NP-MRD: Showing NP-Card for 8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate (NP0244320)

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Record Information

Version

2.0

Created at

2022-09-07 05:05:27 UTC

Updated at

2022-09-07 05:05:27 UTC

NP-MRD ID

NP0244320

Secondary Accession Numbers

None

Natural Product Identification

Common Name

8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate

Description

8-Methyl-8-azabicyclo[3.2.1]Octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate belongs to the class of organic compounds known as hydrolyzable tannins. These are tannins with a structure characterized by either of the following models. In model 1, the structure contains galloyl units (in some cases, shikimic acid units) that are linked to diverse polyol carbohydrate-, catechin-, or triterpenoid units. In model 2, contains at least two galloyl units C-C coupled to each other, and do not contain a glycosidically linked catechin unit. 8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate is found in Distimake guerichii. 8-Methyl-8-azabicyclo[3.2.1]Octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate is a very strong basic compound (based on its pKa).

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1533004161515462D          

 37 40  0  0  0  0            999 V2000
    4.8505    4.2087    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    2.3755    2.7798    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5505    2.7798    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.1380    2.0653    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.3130    2.0653    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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 36 37  1  0  0  0  0
M  END

     RDKit          3D

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M  END


  Mrv1533004161515462D          

 37 40  0  0  0  0            999 V2000
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    0.9807    1.0488    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.9807    0.2238    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.6257   -0.2905    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4300   -0.1070    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.3940    0.6363    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    0.5690    0.6363    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  2  0  0  0  0
  4  5  1  0  0  0  0
  5  6  2  0  0  0  0
  6  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  1  0  0  0  0
  9 10  2  0  0  0  0
 10 11  1  0  0  0  0
 10 12  1  0  0  0  0
  7 13  2  0  0  0  0
  3 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  1  0  0  0  0
 15 16  1  0  0  0  0
 16 17  1  0  0  0  0
 17 18  1  0  0  0  0
 18 19  1  0  0  0  0
 17 20  1  0  0  0  0
 20 21  1  0  0  0  0
 20 22  1  0  0  0  0
 22 23  1  0  0  0  0
 22 24  1  0  0  0  0
 15 24  1  0  0  0  0
 24 25  1  0  0  0  0
  5 26  1  0  0  0  0
 26 27  2  0  0  0  0
 26 28  1  0  0  0  0
 28 29  1  0  0  0  0
 29 30  1  0  0  0  0
 30 31  1  0  0  0  0
 31 32  1  0  0  0  0
 32 33  1  0  0  0  0
 33 34  1  0  0  0  0
 34 35  1  0  0  0  0
 29 35  1  0  0  0  0
 34 36  1  0  0  0  0
 31 36  1  0  0  0  0
 36 37  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0244320

> <DATABASE_NAME>
NP-MRD

> <SMILES>
COC1=CC(=CC(CC=C(C)C)=C1OC1OC(CO)C(O)C(O)C1O)C(=O)OC1CC2CCC(C1)N2C

> <INCHI_IDENTIFIER>
InChI=1S/C27H39NO9/c1-14(2)5-6-15-9-16(26(33)35-19-11-17-7-8-18(12-19)28(17)3)10-20(34-4)25(15)37-27-24(32)23(31)22(30)21(13-29)36-27/h5,9-10,17-19,21-24,27,29-32H,6-8,11-13H2,1-4H3

> <INCHI_KEY>
HAWPTRHHUNNNJJ-UHFFFAOYSA-N

> <FORMULA>
C27H39NO9

> <MOLECULAR_WEIGHT>
521.607

> <EXACT_MASS>
521.26248184

> <JCHEM_ACCEPTOR_COUNT>
9

> <JCHEM_ATOM_COUNT>
76

> <JCHEM_AVERAGE_POLARIZABILITY>
55.61779915427667

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
4

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate

> <ALOGPS_LOGP>
1.53

> <JCHEM_LOGP>
1.528122832333333

> <ALOGPS_LOGS>
-2.73

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
1

> <JCHEM_PKA>
13.196097288615341

> <JCHEM_PKA_STRONGEST_ACIDIC>
12.200557306221972

> <JCHEM_PKA_STRONGEST_BASIC>
9.35325581689515

> <JCHEM_POLAR_SURFACE_AREA>
138.15

> <JCHEM_REFRACTIVITY>
135.24709999999996

> <JCHEM_ROTATABLE_BOND_COUNT>
9

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
9.80e-01 g/l

> <JCHEM_TRADITIONAL_IUPAC>
8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 16-APR-15   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   16-APR-15         0                                  
HETATM    1  C   UNK     0       9.054   7.856   0.000  0.00  0.00           C+0
HETATM    2  O   UNK     0       7.514   7.856   0.000  0.00  0.00           O+0
HETATM    3  C   UNK     0       6.744   6.523   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       7.514   5.189   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       6.744   3.855   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       5.204   3.855   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       4.434   5.189   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       2.894   5.189   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       2.124   3.855   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       0.584   3.855   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0      -0.186   5.189   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      -0.186   2.522   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       5.204   6.523   0.000  0.00  0.00           C+0
HETATM   14  O   UNK     0       4.434   7.856   0.000  0.00  0.00           O+0
HETATM   15  C   UNK     0       5.204   9.190   0.000  0.00  0.00           C+0
HETATM   16  O   UNK     0       6.744   9.190   0.000  0.00  0.00           O+0
HETATM   17  C   UNK     0       7.514  10.524   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       9.054  10.524   0.000  0.00  0.00           C+0
HETATM   19  O   UNK     0       9.824  11.857   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0       6.744  11.857   0.000  0.00  0.00           C+0
HETATM   21  O   UNK     0       7.514  13.191   0.000  0.00  0.00           O+0
HETATM   22  C   UNK     0       5.204  11.857   0.000  0.00  0.00           C+0
HETATM   23  O   UNK     0       4.434  13.191   0.000  0.00  0.00           O+0
HETATM   24  C   UNK     0       4.434  10.524   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0       2.894  10.524   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0       7.514   2.522   0.000  0.00  0.00           C+0
HETATM   27  O   UNK     0       9.054   2.522   0.000  0.00  0.00           O+0
HETATM   28  O   UNK     0       6.744   1.188   0.000  0.00  0.00           O+0
HETATM   29  C   UNK     0       5.204   1.188   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       4.536   2.575   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0       3.035   2.918   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0       1.831   1.958   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0       1.831   0.418   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0       3.035  -0.542   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0       4.536  -0.200   0.000  0.00  0.00           C+0
HETATM   36  N   UNK     0       2.602   1.188   0.000  0.00  0.00           N+0
HETATM   37  C   UNK     0       1.062   1.188   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4   13                                                  
CONECT    4    3    5                                                       
CONECT    5    4    6   26                                                  
CONECT    6    5    7                                                       
CONECT    7    6    8   13                                                  
CONECT    8    7    9                                                       
CONECT    9    8   10                                                       
CONECT   10    9   11   12                                                  
CONECT   11   10                                                            
CONECT   12   10                                                            
CONECT   13    7    3   14                                                  
CONECT   14   13   15                                                       
CONECT   15   14   16   24                                                  
CONECT   16   15   17                                                       
CONECT   17   16   18   20                                                  
CONECT   18   17   19                                                       
CONECT   19   18                                                            
CONECT   20   17   21   22                                                  
CONECT   21   20                                                            
CONECT   22   20   23   24                                                  
CONECT   23   22                                                            
CONECT   24   22   15   25                                                  
CONECT   25   24                                                            
CONECT   26    5   27   28                                                  
CONECT   27   26                                                            
CONECT   28   26   29                                                       
CONECT   29   28   30   35                                                  
CONECT   30   29   31                                                       
CONECT   31   30   32   36                                                  
CONECT   32   31   33                                                       
CONECT   33   32   34                                                       
CONECT   34   33   35   36                                                  
CONECT   35   34   29                                                       
CONECT   36   34   31   37                                                  
CONECT   37   36                                                            
MASTER        0    0    0    0    0    0    0    0   37    0   80    0
END

View in JSmol

Synonyms

Value	Source
8-Methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoic acid	Generator

Chemical Formula

C₂₇H₃₉NO₉

Average Mass

521.6070 Da

Monoisotopic Mass

521.26248 Da

IUPAC Name

8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate

Traditional Name

8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate

CAS Registry Number

Not Available

SMILES

COC1=CC(=CC(CC=C(C)C)=C1OC1OC(CO)C(O)C(O)C1O)C(=O)OC1CC2CCC(C1)N2C

InChI Identifier

InChI=1S/C27H39NO9/c1-14(2)5-6-15-9-16(26(33)35-19-11-17-7-8-18(12-19)28(17)3)10-20(34-4)25(15)37-27-24(32)23(31)22(30)21(13-29)36-27/h5,9-10,17-19,21-24,27,29-32H,6-8,11-13H2,1-4H3

InChI Key

HAWPTRHHUNNNJJ-UHFFFAOYSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Distimake guerichii	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as hydrolyzable tannins. These are tannins with a structure characterized by either of the following models. In model 1, the structure contains galloyl units (in some cases, shikimic acid units) that are linked to diverse polyol carbohydrate-, catechin-, or triterpenoid units. In model 2, contains at least two galloyl units C-C coupled to each other, and do not contain a glycosidically linked catechin unit.

Kingdom

Organic compounds

Super Class

Phenylpropanoids and polyketides

Class

Tannins

Sub Class

Hydrolyzable tannins

Direct Parent

Hydrolyzable tannins

Alternative Parents

Substituents

Hydrolyzable tannin
Phenolic glycoside
Hexose monosaccharide
Glycosyl compound
M-methoxybenzoic acid or derivatives
O-glycosyl compound
Benzoate ester
Benzoic acid or derivatives
Tropane alkaloid
Phenoxy compound
Anisole
Benzoyl
Methoxybenzene
Phenol ether
Alkyl aryl ether
Sugar acid
Monocyclic benzene moiety
Benzenoid
Monosaccharide
N-alkylpyrrolidine
Oxane
Piperidine
Pyrrolidine
Tertiary aliphatic amine
Amino acid or derivatives
Tertiary amine
Secondary alcohol
Carboxylic acid ester
Polyol
Acetal
Carboxylic acid derivative
Ether
Oxacycle
Azacycle
Organoheterocyclic compound
Monocarboxylic acid or derivatives
Hydrocarbon derivative
Organic oxide
Organopnictogen compound
Amine
Organic nitrogen compound
Primary alcohol
Organooxygen compound
Organic oxygen compound
Alcohol
Organonitrogen compound
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	1.53	ALOGPS
logP	1.53	ChemAxon
logS	-2.7	ALOGPS
pKa (Strongest Acidic)	12.2	ChemAxon
pKa (Strongest Basic)	9.35	ChemAxon
Physiological Charge	1	ChemAxon
Hydrogen Acceptor Count	9	ChemAxon
Hydrogen Donor Count	4	ChemAxon
Polar Surface Area	138.15 Å²	ChemAxon
Rotatable Bond Count	9	ChemAxon
Refractivity	135.25 m³·mol⁻¹	ChemAxon
Polarizability	55.62 Å³	ChemAxon
Number of Rings	4	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

Not Available

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for 8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate (NP0244320)

MOL for NP0244320 (8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate)

3D MOL for NP0244320 (8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate)

3D SDF for NP0244320 (8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate)

3D-SDF for NP0244320 (8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate)

PDB for NP0244320 (8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate)

3D PDB for NP0244320 (8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate)

SMILES for NP0244320 (8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate)

INCHI for NP0244320 (8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate)

Structure for NP0244320 (8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate)

3D Structure for NP0244320 (8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-methoxy-5-(3-methylbut-2-en-1-yl)-4-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}benzoate)