NP-MRD: Showing NP-Card for (2s,3r,5r,6r)-2-{5-hydroxy-4,10,14,19-tetramethyl-21,22,23,24-tetraazapentacyclo[16.2.1.1³,⁶.1⁸,¹¹.1¹³,¹⁶]tetracosa-1(21),2,5,7,9,11(23),12,14,16(22),17,19-undecaen-4-yl}-6-methyloxane-3,5-diol (NP0235676)

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Record Information

Version

2.0

Created at

2022-09-06 18:23:05 UTC

Updated at

2022-09-06 18:23:05 UTC

NP-MRD ID

NP0235676

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(2s,3r,5r,6r)-2-{5-hydroxy-4,10,14,19-tetramethyl-21,22,23,24-tetraazapentacyclo[16.2.1.1³,⁶.1⁸,¹¹.1¹³,¹⁶]tetracosa-1(21),2,5,7,9,11(23),12,14,16(22),17,19-undecaen-4-yl}-6-methyloxane-3,5-diol

Description

Tolyporphine K belongs to the class of organic compounds known as tetrapyrroles and derivatives. These are polycyclic aromatic compounds containing four pyrrole rings joined by one-carbon units linking position 2 of one pyrrole ring to position 5 of the next. (2s,3r,5r,6r)-2-{5-hydroxy-4,10,14,19-tetramethyl-21,22,23,24-tetraazapentacyclo[16.2.1.1³,⁶.1⁸,¹¹.1¹³,¹⁶]tetracosa-1(21),2,5,7,9,11(23),12,14,16(22),17,19-undecaen-4-yl}-6-methyloxane-3,5-diol is found in Tolypothrix nodosa. Based on a literature review very few articles have been published on Tolyporphine K.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309062220232D          

 38 43  0  0  1  0            999 V2000
    5.7871    1.6606    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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M  END

     RDKit          3D

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M  END


  Mrv1652309062220232D          

 38 43  0  0  1  0            999 V2000
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    7.5257   -2.1371    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.5795   -1.3138    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.2771   -0.8734    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  2  0  0  0  0
  3  4  1  0  0  0  0
  4  5  2  0  0  0  0
  5  6  1  0  0  0  0
  2  6  1  0  0  0  0
  6  7  2  0  0  0  0
  7  8  1  4  0  0  0
  8  9  2  0  0  0  0
  9 10  1  0  0  0  0
 10 11  2  0  0  0  0
 11 12  1  4  0  0  0
 12 13  2  0  0  0  0
 13 14  1  0  0  0  0
 13 15  1  0  0  0  0
 15 16  1  0  0  0  0
 17 15  1  1  0  0  0
 17 18  1  0  0  0  0
 18 19  1  0  0  0  0
 19 20  1  1  0  0  0
 19 21  1  0  0  0  0
 21 22  1  1  0  0  0
 21 23  1  0  0  0  0
 23 24  1  0  0  0  0
 17 24  1  0  0  0  0
 24 25  1  6  0  0  0
 15 26  1  0  0  0  0
 26 27  2  0  0  0  0
 27 28  1  4  0  0  0
 28 29  2  0  0  0  0
 29 30  1  0  0  0  0
 30 31  2  0  0  0  0
 31  4  1  4  0  0  0
 30 32  1  0  0  0  0
 32 33  1  0  0  0  0
 32 34  2  0  0  0  0
 28 34  1  0  0  0  0
 26 35  1  0  0  0  0
 12 35  1  0  0  0  0
 10 36  1  0  0  0  0
 36 37  2  0  0  0  0
  8 37  1  0  0  0  0
 37 38  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0235676

> <DATABASE_NAME>
NP-MRD

> <SMILES>
C[C@H]1O[C@H]([C@H](O)C[C@H]1O)C1(C)C2=CC3=NC(=CC4=NC(=CC5=NC(C=C5C)=CC(N2)=C1O)C(C)=C4)C(C)=C3

> <INCHI_IDENTIFIER>
InChI=1S/C30H32N4O4/c1-14-8-20-11-27-30(5,29-26(36)13-25(35)17(4)38-29)28(37)24(34-27)10-19-7-16(3)23(32-19)12-22-15(2)6-18(31-22)9-21(14)33-20/h6-12,17,25-26,29,34-37H,13H2,1-5H3/t17-,25-,26-,29-,30?/m1/s1

> <INCHI_KEY>
QZISHXZCHQREEK-DRHIIJKYSA-N

> <FORMULA>
C30H32N4O4

> <MOLECULAR_WEIGHT>
512.61

> <EXACT_MASS>
512.242355526

> <JCHEM_ACCEPTOR_COUNT>
8

> <JCHEM_ATOM_COUNT>
70

> <JCHEM_AVERAGE_POLARIZABILITY>
58.586358818921795

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
4

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(2S,3R,5R,6R)-2-{5-hydroxy-4,10,14,19-tetramethyl-21,22,23,24-tetraazapentacyclo[16.2.1.1^{3,6}.1^{8,11}.1^{13,16}]tetracosa-1(21),2,5,7,9,11(23),12,14,16(22),17,19-undecaen-4-yl}-6-methyloxane-3,5-diol

> <JCHEM_LOGP>
1.5201679126152712

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
6

> <JCHEM_PHYSIOLOGICAL_CHARGE>
1

> <JCHEM_PKA>
13.800520825927904

> <JCHEM_PKA_STRONGEST_ACIDIC>
8.572832661541598

> <JCHEM_PKA_STRONGEST_BASIC>
6.687826169111317

> <JCHEM_POLAR_SURFACE_AREA>
119.03000000000002

> <JCHEM_REFRACTIVITY>
155.72040000000004

> <JCHEM_ROTATABLE_BOND_COUNT>
1

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(2S,3R,5R,6R)-2-{5-hydroxy-4,10,14,19-tetramethyl-21,22,23,24-tetraazapentacyclo[16.2.1.1^{3,6}.1^{8,11}.1^{13,16}]tetracosa-1(21),2,5,7,9,11(23),12,14,16(22),17,19-undecaen-4-yl}-6-methyloxane-3,5-diol

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 06-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   06-SEP-22         0                                  
HETATM    1  C   UNK     0      10.803   3.100   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       9.818   1.915   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       8.281   2.016   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       7.711   0.585   0.000  0.00  0.00           C+0
HETATM    5  N   UNK     0       8.895  -0.399   0.000  0.00  0.00           N+0
HETATM    6  C   UNK     0      10.198   0.423   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0      11.948  -0.549   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      12.718  -1.882   0.000  0.00  0.00           C+0
HETATM    9  N   UNK     0      11.733  -3.066   0.000  0.00  0.00           N+0
HETATM   10  C   UNK     0      12.556  -4.369   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0      11.584  -6.119   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      10.250  -6.889   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       9.680  -8.319   0.000  0.00  0.00           C+0
HETATM   14  O   UNK     0      10.502  -9.622   0.000  0.00  0.00           O+0
HETATM   15  C   UNK     0       8.143  -8.219   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       8.204  -9.758   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       6.619  -8.440   0.000  0.00  0.00           C+0
HETATM   18  O   UNK     0       5.666  -7.231   0.000  0.00  0.00           O+0
HETATM   19  C   UNK     0       4.142  -7.453   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       3.188  -6.244   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       3.571  -8.883   0.000  0.00  0.00           C+0
HETATM   22  O   UNK     0       2.047  -9.105   0.000  0.00  0.00           O+0
HETATM   23  C   UNK     0       4.525 -10.092   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       6.049  -9.871   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0       7.003 -11.080   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0       7.764  -6.727   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       6.014  -5.755   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       5.244  -4.421   0.000  0.00  0.00           C+0
HETATM   29  N   UNK     0       6.228  -3.237   0.000  0.00  0.00           N+0
HETATM   30  C   UNK     0       5.406  -1.935   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0       6.378  -0.185   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0       3.913  -2.314   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0       2.729  -1.330   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0       3.813  -3.851   0.000  0.00  0.00           C+0
HETATM   35  N   UNK     0       9.066  -5.904   0.000  0.00  0.00           N+0
HETATM   36  C   UNK     0      14.048  -3.989   0.000  0.00  0.00           C+0
HETATM   37  C   UNK     0      14.148  -2.453   0.000  0.00  0.00           C+0
HETATM   38  C   UNK     0      15.451  -1.630   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3    6                                                  
CONECT    3    2    4                                                       
CONECT    4    3    5   31                                                  
CONECT    5    4    6                                                       
CONECT    6    5    2    7                                                  
CONECT    7    6    8                                                       
CONECT    8    7    9   37                                                  
CONECT    9    8   10                                                       
CONECT   10    9   11   36                                                  
CONECT   11   10   12                                                       
CONECT   12   11   13   35                                                  
CONECT   13   12   14   15                                                  
CONECT   14   13                                                            
CONECT   15   13   16   17   26                                             
CONECT   16   15                                                            
CONECT   17   15   18   24                                                  
CONECT   18   17   19                                                       
CONECT   19   18   20   21                                                  
CONECT   20   19                                                            
CONECT   21   19   22   23                                                  
CONECT   22   21                                                            
CONECT   23   21   24                                                       
CONECT   24   23   17   25                                                  
CONECT   25   24                                                            
CONECT   26   15   27   35                                                  
CONECT   27   26   28                                                       
CONECT   28   27   29   34                                                  
CONECT   29   28   30                                                       
CONECT   30   29   31   32                                                  
CONECT   31   30    4                                                       
CONECT   32   30   33   34                                                  
CONECT   33   32                                                            
CONECT   34   32   28                                                       
CONECT   35   26   12                                                       
CONECT   36   10   37                                                       
CONECT   37   36    8   38                                                  
CONECT   38   37                                                            
MASTER        0    0    0    0    0    0    0    0   38    0   86    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₃₀H₃₂N₄O₄

Average Mass

512.6100 Da

Monoisotopic Mass

512.24236 Da

IUPAC Name

(2S,3R,5R,6R)-2-{5-hydroxy-4,10,14,19-tetramethyl-21,22,23,24-tetraazapentacyclo[16.2.1.1^{3,6}.1^{8,11}.1^{13,16}]tetracosa-1(21),2,5,7,9,11(23),12,14,16(22),17,19-undecaen-4-yl}-6-methyloxane-3,5-diol

Traditional Name

CAS Registry Number

Not Available

SMILES

C[C@H]1O[C@H]([C@H](O)C[C@H]1O)C1(C)C2=CC3=NC(=CC4=NC(=CC5=NC(C=C5C)=CC(N2)=C1O)C(C)=C4)C(C)=C3

InChI Identifier

InChI=1S/C30H32N4O4/c1-14-8-20-11-27-30(5,29-26(36)13-25(35)17(4)38-29)28(37)24(34-27)10-19-7-16(3)23(32-19)12-22-15(2)6-18(31-22)9-21(14)33-20/h6-12,17,25-26,29,34-37H,13H2,1-5H3/t17-,25-,26-,29-,30?/m1/s1

InChI Key

QZISHXZCHQREEK-DRHIIJKYSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Tolypothrix nodosa	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as tetrapyrroles and derivatives. These are polycyclic aromatic compounds containing four pyrrole rings joined by one-carbon units linking position 2 of one pyrrole ring to position 5 of the next.

Kingdom

Organic compounds

Super Class

Organoheterocyclic compounds

Class

Tetrapyrroles and derivatives

Sub Class

Not Available

Direct Parent

Tetrapyrroles and derivatives

Alternative Parents

Substituents

Tetrapyrrole skeleton
Oxane
Pyrroline
Secondary alcohol
Ketimine
Oxacycle
Azacycle
Organic 1,3-dipolar compound
Propargyl-type 1,3-dipolar organic compound
Secondary amine
Ether
Enamine
Secondary aliphatic amine
Dialkyl ether
Organic nitrogen compound
Organic oxygen compound
Organopnictogen compound
Hydrocarbon derivative
Organooxygen compound
Organonitrogen compound
Imine
Amine
Alcohol
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	1.52	ChemAxon
pKa (Strongest Acidic)	8.57	ChemAxon
pKa (Strongest Basic)	6.69	ChemAxon
Physiological Charge	1	ChemAxon
Hydrogen Acceptor Count	8	ChemAxon
Hydrogen Donor Count	4	ChemAxon
Polar Surface Area	119.03 Å²	ChemAxon
Rotatable Bond Count	1	ChemAxon
Refractivity	155.72 m³·mol⁻¹	ChemAxon
Polarizability	58.59 Å³	ChemAxon
Number of Rings	6	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

154166

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (2s,3r,5r,6r)-2-{5-hydroxy-4,10,14,19-tetramethyl-21,22,23,24-tetraazapentacyclo[16.2.1.1³,⁶.1⁸,¹¹.1¹³,¹⁶]tetracosa-1(21),2,5,7,9,11(23),12,14,16(22),17,19-undecaen-4-yl}-6-methyloxane-3,5-diol (NP0235676)

MOL for NP0235676 ((2s,3r,5r,6r)-2-{5-hydroxy-4,10,14,19-tetramethyl-21,22,23,24-tetraazapentacyclo[16.2.1.1³,⁶.1⁸,¹¹.1¹³,¹⁶]tetracosa-1(21),2,5,7,9,11(23),12,14,16(22),17,19-undecaen-4-yl}-6-methyloxane-3,5-diol)

3D MOL for NP0235676 ((2s,3r,5r,6r)-2-{5-hydroxy-4,10,14,19-tetramethyl-21,22,23,24-tetraazapentacyclo[16.2.1.1³,⁶.1⁸,¹¹.1¹³,¹⁶]tetracosa-1(21),2,5,7,9,11(23),12,14,16(22),17,19-undecaen-4-yl}-6-methyloxane-3,5-diol)

3D SDF for NP0235676 ((2s,3r,5r,6r)-2-{5-hydroxy-4,10,14,19-tetramethyl-21,22,23,24-tetraazapentacyclo[16.2.1.1³,⁶.1⁸,¹¹.1¹³,¹⁶]tetracosa-1(21),2,5,7,9,11(23),12,14,16(22),17,19-undecaen-4-yl}-6-methyloxane-3,5-diol)

3D-SDF for NP0235676 ((2s,3r,5r,6r)-2-{5-hydroxy-4,10,14,19-tetramethyl-21,22,23,24-tetraazapentacyclo[16.2.1.1³,⁶.1⁸,¹¹.1¹³,¹⁶]tetracosa-1(21),2,5,7,9,11(23),12,14,16(22),17,19-undecaen-4-yl}-6-methyloxane-3,5-diol)

PDB for NP0235676 ((2s,3r,5r,6r)-2-{5-hydroxy-4,10,14,19-tetramethyl-21,22,23,24-tetraazapentacyclo[16.2.1.1³,⁶.1⁸,¹¹.1¹³,¹⁶]tetracosa-1(21),2,5,7,9,11(23),12,14,16(22),17,19-undecaen-4-yl}-6-methyloxane-3,5-diol)

3D PDB for NP0235676 ((2s,3r,5r,6r)-2-{5-hydroxy-4,10,14,19-tetramethyl-21,22,23,24-tetraazapentacyclo[16.2.1.1³,⁶.1⁸,¹¹.1¹³,¹⁶]tetracosa-1(21),2,5,7,9,11(23),12,14,16(22),17,19-undecaen-4-yl}-6-methyloxane-3,5-diol)

SMILES for NP0235676 ((2s,3r,5r,6r)-2-{5-hydroxy-4,10,14,19-tetramethyl-21,22,23,24-tetraazapentacyclo[16.2.1.1³,⁶.1⁸,¹¹.1¹³,¹⁶]tetracosa-1(21),2,5,7,9,11(23),12,14,16(22),17,19-undecaen-4-yl}-6-methyloxane-3,5-diol)

INCHI for NP0235676 ((2s,3r,5r,6r)-2-{5-hydroxy-4,10,14,19-tetramethyl-21,22,23,24-tetraazapentacyclo[16.2.1.1³,⁶.1⁸,¹¹.1¹³,¹⁶]tetracosa-1(21),2,5,7,9,11(23),12,14,16(22),17,19-undecaen-4-yl}-6-methyloxane-3,5-diol)

Structure for NP0235676 ((2s,3r,5r,6r)-2-{5-hydroxy-4,10,14,19-tetramethyl-21,22,23,24-tetraazapentacyclo[16.2.1.1³,⁶.1⁸,¹¹.1¹³,¹⁶]tetracosa-1(21),2,5,7,9,11(23),12,14,16(22),17,19-undecaen-4-yl}-6-methyloxane-3,5-diol)

3D Structure for NP0235676 ((2s,3r,5r,6r)-2-{5-hydroxy-4,10,14,19-tetramethyl-21,22,23,24-tetraazapentacyclo[16.2.1.1³,⁶.1⁸,¹¹.1¹³,¹⁶]tetracosa-1(21),2,5,7,9,11(23),12,14,16(22),17,19-undecaen-4-yl}-6-methyloxane-3,5-diol)