NP-MRD: Showing NP-Card for [(1s,2r,5s,6s,9r,10s,13s,14r)-13-[(2r,5r)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0²,⁶.0¹⁰,¹⁴]hexadec-11-en-5-yl]methanol (NP0221963)

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Record Information

Version

2.0

Created at

2022-09-05 23:40:42 UTC

Updated at

2022-09-05 23:40:43 UTC

NP-MRD ID

NP0221963

Secondary Accession Numbers

None

Natural Product Identification

Common Name

[(1s,2r,5s,6s,9r,10s,13s,14r)-13-[(2r,5r)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0²,⁶.0¹⁰,¹⁴]hexadec-11-en-5-yl]methanol

Description

[(1S,2R,5S,6S,9R,10S,13S,14R)-13-[(2R,5R)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0²,⁶.0¹⁰,¹⁴]Hexadec-11-en-5-yl]methanol belongs to the class of organic compounds known as cholestane steroids. These are steroids with a structure containing the 27-carbon cholestane skeleton. [(1s,2r,5s,6s,9r,10s,13s,14r)-13-[(2r,5r)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0²,⁶.0¹⁰,¹⁴]hexadec-11-en-5-yl]methanol is found in Axinella aruensis. Based on a literature review very few articles have been published on [(1S,2R,5S,6S,9R,10S,13S,14R)-13-[(2R,5R)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0²,⁶.0¹⁰,¹⁴]Hexadec-11-en-5-yl]methanol.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309062201402D          

 29 32  0  0  1  0            999 V2000
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M  END

     RDKit          3D

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M  END


  Mrv1652309062201402D          

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M  END
> <DATABASE_ID>
NP0221963

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC(C)[C@H](C)CC[C@@H](C)[C@H]1C=C[C@H]2[C@@H]3CC[C@H]4[C@@H](CO)CC[C@]4(C)[C@H]3CC[C@]12C

> <INCHI_IDENTIFIER>
InChI=1S/C28H48O/c1-18(2)19(3)7-8-20(4)23-11-12-25-22-9-10-24-21(17-29)13-15-28(24,6)26(22)14-16-27(23,25)5/h11-12,18-26,29H,7-10,13-17H2,1-6H3/t19-,20-,21-,22+,23-,24+,25+,26+,27-,28+/m1/s1

> <INCHI_KEY>
KXWXWGQKFMWWAF-BAENYUHTSA-N

> <FORMULA>
C28H48O

> <MOLECULAR_WEIGHT>
400.691

> <EXACT_MASS>
400.370516166

> <JCHEM_ACCEPTOR_COUNT>
1

> <JCHEM_ATOM_COUNT>
77

> <JCHEM_AVERAGE_POLARIZABILITY>
52.30184469377912

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
1

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
[(1S,2R,5S,6S,9R,10S,13S,14R)-13-[(2R,5R)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0^{2,6}.0^{10,14}]hexadec-11-en-5-yl]methanol

> <JCHEM_LOGP>
7.314010023333335

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA_STRONGEST_ACIDIC>
17.905676394443308

> <JCHEM_PKA_STRONGEST_BASIC>
-1.527857145070497

> <JCHEM_POLAR_SURFACE_AREA>
20.23

> <JCHEM_REFRACTIVITY>
125.56149999999998

> <JCHEM_ROTATABLE_BOND_COUNT>
6

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
[(1S,2R,5S,6S,9R,10S,13S,14R)-13-[(2R,5R)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0^{2,6}.0^{10,14}]hexadec-11-en-5-yl]methanol

> <JCHEM_VEBER_RULE>
1

$$$$

HEADER    PROTEIN                                 06-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   06-SEP-22         0                                  
HETATM    1  C   UNK     0       3.153 -10.179   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       4.487 -10.949   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       4.487 -12.489   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       5.820 -10.179   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       5.820  -8.639   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       7.154 -10.949   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       8.488 -10.179   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       9.822 -10.949   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       9.822 -12.489   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0      11.155 -10.179   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0      11.316  -8.647   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      12.823  -8.327   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      13.593  -9.661   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0      15.099  -9.981   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      16.129  -8.837   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0      17.636  -9.157   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0      18.112 -10.621   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0      19.518 -11.248   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0      20.852 -10.478   0.000  0.00  0.00           C+0
HETATM   20  O   UNK     0      20.852  -8.938   0.000  0.00  0.00           O+0
HETATM   21  C   UNK     0      19.357 -12.779   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      17.851 -13.100   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0      17.081 -11.766   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0      16.176 -13.012   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0      15.575 -11.446   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0      14.544 -12.590   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0      13.038 -12.270   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0      12.562 -10.805   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0      11.418 -11.836   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3    4                                                  
CONECT    3    2                                                            
CONECT    4    2    5    6                                                  
CONECT    5    4                                                            
CONECT    6    4    7                                                       
CONECT    7    6    8                                                       
CONECT    8    7    9   10                                                  
CONECT    9    8                                                            
CONECT   10    8   11   28                                                  
CONECT   11   10   12                                                       
CONECT   12   11   13                                                       
CONECT   13   12   14   28                                                  
CONECT   14   13   15   25                                                  
CONECT   15   14   16                                                       
CONECT   16   15   17                                                       
CONECT   17   16   18   23                                                  
CONECT   18   17   19   21                                                  
CONECT   19   18   20                                                       
CONECT   20   19                                                            
CONECT   21   18   22                                                       
CONECT   22   21   23                                                       
CONECT   23   22   17   24   25                                             
CONECT   24   23                                                            
CONECT   25   23   14   26                                                  
CONECT   26   25   27                                                       
CONECT   27   26   28                                                       
CONECT   28   27   10   13   29                                             
CONECT   29   28                                                            
MASTER        0    0    0    0    0    0    0    0   29    0   64    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₈H₄₈O

Average Mass

400.6910 Da

Monoisotopic Mass

400.37052 Da

IUPAC Name

[(1S,2R,5S,6S,9R,10S,13S,14R)-13-[(2R,5R)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0^{2,6}.0^{10,14}]hexadec-11-en-5-yl]methanol

Traditional Name

[(1S,2R,5S,6S,9R,10S,13S,14R)-13-[(2R,5R)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0^{2,6}.0^{10,14}]hexadec-11-en-5-yl]methanol

CAS Registry Number

Not Available

SMILES

CC(C)[C@H](C)CC[C@@H](C)[C@H]1C=C[C@H]2[C@@H]3CC[C@H]4[C@@H](CO)CC[C@]4(C)[C@H]3CC[C@]12C

InChI Identifier

InChI=1S/C28H48O/c1-18(2)19(3)7-8-20(4)23-11-12-25-22-9-10-24-21(17-29)13-15-28(24,6)26(22)14-16-27(23,25)5/h11-12,18-26,29H,7-10,13-17H2,1-6H3/t19-,20-,21-,22+,23-,24+,25+,26+,27-,28+/m1/s1

InChI Key

KXWXWGQKFMWWAF-BAENYUHTSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Axinella aruensis	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as cholestane steroids. These are steroids with a structure containing the 27-carbon cholestane skeleton.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Steroids and steroid derivatives

Sub Class

Cholestane steroids

Direct Parent

Cholestane steroids

Alternative Parents

Substituents

Cholestane-skeleton
Organic oxygen compound
Hydrocarbon derivative
Primary alcohol
Organooxygen compound
Alcohol
Aliphatic homopolycyclic compound

Molecular Framework

Aliphatic homopolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	7.31	ChemAxon
pKa (Strongest Acidic)	17.91	ChemAxon
pKa (Strongest Basic)	-1.5	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	1	ChemAxon
Hydrogen Donor Count	1	ChemAxon
Polar Surface Area	20.23 Å²	ChemAxon
Rotatable Bond Count	6	ChemAxon
Refractivity	125.56 m³·mol⁻¹	ChemAxon
Polarizability	52.3 Å³	ChemAxon
Number of Rings	4	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	Yes	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

29216633

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

163185314

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for [(1s,2r,5s,6s,9r,10s,13s,14r)-13-[(2r,5r)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0²,⁶.0¹⁰,¹⁴]hexadec-11-en-5-yl]methanol (NP0221963)

MOL for NP0221963 ([(1s,2r,5s,6s,9r,10s,13s,14r)-13-[(2r,5r)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0²,⁶.0¹⁰,¹⁴]hexadec-11-en-5-yl]methanol)

3D MOL for NP0221963 ([(1s,2r,5s,6s,9r,10s,13s,14r)-13-[(2r,5r)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0²,⁶.0¹⁰,¹⁴]hexadec-11-en-5-yl]methanol)

3D SDF for NP0221963 ([(1s,2r,5s,6s,9r,10s,13s,14r)-13-[(2r,5r)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0²,⁶.0¹⁰,¹⁴]hexadec-11-en-5-yl]methanol)

3D-SDF for NP0221963 ([(1s,2r,5s,6s,9r,10s,13s,14r)-13-[(2r,5r)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0²,⁶.0¹⁰,¹⁴]hexadec-11-en-5-yl]methanol)

PDB for NP0221963 ([(1s,2r,5s,6s,9r,10s,13s,14r)-13-[(2r,5r)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0²,⁶.0¹⁰,¹⁴]hexadec-11-en-5-yl]methanol)

3D PDB for NP0221963 ([(1s,2r,5s,6s,9r,10s,13s,14r)-13-[(2r,5r)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0²,⁶.0¹⁰,¹⁴]hexadec-11-en-5-yl]methanol)

SMILES for NP0221963 ([(1s,2r,5s,6s,9r,10s,13s,14r)-13-[(2r,5r)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0²,⁶.0¹⁰,¹⁴]hexadec-11-en-5-yl]methanol)

INCHI for NP0221963 ([(1s,2r,5s,6s,9r,10s,13s,14r)-13-[(2r,5r)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0²,⁶.0¹⁰,¹⁴]hexadec-11-en-5-yl]methanol)

Structure for NP0221963 ([(1s,2r,5s,6s,9r,10s,13s,14r)-13-[(2r,5r)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0²,⁶.0¹⁰,¹⁴]hexadec-11-en-5-yl]methanol)

3D Structure for NP0221963 ([(1s,2r,5s,6s,9r,10s,13s,14r)-13-[(2r,5r)-5,6-dimethylheptan-2-yl]-2,14-dimethyltetracyclo[7.7.0.0²,⁶.0¹⁰,¹⁴]hexadec-11-en-5-yl]methanol)