NP-MRD: Showing NP-Card for (1s,10s)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0¹,⁶.0¹¹,¹⁶]heptadeca-2,5,11,13,15-pentaen-4-one (NP0237425)

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Record Information

Version

2.0

Created at

2022-09-06 20:33:25 UTC

Updated at

2022-09-06 20:33:26 UTC

NP-MRD ID

NP0237425

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1s,10s)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0¹,⁶.0¹¹,¹⁶]heptadeca-2,5,11,13,15-pentaen-4-one

Description

(1S,10S)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0¹,⁶.0¹¹,¹⁶]Heptadeca-2,5,11,13,15-pentaen-4-one belongs to the class of organic compounds known as isocoumarans. Isocoumarans are compounds containing the coumaran skeleton, which consists of a benzene ring fused to a 1,3-dihydrofuran ring. (1s,10s)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0¹,⁶.0¹¹,¹⁶]heptadeca-2,5,11,13,15-pentaen-4-one is found in Kadsura coccinea. Based on a literature review very few articles have been published on (1S,10S)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0¹,⁶.0¹¹,¹⁶]Heptadeca-2,5,11,13,15-pentaen-4-one.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309062222332D          

 30 33  0  0  1  0            999 V2000
    0.4085    1.0086    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.0629    0.4392    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4476   -0.3733    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1440   -0.8254    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8300   -0.3142    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.6738    0.6644    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.2150   -1.6686    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.6610   -2.2958    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.2066   -2.7687    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.6272   -2.0002    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.4318   -1.8179    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.6762   -1.0299    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.5513   -1.0289    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.2319   -1.5408    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.1160   -0.4243    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.6366    0.3089    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.3999    0.7171    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.3114   -0.6066    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.2418    0.2793    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.5006    1.1253    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.0670   -1.3946    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.6767   -3.4619    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.1446   -4.1762    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.8164   -3.5377    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.4793   -4.3263    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.2549   -2.8933    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.4249   -2.0518    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7029   -1.5924    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7186   -0.7620    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0788   -0.4552    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  2  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  4  7  1  0  0  0  0
  7  8  1  6  0  0  0
  9  8  1  1  0  0  0
  9 10  1  0  0  0  0
 10 11  2  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 12 15  2  0  0  0  0
 15 16  1  0  0  0  0
 16 17  1  0  0  0  0
 15 18  1  0  0  0  0
 18 19  1  0  0  0  0
 19 20  1  0  0  0  0
 18 21  2  0  0  0  0
 10 21  1  0  0  0  0
  7 21  1  0  0  0  0
  9 22  1  0  0  0  0
 22 23  1  0  0  0  0
 22 24  1  0  0  0  0
 24 25  1  0  0  0  0
 24 26  1  0  0  0  0
 26 27  1  0  0  0  0
  7 27  1  0  0  0  0
 27 28  2  0  0  0  0
 28 29  1  0  0  0  0
  3 29  1  0  0  0  0
 29 30  2  0  0  0  0
M  END

     RDKit          3D

 58 61  0  0  0  0  0  0  0  0999 V2000
   -2.3960   -4.8557   -0.7401 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1027   -3.8230    0.1583 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0936   -2.4768   -0.1978 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0929   -1.7365    0.1903 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0951   -2.2875    0.9701 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.2419   -2.6947    2.2970 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.9550   -0.3037   -0.1452 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.9944    0.4840    1.0358 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.5540    1.6504    0.4462 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.7872    1.2116    0.2052 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.0707    1.6982    0.2707 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.0837    0.9647   -0.3118 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.4074    1.4409   -0.2569 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.6259    2.6679    0.4049 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.7846   -0.2162   -0.9346 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.8505   -0.9153   -1.5120 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.6096   -1.8743   -0.8287 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.4875   -0.7680   -1.0315 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.3630   -1.9426   -1.7009 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.5210   -3.2269   -1.3094 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.4988   -0.0121   -0.4313 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3400    2.6793    0.8825 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.6643    4.0376    0.8282 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.5502    2.6516   -0.0563 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.8189    4.0152   -0.6372 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4224    1.7183   -1.2564 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0317    0.3019   -0.8868 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.0603   -0.4696   -1.2849 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.1736   -1.8897   -0.9889 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.1182   -2.6234   -1.3617 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7131   -4.9085   -1.5984 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2818   -5.8166   -0.1779 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.4380   -4.8462   -1.1078 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0313   -3.4852    2.3150 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4636   -1.8546    2.9654 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.7083   -3.2233    2.5863 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7597    1.7618   -0.7063 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.2285    2.6323    0.7749 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.9141    3.4008   -0.0766 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.6558    3.0215    0.3132 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.2985    2.5424    1.4577 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.5511   -2.8207   -1.4404 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.2069   -2.1389    0.1596 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.6854   -1.6237   -0.7601 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.5549   -3.7923   -1.2214 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.0745   -3.8120   -2.1094 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.0487   -3.3760   -0.3362 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7365    2.5670    1.9253 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0083    4.1461   -0.0584 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0349    4.2179    1.7192 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3933    4.8735    0.7963 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.4407    2.3527    0.5100 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9209    4.4510   -1.1264 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.2965    4.6617    0.0976 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5463    3.8496   -1.4858 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.4992    1.7240   -1.6374 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.8742    2.1261   -2.1087 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.8736   -0.0362   -1.8698 H   0  0  0  0  0  0  0  0  0  0  0  0
 14 13  1  0
 13 12  1  0
 12 15  2  0
 15 16  1  0
 16 17  1  0
 15 18  1  0
 18 19  1  0
 19 20  1  0
 18 21  2  0
 21 10  1  0
 10 11  2  0
 10  9  1  0
  9  8  1  0
  8  7  1  0
  7 27  1  0
 27 26  1  0
 26 24  1  0
 24 25  1  0
 24 22  1  0
 22 23  1  0
 27 28  2  0
 28 29  1  0
 29 30  2  0
 29  3  1  0
  3  2  1  0
  2  1  1  0
  3  4  2  0
  4  5  1  0
  5  6  1  0
 11 12  1  0
 22  9  1  0
  7 21  1  0
  7  4  1  1
 14 39  1  0
 14 40  1  0
 14 41  1  0
 17 42  1  0
 17 43  1  0
 17 44  1  0
 20 45  1  0
 20 46  1  0
 20 47  1  0
 11 38  1  0
  9 37  1  6
 26 56  1  0
 26 57  1  0
 24 52  1  1
 25 53  1  0
 25 54  1  0
 25 55  1  0
 22 48  1  1
 23 49  1  0
 23 50  1  0
 23 51  1  0
 28 58  1  0
  1 31  1  0
  1 32  1  0
  1 33  1  0
  6 34  1  0
  6 35  1  0
  6 36  1  0
M  END


  Mrv1652309062222332D          

 30 33  0  0  1  0            999 V2000
    0.4085    1.0086    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.0629    0.4392    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4476   -0.3733    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1440   -0.8254    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8300   -0.3142    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.6738    0.6644    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.2150   -1.6686    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.6610   -2.2958    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.2066   -2.7687    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.6272   -2.0002    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.4318   -1.8179    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.6762   -1.0299    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.5513   -1.0289    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.2319   -1.5408    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.1160   -0.4243    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.6366    0.3089    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.3999    0.7171    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.3114   -0.6066    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.2418    0.2793    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.5006    1.1253    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.0670   -1.3946    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.6767   -3.4619    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.1446   -4.1762    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.8164   -3.5377    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.4793   -4.3263    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.2549   -2.8933    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.4249   -2.0518    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7029   -1.5924    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7186   -0.7620    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0788   -0.4552    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  2  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  4  7  1  0  0  0  0
  7  8  1  6  0  0  0
  9  8  1  1  0  0  0
  9 10  1  0  0  0  0
 10 11  2  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 12 15  2  0  0  0  0
 15 16  1  0  0  0  0
 16 17  1  0  0  0  0
 15 18  1  0  0  0  0
 18 19  1  0  0  0  0
 19 20  1  0  0  0  0
 18 21  2  0  0  0  0
 10 21  1  0  0  0  0
  7 21  1  0  0  0  0
  9 22  1  0  0  0  0
 22 23  1  0  0  0  0
 22 24  1  0  0  0  0
 24 25  1  0  0  0  0
 24 26  1  0  0  0  0
 26 27  1  0  0  0  0
  7 27  1  0  0  0  0
 27 28  2  0  0  0  0
 28 29  1  0  0  0  0
  3 29  1  0  0  0  0
 29 30  2  0  0  0  0
M  END
> <DATABASE_ID>
NP0237425

> <DATABASE_NAME>
NP-MRD

> <SMILES>
COC1=C(OC)C(OC)=C2C(=C1)[C@H]1O[C@@]22C(CC(C)C1C)=CC(=O)C(OC)=C2OC

> <INCHI_IDENTIFIER>
InChI=1S/C23H28O7/c1-11-8-13-9-15(24)19(26-4)22(29-7)23(13)17-14(18(30-23)12(11)2)10-16(25-3)20(27-5)21(17)28-6/h9-12,18H,8H2,1-7H3/t11?,12?,18-,23-/m0/s1

> <INCHI_KEY>
ASRSGPWPPWDGFA-VNGHIMSSSA-N

> <FORMULA>
C23H28O7

> <MOLECULAR_WEIGHT>
416.47

> <EXACT_MASS>
416.183503242

> <JCHEM_ACCEPTOR_COUNT>
7

> <JCHEM_ATOM_COUNT>
58

> <JCHEM_AVERAGE_POLARIZABILITY>
39.60933904201513

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
0

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
1

> <JCHEM_IUPAC>
(1S,10S)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0^{1,6}.0^{11,16}]heptadeca-2,5,11,13,15-pentaen-4-one

> <JCHEM_LOGP>
2.3853943856666664

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA_STRONGEST_ACIDIC>
16.54638492126828

> <JCHEM_PKA_STRONGEST_BASIC>
-3.9869874472610864

> <JCHEM_POLAR_SURFACE_AREA>
72.45000000000002

> <JCHEM_REFRACTIVITY>
112.79799999999997

> <JCHEM_ROTATABLE_BOND_COUNT>
5

> <JCHEM_RULE_OF_FIVE>
1

> <JCHEM_TRADITIONAL_IUPAC>
(1S,10S)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0^{1,6}.0^{11,16}]heptadeca-2,5,11,13,15-pentaen-4-one

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 06-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   06-SEP-22         0                                  
HETATM    1  C   UNK     0       0.762   1.883   0.000  0.00  0.00           C+0
HETATM    2  O   UNK     0       1.984   0.820   0.000  0.00  0.00           O+0
HETATM    3  C   UNK     0       2.702  -0.697   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       4.002  -1.541   0.000  0.00  0.00           C+0
HETATM    5  O   UNK     0       5.283  -0.587   0.000  0.00  0.00           O+0
HETATM    6  C   UNK     0       4.991   1.240   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       4.135  -3.115   0.000  0.00  0.00           C+0
HETATM    8  O   UNK     0       4.967  -4.286   0.000  0.00  0.00           O+0
HETATM    9  C   UNK     0       5.986  -5.168   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       6.771  -3.734   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       8.273  -3.393   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       8.729  -1.922   0.000  0.00  0.00           C+0
HETATM   13  O   UNK     0      10.362  -1.921   0.000  0.00  0.00           O+0
HETATM   14  C   UNK     0      11.633  -2.876   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       7.683  -0.792   0.000  0.00  0.00           C+0
HETATM   16  O   UNK     0       8.655   0.577   0.000  0.00  0.00           O+0
HETATM   17  C   UNK     0      10.080   1.339   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       6.181  -1.132   0.000  0.00  0.00           C+0
HETATM   19  O   UNK     0       6.051   0.521   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0       6.534   2.101   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       5.725  -2.603   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       4.997  -6.462   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       5.870  -7.796   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       3.391  -6.604   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0       2.761  -8.076   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0       2.342  -5.401   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       2.660  -3.830   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       1.312  -2.972   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       1.341  -1.422   0.000  0.00  0.00           C+0
HETATM   30  O   UNK     0      -0.147  -0.850   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4   29                                                  
CONECT    4    3    5    7                                                  
CONECT    5    4    6                                                       
CONECT    6    5                                                            
CONECT    7    4    8   21   27                                             
CONECT    8    7    9                                                       
CONECT    9    8   10   22                                                  
CONECT   10    9   11   21                                                  
CONECT   11   10   12                                                       
CONECT   12   11   13   15                                                  
CONECT   13   12   14                                                       
CONECT   14   13                                                            
CONECT   15   12   16   18                                                  
CONECT   16   15   17                                                       
CONECT   17   16                                                            
CONECT   18   15   19   21                                                  
CONECT   19   18   20                                                       
CONECT   20   19                                                            
CONECT   21   18   10    7                                                  
CONECT   22    9   23   24                                                  
CONECT   23   22                                                            
CONECT   24   22   25   26                                                  
CONECT   25   24                                                            
CONECT   26   24   27                                                       
CONECT   27   26    7   28                                                  
CONECT   28   27   29                                                       
CONECT   29   28    3   30                                                  
CONECT   30   29                                                            
MASTER        0    0    0    0    0    0    0    0   30    0   66    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₃H₂₈O₇

Average Mass

416.4700 Da

Monoisotopic Mass

416.18350 Da

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

COC1=C(OC)C(OC)=C2C(=C1)[C@H]1O[C@@]22C(CC(C)C1C)=CC(=O)C(OC)=C2OC

InChI Identifier

InChI=1S/C23H28O7/c1-11-8-13-9-15(24)19(26-4)22(29-7)23(13)17-14(18(30-23)12(11)2)10-16(25-3)20(27-5)21(17)28-6/h9-12,18H,8H2,1-7H3/t11?,12?,18-,23-/m0/s1

InChI Key

ASRSGPWPPWDGFA-VNGHIMSSSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Kadsura coccinea	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as isocoumarans. Isocoumarans are compounds containing the coumaran skeleton, which consists of a benzene ring fused to a 1,3-dihydrofuran ring.

Kingdom

Organic compounds

Super Class

Organoheterocyclic compounds

Class

Isocoumarans

Sub Class

Not Available

Direct Parent

Isocoumarans

Alternative Parents

Substituents

Isocoumaran
Anisole
Oxepane
Alkyl aryl ether
Benzenoid
Vinylogous ester
Cyclic ketone
Ketone
Oxacycle
Ether
Dialkyl ether
Organic oxygen compound
Organic oxide
Hydrocarbon derivative
Organooxygen compound
Carbonyl group
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

138112172

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (1s,10s)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0¹,⁶.0¹¹,¹⁶]heptadeca-2,5,11,13,15-pentaen-4-one (NP0237425)

MOL for NP0237425 ((1s,10s)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0¹,⁶.0¹¹,¹⁶]heptadeca-2,5,11,13,15-pentaen-4-one)

3D MOL for NP0237425 ((1s,10s)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0¹,⁶.0¹¹,¹⁶]heptadeca-2,5,11,13,15-pentaen-4-one)

3D SDF for NP0237425 ((1s,10s)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0¹,⁶.0¹¹,¹⁶]heptadeca-2,5,11,13,15-pentaen-4-one)

3D-SDF for NP0237425 ((1s,10s)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0¹,⁶.0¹¹,¹⁶]heptadeca-2,5,11,13,15-pentaen-4-one)

PDB for NP0237425 ((1s,10s)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0¹,⁶.0¹¹,¹⁶]heptadeca-2,5,11,13,15-pentaen-4-one)

3D PDB for NP0237425 ((1s,10s)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0¹,⁶.0¹¹,¹⁶]heptadeca-2,5,11,13,15-pentaen-4-one)

SMILES for NP0237425 ((1s,10s)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0¹,⁶.0¹¹,¹⁶]heptadeca-2,5,11,13,15-pentaen-4-one)

INCHI for NP0237425 ((1s,10s)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0¹,⁶.0¹¹,¹⁶]heptadeca-2,5,11,13,15-pentaen-4-one)

Structure for NP0237425 ((1s,10s)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0¹,⁶.0¹¹,¹⁶]heptadeca-2,5,11,13,15-pentaen-4-one)

3D Structure for NP0237425 ((1s,10s)-2,3,13,14,15-pentamethoxy-8,9-dimethyl-17-oxatetracyclo[8.6.1.0¹,⁶.0¹¹,¹⁶]heptadeca-2,5,11,13,15-pentaen-4-one)