NP-MRD: Showing NP-Card for (4ar,6ar,8ar,12as,12bs,14ar,14br)-4,4,6a,8a,11,11,12b,14b-octamethyl-2,4a,5,6,8,9,10,12,12a,13,14,14a-dodecahydro-1h-picen-3-one (NP0240580)

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Record Information

Version

2.0

Created at

2022-09-07 00:26:19 UTC

Updated at

2022-09-07 00:26:19 UTC

NP-MRD ID

NP0240580

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(4ar,6ar,8ar,12as,12bs,14ar,14br)-4,4,6a,8a,11,11,12b,14b-octamethyl-2,4a,5,6,8,9,10,12,12a,13,14,14a-dodecahydro-1h-picen-3-one

Description

NSC692217 belongs to the class of organic compounds known as scalarane sesterterpenoids. These are sesterterpenoids with a structure based on the scalarane backbone. Scalarane is a tetracyclic compound, which is similar the homoandrostane with five methyl groups at the 4-, 4-, 8-, 17-, 17a-positions. (4ar,6ar,8ar,12as,12bs,14ar,14br)-4,4,6a,8a,11,11,12b,14b-octamethyl-2,4a,5,6,8,9,10,12,12a,13,14,14a-dodecahydro-1h-picen-3-one is found in Alchornea latifolia, Alnus glutinosa, Canarina canariensis, Caraipa densifolia, Cichorium spinosum, Cymbidium giganteum, Diospyros ferrea, Diospyros lotus, Diospyros maingayi, Diospyros maritima, Diospyros rhodocalyx, Dudleya farinosa, Embelia schimperi, Tetradium glabrifolium, Euphorbia cyparissias, Euphorbia drupifera, Euphorbia hirta, Euphorbia lathyris, Euphorbia mellifera, Euphorbia stygiana, Euphorbia tortilis, Excoecaria agallocha, Lepra ophthalmiza, Leucosyke quadrinervia, Mallotus apelta, Mangifera indica, Manihot esculenta, Morella rubra, Neolitsea buisanensis, Neolitsea hiiranensis, Neolitsea villosa, Pieris japonica, Persicaria nepalensis, Rhododendron aureum, Scaevola spinescens and Skimmia laureola. Based on a literature review very few articles have been published on NSC692217.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309072202262D          

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M  END

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M  END


  Mrv1652309072202262D          

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  2  3  1  0  0  0  0
  2  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  6  7  1  1  0  0  0
  6  8  1  0  0  0  0
  8  9  1  0  0  0  0
  9 10  2  0  0  0  0
 10 11  1  0  0  0  0
 11 12  1  6  0  0  0
 11 13  1  0  0  0  0
 13 14  1  0  0  0  0
 15 14  1  1  0  0  0
 15 16  1  0  0  0  0
 10 16  1  0  0  0  0
 16 17  1  1  0  0  0
 16 18  1  0  0  0  0
 18 19  1  0  0  0  0
 20 19  1  1  0  0  0
 20 21  1  0  0  0  0
 21 22  1  0  0  0  0
 21 23  1  0  0  0  0
 21 24  1  0  0  0  0
 24 25  2  0  0  0  0
 24 26  1  0  0  0  0
 26 27  1  0  0  0  0
 27 28  1  0  0  0  0
 20 28  1  0  0  0  0
 15 28  1  0  0  0  0
 28 29  1  1  0  0  0
 11 30  1  0  0  0  0
  6 30  1  0  0  0  0
 30 31  1  1  0  0  0
  2 31  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0240580

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC1(C)CC[C@]2(C)CC=C3[C@]4(C)CC[C@H]5C(C)(C)C(=O)CC[C@]5(C)[C@H]4CC[C@@]3(C)[C@H]2C1

> <INCHI_IDENTIFIER>
InChI=1S/C30H48O/c1-25(2)17-18-27(5)13-9-21-29(7)14-10-20-26(3,4)24(31)12-16-28(20,6)22(29)11-15-30(21,8)23(27)19-25/h9,20,22-23H,10-19H2,1-8H3/t20-,22+,23-,27-,28-,29-,30+/m0/s1

> <INCHI_KEY>
DBCAVZSSFGIHQZ-KGSLAXPJSA-N

> <FORMULA>
C30H48O

> <MOLECULAR_WEIGHT>
424.713

> <EXACT_MASS>
424.370516166

> <JCHEM_ACCEPTOR_COUNT>
1

> <JCHEM_ATOM_COUNT>
79

> <JCHEM_AVERAGE_POLARIZABILITY>
53.505718372936144

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
0

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(4aR,6aR,8aR,12aS,12bS,14aR,14bR)-4,4,6a,8a,11,11,12b,14b-octamethyl-1,2,3,4,4a,5,6,6a,8,8a,9,10,11,12,12a,12b,13,14,14a,14b-icosahydropicen-3-one

> <JCHEM_LOGP>
7.966668539999999

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA_STRONGEST_ACIDIC>
19.95851037956884

> <JCHEM_PKA_STRONGEST_BASIC>
-7.4708850377430505

> <JCHEM_POLAR_SURFACE_AREA>
17.07

> <JCHEM_REFRACTIVITY>
131.08499999999995

> <JCHEM_ROTATABLE_BOND_COUNT>
0

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(4aR,6aR,8aR,12aS,12bS,14aR,14bR)-4,4,6a,8a,11,11,12b,14b-octamethyl-2,4a,5,6,8,9,10,12,12a,13,14,14a-dodecahydro-1H-picen-3-one

> <JCHEM_VEBER_RULE>
1

$$$$

HEADER    PROTEIN                                 07-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   07-SEP-22         0                                  
HETATM    1  C   UNK     0       7.119  -5.710   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       8.566  -5.184   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       8.833  -6.700   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       7.796  -3.850   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       8.566  -2.516   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      10.106  -2.516   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       9.336  -1.183   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      10.876  -1.183   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0      12.416  -1.183   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0      13.186  -2.516   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0      12.416  -3.850   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      11.646  -5.184   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      13.186  -5.184   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0      14.726  -5.184   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      15.496  -3.850   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0      14.726  -2.516   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0      13.956  -1.183   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0      15.496  -1.183   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0      17.036  -1.183   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0      17.806  -2.516   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0      19.346  -2.516   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      19.078  -1.000   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0      20.793  -1.990   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0      20.116  -3.850   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0      21.656  -3.850   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0      19.346  -5.184   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0      17.806  -5.184   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0      17.036  -3.850   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0      16.266  -5.184   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0      10.876  -3.850   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0      10.106  -5.184   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3    4   31                                             
CONECT    3    2                                                            
CONECT    4    2    5                                                       
CONECT    5    4    6                                                       
CONECT    6    5    7    8   30                                             
CONECT    7    6                                                            
CONECT    8    6    9                                                       
CONECT    9    8   10                                                       
CONECT   10    9   11   16                                                  
CONECT   11   10   12   13   30                                             
CONECT   12   11                                                            
CONECT   13   11   14                                                       
CONECT   14   13   15                                                       
CONECT   15   14   16   28                                                  
CONECT   16   15   10   17   18                                             
CONECT   17   16                                                            
CONECT   18   16   19                                                       
CONECT   19   18   20                                                       
CONECT   20   19   21   28                                                  
CONECT   21   20   22   23   24                                             
CONECT   22   21                                                            
CONECT   23   21                                                            
CONECT   24   21   25   26                                                  
CONECT   25   24                                                            
CONECT   26   24   27                                                       
CONECT   27   26   28                                                       
CONECT   28   27   20   15   29                                             
CONECT   29   28                                                            
CONECT   30   11    6   31                                                  
CONECT   31   30    2                                                       
MASTER        0    0    0    0    0    0    0    0   31    0   70    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₃₀H₄₈O

Average Mass

424.7130 Da

Monoisotopic Mass

424.37052 Da

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

CC1(C)CC[C@]2(C)CC=C3[C@]4(C)CC[C@H]5C(C)(C)C(=O)CC[C@]5(C)[C@H]4CC[C@@]3(C)[C@H]2C1

InChI Identifier

InChI=1S/C30H48O/c1-25(2)17-18-27(5)13-9-21-29(7)14-10-20-26(3,4)24(31)12-16-28(20,6)22(29)11-15-30(21,8)23(27)19-25/h9,20,22-23H,10-19H2,1-8H3/t20-,22+,23-,27-,28-,29-,30+/m0/s1

InChI Key

DBCAVZSSFGIHQZ-KGSLAXPJSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Alchornea latifolia	LOTUS Database	35616633
Alnus glutinosa	LOTUS Database	35616633
Canarina canariensis	LOTUS Database	35616633
Caraipa densifolia	LOTUS Database	35616633
Cichorium spinosum	LOTUS Database	35616633
Cymbidium giganteum	LOTUS Database	35616633
Diospyros ferrea	LOTUS Database	35616633
Diospyros lotus	LOTUS Database	35616633
Diospyros maingayi	LOTUS Database	35616633
Diospyros maritima	LOTUS Database	35616633
Diospyros rhodocalyx	LOTUS Database	35616633
Dudleya farinosa	LOTUS Database	35616633
Embelia schimperi	LOTUS Database	35616633
Euodia fargesii	LOTUS Database	35616633
Euphorbia cyparissias	LOTUS Database	35616633
Euphorbia drupifera	LOTUS Database	35616633
Euphorbia hirta	LOTUS Database	35616633
Euphorbia lathyris	LOTUS Database	35616633
Euphorbia mellifera	LOTUS Database	35616633
Euphorbia stygiana	LOTUS Database	35616633
Euphorbia tortilis	LOTUS Database	35616633
Excoecaria agallocha	LOTUS Database	35616633
Lepra ophthalmiza	LOTUS Database	35616633
Leucosyke quadrinervia	LOTUS Database	35616633
Mallotus apelta	LOTUS Database	35616633
Mangifera indica	LOTUS Database	35616633
Manihot esculenta	LOTUS Database	35616633
Morella rubra	LOTUS Database	35616633
Neolitsea buisanensis	LOTUS Database	35616633
Neolitsea hiiranensis	LOTUS Database	35616633
Neolitsea villosa	LOTUS Database	35616633
Pieris japonica	LOTUS Database	35616633
Polygonum nepalense	LOTUS Database	35616633
Rhododendron chrysanthum	LOTUS Database	35616633
Scaevola spinescens	LOTUS Database	35616633
Skimmia laureola	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as scalarane sesterterpenoids. These are sesterterpenoids with a structure based on the scalarane backbone. Scalarane is a tetracyclic compound, which is similar the homoandrostane with five methyl groups at the 4-, 4-, 8-, 17-, 17a-positions.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Sesterterpenoids

Direct Parent

Scalarane sesterterpenoids

Alternative Parents

Substituents

Scalarane sesterterpenoid
Cyclic ketone
Ketone
Organic oxygen compound
Organic oxide
Hydrocarbon derivative
Organooxygen compound
Carbonyl group
Aliphatic homopolycyclic compound

Molecular Framework

Aliphatic homopolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

347579

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

392170

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (4ar,6ar,8ar,12as,12bs,14ar,14br)-4,4,6a,8a,11,11,12b,14b-octamethyl-2,4a,5,6,8,9,10,12,12a,13,14,14a-dodecahydro-1h-picen-3-one (NP0240580)

MOL for NP0240580 ((4ar,6ar,8ar,12as,12bs,14ar,14br)-4,4,6a,8a,11,11,12b,14b-octamethyl-2,4a,5,6,8,9,10,12,12a,13,14,14a-dodecahydro-1h-picen-3-one)

3D MOL for NP0240580 ((4ar,6ar,8ar,12as,12bs,14ar,14br)-4,4,6a,8a,11,11,12b,14b-octamethyl-2,4a,5,6,8,9,10,12,12a,13,14,14a-dodecahydro-1h-picen-3-one)

3D SDF for NP0240580 ((4ar,6ar,8ar,12as,12bs,14ar,14br)-4,4,6a,8a,11,11,12b,14b-octamethyl-2,4a,5,6,8,9,10,12,12a,13,14,14a-dodecahydro-1h-picen-3-one)

3D-SDF for NP0240580 ((4ar,6ar,8ar,12as,12bs,14ar,14br)-4,4,6a,8a,11,11,12b,14b-octamethyl-2,4a,5,6,8,9,10,12,12a,13,14,14a-dodecahydro-1h-picen-3-one)

PDB for NP0240580 ((4ar,6ar,8ar,12as,12bs,14ar,14br)-4,4,6a,8a,11,11,12b,14b-octamethyl-2,4a,5,6,8,9,10,12,12a,13,14,14a-dodecahydro-1h-picen-3-one)

3D PDB for NP0240580 ((4ar,6ar,8ar,12as,12bs,14ar,14br)-4,4,6a,8a,11,11,12b,14b-octamethyl-2,4a,5,6,8,9,10,12,12a,13,14,14a-dodecahydro-1h-picen-3-one)

SMILES for NP0240580 ((4ar,6ar,8ar,12as,12bs,14ar,14br)-4,4,6a,8a,11,11,12b,14b-octamethyl-2,4a,5,6,8,9,10,12,12a,13,14,14a-dodecahydro-1h-picen-3-one)

INCHI for NP0240580 ((4ar,6ar,8ar,12as,12bs,14ar,14br)-4,4,6a,8a,11,11,12b,14b-octamethyl-2,4a,5,6,8,9,10,12,12a,13,14,14a-dodecahydro-1h-picen-3-one)

Structure for NP0240580 ((4ar,6ar,8ar,12as,12bs,14ar,14br)-4,4,6a,8a,11,11,12b,14b-octamethyl-2,4a,5,6,8,9,10,12,12a,13,14,14a-dodecahydro-1h-picen-3-one)

3D Structure for NP0240580 ((4ar,6ar,8ar,12as,12bs,14ar,14br)-4,4,6a,8a,11,11,12b,14b-octamethyl-2,4a,5,6,8,9,10,12,12a,13,14,14a-dodecahydro-1h-picen-3-one)