATABASE_NAME>
NP-MRD

> <SMILES>
C[C@H]1OC2(OC3=C(O2)C(=C2OC4(OC2=C3C2=CC=C(O)C=C2)O[C@H](C)[C@@H](O)C=C4)C2=CC=C(O)C=C2)C=C[C@@H]1O

> <INCHI_IDENTIFIER>
InChI=1S/C30H26O10/c1-15-21(33)11-13-29(35-15)37-25-23(17-3-7-19(31)8-4-17)27-28(40-30(39-27)14-12-22(34)16(2)36-30)24(26(25)38-29)18-5-9-20(32)10-6-18/h3-16,21-22,31-34H,1-2H3/t15-,16-,21+,22+,29-,30-/m1/s1

> <INCHI_KEY>
ZSWKCSFBENJTNB-KBQRGENLSA-N

> <FORMULA>
C30H26O10

> <MOLECULAR_WEIGHT>
546.528

> <EXACT_MASS>
546.152597037

> <JCHEM_ACCEPTOR_COUNT>
10

> <JCHEM_ATOM_COUNT>
66

> <JCHEM_AVERAGE_POLARIZABILITY>
56.83966026556275

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
4

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(5S,5''S,6R,6''R)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0^{3,7}]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol

> <JCHEM_LOGP>
5.145188792

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
7

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
9.798544870956396

> <JCHEM_PKA_STRONGEST_ACIDIC>
9.19439894992876

> <JCHEM_PKA_STRONGEST_BASIC>
-3.3288440084753415

> <JCHEM_POLAR_SURFACE_AREA>
136.3

> <JCHEM_REFRACTIVITY>
143.34600000000003

> <JCHEM_ROTATABLE_BOND_COUNT>
2

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(5S,5''S,6R,6''R)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0^{3,7}]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 07-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   07-SEP-22         0                                  
HETATM    1  C   UNK     0      15.982   2.644   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      15.212   3.977   0.000  0.00  0.00           C+0
HETATM    3  O   UNK     0      13.672   3.977   0.000  0.00  0.00           O+0
HETATM    4  C   UNK     0      12.902   5.311   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      13.672   6.645   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      15.212   6.645   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0      15.982   5.311   0.000  0.00  0.00           C+0
HETATM    8  O   UNK     0      17.522   5.311   0.000  0.00  0.00           O+0
HETATM    9  O   UNK     0      11.997   6.557   0.000  0.00  0.00           O+0
HETATM   10  C   UNK     0      10.533   6.081   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0      10.533   4.541   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       9.199   3.771   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       9.199   2.231   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0      10.533   1.461   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      10.533  -0.079   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       9.199  -0.849   0.000  0.00  0.00           C+0
HETATM   17  O   UNK     0       9.199  -2.389   0.000  0.00  0.00           O+0
HETATM   18  C   UNK     0       7.865  -0.079   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       7.865   1.461   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       7.865   4.541   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       7.865   6.081   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       9.199   6.851   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       9.199   8.391   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       7.865   9.161   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0       7.865  10.701   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0       9.199  11.471   0.000  0.00  0.00           C+0
HETATM   27  O   UNK     0       9.199  13.011   0.000  0.00  0.00           O+0
HETATM   28  C   UNK     0      10.533  10.701   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0      10.533   9.161   0.000  0.00  0.00           C+0
HETATM   30  O   UNK     0       6.401   6.557   0.000  0.00  0.00           O+0
HETATM   31  C   UNK     0       5.495   5.311   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0       4.725   3.977   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0       3.185   3.977   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0       2.415   5.311   0.000  0.00  0.00           C+0
HETATM   35  O   UNK     0       0.875   5.311   0.000  0.00  0.00           O+0
HETATM   36  C   UNK     0       3.185   6.645   0.000  0.00  0.00           C+0
HETATM   37  C   UNK     0       2.415   7.978   0.000  0.00  0.00           C+0
HETATM   38  O   UNK     0       4.725   6.645   0.000  0.00  0.00           O+0
HETATM   39  O   UNK     0       6.401   4.065   0.000  0.00  0.00           O+0
HETATM   40  O   UNK     0      11.997   4.065   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3    7                                                  
CONECT    3    2    4                                                       
CONECT    4    3    5    9   40                                             
CONECT    5    4    6                                                       
CONECT    6    5    7                                                       
CONECT    7    6    2    8                                                  
CONECT    8    7                                                            
CONECT    9    4   10                                                       
CONECT   10    9   11   22                                                  
CONECT   11   10   12   40                                                  
CONECT   12   11   13   20                                                  
CONECT   13   12   14   19                                                  
CONECT   14   13   15                                                       
CONECT   15   14   16                                                       
CONECT   16   15   17   18                                                  
CONECT   17   16                                                            
CONECT   18   16   19                                                       
CONECT   19   18   13                                                       
CONECT   20   12   21   39                                                  
CONECT   21   20   22   30                                                  
CONECT   22   21   10   23                                                  
CONECT   23   22   24   29                                                  
CONECT   24   23   25                                                       
CONECT   25   24   26                                                       
CONECT   26   25   27   28                                                  
CONECT   27   26                                                            
CONECT   28   26   29                                                       
CONECT   29   28   23                                                       
CONECT   30   21   31                                                       
CONECT   31   30   32   38   39                                             
CONECT   32   31   33                                                       
CONECT   33   32   34                                                       
CONECT   34   33   35   36                                                  
CONECT   35   34                                                            
CONECT   36   34   37   38                                                  
CONECT   37   36                                                            
CONECT   38   36   31                                                       
CONECT   39   31   20                                                       
CONECT   40   11    4                                                       
MASTER        0    0    0    0    0    0    0    0   40    0   92    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₃₀H₂₆O₁₀

Average Mass

546.5280 Da

Monoisotopic Mass

546.15260 Da

IUPAC Name

(5S,5''S,6R,6''R)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0^{3,7}]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol

Traditional Name

(5S,5''S,6R,6''R)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0^{3,7}]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol

CAS Registry Number

Not Available

SMILES

C[C@H]1OC2(OC3=C(O2)C(=C2OC4(OC2=C3C2=CC=C(O)C=C2)O[C@H](C)[C@@H](O)C=C4)C2=CC=C(O)C=C2)C=C[C@@H]1O

InChI Identifier

InChI=1S/C30H26O10/c1-15-21(33)11-13-29(35-15)37-25-23(17-3-7-19(31)8-4-17)27-28(40-30(39-27)14-12-22(34)16(2)36-30)24(26(25)38-29)18-5-9-20(32)10-6-18/h3-16,21-22,31-34H,1-2H3/t15-,16-,21+,22+,29-,30-/m1/s1

InChI Key

ZSWKCSFBENJTNB-KBQRGENLSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Tapinella atrotomentosa	LOTUS Database	35616633

Chemical Taxonomy

Classification

Not classified

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	5.15	ChemAxon
pKa (Strongest Acidic)	9.19	ChemAxon
pKa (Strongest Basic)	-3.3	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	10	ChemAxon
Hydrogen Donor Count	4	ChemAxon
Polar Surface Area	136.3 Å²	ChemAxon
Rotatable Bond Count	2	ChemAxon
Refractivity	143.35 m³·mol⁻¹	ChemAxon
Polarizability	56.84 Å³	ChemAxon
Number of Rings	7	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (5s,5''s,6r,6''r)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0³,⁷]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol (NP0246673)

MOL for NP0246673 ((5s,5''s,6r,6''r)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0³,⁷]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol)

3D MOL for NP0246673 ((5s,5''s,6r,6''r)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0³,⁷]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol)

3D SDF for NP0246673 ((5s,5''s,6r,6''r)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0³,⁷]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol)

3D-SDF for NP0246673 ((5s,5''s,6r,6''r)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0³,⁷]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol)

PDB for NP0246673 ((5s,5''s,6r,6''r)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0³,⁷]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol)

3D PDB for NP0246673 ((5s,5''s,6r,6''r)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0³,⁷]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol)

SMILES for NP0246673 ((5s,5''s,6r,6''r)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0³,⁷]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol)

INCHI for NP0246673 ((5s,5''s,6r,6''r)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0³,⁷]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol)

Structure for NP0246673 ((5s,5''s,6r,6''r)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0³,⁷]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol)

3D Structure for NP0246673 ((5s,5''s,6r,6''r)-2',8'-bis(4-hydroxyphenyl)-6,6''-dimethyl-5,5'',6,6''-tetrahydrodispiro[pyran-2,5'-[4,6,10,12]tetraoxatricyclo[7.3.0.0³,⁷]dodecane-11',2''-pyran]-1',3'(7'),8'-triene-5,5''-diol)