NP-MRD: Showing NP-Card for (2e)-6-[(3s,3ar,5as,6s,7s,9ar,9br)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-decahydrocyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid (NP0246327)

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Record Information

Version

2.0

Created at

2022-09-07 07:45:37 UTC

Updated at

2022-09-07 07:45:37 UTC

NP-MRD ID

NP0246327

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(2e)-6-[(3s,3ar,5as,6s,7s,9ar,9br)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-decahydrocyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid

Description

(2E)-6-[(3S,3aR,5aS,6S,7S,9aR,9bR)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-dodecahydro-1H-cyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid belongs to the class of organic compounds known as sesterterpenoids. These are terpenes composed of five consecutive isoprene units. (2e)-6-[(3s,3ar,5as,6s,7s,9ar,9br)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-decahydrocyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid is found in Alnus japonica. Based on a literature review very few articles have been published on (2E)-6-[(3S,3aR,5aS,6S,7S,9aR,9bR)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-dodecahydro-1H-cyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309072209452D          

 35 37  0  0  1  0            999 V2000
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   -4.4039    6.3520    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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M  END

     RDKit          3D

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M  END


  Mrv1652309072209452D          

 35 37  0  0  1  0            999 V2000
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   -1.0946   -0.9185    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3802   -0.5060    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3802    0.3190    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.3343   -0.9185    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.0488   -0.5060    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.0539   -1.5505    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -2.7717   -2.3257    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3020   -2.9577    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9592   -2.4690    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.8663   -1.4072    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.1485   -0.6320    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.6182   -0.0000    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -4.4352   -0.1148    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  2  0  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  2  0  0  0  0
  6  7  1  0  0  0  0
  6  8  1  0  0  0  0
  8  9  2  0  0  0  0
  8 10  1  0  0  0  0
 11  2  1  6  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  1  1  0  0  0
 14 16  1  0  0  0  0
 11 16  1  0  0  0  0
 16 17  1  1  0  0  0
 17 18  1  0  0  0  0
 19 18  1  1  0  0  0
 19 20  1  0  0  0  0
 20 21  1  6  0  0  0
 20 22  1  1  0  0  0
 22 23  1  0  0  0  0
 23 24  1  0  0  0  0
 24 25  2  0  0  0  0
 24 26  1  0  0  0  0
 26 27  1  0  0  0  0
 20 28  1  0  0  0  0
 28 29  1  6  0  0  0
 29 30  2  0  0  0  0
 29 31  1  0  0  0  0
 28 32  1  0  0  0  0
 32 33  1  0  0  0  0
 33 34  1  0  0  0  0
 19 34  1  0  0  0  0
 14 34  1  0  0  0  0
 34 35  1  6  0  0  0
M  END
> <DATABASE_ID>
NP0246327

> <DATABASE_NAME>
NP-MRD

> <SMILES>
COC(=O)CC[C@@]1(C)[C@@H](CC[C@]2(C)[C@H]1CC[C@@H]1[C@H](CC[C@@]21C)C(=C)CC\C=C(/C)C(O)=O)C(C)=C

> <INCHI_IDENTIFIER>
InChI=1S/C31H48O4/c1-20(2)24-15-19-31(7)26(29(24,5)17-16-27(32)35-8)13-12-25-23(14-18-30(25,31)6)21(3)10-9-11-22(4)28(33)34/h11,23-26H,1,3,9-10,12-19H2,2,4-8H3,(H,33,34)/b22-11+/t23-,24+,25-,26+,29+,30-,31-/m1/s1

> <INCHI_KEY>
FCJMSYBZNPUJID-XSDUFFGSSA-N

> <FORMULA>
C31H48O4

> <MOLECULAR_WEIGHT>
484.721

> <EXACT_MASS>
484.355260026

> <JCHEM_ACCEPTOR_COUNT>
3

> <JCHEM_ATOM_COUNT>
83

> <JCHEM_AVERAGE_POLARIZABILITY>
57.572503418622915

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
1

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(2E)-6-[(3S,3aR,5aS,6S,7S,9aR,9bR)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-dodecahydro-1H-cyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid

> <JCHEM_LOGP>
7.317021609666667

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
3

> <JCHEM_PHYSIOLOGICAL_CHARGE>
-1

> <JCHEM_PKA_STRONGEST_ACIDIC>
4.684013689436752

> <JCHEM_PKA_STRONGEST_BASIC>
-7.0242030638010995

> <JCHEM_POLAR_SURFACE_AREA>
63.599999999999994

> <JCHEM_REFRACTIVITY>
142.08059999999995

> <JCHEM_ROTATABLE_BOND_COUNT>
10

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(2E)-6-[(3S,3aR,5aS,6S,7S,9aR,9bR)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-decahydrocyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 07-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   07-SEP-22         0                                  
HETATM    1  C   UNK     0      -5.005   5.575   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      -6.530   5.361   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      -7.478   6.574   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -6.901   8.002   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -7.849   9.216   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -7.272  10.643   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0      -5.747  10.858   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      -8.221  11.857   0.000  0.00  0.00           C+0
HETATM    9  O   UNK     0      -7.644  13.285   0.000  0.00  0.00           O+0
HETATM   10  O   UNK     0      -9.746  11.643   0.000  0.00  0.00           O+0
HETATM   11  C   UNK     0      -7.107   3.933   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      -8.601   3.560   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      -8.709   2.024   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0      -7.281   1.447   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      -8.388   0.377   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0      -6.291   2.627   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0      -4.774   2.359   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0      -4.247   0.912   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0      -5.237  -0.267   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0      -4.711  -1.715   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0      -3.721  -2.894   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      -3.377  -0.945   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0      -2.043  -1.715   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0      -0.710  -0.945   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0      -0.710   0.595   0.000  0.00  0.00           O+0
HETATM   26  O   UNK     0       0.624  -1.715   0.000  0.00  0.00           O+0
HETATM   27  C   UNK     0       1.958  -0.945   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0      -5.701  -2.894   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0      -5.174  -4.341   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0      -6.164  -5.521   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0      -3.657  -4.609   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0      -7.217  -2.627   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0      -7.744  -1.180   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0      -6.754  -0.000   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0      -8.279  -0.214   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3   11                                                  
CONECT    3    2    4                                                       
CONECT    4    3    5                                                       
CONECT    5    4    6                                                       
CONECT    6    5    7    8                                                  
CONECT    7    6                                                            
CONECT    8    6    9   10                                                  
CONECT    9    8                                                            
CONECT   10    8                                                            
CONECT   11    2   12   16                                                  
CONECT   12   11   13                                                       
CONECT   13   12   14                                                       
CONECT   14   13   15   16   34                                             
CONECT   15   14                                                            
CONECT   16   14   11   17                                                  
CONECT   17   16   18                                                       
CONECT   18   17   19                                                       
CONECT   19   18   20   34                                                  
CONECT   20   19   21   22   28                                             
CONECT   21   20                                                            
CONECT   22   20   23                                                       
CONECT   23   22   24                                                       
CONECT   24   23   25   26                                                  
CONECT   25   24                                                            
CONECT   26   24   27                                                       
CONECT   27   26                                                            
CONECT   28   20   29   32                                                  
CONECT   29   28   30   31                                                  
CONECT   30   29                                                            
CONECT   31   29                                                            
CONECT   32   28   33                                                       
CONECT   33   32   34                                                       
CONECT   34   33   19   14   35                                             
CONECT   35   34                                                            
MASTER        0    0    0    0    0    0    0    0   35    0   74    0
END

View in JSmol

Synonyms

Value	Source
(2E)-6-[(3S,3AR,5as,6S,7S,9ar,9BR)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-dodecahydro-1H-cyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoate	Generator

Chemical Formula

C₃₁H₄₈O₄

Average Mass

484.7210 Da

Monoisotopic Mass

484.35526 Da

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

COC(=O)CC[C@@]1(C)[C@@H](CC[C@]2(C)[C@H]1CC[C@@H]1[C@H](CC[C@@]21C)C(=C)CC\C=C(/C)C(O)=O)C(C)=C

InChI Identifier

InChI=1S/C31H48O4/c1-20(2)24-15-19-31(7)26(29(24,5)17-16-27(32)35-8)13-12-25-23(14-18-30(25,31)6)21(3)10-9-11-22(4)28(33)34/h11,23-26H,1,3,9-10,12-19H2,2,4-8H3,(H,33,34)/b22-11+/t23-,24+,25-,26+,29+,30-,31-/m1/s1

InChI Key

FCJMSYBZNPUJID-XSDUFFGSSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Alnus japonica	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as sesterterpenoids. These are terpenes composed of five consecutive isoprene units.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Sesterterpenoids

Direct Parent

Sesterterpenoids

Alternative Parents

Substituents

Sesterterpenoid
Medium-chain fatty acid
Branched fatty acid
Fatty acid ester
Methyl-branched fatty acid
Unsaturated fatty acid
Dicarboxylic acid or derivatives
Fatty acyl
Methyl ester
Carboxylic acid ester
Carboxylic acid
Carboxylic acid derivative
Organic oxide
Organic oxygen compound
Organooxygen compound
Carbonyl group
Hydrocarbon derivative
Aliphatic homopolycyclic compound

Molecular Framework

Aliphatic homopolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

162984974

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (2e)-6-[(3s,3ar,5as,6s,7s,9ar,9br)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-decahydrocyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid (NP0246327)

MOL for NP0246327 ((2e)-6-[(3s,3ar,5as,6s,7s,9ar,9br)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-decahydrocyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid)

3D MOL for NP0246327 ((2e)-6-[(3s,3ar,5as,6s,7s,9ar,9br)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-decahydrocyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid)

3D SDF for NP0246327 ((2e)-6-[(3s,3ar,5as,6s,7s,9ar,9br)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-decahydrocyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid)

3D-SDF for NP0246327 ((2e)-6-[(3s,3ar,5as,6s,7s,9ar,9br)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-decahydrocyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid)

PDB for NP0246327 ((2e)-6-[(3s,3ar,5as,6s,7s,9ar,9br)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-decahydrocyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid)

3D PDB for NP0246327 ((2e)-6-[(3s,3ar,5as,6s,7s,9ar,9br)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-decahydrocyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid)

SMILES for NP0246327 ((2e)-6-[(3s,3ar,5as,6s,7s,9ar,9br)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-decahydrocyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid)

INCHI for NP0246327 ((2e)-6-[(3s,3ar,5as,6s,7s,9ar,9br)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-decahydrocyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid)

Structure for NP0246327 ((2e)-6-[(3s,3ar,5as,6s,7s,9ar,9br)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-decahydrocyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid)

3D Structure for NP0246327 ((2e)-6-[(3s,3ar,5as,6s,7s,9ar,9br)-6-(3-methoxy-3-oxopropyl)-6,9a,9b-trimethyl-7-(prop-1-en-2-yl)-decahydrocyclopenta[a]naphthalen-3-yl]-2-methylhepta-2,6-dienoic acid)