NP-MRD: Showing NP-Card for [(1r,5as,5bs,7as,11as,11br,13s,13as,13bs)-13-(acetyloxy)-1-hydroxy-8,8,11a,13a-tetramethyl-1h,3h,5h,5ah,6h,7h,7ah,9h,10h,11h,11bh,12h,13h,13bh-chryseno[1,2-c]furan-5b-yl]methyl acetate (NP0234261)

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Record Information

Version

2.0

Created at

2022-09-06 16:11:31 UTC

Updated at

2022-09-06 16:11:31 UTC

NP-MRD ID

NP0234261

Secondary Accession Numbers

None

Natural Product Identification

Common Name

[(1r,5as,5bs,7as,11as,11br,13s,13as,13bs)-13-(acetyloxy)-1-hydroxy-8,8,11a,13a-tetramethyl-1h,3h,5h,5ah,6h,7h,7ah,9h,10h,11h,11bh,12h,13h,13bh-chryseno[1,2-c]furan-5b-yl]methyl acetate

Description

[(1S,2S,8R,9S,10S,11S,13R,14S,19S)-11-(acetyloxy)-8-hydroxy-10,14,18,18-tetramethyl-7-oxapentacyclo[11.8.0.0²,¹⁰.0⁵,⁹.0¹⁴,¹⁹]Henicos-4-en-1-yl]methyl acetate belongs to the class of organic compounds known as scalarane sesterterpenoids. These are sesterterpenoids with a structure based on the scalarane backbone. Scalarane is a tetracyclic compound, which is similar the homoandrostane with five methyl groups at the 4-, 4-, 8-, 17-, 17a-positions. [(1r,5as,5bs,7as,11as,11br,13s,13as,13bs)-13-(acetyloxy)-1-hydroxy-8,8,11a,13a-tetramethyl-1h,3h,5h,5ah,6h,7h,7ah,9h,10h,11h,11bh,12h,13h,13bh-chryseno[1,2-c]furan-5b-yl]methyl acetate is found in Hyrtios erectus. Based on a literature review very few articles have been published on [(1S,2S,8R,9S,10S,11S,13R,14S,19S)-11-(acetyloxy)-8-hydroxy-10,14,18,18-tetramethyl-7-oxapentacyclo[11.8.0.0²,¹⁰.0⁵,⁹.0¹⁴,¹⁹]Henicos-4-en-1-yl]methyl acetate.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309062218112D          

 35 39  0  0  1  0            999 V2000
    2.1392    3.9531    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.7376    3.2324    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.9127    3.2199    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.1609    2.5243    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.7593    1.8036    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1826    1.0955    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.5842    1.8162    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.4091    1.8287    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.8324    1.1206    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    4.6573    1.1332    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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  6 18  1  0  0  0  0
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 33 34  1  0  0  0  0
 27 34  1  0  0  0  0
 34 35  1  6  0  0  0
M  END

     RDKit          3D

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M  END


  Mrv1652309062218112D          

 35 39  0  0  1  0            999 V2000
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    0.1312    0.3498    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.2921    1.0579    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.1095    1.7785    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.9344    1.7911    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.3577    1.0830    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -1.0964    0.8741    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.1701    0.0524    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4114   -0.2717    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.2276   -1.0759    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  2  0  0  0  0
  2  4  1  0  0  0  0
  4  5  1  0  0  0  0
  6  5  1  1  0  0  0
  6  7  1  0  0  0  0
  7  8  1  0  0  0  0
  9  8  1  1  0  0  0
  9 10  1  0  0  0  0
 10 11  1  0  0  0  0
 10 12  1  0  0  0  0
 10 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  1  0  0  0  0
 15 16  1  0  0  0  0
  9 16  1  0  0  0  0
 16 17  1  1  0  0  0
 16 18  1  0  0  0  0
  6 18  1  0  0  0  0
 18 19  1  1  0  0  0
 19 20  1  0  0  0  0
 20 21  1  6  0  0  0
 21 22  1  0  0  0  0
 22 23  1  0  0  0  0
 22 24  2  0  0  0  0
 20 25  1  0  0  0  0
 25 26  1  1  0  0  0
 25 27  1  0  0  0  0
 27 28  1  1  0  0  0
 28 29  2  0  0  0  0
 29 30  1  0  0  0  0
 31 30  1  1  0  0  0
 25 31  1  0  0  0  0
  6 31  1  0  0  0  0
 28 32  1  0  0  0  0
 32 33  1  0  0  0  0
 33 34  1  0  0  0  0
 27 34  1  0  0  0  0
 34 35  1  6  0  0  0
M  END
> <DATABASE_ID>
NP0234261

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC(=O)OC[C@@]12CC[C@H]3C(C)(C)CCC[C@]3(C)[C@H]1C[C@H](OC(C)=O)[C@]1(C)[C@H]3[C@H](O)OCC3=CC[C@@H]21

> <INCHI_IDENTIFIER>
InChI=1S/C29H44O6/c1-17(30)34-16-29-13-10-20-26(3,4)11-7-12-27(20,5)22(29)14-23(35-18(2)31)28(6)21(29)9-8-19-15-33-25(32)24(19)28/h8,20-25,32H,7,9-16H2,1-6H3/t20-,21+,22+,23-,24+,25+,27-,28+,29+/m0/s1

> <INCHI_KEY>
RYAKMXYURBKSKR-RAGQBINASA-N

> <FORMULA>
C29H44O6

> <MOLECULAR_WEIGHT>
488.665

> <EXACT_MASS>
488.313789137

> <JCHEM_ACCEPTOR_COUNT>
4

> <JCHEM_ATOM_COUNT>
79

> <JCHEM_AVERAGE_POLARIZABILITY>
54.958359590393826

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
1

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
[(1S,2S,8R,9S,10S,11S,13R,14S,19S)-11-(acetyloxy)-8-hydroxy-10,14,18,18-tetramethyl-7-oxapentacyclo[11.8.0.0^{2,10}.0^{5,9}.0^{14,19}]henicos-4-en-1-yl]methyl acetate

> <JCHEM_LOGP>
3.7357285889999985

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA_STRONGEST_ACIDIC>
12.094342812313844

> <JCHEM_PKA_STRONGEST_BASIC>
-4.069734453893923

> <JCHEM_POLAR_SURFACE_AREA>
82.06

> <JCHEM_REFRACTIVITY>
132.2878

> <JCHEM_ROTATABLE_BOND_COUNT>
5

> <JCHEM_RULE_OF_FIVE>
1

> <JCHEM_TRADITIONAL_IUPAC>
[(1S,2S,8R,9S,10S,11S,13R,14S,19S)-11-(acetyloxy)-8-hydroxy-10,14,18,18-tetramethyl-7-oxapentacyclo[11.8.0.0^{2,10}.0^{5,9}.0^{14,19}]henicos-4-en-1-yl]methyl acetate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 06-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   06-SEP-22         0                                  
HETATM    1  C   UNK     0       3.993   7.379   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       3.243   6.034   0.000  0.00  0.00           C+0
HETATM    3  O   UNK     0       1.704   6.010   0.000  0.00  0.00           O+0
HETATM    4  O   UNK     0       4.034   4.712   0.000  0.00  0.00           O+0
HETATM    5  C   UNK     0       3.284   3.367   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       4.074   2.045   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       4.824   3.390   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       6.364   3.414   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       7.154   2.092   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       8.694   2.115   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       8.403   3.628   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      10.133   2.664   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       9.484   0.793   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       8.734  -0.552   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       7.194  -0.575   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       6.404   0.747   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       5.655  -0.599   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       4.864   0.723   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       4.115  -0.622   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       2.575  -0.645   0.000  0.00  0.00           C+0
HETATM   21  O   UNK     0       1.825  -1.991   0.000  0.00  0.00           O+0
HETATM   22  C   UNK     0       2.616  -3.313   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       4.155  -3.289   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0       1.866  -4.658   0.000  0.00  0.00           O+0
HETATM   25  C   UNK     0       1.785   0.676   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0       1.035  -0.669   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       0.245   0.653   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0      -0.545   1.975   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       0.204   3.320   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       1.744   3.343   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0       2.534   2.022   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0      -2.047   1.632   0.000  0.00  0.00           C+0
HETATM   33  O   UNK     0      -2.184   0.098   0.000  0.00  0.00           O+0
HETATM   34  C   UNK     0      -0.768  -0.507   0.000  0.00  0.00           C+0
HETATM   35  O   UNK     0      -0.425  -2.008   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3    4                                                  
CONECT    3    2                                                            
CONECT    4    2    5                                                       
CONECT    5    4    6                                                       
CONECT    6    5    7   18   31                                             
CONECT    7    6    8                                                       
CONECT    8    7    9                                                       
CONECT    9    8   10   16                                                  
CONECT   10    9   11   12   13                                             
CONECT   11   10                                                            
CONECT   12   10                                                            
CONECT   13   10   14                                                       
CONECT   14   13   15                                                       
CONECT   15   14   16                                                       
CONECT   16   15    9   17   18                                             
CONECT   17   16                                                            
CONECT   18   16    6   19                                                  
CONECT   19   18   20                                                       
CONECT   20   19   21   25                                                  
CONECT   21   20   22                                                       
CONECT   22   21   23   24                                                  
CONECT   23   22                                                            
CONECT   24   22                                                            
CONECT   25   20   26   27   31                                             
CONECT   26   25                                                            
CONECT   27   25   28   34                                                  
CONECT   28   27   29   32                                                  
CONECT   29   28   30                                                       
CONECT   30   29   31                                                       
CONECT   31   30   25    6                                                  
CONECT   32   28   33                                                       
CONECT   33   32   34                                                       
CONECT   34   33   27   35                                                  
CONECT   35   34                                                            
MASTER        0    0    0    0    0    0    0    0   35    0   78    0
END

View in JSmol

Synonyms

Value	Source
[(1S,2S,8R,9S,10S,11S,13R,14S,19S)-11-(Acetyloxy)-8-hydroxy-10,14,18,18-tetramethyl-7-oxapentacyclo[11.8.0.0,.0,.0,]henicos-4-en-1-yl]methyl acetic acid	Generator

Chemical Formula

C₂₉H₄₄O₆

Average Mass

488.6650 Da

Monoisotopic Mass

488.31379 Da

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

CC(=O)OC[C@@]12CC[C@H]3C(C)(C)CCC[C@]3(C)[C@H]1C[C@H](OC(C)=O)[C@]1(C)[C@H]3[C@H](O)OCC3=CC[C@@H]21

InChI Identifier

InChI=1S/C29H44O6/c1-17(30)34-16-29-13-10-20-26(3,4)11-7-12-27(20,5)22(29)14-23(35-18(2)31)28(6)21(29)9-8-19-15-33-25(32)24(19)28/h8,20-25,32H,7,9-16H2,1-6H3/t20-,21+,22+,23-,24+,25+,27-,28+,29+/m0/s1

InChI Key

RYAKMXYURBKSKR-RAGQBINASA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Hyrtios erectus	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as scalarane sesterterpenoids. These are sesterterpenoids with a structure based on the scalarane backbone. Scalarane is a tetracyclic compound, which is similar the homoandrostane with five methyl groups at the 4-, 4-, 8-, 17-, 17a-positions.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Sesterterpenoids

Direct Parent

Scalarane sesterterpenoids

Alternative Parents

Substituents

Scalarane sesterterpenoid
15-hydroxysteroid
Hydroxysteroid
16-oxasteroid
Steroid
Dicarboxylic acid or derivatives
Tetrahydrofuran
Hemiacetal
Carboxylic acid ester
Organoheterocyclic compound
Oxacycle
Carboxylic acid derivative
Hydrocarbon derivative
Organooxygen compound
Organic oxide
Organic oxygen compound
Carbonyl group
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

162882803

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for [(1r,5as,5bs,7as,11as,11br,13s,13as,13bs)-13-(acetyloxy)-1-hydroxy-8,8,11a,13a-tetramethyl-1h,3h,5h,5ah,6h,7h,7ah,9h,10h,11h,11bh,12h,13h,13bh-chryseno[1,2-c]furan-5b-yl]methyl acetate (NP0234261)

MOL for NP0234261 ([(1r,5as,5bs,7as,11as,11br,13s,13as,13bs)-13-(acetyloxy)-1-hydroxy-8,8,11a,13a-tetramethyl-1h,3h,5h,5ah,6h,7h,7ah,9h,10h,11h,11bh,12h,13h,13bh-chryseno[1,2-c]furan-5b-yl]methyl acetate)

3D MOL for NP0234261 ([(1r,5as,5bs,7as,11as,11br,13s,13as,13bs)-13-(acetyloxy)-1-hydroxy-8,8,11a,13a-tetramethyl-1h,3h,5h,5ah,6h,7h,7ah,9h,10h,11h,11bh,12h,13h,13bh-chryseno[1,2-c]furan-5b-yl]methyl acetate)

3D SDF for NP0234261 ([(1r,5as,5bs,7as,11as,11br,13s,13as,13bs)-13-(acetyloxy)-1-hydroxy-8,8,11a,13a-tetramethyl-1h,3h,5h,5ah,6h,7h,7ah,9h,10h,11h,11bh,12h,13h,13bh-chryseno[1,2-c]furan-5b-yl]methyl acetate)

3D-SDF for NP0234261 ([(1r,5as,5bs,7as,11as,11br,13s,13as,13bs)-13-(acetyloxy)-1-hydroxy-8,8,11a,13a-tetramethyl-1h,3h,5h,5ah,6h,7h,7ah,9h,10h,11h,11bh,12h,13h,13bh-chryseno[1,2-c]furan-5b-yl]methyl acetate)

PDB for NP0234261 ([(1r,5as,5bs,7as,11as,11br,13s,13as,13bs)-13-(acetyloxy)-1-hydroxy-8,8,11a,13a-tetramethyl-1h,3h,5h,5ah,6h,7h,7ah,9h,10h,11h,11bh,12h,13h,13bh-chryseno[1,2-c]furan-5b-yl]methyl acetate)

3D PDB for NP0234261 ([(1r,5as,5bs,7as,11as,11br,13s,13as,13bs)-13-(acetyloxy)-1-hydroxy-8,8,11a,13a-tetramethyl-1h,3h,5h,5ah,6h,7h,7ah,9h,10h,11h,11bh,12h,13h,13bh-chryseno[1,2-c]furan-5b-yl]methyl acetate)

SMILES for NP0234261 ([(1r,5as,5bs,7as,11as,11br,13s,13as,13bs)-13-(acetyloxy)-1-hydroxy-8,8,11a,13a-tetramethyl-1h,3h,5h,5ah,6h,7h,7ah,9h,10h,11h,11bh,12h,13h,13bh-chryseno[1,2-c]furan-5b-yl]methyl acetate)

INCHI for NP0234261 ([(1r,5as,5bs,7as,11as,11br,13s,13as,13bs)-13-(acetyloxy)-1-hydroxy-8,8,11a,13a-tetramethyl-1h,3h,5h,5ah,6h,7h,7ah,9h,10h,11h,11bh,12h,13h,13bh-chryseno[1,2-c]furan-5b-yl]methyl acetate)

Structure for NP0234261 ([(1r,5as,5bs,7as,11as,11br,13s,13as,13bs)-13-(acetyloxy)-1-hydroxy-8,8,11a,13a-tetramethyl-1h,3h,5h,5ah,6h,7h,7ah,9h,10h,11h,11bh,12h,13h,13bh-chryseno[1,2-c]furan-5b-yl]methyl acetate)

3D Structure for NP0234261 ([(1r,5as,5bs,7as,11as,11br,13s,13as,13bs)-13-(acetyloxy)-1-hydroxy-8,8,11a,13a-tetramethyl-1h,3h,5h,5ah,6h,7h,7ah,9h,10h,11h,11bh,12h,13h,13bh-chryseno[1,2-c]furan-5b-yl]methyl acetate)