NP-MRD: Showing NP-Card for {6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate (NP0219722)

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Record Information

Version

1.0

Created at

2022-09-05 20:49:06 UTC

Updated at

2022-09-05 20:49:06 UTC

NP-MRD ID

NP0219722

Secondary Accession Numbers

None

Natural Product Identification

Common Name

{6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate

Description

{6-[4-({4-[(3,4-Dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate belongs to the class of organic compounds known as lignan glycosides. These are aromatic polycyclic compounds containing a carbohydrate component glycosidically linked to a lignan moiety. They include 1-aryltetralin lactones. {6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate is found in Saussurea involucrata. {6-[4-({4-[(3,4-Dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate is an extremely weak basic (essentially neutral) compound (based on its pKa).

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1533004251505212D          

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M  END

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M  END


  Mrv1533004251505212D          

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    4.5957    3.2317    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.2088    3.7837    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.7672    2.4247    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.5519    2.1698    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.1541    1.8727    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.3257    1.0657    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.3149    0.2166    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5302    0.4715    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.9171   -0.0805    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4864   -0.5904    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.6091    0.6402    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.3235    1.0527    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.3235    1.8777    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    7.0380    2.2902    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  2  0  0  0  0
  4  5  1  0  0  0  0
  5  6  2  0  0  0  0
  6  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  1  0  0  0  0
  9 10  1  0  0  0  0
 10 11  1  0  0  0  0
 11 12  2  0  0  0  0
 11 13  1  0  0  0  0
  8 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  1  0  0  0  0
 15 16  2  0  0  0  0
 16 17  1  0  0  0  0
 17 18  2  0  0  0  0
 18 19  1  0  0  0  0
 19 20  1  0  0  0  0
 20 21  1  0  0  0  0
 21 22  1  0  0  0  0
 22 23  1  0  0  0  0
 23 24  1  0  0  0  0
 24 25  1  0  0  0  0
 25 26  2  0  0  0  0
 25 27  1  0  0  0  0
 22 28  1  0  0  0  0
 28 29  1  0  0  0  0
 28 30  1  0  0  0  0
 30 31  1  0  0  0  0
 30 32  1  0  0  0  0
 20 32  1  0  0  0  0
 32 33  1  0  0  0  0
 18 34  1  0  0  0  0
 34 35  1  0  0  0  0
 35 36  1  0  0  0  0
 34 37  2  0  0  0  0
 15 37  1  0  0  0  0
  6 38  1  0  0  0  0
 38 39  2  0  0  0  0
  3 39  1  0  0  0  0
 39 40  1  0  0  0  0
 40 41  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0219722

> <DATABASE_NAME>
NP-MRD

> <SMILES>
COC1=CC=C(CC2COC(=O)C2CC2=CC=C(OC3OC(COC(C)=O)C(O)C(O)C3O)C(OC)=C2)C=C1OC

> <INCHI_IDENTIFIER>
InChI=1S/C29H36O12/c1-15(30)38-14-24-25(31)26(32)27(33)29(41-24)40-21-8-6-17(12-23(21)37-4)10-19-18(13-39-28(19)34)9-16-5-7-20(35-2)22(11-16)36-3/h5-8,11-12,18-19,24-27,29,31-33H,9-10,13-14H2,1-4H3

> <INCHI_KEY>
DUXDJPWVNHZEDV-UHFFFAOYSA-N

> <FORMULA>
C29H36O12

> <MOLECULAR_WEIGHT>
576.595

> <EXACT_MASS>
576.220676599

> <JCHEM_ACCEPTOR_COUNT>
10

> <JCHEM_ATOM_COUNT>
77

> <JCHEM_AVERAGE_POLARIZABILITY>
58.589474387419145

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
3

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
{6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate

> <ALOGPS_LOGP>
2.40

> <JCHEM_LOGP>
1.610733884000001

> <ALOGPS_LOGS>
-3.87

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
13.210650799880884

> <JCHEM_PKA_STRONGEST_ACIDIC>
12.201581751254398

> <JCHEM_PKA_STRONGEST_BASIC>
-3.6491028350711314

> <JCHEM_POLAR_SURFACE_AREA>
159.44

> <JCHEM_REFRACTIVITY>
141.41260000000003

> <JCHEM_ROTATABLE_BOND_COUNT>
12

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
7.84e-02 g/l

> <JCHEM_TRADITIONAL_IUPAC>
{6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 25-APR-15   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   25-APR-15         0                                  
HETATM    1  C   UNK     0      14.471   3.505   0.000  0.00  0.00           C+0
HETATM    2  O   UNK     0      14.471   1.965   0.000  0.00  0.00           O+0
HETATM    3  C   UNK     0      13.138   1.195   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      13.138  -0.345   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      11.804  -1.115   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      10.470  -0.345   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       9.137  -1.115   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       9.137  -2.655   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0      10.382  -3.560   0.000  0.00  0.00           C+0
HETATM   10  O   UNK     0       9.907  -5.025   0.000  0.00  0.00           O+0
HETATM   11  C   UNK     0       8.367  -5.025   0.000  0.00  0.00           C+0
HETATM   12  O   UNK     0       7.461  -6.271   0.000  0.00  0.00           O+0
HETATM   13  C   UNK     0       7.891  -3.560   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       6.426  -3.084   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       6.106  -1.578   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       7.250  -0.547   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       6.930   0.959   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       5.466   1.435   0.000  0.00  0.00           C+0
HETATM   19  O   UNK     0       5.145   2.941   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0       6.290   3.972   0.000  0.00  0.00           C+0
HETATM   21  O   UNK     0       5.970   5.478   0.000  0.00  0.00           O+0
HETATM   22  C   UNK     0       7.114   6.508   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       6.794   8.015   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0       5.329   8.491   0.000  0.00  0.00           O+0
HETATM   25  C   UNK     0       5.009   9.997   0.000  0.00  0.00           C+0
HETATM   26  O   UNK     0       3.544  10.473   0.000  0.00  0.00           O+0
HETATM   27  C   UNK     0       6.153  11.027   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       8.579   6.032   0.000  0.00  0.00           C+0
HETATM   29  O   UNK     0       9.723   7.063   0.000  0.00  0.00           O+0
HETATM   30  C   UNK     0       8.899   4.526   0.000  0.00  0.00           C+0
HETATM   31  O   UNK     0      10.363   4.050   0.000  0.00  0.00           O+0
HETATM   32  C   UNK     0       7.754   3.496   0.000  0.00  0.00           C+0
HETATM   33  O   UNK     0       8.075   1.989   0.000  0.00  0.00           O+0
HETATM   34  C   UNK     0       4.321   0.404   0.000  0.00  0.00           C+0
HETATM   35  O   UNK     0       2.856   0.880   0.000  0.00  0.00           O+0
HETATM   36  C   UNK     0       1.712  -0.150   0.000  0.00  0.00           C+0
HETATM   37  C   UNK     0       4.641  -1.102   0.000  0.00  0.00           C+0
HETATM   38  C   UNK     0      10.470   1.195   0.000  0.00  0.00           C+0
HETATM   39  C   UNK     0      11.804   1.965   0.000  0.00  0.00           C+0
HETATM   40  O   UNK     0      11.804   3.505   0.000  0.00  0.00           O+0
HETATM   41  C   UNK     0      13.138   4.275   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4   39                                                  
CONECT    4    3    5                                                       
CONECT    5    4    6                                                       
CONECT    6    5    7   38                                                  
CONECT    7    6    8                                                       
CONECT    8    7    9   13                                                  
CONECT    9    8   10                                                       
CONECT   10    9   11                                                       
CONECT   11   10   12   13                                                  
CONECT   12   11                                                            
CONECT   13   11    8   14                                                  
CONECT   14   13   15                                                       
CONECT   15   14   16   37                                                  
CONECT   16   15   17                                                       
CONECT   17   16   18                                                       
CONECT   18   17   19   34                                                  
CONECT   19   18   20                                                       
CONECT   20   19   21   32                                                  
CONECT   21   20   22                                                       
CONECT   22   21   23   28                                                  
CONECT   23   22   24                                                       
CONECT   24   23   25                                                       
CONECT   25   24   26   27                                                  
CONECT   26   25                                                            
CONECT   27   25                                                            
CONECT   28   22   29   30                                                  
CONECT   29   28                                                            
CONECT   30   28   31   32                                                  
CONECT   31   30                                                            
CONECT   32   30   20   33                                                  
CONECT   33   32                                                            
CONECT   34   18   35   37                                                  
CONECT   35   34   36                                                       
CONECT   36   35                                                            
CONECT   37   34   15                                                       
CONECT   38    6   39                                                       
CONECT   39   38    3   40                                                  
CONECT   40   39   41                                                       
CONECT   41   40                                                            
MASTER        0    0    0    0    0    0    0    0   41    0   88    0
END

View in JSmol

Synonyms

Value	Source
{6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetic acid	Generator

Chemical Formula

C₂₉H₃₆O₁₂

Average Mass

576.5950 Da

Monoisotopic Mass

576.22068 Da

IUPAC Name

{6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate

Traditional Name

{6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate

CAS Registry Number

Not Available

SMILES

COC1=CC=C(CC2COC(=O)C2CC2=CC=C(OC3OC(COC(C)=O)C(O)C(O)C3O)C(OC)=C2)C=C1OC

InChI Identifier

InChI=1S/C29H36O12/c1-15(30)38-14-24-25(31)26(32)27(33)29(41-24)40-21-8-6-17(12-23(21)37-4)10-19-18(13-39-28(19)34)9-16-5-7-20(35-2)22(11-16)36-3/h5-8,11-12,18-19,24-27,29,31-33H,9-10,13-14H2,1-4H3

InChI Key

DUXDJPWVNHZEDV-UHFFFAOYSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Saussurea involucrata	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as lignan glycosides. These are aromatic polycyclic compounds containing a carbohydrate component glycosidically linked to a lignan moiety. They include 1-aryltetralin lactones.

Kingdom

Organic compounds

Super Class

Lignans, neolignans and related compounds

Class

Lignan glycosides

Sub Class

Not Available

Direct Parent

Lignan glycosides

Alternative Parents

Substituents

Lignan glycoside
Dibenzylbutyrolactone
Lignan lactone
Tetrahydrofuran lignan
9,9p-epoxylignan
Furanoid lignan
Fatty acyl glycoside
Fatty acyl glycoside of mono- or disaccharide
Phenolic glycoside
Alkyl glycoside
Glycosyl compound
O-glycosyl compound
O-dimethoxybenzene
Dimethoxybenzene
Methoxybenzene
Phenoxy compound
Anisole
Phenol ether
Alkyl aryl ether
Fatty acyl
Dicarboxylic acid or derivatives
Benzenoid
Gamma butyrolactone
Monocyclic benzene moiety
Monosaccharide
Oxane
Tetrahydrofuran
Carboxylic acid ester
Lactone
Secondary alcohol
Carboxylic acid derivative
Polyol
Acetal
Ether
Oxacycle
Organoheterocyclic compound
Organic oxide
Carbonyl group
Organic oxygen compound
Organooxygen compound
Hydrocarbon derivative
Alcohol
Aromatic heteromonocyclic compound

Molecular Framework

Aromatic heteromonocyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	2.4	ALOGPS
logP	1.61	ChemAxon
logS	-3.9	ALOGPS
pKa (Strongest Acidic)	12.2	ChemAxon
pKa (Strongest Basic)	-3.6	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	10	ChemAxon
Hydrogen Donor Count	3	ChemAxon
Polar Surface Area	159.44 Å²	ChemAxon
Rotatable Bond Count	12	ChemAxon
Refractivity	141.41 m³·mol⁻¹	ChemAxon
Polarizability	58.59 Å³	ChemAxon
Number of Rings	4	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

Not Available

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for {6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate (NP0219722)

MOL for NP0219722 ({6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate)

3D MOL for NP0219722 ({6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate)

3D SDF for NP0219722 ({6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate)

3D-SDF for NP0219722 ({6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate)

PDB for NP0219722 ({6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate)

3D PDB for NP0219722 ({6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate)

SMILES for NP0219722 ({6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate)

INCHI for NP0219722 ({6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate)

Structure for NP0219722 ({6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate)

3D Structure for NP0219722 ({6-[4-({4-[(3,4-dimethoxyphenyl)methyl]-2-oxooxolan-3-yl}methyl)-2-methoxyphenoxy]-3,4,5-trihydroxyoxan-2-yl}methyl acetate)