NP-MRD: Showing NP-Card for (1's,2s,2'r,7'r,9'r,10'r,11's)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0²,⁷]dodecan]-5'-en-11'-yl (2z)-but-2-enoate (NP0219399)

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Record Information

Version

2.0

Created at

2022-09-05 20:22:27 UTC

Updated at

2022-09-05 20:22:27 UTC

NP-MRD ID

NP0219399

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1's,2s,2'r,7'r,9'r,10'r,11's)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0²,⁷]dodecan]-5'-en-11'-yl (2z)-but-2-enoate

Description

Trichothecinol A belongs to the class of organic compounds known as trichothecenes. These are sesquiterpene mycotoxins structurally characterized by the presence of an epoxide ring and a benzopyran derivative with a variant number of hydroxyl, acetyl, or other substituents. The most important structural features causing the biological activities of trichothecenes are the 12,13-epoxy ring, the presence of hydroxyl or acetyl groups at appropriate positions on the trichothecene nucleus and the structure and position of the side-chain. (1's,2s,2'r,7'r,9'r,10'r,11's)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0²,⁷]dodecan]-5'-en-11'-yl (2z)-but-2-enoate is found in Holarrhena floribunda and Trichothecium roseum. (1's,2s,2'r,7'r,9'r,10'r,11's)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0²,⁷]dodecan]-5'-en-11'-yl (2z)-but-2-enoate was first documented in 2015 (PMID: 25633363). Based on a literature review very few articles have been published on Trichothecinol A.

Structure

MOL SDF PDB SMILES InChI

  Mrv1652309052222222D          

 25 28  0  0  1  0            999 V2000
   -0.5871    2.5999    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3878    2.4011    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.6160    1.6082    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0434    1.0142    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.2716    0.2214    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.2428    1.2130    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.3298    0.6190    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.0430   -0.1545    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.7784   -0.2318    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.4690   -0.8610    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.2869   -0.9685    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.8809   -0.3960    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.6309   -0.7398    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.3036   -0.2622    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.0536   -0.6059    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.2264    0.5592    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.8991    1.0368    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.4764    0.9030    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.8037    0.4254    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.7880    1.2503    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.1133    0.8771    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.2208    1.6951    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.0084   -0.0725    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.8217    0.0659    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5350   -0.7076    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  2  0  0  0  0
  3  4  1  0  0  0  0
  4  5  2  0  0  0  0
  4  6  1  0  0  0  0
  7  6  1  1  0  0  0
  7  8  1  0  0  0  0
  8  9  1  6  0  0  0
  8 10  1  0  0  0  0
 10 11  1  6  0  0  0
 12 11  1  1  0  0  0
 12 13  1  0  0  0  0
 13 14  2  0  0  0  0
 14 15  1  0  0  0  0
 14 16  1  0  0  0  0
 16 17  2  0  0  0  0
 16 18  1  0  0  0  0
 18 19  1  0  0  0  0
 12 19  1  0  0  0  0
 19 20  1  6  0  0  0
 19 21  1  0  0  0  0
  7 21  1  0  0  0  0
 21 22  1  1  0  0  0
 21 23  1  0  0  0  0
 10 23  1  0  0  0  0
 23 24  1  0  0  0  0
 24 25  1  0  0  0  0
 23 25  1  1  0  0  0
M  END

  Mrv1652309052222222D          

 25 28  0  0  1  0            999 V2000
   -0.5871    2.5999    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3878    2.4011    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.6160    1.6082    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0434    1.0142    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.2716    0.2214    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.2428    1.2130    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.3298    0.6190    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.0430   -0.1545    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.7784   -0.2318    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.4690   -0.8610    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.2869   -0.9685    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.8809   -0.3960    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.6309   -0.7398    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.3036   -0.2622    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.0536   -0.6059    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.2264    0.5592    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.8991    1.0368    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.4764    0.9030    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.8037    0.4254    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.7880    1.2503    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.1133    0.8771    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.2208    1.6951    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.0084   -0.0725    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.8217    0.0659    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5350   -0.7076    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  2  0  0  0  0
  3  4  1  0  0  0  0
  4  5  2  0  0  0  0
  4  6  1  0  0  0  0
  7  6  1  1  0  0  0
  7  8  1  0  0  0  0
  8  9  1  6  0  0  0
  8 10  1  0  0  0  0
 10 11  1  6  0  0  0
 12 11  1  1  0  0  0
 12 13  1  0  0  0  0
 13 14  2  0  0  0  0
 14 15  1  0  0  0  0
 14 16  1  0  0  0  0
 16 17  2  0  0  0  0
 16 18  1  0  0  0  0
 18 19  1  0  0  0  0
 12 19  1  0  0  0  0
 19 20  1  6  0  0  0
 19 21  1  0  0  0  0
  7 21  1  0  0  0  0
 21 22  1  1  0  0  0
 21 23  1  0  0  0  0
 10 23  1  0  0  0  0
 23 24  1  0  0  0  0
 24 25  1  0  0  0  0
 23 25  1  1  0  0  0
M  END
> <DATABASE_ID>
NP0219399

> <DATABASE_NAME>
NP-MRD

> <SMILES>
C\C=C/C(=O)O[C@@H]1[C@@H](O)[C@H]2O[C@@H]3C=C(C)C(=O)C[C@]3(C)[C@]1(C)[C@]21CO1

> <INCHI_IDENTIFIER>
InChI=1S/C19H24O6/c1-5-6-13(21)25-15-14(22)16-19(9-23-19)18(15,4)17(3)8-11(20)10(2)7-12(17)24-16/h5-7,12,14-16,22H,8-9H2,1-4H3/b6-5-/t12-,14-,15-,16-,17+,18-,19+/m1/s1

> <INCHI_KEY>
RVOJMELIZZNGBE-DUGZWPNFSA-N

> <FORMULA>
C19H24O6

> <MOLECULAR_WEIGHT>
348.395

> <EXACT_MASS>
348.157288493

> <JCHEM_ACCEPTOR_COUNT>
5

> <JCHEM_ATOM_COUNT>
49

> <JCHEM_AVERAGE_POLARIZABILITY>
35.548734315267104

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
1

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
1

> <JCHEM_IUPAC>
(1'S,2S,2'R,7'R,9'R,10'R,11'S)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0^{2,7}]dodecan]-5'-en-11'-yl (2Z)-but-2-enoate

> <JCHEM_LOGP>
1.925623325333333

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
18.100201450413756

> <JCHEM_PKA_STRONGEST_ACIDIC>
13.071807016072142

> <JCHEM_PKA_STRONGEST_BASIC>
-3.6421896339950735

> <JCHEM_POLAR_SURFACE_AREA>
85.36000000000001

> <JCHEM_REFRACTIVITY>
89.18789999999997

> <JCHEM_ROTATABLE_BOND_COUNT>
3

> <JCHEM_RULE_OF_FIVE>
1

> <JCHEM_TRADITIONAL_IUPAC>
(1'S,2S,2'R,7'R,9'R,10'R,11'S)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0^{2,7}]dodecan]-5'-en-11'-yl (2Z)-but-2-enoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 05-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   05-SEP-22         0                                  
HETATM    1  C   UNK     0      -1.096   4.853   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      -2.591   4.482   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      -3.016   3.002   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -1.948   1.893   0.000  0.00  0.00           C+0
HETATM    5  O   UNK     0      -2.374   0.413   0.000  0.00  0.00           O+0
HETATM    6  O   UNK     0      -0.453   2.264   0.000  0.00  0.00           O+0
HETATM    7  C   UNK     0       0.616   1.156   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       0.080  -0.288   0.000  0.00  0.00           C+0
HETATM    9  O   UNK     0      -1.453  -0.433   0.000  0.00  0.00           O+0
HETATM   10  C   UNK     0       0.875  -1.607   0.000  0.00  0.00           C+0
HETATM   11  O   UNK     0       2.402  -1.808   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0       3.511  -0.739   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       4.911  -1.381   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       6.167  -0.489   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       7.567  -1.131   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       6.023   1.044   0.000  0.00  0.00           C+0
HETATM   17  O   UNK     0       7.278   1.935   0.000  0.00  0.00           O+0
HETATM   18  C   UNK     0       4.623   1.686   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       3.367   0.794   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       3.338   2.334   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       2.078   1.637   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       2.279   3.164   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       1.882  -0.135   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       3.401   0.123   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0       2.865  -1.321   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4                                                       
CONECT    4    3    5    6                                                  
CONECT    5    4                                                            
CONECT    6    4    7                                                       
CONECT    7    6    8   21                                                  
CONECT    8    7    9   10                                                  
CONECT    9    8                                                            
CONECT   10    8   11   23                                                  
CONECT   11   10   12                                                       
CONECT   12   11   13   19                                                  
CONECT   13   12   14                                                       
CONECT   14   13   15   16                                                  
CONECT   15   14                                                            
CONECT   16   14   17   18                                                  
CONECT   17   16                                                            
CONECT   18   16   19                                                       
CONECT   19   18   12   20   21                                             
CONECT   20   19                                                            
CONECT   21   19    7   22   23                                             
CONECT   22   21                                                            
CONECT   23   21   10   24   25                                             
CONECT   24   23   25                                                       
CONECT   25   24   23                                                       
MASTER        0    0    0    0    0    0    0    0   25    0   56    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₁₉H₂₄O₆

Average Mass

348.3950 Da

Monoisotopic Mass

348.15729 Da

IUPAC Name

(1'S,2S,2'R,7'R,9'R,10'R,11'S)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0^{2,7}]dodecan]-5'-en-11'-yl (2Z)-but-2-enoate

Traditional Name

(1'S,2S,2'R,7'R,9'R,10'R,11'S)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0^{2,7}]dodecan]-5'-en-11'-yl (2Z)-but-2-enoate

CAS Registry Number

Not Available

SMILES

C\C=C/C(=O)O[C@@H]1[C@@H](O)[C@H]2O[C@@H]3C=C(C)C(=O)C[C@]3(C)[C@]1(C)[C@]21CO1

InChI Identifier

InChI=1S/C19H24O6/c1-5-6-13(21)25-15-14(22)16-19(9-23-19)18(15,4)17(3)8-11(20)10(2)7-12(17)24-16/h5-7,12,14-16,22H,8-9H2,1-4H3/b6-5-/t12-,14-,15-,16-,17+,18-,19+/m1/s1

InChI Key

RVOJMELIZZNGBE-DUGZWPNFSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Holarrhena floribunda	LOTUS Database	35616633
Trichothecium roseum	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as trichothecenes. These are sesquiterpene mycotoxins structurally characterized by the presence of an epoxide ring and a benzopyran derivative with a variant number of hydroxyl, acetyl, or other substituents. The most important structural features causing the biological activities of trichothecenes are the 12,13-epoxy ring, the presence of hydroxyl or acetyl groups at appropriate positions on the trichothecene nucleus and the structure and position of the side-chain.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Sesquiterpenoids

Direct Parent

Trichothecenes

Alternative Parents

Substituents

Trichothecene skeleton
Fatty acid ester
Cyclohexenone
Oxepane
Oxane
Fatty acyl
Cyclic alcohol
Enoate ester
Alpha,beta-unsaturated carboxylic ester
Cyclic ketone
Secondary alcohol
Carboxylic acid ester
Ketone
Oxacycle
Organoheterocyclic compound
Carboxylic acid derivative
Monocarboxylic acid or derivatives
Dialkyl ether
Ether
Oxirane
Hydrocarbon derivative
Organic oxygen compound
Alcohol
Organooxygen compound
Organic oxide
Carbonyl group
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	1.93	ChemAxon
pKa (Strongest Acidic)	13.07	ChemAxon
pKa (Strongest Basic)	-3.6	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	5	ChemAxon
Hydrogen Donor Count	1	ChemAxon
Polar Surface Area	85.36 Å²	ChemAxon
Rotatable Bond Count	3	ChemAxon
Refractivity	89.19 m³·mol⁻¹	ChemAxon
Polarizability	35.55 Å³	ChemAxon
Number of Rings	4	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	Yes	ChemAxon
Ghose Filter	Yes	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

C00046956

Chemspider ID

8648340

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

10472929

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

Wang Y, Zhang L, Li GT, Li ZH, Dong ZJ, Li Y, Liu JK: Identification and Cytotoxic Activities of Two New Trichothecenes and a New Cuparane-Type Sesquiterpenoid from the Cultures of the Mushroom Engleromyces goetzii. Nat Prod Bioprospect. 2015 Jan 30. doi: 10.1007/s13659-014-0051-1. [PubMed:25633363 ]
LOTUS database [Link]

Showing NP-Card for (1's,2s,2'r,7'r,9'r,10'r,11's)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0²,⁷]dodecan]-5'-en-11'-yl (2z)-but-2-enoate (NP0219399)

MOL for NP0219399 ((1's,2s,2'r,7'r,9'r,10'r,11's)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0²,⁷]dodecan]-5'-en-11'-yl (2z)-but-2-enoate)

3D MOL for NP0219399 ((1's,2s,2'r,7'r,9'r,10'r,11's)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0²,⁷]dodecan]-5'-en-11'-yl (2z)-but-2-enoate)

3D SDF for NP0219399 ((1's,2s,2'r,7'r,9'r,10'r,11's)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0²,⁷]dodecan]-5'-en-11'-yl (2z)-but-2-enoate)

3D-SDF for NP0219399 ((1's,2s,2'r,7'r,9'r,10'r,11's)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0²,⁷]dodecan]-5'-en-11'-yl (2z)-but-2-enoate)

PDB for NP0219399 ((1's,2s,2'r,7'r,9'r,10'r,11's)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0²,⁷]dodecan]-5'-en-11'-yl (2z)-but-2-enoate)

3D PDB for NP0219399 ((1's,2s,2'r,7'r,9'r,10'r,11's)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0²,⁷]dodecan]-5'-en-11'-yl (2z)-but-2-enoate)

SMILES for NP0219399 ((1's,2s,2'r,7'r,9'r,10'r,11's)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0²,⁷]dodecan]-5'-en-11'-yl (2z)-but-2-enoate)

INCHI for NP0219399 ((1's,2s,2'r,7'r,9'r,10'r,11's)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0²,⁷]dodecan]-5'-en-11'-yl (2z)-but-2-enoate)

Structure for NP0219399 ((1's,2s,2'r,7'r,9'r,10'r,11's)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0²,⁷]dodecan]-5'-en-11'-yl (2z)-but-2-enoate)

3D Structure for NP0219399 ((1's,2s,2'r,7'r,9'r,10'r,11's)-10'-hydroxy-1',2',5'-trimethyl-4'-oxo-8'-oxaspiro[oxirane-2,12'-tricyclo[7.2.1.0²,⁷]dodecan]-5'-en-11'-yl (2z)-but-2-enoate)