NP-MRD: Showing NP-Card for (4s,5r,8s,13r,16s,19r,22r)-8-{[(2r,4r,5r,6r)-5-hydroxy-4-methoxy-6-methyloxan-2-yl]oxy}-5,19-dimethyl-15,18,20-trioxapentacyclo[14.5.1.0⁴,¹³.0⁵,¹⁰.0¹⁹,²²]docosa-1(21),10-dien-14-one (NP0237804)

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Record Information

Version

2.0

Created at

2022-09-06 21:03:06 UTC

Updated at

2022-09-06 21:03:06 UTC

NP-MRD ID

NP0237804

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(4s,5r,8s,13r,16s,19r,22r)-8-{[(2r,4r,5r,6r)-5-hydroxy-4-methoxy-6-methyloxan-2-yl]oxy}-5,19-dimethyl-15,18,20-trioxapentacyclo[14.5.1.0⁴,¹³.0⁵,¹⁰.0¹⁹,²²]docosa-1(21),10-dien-14-one

Description

Cynatratoside A belongs to the class of organic compounds known as o-glycosyl compounds. These are glycoside in which a sugar group is bonded through one carbon to another group via a O-glycosidic bond. (4s,5r,8s,13r,16s,19r,22r)-8-{[(2r,4r,5r,6r)-5-hydroxy-4-methoxy-6-methyloxan-2-yl]oxy}-5,19-dimethyl-15,18,20-trioxapentacyclo[14.5.1.0⁴,¹³.0⁵,¹⁰.0¹⁹,²²]docosa-1(21),10-dien-14-one is found in Vincetoxicum amplexicaule and Vincetoxicum forrestii. (4s,5r,8s,13r,16s,19r,22r)-8-{[(2r,4r,5r,6r)-5-hydroxy-4-methoxy-6-methyloxan-2-yl]oxy}-5,19-dimethyl-15,18,20-trioxapentacyclo[14.5.1.0⁴,¹³.0⁵,¹⁰.0¹⁹,²²]docosa-1(21),10-dien-14-one was first documented in 2008 (PMID: 18343471). Based on a literature review a small amount of articles have been published on Cynatratoside A (PMID: 34662666) (PMID: 30893870) (PMID: 26465069).

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309062223032D          

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M  END

     RDKit          3D

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M  END


  Mrv1652309062223032D          

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    4.4062   -0.4421    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.0925    0.0963    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    6.5396   -0.9036    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.9966   -0.6063    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    9.4920   -1.2660    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   10.3110   -1.1669    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.1683   -2.0249    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    9.6637   -2.6846    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  3  2  1  6  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  6  0  0  0
  7  6  1  6  0  0  0
  7  8  1  0  0  0  0
  8  9  1  0  0  0  0
  9 10  1  0  0  0  0
 10 11  1  6  0  0  0
 10 12  1  0  0  0  0
 12 13  2  0  0  0  0
 13 14  1  0  0  0  0
 15 14  1  1  0  0  0
 15 16  1  0  0  0  0
 16 17  2  0  0  0  0
 16 18  1  0  0  0  0
 18 19  1  0  0  0  0
 19 20  1  6  0  0  0
 20 21  1  0  0  0  0
 21 22  1  0  0  0  0
 22 23  1  1  0  0  0
 22 24  1  0  0  0  0
 24 25  1  0  0  0  0
 25 26  2  0  0  0  0
 26 27  1  0  0  0  0
 27 28  1  0  0  0  0
 29 28  1  6  0  0  0
 15 29  1  0  0  0  0
 10 29  1  0  0  0  0
 30 26  1  6  0  0  0
 19 30  1  0  0  0  0
 22 30  1  0  0  0  0
 12 31  1  0  0  0  0
  7 31  1  0  0  0  0
  5 32  1  0  0  0  0
 32 33  1  0  0  0  0
 33 34  1  6  0  0  0
 33 35  1  0  0  0  0
  3 35  1  0  0  0  0
 35 36  1  1  0  0  0
M  END
> <DATABASE_ID>
NP0237804

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CO[C@@H]1C[C@H](O[C@H]2CC[C@]3(C)[C@H]4CCC5=CO[C@@]6(C)OC[C@@H](OC(=O)[C@@H]4CC=C3C2)[C@@H]56)O[C@H](C)[C@H]1O

> <INCHI_IDENTIFIER>
InChI=1S/C28H40O8/c1-15-25(29)21(31-4)12-23(34-15)35-18-9-10-27(2)17(11-18)6-7-19-20(27)8-5-16-13-32-28(3)24(16)22(14-33-28)36-26(19)30/h6,13,15,18-25,29H,5,7-12,14H2,1-4H3/t15-,18+,19-,20+,21-,22-,23+,24-,25-,27+,28+/m1/s1

> <INCHI_KEY>
QANVGLGBLJFUIP-KTQVWRAASA-N

> <FORMULA>
C28H40O8

> <MOLECULAR_WEIGHT>
504.62

> <EXACT_MASS>
504.272318248

> <JCHEM_ACCEPTOR_COUNT>
7

> <JCHEM_ATOM_COUNT>
76

> <JCHEM_AVERAGE_POLARIZABILITY>
55.41185621943454

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
1

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(4S,5R,8S,13R,16S,19R,22R)-8-{[(2R,4R,5R,6R)-5-hydroxy-4-methoxy-6-methyloxan-2-yl]oxy}-5,19-dimethyl-15,18,20-trioxapentacyclo[14.5.1.0^{4,13}.0^{5,10}.0^{19,22}]docosa-1(21),10-dien-14-one

> <JCHEM_LOGP>
2.9808757013333307

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
6

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA_STRONGEST_ACIDIC>
13.215144980908246

> <JCHEM_PKA_STRONGEST_BASIC>
-3.5794955853507338

> <JCHEM_POLAR_SURFACE_AREA>
92.68000000000002

> <JCHEM_REFRACTIVITY>
130.22920000000002

> <JCHEM_ROTATABLE_BOND_COUNT>
3

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(4S,5R,8S,13R,16S,19R,22R)-8-{[(2R,4R,5R,6R)-5-hydroxy-4-methoxy-6-methyloxan-2-yl]oxy}-5,19-dimethyl-15,18,20-trioxapentacyclo[14.5.1.0^{4,13}.0^{5,10}.0^{19,22}]docosa-1(21),10-dien-14-one

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 06-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   06-SEP-22         0                                  
HETATM    1  C   UNK     0      15.906  -6.613   0.000  0.00  0.00           C+0
HETATM    2  O   UNK     0      14.981  -5.381   0.000  0.00  0.00           O+0
HETATM    3  C   UNK     0      15.585  -3.965   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      14.661  -2.733   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      15.265  -1.317   0.000  0.00  0.00           C+0
HETATM    6  O   UNK     0      14.340  -0.085   0.000  0.00  0.00           O+0
HETATM    7  C   UNK     0      12.811  -0.270   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      11.887   0.961   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0      10.358   0.776   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       9.754  -0.640   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       8.829   0.591   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      10.678  -1.872   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      10.074  -3.288   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       8.545  -3.473   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       7.621  -2.242   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       6.247  -2.939   0.000  0.00  0.00           C+0
HETATM   17  O   UNK     0       6.432  -4.467   0.000  0.00  0.00           O+0
HETATM   18  O   UNK     0       4.747  -2.589   0.000  0.00  0.00           O+0
HETATM   19  C   UNK     0       3.823  -1.358   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       2.203  -1.640   0.000  0.00  0.00           C+0
HETATM   21  O   UNK     0       1.459  -0.291   0.000  0.00  0.00           O+0
HETATM   22  C   UNK     0       2.511   0.833   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       1.117   1.486   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0       2.702   2.361   0.000  0.00  0.00           O+0
HETATM   25  C   UNK     0       4.214   2.652   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0       4.958   1.304   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       6.487   1.489   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       7.777   0.648   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       8.225  -0.825   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       3.906   0.180   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0      12.207  -1.687   0.000  0.00  0.00           C+0
HETATM   32  O   UNK     0      16.794  -1.132   0.000  0.00  0.00           O+0
HETATM   33  C   UNK     0      17.718  -2.363   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0      19.247  -2.178   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0      17.114  -3.780   0.000  0.00  0.00           C+0
HETATM   36  O   UNK     0      18.039  -5.011   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4   35                                                  
CONECT    4    3    5                                                       
CONECT    5    4    6   32                                                  
CONECT    6    5    7                                                       
CONECT    7    6    8   31                                                  
CONECT    8    7    9                                                       
CONECT    9    8   10                                                       
CONECT   10    9   11   12   29                                             
CONECT   11   10                                                            
CONECT   12   10   13   31                                                  
CONECT   13   12   14                                                       
CONECT   14   13   15                                                       
CONECT   15   14   16   29                                                  
CONECT   16   15   17   18                                                  
CONECT   17   16                                                            
CONECT   18   16   19                                                       
CONECT   19   18   20   30                                                  
CONECT   20   19   21                                                       
CONECT   21   20   22                                                       
CONECT   22   21   23   24   30                                             
CONECT   23   22                                                            
CONECT   24   22   25                                                       
CONECT   25   24   26                                                       
CONECT   26   25   27   30                                                  
CONECT   27   26   28                                                       
CONECT   28   27   29                                                       
CONECT   29   28   15   10                                                  
CONECT   30   26   19   22                                                  
CONECT   31   12    7                                                       
CONECT   32    5   33                                                       
CONECT   33   32   34   35                                                  
CONECT   34   33                                                            
CONECT   35   33    3   36                                                  
CONECT   36   35                                                            
MASTER        0    0    0    0    0    0    0    0   36    0   82    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₈H₄₀O₈

Average Mass

504.6200 Da

Monoisotopic Mass

504.27232 Da

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

CO[C@@H]1C[C@H](O[C@H]2CC[C@]3(C)[C@H]4CCC5=CO[C@@]6(C)OC[C@@H](OC(=O)[C@@H]4CC=C3C2)[C@@H]56)O[C@H](C)[C@H]1O

InChI Identifier

InChI=1S/C28H40O8/c1-15-25(29)21(31-4)12-23(34-15)35-18-9-10-27(2)17(11-18)6-7-19-20(27)8-5-16-13-32-28(3)24(16)22(14-33-28)36-26(19)30/h6,13,15,18-25,29H,5,7-12,14H2,1-4H3/t15-,18+,19-,20+,21-,22-,23+,24-,25-,27+,28+/m1/s1

InChI Key

QANVGLGBLJFUIP-KTQVWRAASA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Vincetoxicum amplexicaule	LOTUS Database	35616633
Vincetoxicum forrestii	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as o-glycosyl compounds. These are glycoside in which a sugar group is bonded through one carbon to another group via a O-glycosidic bond.

Kingdom

Organic compounds

Super Class

Organic oxygen compounds

Class

Organooxygen compounds

Sub Class

Carbohydrates and carbohydrate conjugates

Direct Parent

O-glycosyl compounds

Alternative Parents

Substituents

Hexose monosaccharide
O-glycosyl compound
Furofuran
Ketal
Monosaccharide
Oxane
Dihydrofuran
Oxolane
Carboxylic acid ester
Lactone
Secondary alcohol
Oxacycle
Ether
Dialkyl ether
Acetal
Carboxylic acid derivative
Monocarboxylic acid or derivatives
Organoheterocyclic compound
Alcohol
Hydrocarbon derivative
Organic oxide
Carbonyl group
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

10182484

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

21574520

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

Chen H, Xu N, Zhou Y, Qiao L, Cao J, Yao Y, Hua H, Pei Y: Steroidal glycosides from the roots of Cynanchum amplexicaule Sieb. et Zucc. Steroids. 2008 Jul;73(6):629-36. doi: 10.1016/j.steroids.2008.01.024. Epub 2008 Feb 9. [PubMed:18343471 ]
Zhang Y, Yang Y, Yan C, Li J, Zhang P, Liu R, He J, Chang YX: A review of the ethnopharmacology, phytochemistry and pharmacology of Cynanchumatratum. J Ethnopharmacol. 2022 Feb 10;284:114748. doi: 10.1016/j.jep.2021.114748. Epub 2021 Oct 15. [PubMed:34662666 ]
Yang J, Wang B, Zhang CF, Xu XH, Zhang M: A C(21)-Steroidal Glycoside from Cynanchum atratum Attenuates Concanavalin A-Induced Liver Injury in Mice. Molecules. 2019 Mar 19;24(6):1087. doi: 10.3390/molecules24061087. [PubMed:30893870 ]
Zhao D, Wang HF, Chen G, Li YP, Hua HM, Pei YH: Two new 13,14:14,15-disecopregnane-type compounds from the roots of Cynanchum paniculatum. J Asian Nat Prod Res. 2016;18(4):339-43. doi: 10.1080/10286020.2015.1080246. Epub 2015 Oct 14. [PubMed:26465069 ]
LOTUS database [Link]

Showing NP-Card for (4s,5r,8s,13r,16s,19r,22r)-8-{[(2r,4r,5r,6r)-5-hydroxy-4-methoxy-6-methyloxan-2-yl]oxy}-5,19-dimethyl-15,18,20-trioxapentacyclo[14.5.1.0⁴,¹³.0⁵,¹⁰.0¹⁹,²²]docosa-1(21),10-dien-14-one (NP0237804)

MOL for NP0237804 ((4s,5r,8s,13r,16s,19r,22r)-8-{[(2r,4r,5r,6r)-5-hydroxy-4-methoxy-6-methyloxan-2-yl]oxy}-5,19-dimethyl-15,18,20-trioxapentacyclo[14.5.1.0⁴,¹³.0⁵,¹⁰.0¹⁹,²²]docosa-1(21),10-dien-14-one)

3D MOL for NP0237804 ((4s,5r,8s,13r,16s,19r,22r)-8-{[(2r,4r,5r,6r)-5-hydroxy-4-methoxy-6-methyloxan-2-yl]oxy}-5,19-dimethyl-15,18,20-trioxapentacyclo[14.5.1.0⁴,¹³.0⁵,¹⁰.0¹⁹,²²]docosa-1(21),10-dien-14-one)

3D SDF for NP0237804 ((4s,5r,8s,13r,16s,19r,22r)-8-{[(2r,4r,5r,6r)-5-hydroxy-4-methoxy-6-methyloxan-2-yl]oxy}-5,19-dimethyl-15,18,20-trioxapentacyclo[14.5.1.0⁴,¹³.0⁵,¹⁰.0¹⁹,²²]docosa-1(21),10-dien-14-one)

3D-SDF for NP0237804 ((4s,5r,8s,13r,16s,19r,22r)-8-{[(2r,4r,5r,6r)-5-hydroxy-4-methoxy-6-methyloxan-2-yl]oxy}-5,19-dimethyl-15,18,20-trioxapentacyclo[14.5.1.0⁴,¹³.0⁵,¹⁰.0¹⁹,²²]docosa-1(21),10-dien-14-one)

PDB for NP0237804 ((4s,5r,8s,13r,16s,19r,22r)-8-{[(2r,4r,5r,6r)-5-hydroxy-4-methoxy-6-methyloxan-2-yl]oxy}-5,19-dimethyl-15,18,20-trioxapentacyclo[14.5.1.0⁴,¹³.0⁵,¹⁰.0¹⁹,²²]docosa-1(21),10-dien-14-one)

3D PDB for NP0237804 ((4s,5r,8s,13r,16s,19r,22r)-8-{[(2r,4r,5r,6r)-5-hydroxy-4-methoxy-6-methyloxan-2-yl]oxy}-5,19-dimethyl-15,18,20-trioxapentacyclo[14.5.1.0⁴,¹³.0⁵,¹⁰.0¹⁹,²²]docosa-1(21),10-dien-14-one)

SMILES for NP0237804 ((4s,5r,8s,13r,16s,19r,22r)-8-{[(2r,4r,5r,6r)-5-hydroxy-4-methoxy-6-methyloxan-2-yl]oxy}-5,19-dimethyl-15,18,20-trioxapentacyclo[14.5.1.0⁴,¹³.0⁵,¹⁰.0¹⁹,²²]docosa-1(21),10-dien-14-one)

INCHI for NP0237804 ((4s,5r,8s,13r,16s,19r,22r)-8-{[(2r,4r,5r,6r)-5-hydroxy-4-methoxy-6-methyloxan-2-yl]oxy}-5,19-dimethyl-15,18,20-trioxapentacyclo[14.5.1.0⁴,¹³.0⁵,¹⁰.0¹⁹,²²]docosa-1(21),10-dien-14-one)

Structure for NP0237804 ((4s,5r,8s,13r,16s,19r,22r)-8-{[(2r,4r,5r,6r)-5-hydroxy-4-methoxy-6-methyloxan-2-yl]oxy}-5,19-dimethyl-15,18,20-trioxapentacyclo[14.5.1.0⁴,¹³.0⁵,¹⁰.0¹⁹,²²]docosa-1(21),10-dien-14-one)

3D Structure for NP0237804 ((4s,5r,8s,13r,16s,19r,22r)-8-{[(2r,4r,5r,6r)-5-hydroxy-4-methoxy-6-methyloxan-2-yl]oxy}-5,19-dimethyl-15,18,20-trioxapentacyclo[14.5.1.0⁴,¹³.0⁵,¹⁰.0¹⁹,²²]docosa-1(21),10-dien-14-one)