NP-MRD: Showing NP-Card for 4-[(1e,3e,5e,7e,9e,11e)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol (NP0235314)

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Record Information

Version

2.0

Created at

2022-09-06 17:52:02 UTC

Updated at

2022-09-06 17:52:02 UTC

NP-MRD ID

NP0235314

Secondary Accession Numbers

None

Natural Product Identification

Common Name

4-[(1e,3e,5e,7e,9e,11e)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol

Description

Beta-Micropteroxanthin belongs to the class of organic compounds known as sesterterpenoids. These are terpenes composed of five consecutive isoprene units. Beta-Micropteroxanthin is an extremely weak basic (essentially neutral) compound (based on its pKa). Outside of the human body, beta-Micropteroxanthin has been detected, but not quantified in, fishes. 4-[(1e,3e,5e,7e,9e,11e)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol is found in Micropterus salmoides. This could make beta-micropteroxanthin a potential biomarker for the consumption of these foods.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv0541 02241209452D          

 29 29  0  0  0  0            999 V2000
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   -4.2932   -0.8252    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.2932    0.0000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -5.0058    0.4112    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -6.4348   -1.2378    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5780   -1.2378    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5780    0.4112    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8628    0.0000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1476    0.4112    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4325    0.0000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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M  END

     RDKit          3D

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M  END


  Mrv0541 02241209452D          

 29 29  0  0  0  0            999 V2000
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M  END
> <DATABASE_ID>
NP0235314

> <DATABASE_NAME>
NP-MRD

> <SMILES>
C\C(CCCO)=C/C=C/C=C(\C)/C=C/C=C(\C)/C=C/C1=C(C)CC(O)CC1(C)C

> <INCHI_IDENTIFIER>
InChI=1S/C27H40O2/c1-21(11-7-8-12-22(2)15-10-18-28)13-9-14-23(3)16-17-26-24(4)19-25(29)20-27(26,5)6/h7-9,11-14,16-17,25,28-29H,10,15,18-20H2,1-6H3/b8-7+,13-9+,17-16+,21-11+,22-12+,23-14+

> <INCHI_KEY>
IXMBIKPYQQTHKK-GYVFJTMISA-N

> <FORMULA>
C27H40O2

> <MOLECULAR_WEIGHT>
396.6053

> <EXACT_MASS>
396.302830524

> <JCHEM_ACCEPTOR_COUNT>
2

> <JCHEM_AVERAGE_POLARIZABILITY>
50.749299277904335

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
2

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
4-[(1E,3E,5E,7E,9E,11E)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol

> <ALOGPS_LOGP>
6.37

> <JCHEM_LOGP>
5.338397134333334

> <ALOGPS_LOGS>
-5.17

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
1

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
18.907213404525137

> <JCHEM_PKA_STRONGEST_ACIDIC>
16.88677110555498

> <JCHEM_PKA_STRONGEST_BASIC>
-1.0364394354044775

> <JCHEM_POLAR_SURFACE_AREA>
40.46

> <JCHEM_REFRACTIVITY>
133.86810000000003

> <JCHEM_ROTATABLE_BOND_COUNT>
9

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
2.68e-03 g/l

> <JCHEM_TRADITIONAL_IUPAC>
4-[(1E,3E,5E,7E,9E,11E)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 24-FEB-12   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   24-FEB-12         0                                  
HETATM    1  C   UNK     0     -10.677   0.000   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0     -10.677  -1.540   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      -9.344  -2.311   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -8.014  -1.540   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -8.014   0.000   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -9.344   0.768   0.000  0.00  0.00           C+0
HETATM    7  O   UNK     0     -12.012  -2.311   0.000  0.00  0.00           O+0
HETATM    8  C   UNK     0      -6.679  -2.311   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0      -6.679   0.768   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0      -5.344   0.000   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0      -4.009   0.768   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      -2.674   0.000   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      -1.339   0.768   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0      -0.004   0.000   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       1.331   0.768   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       2.666   0.000   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       4.001   0.768   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       5.336   0.000   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       6.671   0.768   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       8.007   0.000   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       9.342   0.768   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      10.677   0.000   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0      12.012   0.768   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0      -4.009   2.311   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0       1.331   2.311   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0       8.007  -1.540   0.000  0.00  0.00           C+0
HETATM   27  O   UNK     0      12.012   2.311   0.000  0.00  0.00           O+0
HETATM   28  C   UNK     0     -10.433   1.856   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0      -8.256   1.856   0.000  0.00  0.00           C+0
CONECT    1    2    6                                                       
CONECT    2    1    3    7                                                  
CONECT    3    2    4                                                       
CONECT    4    3    5    8                                                  
CONECT    5    4    6    9                                                  
CONECT    6    1    5   28   29                                             
CONECT    7    2                                                            
CONECT    8    4                                                            
CONECT    9    5   10                                                       
CONECT   10    9   11                                                       
CONECT   11   10   12   24                                                  
CONECT   12   11   13                                                       
CONECT   13   12   14                                                       
CONECT   14   13   15                                                       
CONECT   15   14   16   25                                                  
CONECT   16   15   17                                                       
CONECT   17   16   18                                                       
CONECT   18   17   19                                                       
CONECT   19   18   20                                                       
CONECT   20   19   21   26                                                  
CONECT   21   20   22                                                       
CONECT   22   21   23                                                       
CONECT   23   22   27                                                       
CONECT   24   11                                                            
CONECT   25   15                                                            
CONECT   26   20                                                            
CONECT   27   23                                                            
CONECT   28    6                                                            
CONECT   29    6                                                            
MASTER        0    0    0    0    0    0    0    0   29    0   58    0
END

View in JSmol

Synonyms

Value	Source
b-Micropteroxanthin	Generator
Β-micropteroxanthin	Generator
(3R)-11',12'-Dihydro-10'-apo-beta,psi-carotene-3,10'-diol	HMDB
11',12'-Dihydro-10'-apo-b-carotene-3,10'-diol	HMDB

Chemical Formula

C₂₇H₄₀O₂

Average Mass

396.6053 Da

Monoisotopic Mass

396.30283 Da

IUPAC Name

4-[(1E,3E,5E,7E,9E,11E)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol

Traditional Name

4-[(1E,3E,5E,7E,9E,11E)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol

CAS Registry Number

Not Available

SMILES

C\C(CCCO)=C/C=C/C=C(\C)/C=C/C=C(\C)/C=C/C1=C(C)CC(O)CC1(C)C

InChI Identifier

InChI=1S/C27H40O2/c1-21(11-7-8-12-22(2)15-10-18-28)13-9-14-23(3)16-17-26-24(4)19-25(29)20-27(26,5)6/h7-9,11-14,16-17,25,28-29H,10,15,18-20H2,1-6H3/b8-7+,13-9+,17-16+,21-11+,22-12+,23-14+

InChI Key

IXMBIKPYQQTHKK-GYVFJTMISA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Micropterus salmoides	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as sesterterpenoids. These are terpenes composed of five consecutive isoprene units.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Sesterterpenoids

Direct Parent

Sesterterpenoids

Alternative Parents

Substituents

Sesterterpenoid
Long chain fatty alcohol
Fatty alcohol
Fatty acyl
Secondary alcohol
Organic oxygen compound
Hydrocarbon derivative
Primary alcohol
Organooxygen compound
Alcohol
Aliphatic homomonocyclic compound

Molecular Framework

Aliphatic homomonocyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	6.37	ALOGPS
logP	5.34	ChemAxon
logS	-5.2	ALOGPS
pKa (Strongest Acidic)	16.89	ChemAxon
pKa (Strongest Basic)	-1	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	2	ChemAxon
Hydrogen Donor Count	2	ChemAxon
Polar Surface Area	40.46 Å²	ChemAxon
Rotatable Bond Count	9	ChemAxon
Refractivity	133.87 m³·mol⁻¹	ChemAxon
Polarizability	50.75 Å³	ChemAxon
Number of Rings	1	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

HMDB0038505

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

FDB017882

KNApSAcK ID

C00023123

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

131752384

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for 4-[(1e,3e,5e,7e,9e,11e)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol (NP0235314)

MOL for NP0235314 (4-[(1e,3e,5e,7e,9e,11e)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol)

3D MOL for NP0235314 (4-[(1e,3e,5e,7e,9e,11e)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol)

3D SDF for NP0235314 (4-[(1e,3e,5e,7e,9e,11e)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol)

3D-SDF for NP0235314 (4-[(1e,3e,5e,7e,9e,11e)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol)

PDB for NP0235314 (4-[(1e,3e,5e,7e,9e,11e)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol)

3D PDB for NP0235314 (4-[(1e,3e,5e,7e,9e,11e)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol)

SMILES for NP0235314 (4-[(1e,3e,5e,7e,9e,11e)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol)

INCHI for NP0235314 (4-[(1e,3e,5e,7e,9e,11e)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol)

Structure for NP0235314 (4-[(1e,3e,5e,7e,9e,11e)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol)

3D Structure for NP0235314 (4-[(1e,3e,5e,7e,9e,11e)-15-hydroxy-3,7,12-trimethylpentadeca-1,3,5,7,9,11-hexaen-1-yl]-3,5,5-trimethylcyclohex-3-en-1-ol)