NP-MRD: Showing NP-Card for (1r,2s,4s,5r,6s,7s,8s,9r,12r)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl benzoate (NP0242645)

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Record Information

Version

2.0

Created at

2022-09-07 03:00:09 UTC

Updated at

2022-09-07 03:00:10 UTC

NP-MRD ID

NP0242645

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1r,2s,4s,5r,6s,7s,8s,9r,12r)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl benzoate

Description

(1R,2S,4S,5R,6S,7S,8S,9R,12R)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]Dodecan-7-yl benzoate belongs to the class of organic compounds known as pentacarboxylic acids and derivatives. These are carboxylic acids containing exactly five carboxyl groups. (1r,2s,4s,5r,6s,7s,8s,9r,12r)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl benzoate is found in Celastrus angulatus. Based on a literature review very few articles have been published on (1R,2S,4S,5R,6S,7S,8S,9R,12R)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]Dodecan-7-yl benzoate.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309072205002D          

 48 51  0  0  1  0            999 V2000
    0.1896    4.4885    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3780    3.8898    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.1803    4.0820    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1434    3.0988    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7110    2.5001    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -1.5180    2.6981    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0918    2.1034    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -2.5659    2.7786    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8447    1.7662    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.8994    1.2818    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.7841    1.1404    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9554    0.2879    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.2831   -0.4692    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.7428    0.5344    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2035   -0.1360    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -1.3692   -0.3638    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -1.1574   -1.1611    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7421   -1.7432    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.5385   -1.5279    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.5304   -2.5406    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7340   -2.7559    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1150   -3.1226    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7611    0.2447    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.0415    0.0535    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.2773   -0.7370    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.2895   -1.3365    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.0798   -0.9282    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.6466   -0.3287    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4492   -0.5198    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.6849   -1.3104    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1181   -1.9099    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.3156   -1.7188    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0357    1.0803    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.3213    0.6678    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.3932    1.0803    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.1077    0.6678    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.1077   -0.1572    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.8221    1.0803    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.5366    0.6678    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.2511    1.0803    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.5366   -0.1572    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4701    1.7042    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.3348    1.5232    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.8940    2.1297    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.6484    2.9172    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.6989    1.9486    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9910    0.5738    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -1.1840    0.4021    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  2  0  0  0  0
  2  4  1  0  0  0  0
  5  4  1  6  0  0  0
  5  6  1  0  0  0  0
  6  7  1  0  0  0  0
  7  8  1  6  0  0  0
  7  9  1  1  0  0  0
  7 10  1  0  0  0  0
 10 11  1  6  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 12 14  1  0  0  0  0
 15 12  1  6  0  0  0
 15 16  1  0  0  0  0
 16 17  1  1  0  0  0
 17 18  1  0  0  0  0
 18 19  2  0  0  0  0
 18 20  1  0  0  0  0
 20 21  1  0  0  0  0
 20 22  1  0  0  0  0
 16 23  1  0  0  0  0
 23 24  1  6  0  0  0
 24 25  1  0  0  0  0
 25 26  2  0  0  0  0
 25 27  1  0  0  0  0
 27 28  2  0  0  0  0
 28 29  1  0  0  0  0
 29 30  2  0  0  0  0
 30 31  1  0  0  0  0
 31 32  2  0  0  0  0
 27 32  1  0  0  0  0
 23 33  1  0  0  0  0
 10 33  1  0  0  0  0
 33 34  1  6  0  0  0
 34 35  1  0  0  0  0
 35 36  1  0  0  0  0
 36 37  2  0  0  0  0
 36 38  1  0  0  0  0
 38 39  1  0  0  0  0
 39 40  1  0  0  0  0
 39 41  1  0  0  0  0
 33 42  1  0  0  0  0
  5 42  1  0  0  0  0
 42 43  1  6  0  0  0
 43 44  1  0  0  0  0
 44 45  1  0  0  0  0
 44 46  2  0  0  0  0
 15 47  1  0  0  0  0
 10 47  1  0  0  0  0
 47 48  1  6  0  0  0
M  END

     RDKit          3D

 96 99  0  0  0  0  0  0  0  0999 V2000
    1.1229    0.2874   -5.1601 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.1644   -0.8796   -4.2236 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7286   -1.9801   -4.6446 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.6664   -0.7260   -2.9533 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.7195   -1.7887   -2.0581 C   0  0  1  0  0  0  0  0  0  0  0  0
    3.1198   -2.1158   -1.6773 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.6821   -1.1321   -0.6842 C   0  0  2  0  0  0  0  0  0  0  0  0
    4.2871    0.0692   -1.3831 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.7765   -1.8311   -0.0986 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.8099   -0.7345    0.4205 C   0  0  1  0  0  0  0  0  0  0  0  0
    3.2610    0.5236    0.8595 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.6012    0.4265    2.1797 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.2857    1.7300    2.8685 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.0476    0.1012    2.4169 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.6742   -0.6990    2.6984 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.2697   -0.1706    2.6320 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.5626   -0.7225    3.7286 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.0430    0.0308    4.7686 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.2120    1.2593    4.7281 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6927   -0.5656    5.9054 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9026   -1.2825    5.3078 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.2420    0.5498    6.7610 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.5344   -0.6078    1.3783 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.6810    0.0400    1.2356 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9203   -0.5145    1.4892 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.8368   -1.7105    1.8639 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.2017    0.1450    1.3615 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3443    1.4697    1.0297 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.5840    2.0444    0.9095 C   0  0  0  0  0  0  0  0  0  0  0  0
   -5.7568    1.3146    1.1179 C   0  0  0  0  0  0  0  0  0  0  0  0
   -5.6155   -0.0157    1.4515 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.3530   -0.5795    1.5682 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.3163   -0.5616    0.1208 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.2266    0.8018   -0.5177 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0974    1.1032   -0.9299 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3650    2.2924   -1.5938 C   0  0  0  0  0  0  0  0  0  0  0  0
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   -0.6565    3.9962   -3.9884 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9779    4.4035   -3.3566 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.8370   -1.6074   -0.8254 C   0  0  1  0  0  0  0  0  0  0  0  0
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   -1.4028   -2.3918   -1.2074 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8015   -2.1989   -1.7114 C   0  0  0  0  0  0  0  0  0  0  0  0
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    2.9641   -1.6705    1.5626 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.2594   -2.8123    1.5536 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.0370    0.4846   -5.3476 H   0  0  0  0  0  0  0  0  0  0  0  0
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    3.2205   -3.1272   -1.2554 H   0  0  0  0  0  0  0  0  0  0  0  0
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    3.8967    0.1848   -2.4164 H   0  0  0  0  0  0  0  0  0  0  0  0
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    5.5815   -1.7638   -0.6695 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.6338    2.3951    2.2517 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.2382    2.3015    2.9836 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.9093    1.5399    3.8725 H   0  0  0  0  0  0  0  0  0  0  0  0
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    2.9881   -1.0644    3.6746 H   0  0  0  0  0  0  0  0  0  0  0  0
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    4.0424   -1.9147    1.6614 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.0069   -3.0953    2.4710 H   0  0  0  0  0  0  0  0  0  0  0  0
 40 39  1  0
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 40 87  1  0
 39 84  1  0
 41 88  1  0
 41 89  1  0
 41 90  1  0
 38 82  1  0
 38 83  1  0
 34 80  1  0
 34 81  1  0
 42 91  1  1
 45 92  1  0
 45 93  1  0
 45 94  1  0
  5 52  1  6
  6 53  1  0
  6 54  1  0
  8 55  1  0
  8 56  1  0
  8 57  1  0
  9 58  1  0
 13 59  1  0
 13 60  1  0
 13 61  1  0
 14 62  1  0
 14 63  1  0
 14 64  1  0
 15 65  1  1
 47 95  1  1
 48 96  1  0
 16 66  1  1
 20 67  1  0
 21 68  1  0
 21 69  1  0
 21 70  1  0
 22 71  1  0
 22 72  1  0
 22 73  1  0
 23 74  1  1
 28 75  1  0
 29 76  1  0
 30 77  1  0
 31 78  1  0
 32 79  1  0
  1 49  1  0
  1 50  1  0
  1 51  1  0
M  END


  Mrv1652309072205002D          

 48 51  0  0  1  0            999 V2000
    0.1896    4.4885    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3780    3.8898    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.1803    4.0820    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1434    3.0988    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7110    2.5001    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -1.5180    2.6981    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0918    2.1034    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -2.5659    2.7786    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8447    1.7662    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.8994    1.2818    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.7841    1.1404    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9554    0.2879    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.2831   -0.4692    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.7428    0.5344    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2035   -0.1360    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -1.3692   -0.3638    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -1.1574   -1.1611    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7421   -1.7432    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.5385   -1.5279    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.5304   -2.5406    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7340   -2.7559    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1150   -3.1226    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7611    0.2447    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.0415    0.0535    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.2773   -0.7370    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.2895   -1.3365    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.0798   -0.9282    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.6466   -0.3287    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4492   -0.5198    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.6849   -1.3104    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1181   -1.9099    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.3156   -1.7188    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0357    1.0803    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.3213    0.6678    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.3932    1.0803    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.1077    0.6678    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.1077   -0.1572    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.8221    1.0803    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.5366    0.6678    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.2511    1.0803    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.5366   -0.1572    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4701    1.7042    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.3348    1.5232    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.8940    2.1297    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.6484    2.9172    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.6989    1.9486    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9910    0.5738    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -1.1840    0.4021    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  2  0  0  0  0
  2  4  1  0  0  0  0
  5  4  1  6  0  0  0
  5  6  1  0  0  0  0
  6  7  1  0  0  0  0
  7  8  1  6  0  0  0
  7  9  1  1  0  0  0
  7 10  1  0  0  0  0
 10 11  1  6  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 12 14  1  0  0  0  0
 15 12  1  6  0  0  0
 15 16  1  0  0  0  0
 16 17  1  1  0  0  0
 17 18  1  0  0  0  0
 18 19  2  0  0  0  0
 18 20  1  0  0  0  0
 20 21  1  0  0  0  0
 20 22  1  0  0  0  0
 16 23  1  0  0  0  0
 23 24  1  6  0  0  0
 24 25  1  0  0  0  0
 25 26  2  0  0  0  0
 25 27  1  0  0  0  0
 27 28  2  0  0  0  0
 28 29  1  0  0  0  0
 29 30  2  0  0  0  0
 30 31  1  0  0  0  0
 31 32  2  0  0  0  0
 27 32  1  0  0  0  0
 23 33  1  0  0  0  0
 10 33  1  0  0  0  0
 33 34  1  6  0  0  0
 34 35  1  0  0  0  0
 35 36  1  0  0  0  0
 36 37  2  0  0  0  0
 36 38  1  0  0  0  0
 38 39  1  0  0  0  0
 39 40  1  0  0  0  0
 39 41  1  0  0  0  0
 33 42  1  0  0  0  0
  5 42  1  0  0  0  0
 42 43  1  6  0  0  0
 43 44  1  0  0  0  0
 44 45  1  0  0  0  0
 44 46  2  0  0  0  0
 15 47  1  0  0  0  0
 10 47  1  0  0  0  0
 47 48  1  6  0  0  0
M  END
> <DATABASE_ID>
NP0242645

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC(C)CC(=O)OC[C@@]12[C@@H](OC(C)=O)[C@H](C[C@](C)(O)[C@@]11OC(C)(C)[C@H]([C@H]1O)[C@H](OC(=O)C(C)C)[C@H]2OC(=O)C1=CC=CC=C1)OC(C)=O

> <INCHI_IDENTIFIER>
InChI=1S/C35H48O13/c1-18(2)15-24(38)43-17-34-28(45-21(6)37)23(44-20(5)36)16-33(9,42)35(34)27(39)25(32(7,8)48-35)26(46-30(40)19(3)4)29(34)47-31(41)22-13-11-10-12-14-22/h10-14,18-19,23,25-29,39,42H,15-17H2,1-9H3/t23-,25-,26-,27+,28-,29+,33-,34-,35+/m0/s1

> <INCHI_KEY>
LRFCSDYUPSIBOI-VLJLBPJCSA-N

> <FORMULA>
C35H48O13

> <MOLECULAR_WEIGHT>
676.756

> <EXACT_MASS>
676.309491606

> <JCHEM_ACCEPTOR_COUNT>
8

> <JCHEM_ATOM_COUNT>
96

> <JCHEM_AVERAGE_POLARIZABILITY>
69.25385542816736

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
2

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(1R,2S,4S,5R,6S,7S,8S,9R,12R)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0^{1,6}]dodecan-7-yl benzoate

> <JCHEM_LOGP>
2.998616485333333

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
13.985456982740136

> <JCHEM_PKA_STRONGEST_ACIDIC>
13.26856217368719

> <JCHEM_PKA_STRONGEST_BASIC>
-3.380437225866725

> <JCHEM_POLAR_SURFACE_AREA>
181.19

> <JCHEM_REFRACTIVITY>
165.84600000000006

> <JCHEM_ROTATABLE_BOND_COUNT>
15

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(1R,2S,4S,5R,6S,7S,8S,9R,12R)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0^{1,6}]dodecan-7-yl benzoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 07-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   07-SEP-22         0                                  
HETATM    1  C   UNK     0       0.354   8.378   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      -0.706   7.261   0.000  0.00  0.00           C+0
HETATM    3  O   UNK     0      -2.203   7.620   0.000  0.00  0.00           O+0
HETATM    4  O   UNK     0      -0.268   5.785   0.000  0.00  0.00           O+0
HETATM    5  C   UNK     0      -1.327   4.667   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -2.834   5.036   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0      -3.905   3.926   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      -4.790   5.187   0.000  0.00  0.00           C+0
HETATM    9  O   UNK     0      -5.310   3.297   0.000  0.00  0.00           O+0
HETATM   10  C   UNK     0      -3.546   2.393   0.000  0.00  0.00           C+0
HETATM   11  O   UNK     0      -5.197   2.129   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0      -5.517   0.537   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      -6.128  -0.876   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0      -6.986   0.998   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      -4.113  -0.254   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0      -2.556  -0.679   0.000  0.00  0.00           C+0
HETATM   17  O   UNK     0      -2.161  -2.167   0.000  0.00  0.00           O+0
HETATM   18  C   UNK     0      -3.252  -3.254   0.000  0.00  0.00           C+0
HETATM   19  O   UNK     0      -4.739  -2.852   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0      -2.857  -4.742   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0      -1.370  -5.144   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      -3.948  -5.829   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0      -1.421   0.457   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0       0.077   0.100   0.000  0.00  0.00           O+0
HETATM   25  C   UNK     0       0.518  -1.376   0.000  0.00  0.00           C+0
HETATM   26  O   UNK     0      -0.540  -2.495   0.000  0.00  0.00           O+0
HETATM   27  C   UNK     0       2.016  -1.733   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       3.074  -0.614   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       4.572  -0.970   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       5.012  -2.446   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0       3.954  -3.565   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0       2.456  -3.208   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0      -1.933   2.017   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0      -0.600   1.247   0.000  0.00  0.00           C+0
HETATM   35  O   UNK     0       0.734   2.017   0.000  0.00  0.00           O+0
HETATM   36  C   UNK     0       2.068   1.247   0.000  0.00  0.00           C+0
HETATM   37  O   UNK     0       2.068  -0.293   0.000  0.00  0.00           O+0
HETATM   38  C   UNK     0       3.401   2.017   0.000  0.00  0.00           C+0
HETATM   39  C   UNK     0       4.735   1.247   0.000  0.00  0.00           C+0
HETATM   40  C   UNK     0       6.069   2.017   0.000  0.00  0.00           C+0
HETATM   41  C   UNK     0       4.735  -0.293   0.000  0.00  0.00           C+0
HETATM   42  C   UNK     0      -0.878   3.181   0.000  0.00  0.00           C+0
HETATM   43  O   UNK     0       0.625   2.843   0.000  0.00  0.00           O+0
HETATM   44  C   UNK     0       1.669   3.975   0.000  0.00  0.00           C+0
HETATM   45  C   UNK     0       1.210   5.446   0.000  0.00  0.00           C+0
HETATM   46  O   UNK     0       3.171   3.637   0.000  0.00  0.00           O+0
HETATM   47  C   UNK     0      -3.716   1.071   0.000  0.00  0.00           C+0
HETATM   48  O   UNK     0      -2.210   0.751   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3    4                                                  
CONECT    3    2                                                            
CONECT    4    2    5                                                       
CONECT    5    4    6   42                                                  
CONECT    6    5    7                                                       
CONECT    7    6    8    9   10                                             
CONECT    8    7                                                            
CONECT    9    7                                                            
CONECT   10    7   11   33   47                                             
CONECT   11   10   12                                                       
CONECT   12   11   13   14   15                                             
CONECT   13   12                                                            
CONECT   14   12                                                            
CONECT   15   12   16   47                                                  
CONECT   16   15   17   23                                                  
CONECT   17   16   18                                                       
CONECT   18   17   19   20                                                  
CONECT   19   18                                                            
CONECT   20   18   21   22                                                  
CONECT   21   20                                                            
CONECT   22   20                                                            
CONECT   23   16   24   33                                                  
CONECT   24   23   25                                                       
CONECT   25   24   26   27                                                  
CONECT   26   25                                                            
CONECT   27   25   28   32                                                  
CONECT   28   27   29                                                       
CONECT   29   28   30                                                       
CONECT   30   29   31                                                       
CONECT   31   30   32                                                       
CONECT   32   31   27                                                       
CONECT   33   23   10   34   42                                             
CONECT   34   33   35                                                       
CONECT   35   34   36                                                       
CONECT   36   35   37   38                                                  
CONECT   37   36                                                            
CONECT   38   36   39                                                       
CONECT   39   38   40   41                                                  
CONECT   40   39                                                            
CONECT   41   39                                                            
CONECT   42   33    5   43                                                  
CONECT   43   42   44                                                       
CONECT   44   43   45   46                                                  
CONECT   45   44                                                            
CONECT   46   44                                                            
CONECT   47   15   10   48                                                  
CONECT   48   47                                                            
MASTER        0    0    0    0    0    0    0    0   48    0  102    0
END

View in JSmol

Synonyms

Value	Source
(1R,2S,4S,5R,6S,7S,8S,9R,12R)-4,5-Bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0,]dodecan-7-yl benzoic acid	Generator

Chemical Formula

C₃₅H₄₈O₁₃

Average Mass

676.7560 Da

Monoisotopic Mass

676.30949 Da

IUPAC Name

(1R,2S,4S,5R,6S,7S,8S,9R,12R)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0^{1,6}]dodecan-7-yl benzoate

Traditional Name

(1R,2S,4S,5R,6S,7S,8S,9R,12R)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0^{1,6}]dodecan-7-yl benzoate

CAS Registry Number

Not Available

SMILES

CC(C)CC(=O)OC[C@@]12[C@@H](OC(C)=O)[C@H](C[C@](C)(O)[C@@]11OC(C)(C)[C@H]([C@H]1O)[C@H](OC(=O)C(C)C)[C@H]2OC(=O)C1=CC=CC=C1)OC(C)=O

InChI Identifier

InChI=1S/C35H48O13/c1-18(2)15-24(38)43-17-34-28(45-21(6)37)23(44-20(5)36)16-33(9,42)35(34)27(39)25(32(7,8)48-35)26(46-30(40)19(3)4)29(34)47-31(41)22-13-11-10-12-14-22/h10-14,18-19,23,25-29,39,42H,15-17H2,1-9H3/t23-,25-,26-,27+,28-,29+,33-,34-,35+/m0/s1

InChI Key

LRFCSDYUPSIBOI-VLJLBPJCSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Celastrus angulatus	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as pentacarboxylic acids and derivatives. These are carboxylic acids containing exactly five carboxyl groups.

Kingdom

Organic compounds

Super Class

Organic acids and derivatives

Class

Carboxylic acids and derivatives

Sub Class

Pentacarboxylic acids and derivatives

Direct Parent

Pentacarboxylic acids and derivatives

Alternative Parents

Substituents

Pentacarboxylic acid or derivatives
Agarofuran
Sesquiterpenoid
Benzoate ester
Benzoic acid or derivatives
Benzoyl
Fatty acid ester
Oxepane
Cyclitol or derivatives
Monocyclic benzene moiety
Fatty acyl
Benzenoid
Cyclic alcohol
Tetrahydrofuran
Tertiary alcohol
Carboxylic acid ester
Secondary alcohol
Organoheterocyclic compound
Ether
Dialkyl ether
Oxacycle
Organooxygen compound
Organic oxygen compound
Carbonyl group
Hydrocarbon derivative
Organic oxide
Alcohol
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	3	ChemAxon
pKa (Strongest Acidic)	13.27	ChemAxon
pKa (Strongest Basic)	-3.4	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	8	ChemAxon
Hydrogen Donor Count	2	ChemAxon
Polar Surface Area	181.19 Å²	ChemAxon
Rotatable Bond Count	15	ChemAxon
Refractivity	165.85 m³·mol⁻¹	ChemAxon
Polarizability	69.25 Å³	ChemAxon
Number of Rings	4	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

162960396

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (1r,2s,4s,5r,6s,7s,8s,9r,12r)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl benzoate (NP0242645)

MOL for NP0242645 ((1r,2s,4s,5r,6s,7s,8s,9r,12r)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl benzoate)

3D MOL for NP0242645 ((1r,2s,4s,5r,6s,7s,8s,9r,12r)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl benzoate)

3D SDF for NP0242645 ((1r,2s,4s,5r,6s,7s,8s,9r,12r)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl benzoate)

3D-SDF for NP0242645 ((1r,2s,4s,5r,6s,7s,8s,9r,12r)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl benzoate)

PDB for NP0242645 ((1r,2s,4s,5r,6s,7s,8s,9r,12r)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl benzoate)

3D PDB for NP0242645 ((1r,2s,4s,5r,6s,7s,8s,9r,12r)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl benzoate)

SMILES for NP0242645 ((1r,2s,4s,5r,6s,7s,8s,9r,12r)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl benzoate)

INCHI for NP0242645 ((1r,2s,4s,5r,6s,7s,8s,9r,12r)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl benzoate)

Structure for NP0242645 ((1r,2s,4s,5r,6s,7s,8s,9r,12r)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl benzoate)

3D Structure for NP0242645 ((1r,2s,4s,5r,6s,7s,8s,9r,12r)-4,5-bis(acetyloxy)-2,12-dihydroxy-2,10,10-trimethyl-6-{[(3-methylbutanoyl)oxy]methyl}-8-[(2-methylpropanoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-7-yl benzoate)