NP-MRD: Showing NP-Card for (1r,2r,5s,6s,9s,11r,12s,13s,14r,17r,22s)-6-(furan-3-yl)-13-hydroxy-1,5,12,17-tetramethyl-7,10,15,18-tetraoxahexacyclo[12.7.1.0²,¹².0⁵,¹¹.0⁹,¹¹.0¹⁷,²²]docos-20-ene-8,19-dione (NP0244300)

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Record Information

Version

2.0

Created at

2022-09-07 05:03:55 UTC

Updated at

2022-09-07 05:03:55 UTC

NP-MRD ID

NP0244300

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1r,2r,5s,6s,9s,11r,12s,13s,14r,17r,22s)-6-(furan-3-yl)-13-hydroxy-1,5,12,17-tetramethyl-7,10,15,18-tetraoxahexacyclo[12.7.1.0²,¹².0⁵,¹¹.0⁹,¹¹.0¹⁷,²²]docos-20-ene-8,19-dione

Description

Dysoxylin belongs to the class of organic compounds known as limonoids. These are highly oxygenated, modified terpenoids with a prototypical structure either containing or derived from a precursor with a 4,4,8-trimethyl-17-furanylsteroid skeleton. All naturally occurring citrus limonoids contain a furan ring attached to the D-ring, at C-17, as well as oxygen containing functional groups at C-3, C-4, C-7, C-16 and C-17. Based on a literature review very few articles have been published on Dysoxylin.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309072207032D          

 34 40  0  0  1  0            999 V2000
    2.8836   -4.0051    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.1527   -3.2252    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    3.6935   -3.8481    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.5035   -3.6912    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.7725   -2.9113    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    4.2316   -2.2883    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    4.1602   -1.4664    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.5007   -1.5084    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.9598   -0.8855    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.3106   -1.3515    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    5.7360   -0.6446    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.5397   -0.8307    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.6111   -1.6526    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
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    7.4812   -2.8580    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.2758   -3.0799    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.9365   -3.4776    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.1124   -3.4380    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.6296   -2.7691    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
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    3.6908   -1.6654    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.8808   -1.8223    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
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    1.2846   -4.4027    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  2  1  1  6  0  0  0
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M  END

     RDKit          3D

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M  END


  Mrv1652309072207032D          

 34 40  0  0  1  0            999 V2000
    2.8836   -4.0051    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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M  END
> <DATABASE_ID>
NP0244300

> <DATABASE_NAME>
NP-MRD

> <SMILES>
C[C@]12CO[C@@H]3[C@@H]1[C@](C)(C=CC(=O)O2)[C@H]1CC[C@@]2(C)[C@@H](OC(=O)[C@H]4O[C@@]24[C@]1(C)[C@@H]3O)C1=COC=C1

> <INCHI_IDENTIFIER>
InChI=1S/C26H30O8/c1-22-8-6-15(27)33-24(3)12-31-16(17(22)24)18(28)25(4)14(22)5-9-23(2)19(13-7-10-30-11-13)32-21(29)20-26(23,25)34-20/h6-8,10-11,14,16-20,28H,5,9,12H2,1-4H3/t14-,16-,17-,18-,19+,20-,22-,23+,24+,25+,26-/m1/s1

> <INCHI_KEY>
TVLJKMICEJUYOB-XDZXTQRNSA-N

> <FORMULA>
C26H30O8

> <MOLECULAR_WEIGHT>
470.518

> <EXACT_MASS>
470.194067926

> <JCHEM_ACCEPTOR_COUNT>
5

> <JCHEM_ATOM_COUNT>
64

> <JCHEM_AVERAGE_POLARIZABILITY>
47.83808143731384

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
1

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
1

> <JCHEM_IUPAC>
(1R,2R,5S,6R,9S,11R,12S,13S,14R,17R,22S)-6-(furan-3-yl)-13-hydroxy-1,5,12,17-tetramethyl-7,10,15,18-tetraoxahexacyclo[12.7.1.0^{2,12}.0^{5,11}.0^{9,11}.0^{17,22}]docos-20-ene-8,19-dione

> <JCHEM_LOGP>
2.4002381753333335

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
7

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA_STRONGEST_ACIDIC>
13.643909188074197

> <JCHEM_PKA_STRONGEST_BASIC>
-2.8520540066518696

> <JCHEM_POLAR_SURFACE_AREA>
107.72999999999999

> <JCHEM_REFRACTIVITY>
116.305

> <JCHEM_ROTATABLE_BOND_COUNT>
1

> <JCHEM_RULE_OF_FIVE>
1

> <JCHEM_TRADITIONAL_IUPAC>
(1R,2R,5S,6R,9S,11R,12S,13S,14R,17R,22S)-6-(furan-3-yl)-13-hydroxy-1,5,12,17-tetramethyl-7,10,15,18-tetraoxahexacyclo[12.7.1.0^{2,12}.0^{5,11}.0^{9,11}.0^{17,22}]docos-20-ene-8,19-dione

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 07-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   07-SEP-22         0                                  
HETATM    1  C   UNK     0       5.383  -7.476   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       5.885  -6.020   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       6.895  -7.183   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       8.406  -6.890   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       8.909  -5.434   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       7.899  -4.272   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       7.766  -2.737   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       8.401  -2.816   0.000  0.00  0.00           C+0
HETATM    9  O   UNK     0       7.392  -1.653   0.000  0.00  0.00           O+0
HETATM   10  C   UNK     0       9.913  -2.523   0.000  0.00  0.00           C+0
HETATM   11  O   UNK     0      10.707  -1.203   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0      12.207  -1.551   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      12.341  -3.085   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0      13.629  -2.240   0.000  0.00  0.00           C+0
HETATM   15  O   UNK     0      13.695  -3.819   0.000  0.00  0.00           O+0
HETATM   16  C   UNK     0      13.965  -5.335   0.000  0.00  0.00           C+0
HETATM   17  O   UNK     0      15.448  -5.749   0.000  0.00  0.00           O+0
HETATM   18  C   UNK     0      12.948  -6.491   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0      11.410  -6.418   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0      10.509  -5.169   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       9.922  -6.593   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      10.923  -3.686   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       6.387  -4.565   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0       6.889  -3.109   0.000  0.00  0.00           O+0
HETATM   25  C   UNK     0       5.378  -3.402   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0       3.866  -3.695   0.000  0.00  0.00           C+0
HETATM   27  O   UNK     0       2.856  -2.532   0.000  0.00  0.00           O+0
HETATM   28  O   UNK     0       3.363  -5.150   0.000  0.00  0.00           O+0
HETATM   29  C   UNK     0       4.373  -6.313   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       3.871  -7.769   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0       4.753  -9.031   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0       3.826 -10.260   0.000  0.00  0.00           C+0
HETATM   33  O   UNK     0       2.370  -9.758   0.000  0.00  0.00           O+0
HETATM   34  C   UNK     0       2.398  -8.218   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3   23   29                                             
CONECT    3    2    4                                                       
CONECT    4    3    5                                                       
CONECT    5    4    6   20                                                  
CONECT    6    5    7    8   23                                             
CONECT    7    6                                                            
CONECT    8    6    9   10                                                  
CONECT    9    8                                                            
CONECT   10    8   11   22                                                  
CONECT   11   10   12                                                       
CONECT   12   11   13                                                       
CONECT   13   12   14   15   22                                             
CONECT   14   13                                                            
CONECT   15   13   16                                                       
CONECT   16   15   17   18                                                  
CONECT   17   16                                                            
CONECT   18   16   19                                                       
CONECT   19   18   20                                                       
CONECT   20   19    5   21   22                                             
CONECT   21   20                                                            
CONECT   22   20   10   13                                                  
CONECT   23    6    2   24   25                                             
CONECT   24   23   25                                                       
CONECT   25   24   23   26                                                  
CONECT   26   25   27   28                                                  
CONECT   27   26                                                            
CONECT   28   26   29                                                       
CONECT   29   28    2   30                                                  
CONECT   30   29   31   34                                                  
CONECT   31   30   32                                                       
CONECT   32   31   33                                                       
CONECT   33   32   34                                                       
CONECT   34   33   30                                                       
MASTER        0    0    0    0    0    0    0    0   34    0   80    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₆H₃₀O₈

Average Mass

470.5180 Da

Monoisotopic Mass

470.19407 Da

IUPAC Name

(1R,2R,5S,6R,9S,11R,12S,13S,14R,17R,22S)-6-(furan-3-yl)-13-hydroxy-1,5,12,17-tetramethyl-7,10,15,18-tetraoxahexacyclo[12.7.1.0^{2,12}.0^{5,11}.0^{9,11}.0^{17,22}]docos-20-ene-8,19-dione

Traditional Name

(1R,2R,5S,6R,9S,11R,12S,13S,14R,17R,22S)-6-(furan-3-yl)-13-hydroxy-1,5,12,17-tetramethyl-7,10,15,18-tetraoxahexacyclo[12.7.1.0^{2,12}.0^{5,11}.0^{9,11}.0^{17,22}]docos-20-ene-8,19-dione

CAS Registry Number

Not Available

SMILES

C[C@]12CO[C@@H]3[C@@H]1[C@](C)(C=CC(=O)O2)[C@H]1CC[C@@]2(C)[C@@H](OC(=O)[C@H]4O[C@@]24[C@]1(C)[C@@H]3O)C1=COC=C1

InChI Identifier

InChI=1S/C26H30O8/c1-22-8-6-15(27)33-24(3)12-31-16(17(22)24)18(28)25(4)14(22)5-9-23(2)19(13-7-10-30-11-13)32-21(29)20-26(23,25)34-20/h6-8,10-11,14,16-20,28H,5,9,12H2,1-4H3/t14-,16-,17-,18-,19+,20-,22-,23+,24+,25+,26-/m1/s1

InChI Key

TVLJKMICEJUYOB-XDZXTQRNSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Not Available

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as limonoids. These are highly oxygenated, modified terpenoids with a prototypical structure either containing or derived from a precursor with a 4,4,8-trimethyl-17-furanylsteroid skeleton. All naturally occurring citrus limonoids contain a furan ring attached to the D-ring, at C-17, as well as oxygen containing functional groups at C-3, C-4, C-7, C-16 and C-17.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Triterpenoids

Direct Parent

Limonoids

Alternative Parents

Substituents

Limonoid skeleton
Naphthopyran
Naphthofuran
Naphthalene
1,4-dioxepane
Delta valerolactone
Dioxepane
Delta_valerolactone
Dicarboxylic acid or derivatives
Oxane
Pyran
Cyclic alcohol
Heteroaromatic compound
Furan
Alpha,beta-unsaturated carboxylic ester
Enoate ester
Tetrahydrofuran
Lactone
Carboxylic acid ester
Secondary alcohol
Oxacycle
Ether
Oxirane
Dialkyl ether
Organoheterocyclic compound
Carboxylic acid derivative
Alcohol
Hydrocarbon derivative
Organic oxide
Organic oxygen compound
Carbonyl group
Organooxygen compound
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	2.4	ChemAxon
pKa (Strongest Acidic)	13.64	ChemAxon
pKa (Strongest Basic)	-2.9	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	5	ChemAxon
Hydrogen Donor Count	1	ChemAxon
Polar Surface Area	107.73 Å²	ChemAxon
Rotatable Bond Count	1	ChemAxon
Refractivity	116.3 m³·mol⁻¹	ChemAxon
Polarizability	47.84 Å³	ChemAxon
Number of Rings	7	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	Yes	ChemAxon
Ghose Filter	Yes	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

C00039074

Chemspider ID

2343152

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

3086555

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (1r,2r,5s,6s,9s,11r,12s,13s,14r,17r,22s)-6-(furan-3-yl)-13-hydroxy-1,5,12,17-tetramethyl-7,10,15,18-tetraoxahexacyclo[12.7.1.0²,¹².0⁵,¹¹.0⁹,¹¹.0¹⁷,²²]docos-20-ene-8,19-dione (NP0244300)

MOL for NP0244300 ((1r,2r,5s,6s,9s,11r,12s,13s,14r,17r,22s)-6-(furan-3-yl)-13-hydroxy-1,5,12,17-tetramethyl-7,10,15,18-tetraoxahexacyclo[12.7.1.0²,¹².0⁵,¹¹.0⁹,¹¹.0¹⁷,²²]docos-20-ene-8,19-dione)

3D MOL for NP0244300 ((1r,2r,5s,6s,9s,11r,12s,13s,14r,17r,22s)-6-(furan-3-yl)-13-hydroxy-1,5,12,17-tetramethyl-7,10,15,18-tetraoxahexacyclo[12.7.1.0²,¹².0⁵,¹¹.0⁹,¹¹.0¹⁷,²²]docos-20-ene-8,19-dione)

3D SDF for NP0244300 ((1r,2r,5s,6s,9s,11r,12s,13s,14r,17r,22s)-6-(furan-3-yl)-13-hydroxy-1,5,12,17-tetramethyl-7,10,15,18-tetraoxahexacyclo[12.7.1.0²,¹².0⁵,¹¹.0⁹,¹¹.0¹⁷,²²]docos-20-ene-8,19-dione)

3D-SDF for NP0244300 ((1r,2r,5s,6s,9s,11r,12s,13s,14r,17r,22s)-6-(furan-3-yl)-13-hydroxy-1,5,12,17-tetramethyl-7,10,15,18-tetraoxahexacyclo[12.7.1.0²,¹².0⁵,¹¹.0⁹,¹¹.0¹⁷,²²]docos-20-ene-8,19-dione)

PDB for NP0244300 ((1r,2r,5s,6s,9s,11r,12s,13s,14r,17r,22s)-6-(furan-3-yl)-13-hydroxy-1,5,12,17-tetramethyl-7,10,15,18-tetraoxahexacyclo[12.7.1.0²,¹².0⁵,¹¹.0⁹,¹¹.0¹⁷,²²]docos-20-ene-8,19-dione)

3D PDB for NP0244300 ((1r,2r,5s,6s,9s,11r,12s,13s,14r,17r,22s)-6-(furan-3-yl)-13-hydroxy-1,5,12,17-tetramethyl-7,10,15,18-tetraoxahexacyclo[12.7.1.0²,¹².0⁵,¹¹.0⁹,¹¹.0¹⁷,²²]docos-20-ene-8,19-dione)

SMILES for NP0244300 ((1r,2r,5s,6s,9s,11r,12s,13s,14r,17r,22s)-6-(furan-3-yl)-13-hydroxy-1,5,12,17-tetramethyl-7,10,15,18-tetraoxahexacyclo[12.7.1.0²,¹².0⁵,¹¹.0⁹,¹¹.0¹⁷,²²]docos-20-ene-8,19-dione)

INCHI for NP0244300 ((1r,2r,5s,6s,9s,11r,12s,13s,14r,17r,22s)-6-(furan-3-yl)-13-hydroxy-1,5,12,17-tetramethyl-7,10,15,18-tetraoxahexacyclo[12.7.1.0²,¹².0⁵,¹¹.0⁹,¹¹.0¹⁷,²²]docos-20-ene-8,19-dione)

Structure for NP0244300 ((1r,2r,5s,6s,9s,11r,12s,13s,14r,17r,22s)-6-(furan-3-yl)-13-hydroxy-1,5,12,17-tetramethyl-7,10,15,18-tetraoxahexacyclo[12.7.1.0²,¹².0⁵,¹¹.0⁹,¹¹.0¹⁷,²²]docos-20-ene-8,19-dione)

3D Structure for NP0244300 ((1r,2r,5s,6s,9s,11r,12s,13s,14r,17r,22s)-6-(furan-3-yl)-13-hydroxy-1,5,12,17-tetramethyl-7,10,15,18-tetraoxahexacyclo[12.7.1.0²,¹².0⁵,¹¹.0⁹,¹¹.0¹⁷,²²]docos-20-ene-8,19-dione)