NP-MRD: Showing NP-Card for 7-methoxy-3a,6,6,9a,11a-pentamethyl-1-(5,5,6-trimethylhept-6-en-2-yl)-1h,2h,3h,3bh,4h,5h,5ah,7h,8h,9h,11h-cyclopenta[a]phenanthrene (NP0214419)

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Record Information

Version

2.0

Created at

2022-09-05 13:42:58 UTC

Updated at

2022-09-05 13:42:58 UTC

NP-MRD ID

NP0214419

Secondary Accession Numbers

None

Natural Product Identification

Common Name

7-methoxy-3a,6,6,9a,11a-pentamethyl-1-(5,5,6-trimethylhept-6-en-2-yl)-1h,2h,3h,3bh,4h,5h,5ah,7h,8h,9h,11h-cyclopenta[a]phenanthrene

Description

5-Methoxy-2,6,6,11,15-pentamethyl-14-(5,5,6-trimethylhept-6-en-2-yl)tetracyclo[8.7.0.0²,⁷.0¹¹,¹⁵]Heptadec-1(17)-ene belongs to the class of organic compounds known as triterpenoids. These are terpene molecules containing six isoprene units. 7-methoxy-3a,6,6,9a,11a-pentamethyl-1-(5,5,6-trimethylhept-6-en-2-yl)-1h,2h,3h,3bh,4h,5h,5ah,7h,8h,9h,11h-cyclopenta[a]phenanthrene is found in Neolitsea pulchella. Based on a literature review very few articles have been published on 5-methoxy-2,6,6,11,15-pentamethyl-14-(5,5,6-trimethylhept-6-en-2-yl)tetracyclo[8.7.0.0²,⁷.0¹¹,¹⁵]Heptadec-1(17)-ene.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309052215422D          

 34 37  0  0  0  0            999 V2000
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M  END

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M  END


  Mrv1652309052215422D          

 34 37  0  0  0  0            999 V2000
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    0.5086   -3.1969    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.0404   -2.5662    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7601   -1.7902    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.4798   -1.0143    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.2920   -1.1595    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1041   -1.3047    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.3844   -2.0807    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.1965   -2.2259    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.7283   -1.5952    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.8526   -2.7114    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4643   -3.2649    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.7358   -3.5281    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0520   -1.6450    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3323   -0.8691    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.1444   -0.7239    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.6762   -1.3546    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0361   -0.6122    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  2  0  0  0  0
  2  3  1  0  0  0  0
  2  4  1  0  0  0  0
  4  5  1  0  0  0  0
  4  6  1  0  0  0  0
  4  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  1  0  0  0  0
  9 10  1  0  0  0  0
  9 11  1  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  1  0  0  0  0
 14 16  1  0  0  0  0
 16 17  1  0  0  0  0
 17 18  1  0  0  0  0
 18 19  1  0  0  0  0
 19 20  1  0  0  0  0
 20 21  1  0  0  0  0
 20 22  1  0  0  0  0
 22 23  1  0  0  0  0
 23 24  1  0  0  0  0
 24 25  1  0  0  0  0
 25 26  1  0  0  0  0
 24 27  1  0  0  0  0
 19 27  1  0  0  0  0
 27 28  1  0  0  0  0
 27 29  1  0  0  0  0
 20 30  1  0  0  0  0
 16 30  1  0  0  0  0
 30 31  2  0  0  0  0
 31 32  1  0  0  0  0
 32 33  1  0  0  0  0
 11 33  1  0  0  0  0
 14 33  1  0  0  0  0
 33 34  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0214419

> <DATABASE_NAME>
NP-MRD

> <SMILES>
COC1CCC2(C)C(CCC3C2=CCC2(C)C(CCC32C)C(C)CCC(C)(C)C(C)=C)C1(C)C

> <INCHI_IDENTIFIER>
InChI=1S/C33H56O/c1-22(2)29(4,5)18-14-23(3)24-15-20-33(10)26-12-13-27-30(6,7)28(34-11)17-19-31(27,8)25(26)16-21-32(24,33)9/h16,23-24,26-28H,1,12-15,17-21H2,2-11H3

> <INCHI_KEY>
GOFCNAACXLOQDI-UHFFFAOYSA-N

> <FORMULA>
C33H56O

> <MOLECULAR_WEIGHT>
468.81

> <EXACT_MASS>
468.433116423

> <JCHEM_ACCEPTOR_COUNT>
1

> <JCHEM_ATOM_COUNT>
90

> <JCHEM_AVERAGE_POLARIZABILITY>
61.06994943099063

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
0

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
5-methoxy-2,6,6,11,15-pentamethyl-14-(5,5,6-trimethylhept-6-en-2-yl)tetracyclo[8.7.0.0^{2,7}.0^{11,15}]heptadec-1(17)-ene

> <JCHEM_LOGP>
9.038456736

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA_STRONGEST_BASIC>
-4.126415556826106

> <JCHEM_POLAR_SURFACE_AREA>
9.23

> <JCHEM_REFRACTIVITY>
147.51369999999997

> <JCHEM_ROTATABLE_BOND_COUNT>
6

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
5-methoxy-2,6,6,11,15-pentamethyl-14-(5,5,6-trimethylhept-6-en-2-yl)tetracyclo[8.7.0.0^{2,7}.0^{11,15}]heptadec-1(17)-ene

> <JCHEM_VEBER_RULE>
1

$$$$

HEADER    PROTEIN                                 05-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   05-SEP-22         0                                  
HETATM    1  C   UNK     0     -12.080   0.437   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0     -11.135  -0.779   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0     -11.715  -2.205   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -9.610  -0.568   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -9.399  -2.094   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -9.820   0.957   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0      -8.084  -0.358   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      -7.139  -1.573   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0      -5.613  -1.363   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0      -5.033   0.064   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0      -4.668  -2.579   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      -5.096  -4.058   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      -3.822  -4.922   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0      -2.606  -3.977   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      -2.237  -5.472   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0      -1.090  -4.248   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0      -0.567  -5.696   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       0.949  -5.967   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       1.942  -4.790   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       1.419  -3.342   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       0.896  -1.893   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       2.412  -2.164   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       3.928  -2.436   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       4.451  -3.884   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0       5.967  -4.155   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0       6.960  -2.978   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       3.458  -5.061   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       4.600  -6.094   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       3.240  -6.586   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0      -0.097  -3.071   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0      -0.620  -1.622   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0      -2.136  -1.351   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0      -3.129  -2.529   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0      -3.801  -1.143   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3    4                                                  
CONECT    3    2                                                            
CONECT    4    2    5    6    7                                             
CONECT    5    4                                                            
CONECT    6    4                                                            
CONECT    7    4    8                                                       
CONECT    8    7    9                                                       
CONECT    9    8   10   11                                                  
CONECT   10    9                                                            
CONECT   11    9   12   33                                                  
CONECT   12   11   13                                                       
CONECT   13   12   14                                                       
CONECT   14   13   15   16   33                                             
CONECT   15   14                                                            
CONECT   16   14   17   30                                                  
CONECT   17   16   18                                                       
CONECT   18   17   19                                                       
CONECT   19   18   20   27                                                  
CONECT   20   19   21   22   30                                             
CONECT   21   20                                                            
CONECT   22   20   23                                                       
CONECT   23   22   24                                                       
CONECT   24   23   25   27                                                  
CONECT   25   24   26                                                       
CONECT   26   25                                                            
CONECT   27   24   19   28   29                                             
CONECT   28   27                                                            
CONECT   29   27                                                            
CONECT   30   20   16   31                                                  
CONECT   31   30   32                                                       
CONECT   32   31   33                                                       
CONECT   33   32   11   14   34                                             
CONECT   34   33                                                            
MASTER        0    0    0    0    0    0    0    0   34    0   74    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₃₃H₅₆O

Average Mass

468.8100 Da

Monoisotopic Mass

468.43312 Da

IUPAC Name

5-methoxy-2,6,6,11,15-pentamethyl-14-(5,5,6-trimethylhept-6-en-2-yl)tetracyclo[8.7.0.0^{2,7}.0^{11,15}]heptadec-1(17)-ene

Traditional Name

5-methoxy-2,6,6,11,15-pentamethyl-14-(5,5,6-trimethylhept-6-en-2-yl)tetracyclo[8.7.0.0^{2,7}.0^{11,15}]heptadec-1(17)-ene

CAS Registry Number

Not Available

SMILES

COC1CCC2(C)C(CCC3C2=CCC2(C)C(CCC32C)C(C)CCC(C)(C)C(C)=C)C1(C)C

InChI Identifier

InChI=1S/C33H56O/c1-22(2)29(4,5)18-14-23(3)24-15-20-33(10)26-12-13-27-30(6,7)28(34-11)17-19-31(27,8)25(26)16-21-32(24,33)9/h16,23-24,26-28H,1,12-15,17-21H2,2-11H3

InChI Key

GOFCNAACXLOQDI-UHFFFAOYSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Neolitsea pulchella	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as triterpenoids. These are terpene molecules containing six isoprene units.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Triterpenoids

Direct Parent

Triterpenoids

Alternative Parents

Substituents

Triterpenoid
Ergostane-skeleton
Cholane-skeleton
Steroid
Ether
Dialkyl ether
Organic oxygen compound
Hydrocarbon derivative
Organooxygen compound
Aliphatic homopolycyclic compound

Molecular Framework

Aliphatic homopolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	9.04	ChemAxon
pKa (Strongest Basic)	-4.1	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	1	ChemAxon
Hydrogen Donor Count	0	ChemAxon
Polar Surface Area	9.23 Å²	ChemAxon
Rotatable Bond Count	6	ChemAxon
Refractivity	147.51 m³·mol⁻¹	ChemAxon
Polarizability	61.07 Å³	ChemAxon
Number of Rings	4	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	Yes	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

162989253

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for 7-methoxy-3a,6,6,9a,11a-pentamethyl-1-(5,5,6-trimethylhept-6-en-2-yl)-1h,2h,3h,3bh,4h,5h,5ah,7h,8h,9h,11h-cyclopenta[a]phenanthrene (NP0214419)

MOL for NP0214419 (7-methoxy-3a,6,6,9a,11a-pentamethyl-1-(5,5,6-trimethylhept-6-en-2-yl)-1h,2h,3h,3bh,4h,5h,5ah,7h,8h,9h,11h-cyclopenta[a]phenanthrene)

3D MOL for NP0214419 (7-methoxy-3a,6,6,9a,11a-pentamethyl-1-(5,5,6-trimethylhept-6-en-2-yl)-1h,2h,3h,3bh,4h,5h,5ah,7h,8h,9h,11h-cyclopenta[a]phenanthrene)

3D SDF for NP0214419 (7-methoxy-3a,6,6,9a,11a-pentamethyl-1-(5,5,6-trimethylhept-6-en-2-yl)-1h,2h,3h,3bh,4h,5h,5ah,7h,8h,9h,11h-cyclopenta[a]phenanthrene)

3D-SDF for NP0214419 (7-methoxy-3a,6,6,9a,11a-pentamethyl-1-(5,5,6-trimethylhept-6-en-2-yl)-1h,2h,3h,3bh,4h,5h,5ah,7h,8h,9h,11h-cyclopenta[a]phenanthrene)

PDB for NP0214419 (7-methoxy-3a,6,6,9a,11a-pentamethyl-1-(5,5,6-trimethylhept-6-en-2-yl)-1h,2h,3h,3bh,4h,5h,5ah,7h,8h,9h,11h-cyclopenta[a]phenanthrene)

3D PDB for NP0214419 (7-methoxy-3a,6,6,9a,11a-pentamethyl-1-(5,5,6-trimethylhept-6-en-2-yl)-1h,2h,3h,3bh,4h,5h,5ah,7h,8h,9h,11h-cyclopenta[a]phenanthrene)

SMILES for NP0214419 (7-methoxy-3a,6,6,9a,11a-pentamethyl-1-(5,5,6-trimethylhept-6-en-2-yl)-1h,2h,3h,3bh,4h,5h,5ah,7h,8h,9h,11h-cyclopenta[a]phenanthrene)

INCHI for NP0214419 (7-methoxy-3a,6,6,9a,11a-pentamethyl-1-(5,5,6-trimethylhept-6-en-2-yl)-1h,2h,3h,3bh,4h,5h,5ah,7h,8h,9h,11h-cyclopenta[a]phenanthrene)

Structure for NP0214419 (7-methoxy-3a,6,6,9a,11a-pentamethyl-1-(5,5,6-trimethylhept-6-en-2-yl)-1h,2h,3h,3bh,4h,5h,5ah,7h,8h,9h,11h-cyclopenta[a]phenanthrene)

3D Structure for NP0214419 (7-methoxy-3a,6,6,9a,11a-pentamethyl-1-(5,5,6-trimethylhept-6-en-2-yl)-1h,2h,3h,3bh,4h,5h,5ah,7h,8h,9h,11h-cyclopenta[a]phenanthrene)