NP-MRD: Showing NP-Card for (2r,3s,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2e)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate (NP0213352)

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Record Information

Version

2.0

Created at

2022-09-05 12:18:51 UTC

Updated at

2022-09-05 12:18:52 UTC

NP-MRD ID

NP0213352

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(2r,3s,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2e)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate

Description

(2R,3S,4R,5R,6S)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2E)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate belongs to the class of organic compounds known as tannins. These are naturally occurring polyphenols which be categorized into four main classes: Hydrolyzable tannin (based on ellagic acid or gallic acid), condensed tannins (made of oligomeric or polymeric proanthocyanidins), complex tannins (made of a catechin bound to a gallotannin or elagitannin), and phlorotannins (oligomers of phloroglucinol). (2r,3s,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2e)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate is found in Balanophora fungosa. Based on a literature review very few articles have been published on (2R,3S,4R,5R,6S)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2E)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309052214182D          

 33 35  0  0  1  0            999 V2000
    2.8579   -4.9500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434   -5.3625    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434   -6.1875    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8579   -6.6000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8579   -7.4250    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5724   -7.8375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5724   -8.6625    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8579   -9.0750    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434   -8.6625    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434   -7.8375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289   -4.9500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289   -4.1250    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.7145   -3.7125    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145   -2.8875    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.0000   -2.4750    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145   -2.8875    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289   -2.4750    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.4289   -1.6500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145   -1.2375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000   -1.6500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145   -0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000    0.0000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000    0.8250    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145    1.2375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145    1.2375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145    2.0625    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289    0.8250    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434    1.2375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289    0.0000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434   -2.8875    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.8579   -2.4750    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434   -3.7125    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.8579   -4.1250    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  2  0  0  0  0
  2  3  1  0  0  0  0
  3  4  2  0  0  0  0
  4  5  1  0  0  0  0
  5  6  2  0  0  0  0
  6  7  1  0  0  0  0
  7  8  2  0  0  0  0
  8  9  1  0  0  0  0
  9 10  2  0  0  0  0
  5 10  1  0  0  0  0
  2 11  1  0  0  0  0
 12 11  1  6  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  1  6  0  0  0
 15 16  1  0  0  0  0
 14 17  1  0  0  0  0
 17 18  1  1  0  0  0
 18 19  1  0  0  0  0
 19 20  2  0  0  0  0
 19 21  1  0  0  0  0
 21 22  2  0  0  0  0
 22 23  1  0  0  0  0
 23 24  1  0  0  0  0
 23 25  2  0  0  0  0
 25 26  1  0  0  0  0
 25 27  1  0  0  0  0
 27 28  1  0  0  0  0
 27 29  2  0  0  0  0
 21 29  1  0  0  0  0
 17 30  1  0  0  0  0
 30 31  1  6  0  0  0
 30 32  1  0  0  0  0
 12 32  1  0  0  0  0
 32 33  1  1  0  0  0
M  END

     RDKit          3D

 55 57  0  0  0  0  0  0  0  0999 V2000
    3.0641   -0.2529   -3.3039 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.2364   -0.2863   -2.0810 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.5792   -0.1637   -1.5345 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.7973   -0.1955   -0.2322 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.1008   -0.0807    0.3982 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.2417    0.0755   -0.3349 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.4878    0.1844    0.2859 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.5279    0.1296    1.6500 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.3856   -0.0278    2.4058 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.1688   -0.1340    1.7951 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1709   -0.4376   -1.2437 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.8258   -0.5654   -1.6703 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.1440    0.5455   -1.2564 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4069    0.4785   -0.0125 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.5921    0.3297    1.1024 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0446    0.2682    2.3402 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4468   -0.5857    0.0958 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.7484   -0.0605   -0.1384 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.7442   -0.0520    0.8072 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.4735   -0.5378    1.9326 O   0  0  0  0  0  0  0  0  0  0  0  0
   -5.0491    0.5063    0.4817 C   0  0  0  0  0  0  0  0  0  0  0  0
   -5.2890    1.0264   -0.7709 C   0  0  0  0  0  0  0  0  0  0  0  0
   -6.5363    1.5636   -1.0929 C   0  0  0  0  0  0  0  0  0  0  0  0
   -6.7929    2.0918   -2.3521 O   0  0  0  0  0  0  0  0  0  0  0  0
   -7.5675    1.5948   -0.1794 C   0  0  0  0  0  0  0  0  0  0  0  0
   -8.8214    2.1309   -0.4917 O   0  0  0  0  0  0  0  0  0  0  0  0
   -7.3233    1.0736    1.0722 C   0  0  0  0  0  0  0  0  0  0  0  0
   -8.3621    1.1037    1.9962 O   0  0  0  0  0  0  0  0  0  0  0  0
   -6.0896    0.5441    1.3852 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.1790   -1.7867   -0.7708 C   0  0  2  0  0  0  0  0  0  0  0  0
   -1.4446   -2.9894   -0.0947 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.2094   -1.8655   -1.3064 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.1618   -2.7344   -2.4225 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.4034   -0.0453   -2.2115 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.8980   -0.3194    0.3801 H   0  0  0  0  0  0  0  0  0  0  0  0
    7.2226    0.1208   -1.4271 H   0  0  0  0  0  0  0  0  0  0  0  0
    9.3873    0.3088   -0.3149 H   0  0  0  0  0  0  0  0  0  0  0  0
    9.4685    0.2087    2.1886 H   0  0  0  0  0  0  0  0  0  0  0  0
    7.4143   -0.0720    3.4945 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.2465   -0.2586    2.3488 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.8697   -0.5130   -2.7988 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.9245    1.4662    0.1685 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.1885   -0.5981    0.9955 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.3146    1.1659    1.1590 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.4779    0.6782    3.0581 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4557   -0.9509    1.1497 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.4934    1.0188   -1.5223 H   0  0  0  0  0  0  0  0  0  0  0  0
   -6.1377    2.1307   -3.0994 H   0  0  0  0  0  0  0  0  0  0  0  0
   -9.0271    2.5162   -1.3923 H   0  0  0  0  0  0  0  0  0  0  0  0
   -9.2635    1.4783    1.8031 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.9064    0.1386    2.3654 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.8770   -1.7966   -1.6582 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0299   -2.9338    0.7904 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.8758   -2.3842   -0.5739 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0262   -2.2500   -3.2460 H   0  0  0  0  0  0  0  0  0  0  0  0
 16 15  1  0
 15 14  1  0
 14 13  1  0
 13 12  1  0
 12 11  1  0
 11  2  1  0
  2  1  2  0
  2  3  1  0
  3  4  2  0
  4  5  1  0
  5  6  2  0
  6  7  1  0
  7  8  2  0
  8  9  1  0
  9 10  2  0
 12 32  1  0
 32 33  1  0
 32 30  1  0
 30 31  1  0
 30 17  1  0
 17 18  1  0
 18 19  1  0
 19 20  2  0
 19 21  1  0
 21 22  2  0
 22 23  1  0
 23 24  1  0
 23 25  2  0
 25 26  1  0
 25 27  1  0
 27 28  1  0
 27 29  2  0
 17 14  1  0
 29 21  1  0
 10  5  1  0
 16 45  1  0
 15 43  1  0
 15 44  1  0
 14 42  1  1
 12 41  1  6
  3 34  1  0
  4 35  1  0
  6 36  1  0
  7 37  1  0
  8 38  1  0
  9 39  1  0
 10 40  1  0
 32 54  1  1
 33 55  1  0
 30 52  1  6
 31 53  1  0
 17 46  1  1
 22 47  1  0
 24 48  1  0
 26 49  1  0
 28 50  1  0
 29 51  1  0
M  END


  Mrv1652309052214182D          

 33 35  0  0  1  0            999 V2000
    2.8579   -4.9500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434   -5.3625    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434   -6.1875    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8579   -6.6000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8579   -7.4250    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5724   -7.8375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5724   -8.6625    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8579   -9.0750    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434   -8.6625    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434   -7.8375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289   -4.9500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289   -4.1250    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.7145   -3.7125    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145   -2.8875    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.0000   -2.4750    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145   -2.8875    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289   -2.4750    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.4289   -1.6500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145   -1.2375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000   -1.6500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145   -0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000    0.0000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000    0.8250    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145    1.2375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145    1.2375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145    2.0625    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289    0.8250    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434    1.2375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289    0.0000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434   -2.8875    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.8579   -2.4750    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434   -3.7125    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.8579   -4.1250    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  2  0  0  0  0
  2  3  1  0  0  0  0
  3  4  2  0  0  0  0
  4  5  1  0  0  0  0
  5  6  2  0  0  0  0
  6  7  1  0  0  0  0
  7  8  2  0  0  0  0
  8  9  1  0  0  0  0
  9 10  2  0  0  0  0
  5 10  1  0  0  0  0
  2 11  1  0  0  0  0
 12 11  1  6  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  1  6  0  0  0
 15 16  1  0  0  0  0
 14 17  1  0  0  0  0
 17 18  1  1  0  0  0
 18 19  1  0  0  0  0
 19 20  2  0  0  0  0
 19 21  1  0  0  0  0
 21 22  2  0  0  0  0
 22 23  1  0  0  0  0
 23 24  1  0  0  0  0
 23 25  2  0  0  0  0
 25 26  1  0  0  0  0
 25 27  1  0  0  0  0
 27 28  1  0  0  0  0
 27 29  2  0  0  0  0
 21 29  1  0  0  0  0
 17 30  1  0  0  0  0
 30 31  1  6  0  0  0
 30 32  1  0  0  0  0
 12 32  1  0  0  0  0
 32 33  1  1  0  0  0
M  END
> <DATABASE_ID>
NP0213352

> <DATABASE_NAME>
NP-MRD

> <SMILES>
OC[C@H]1O[C@@H](OC(=O)\C=C\C2=CC=CC=C2)[C@H](O)[C@@H](O)[C@@H]1OC(=O)C1=CC(O)=C(O)C(O)=C1

> <INCHI_IDENTIFIER>
InChI=1S/C22H22O11/c23-10-15-20(33-21(30)12-8-13(24)17(27)14(25)9-12)18(28)19(29)22(31-15)32-16(26)7-6-11-4-2-1-3-5-11/h1-9,15,18-20,22-25,27-29H,10H2/b7-6+/t15-,18-,19-,20-,22+/m1/s1

> <INCHI_KEY>
BBMUNSXHZJHBFQ-SXFDBIINSA-N

> <FORMULA>
C22H22O11

> <MOLECULAR_WEIGHT>
462.407

> <EXACT_MASS>
462.116211528

> <JCHEM_ACCEPTOR_COUNT>
9

> <JCHEM_ATOM_COUNT>
55

> <JCHEM_AVERAGE_POLARIZABILITY>
44.401327836351086

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
6

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
1

> <JCHEM_IUPAC>
(2R,3S,4R,5R,6S)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2E)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate

> <JCHEM_LOGP>
1.685955383666667

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
3

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
11.242031401076014

> <JCHEM_PKA_STRONGEST_ACIDIC>
8.103157723468778

> <JCHEM_PKA_STRONGEST_BASIC>
-2.981818169615125

> <JCHEM_POLAR_SURFACE_AREA>
183.20999999999998

> <JCHEM_REFRACTIVITY>
111.25579999999998

> <JCHEM_ROTATABLE_BOND_COUNT>
8

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(2R,3S,4R,5R,6S)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2E)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 05-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   05-SEP-22         0                                  
HETATM    1  O   UNK     0       5.335  -9.240   0.000  0.00  0.00           O+0
HETATM    2  C   UNK     0       4.001 -10.010   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       4.001 -11.550   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       5.335 -12.320   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       5.335 -13.860   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       6.668 -14.630   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       6.668 -16.170   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       5.335 -16.940   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       4.001 -16.170   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       4.001 -14.630   0.000  0.00  0.00           C+0
HETATM   11  O   UNK     0       2.667  -9.240   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0       2.667  -7.700   0.000  0.00  0.00           C+0
HETATM   13  O   UNK     0       1.334  -6.930   0.000  0.00  0.00           O+0
HETATM   14  C   UNK     0       1.334  -5.390   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       0.000  -4.620   0.000  0.00  0.00           C+0
HETATM   16  O   UNK     0      -1.334  -5.390   0.000  0.00  0.00           O+0
HETATM   17  C   UNK     0       2.667  -4.620   0.000  0.00  0.00           C+0
HETATM   18  O   UNK     0       2.667  -3.080   0.000  0.00  0.00           O+0
HETATM   19  C   UNK     0       1.334  -2.310   0.000  0.00  0.00           C+0
HETATM   20  O   UNK     0       0.000  -3.080   0.000  0.00  0.00           O+0
HETATM   21  C   UNK     0       1.334  -0.770   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       0.000   1.540   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0      -1.334   2.310   0.000  0.00  0.00           O+0
HETATM   25  C   UNK     0       1.334   2.310   0.000  0.00  0.00           C+0
HETATM   26  O   UNK     0       1.334   3.850   0.000  0.00  0.00           O+0
HETATM   27  C   UNK     0       2.667   1.540   0.000  0.00  0.00           C+0
HETATM   28  O   UNK     0       4.001   2.310   0.000  0.00  0.00           O+0
HETATM   29  C   UNK     0       2.667   0.000   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       4.001  -5.390   0.000  0.00  0.00           C+0
HETATM   31  O   UNK     0       5.335  -4.620   0.000  0.00  0.00           O+0
HETATM   32  C   UNK     0       4.001  -6.930   0.000  0.00  0.00           C+0
HETATM   33  O   UNK     0       5.335  -7.700   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3   11                                                  
CONECT    3    2    4                                                       
CONECT    4    3    5                                                       
CONECT    5    4    6   10                                                  
CONECT    6    5    7                                                       
CONECT    7    6    8                                                       
CONECT    8    7    9                                                       
CONECT    9    8   10                                                       
CONECT   10    9    5                                                       
CONECT   11    2   12                                                       
CONECT   12   11   13   32                                                  
CONECT   13   12   14                                                       
CONECT   14   13   15   17                                                  
CONECT   15   14   16                                                       
CONECT   16   15                                                            
CONECT   17   14   18   30                                                  
CONECT   18   17   19                                                       
CONECT   19   18   20   21                                                  
CONECT   20   19                                                            
CONECT   21   19   22   29                                                  
CONECT   22   21   23                                                       
CONECT   23   22   24   25                                                  
CONECT   24   23                                                            
CONECT   25   23   26   27                                                  
CONECT   26   25                                                            
CONECT   27   25   28   29                                                  
CONECT   28   27                                                            
CONECT   29   27   21                                                       
CONECT   30   17   31   32                                                  
CONECT   31   30                                                            
CONECT   32   30   12   33                                                  
CONECT   33   32                                                            
MASTER        0    0    0    0    0    0    0    0   33    0   70    0
END

View in JSmol

Synonyms

Value	Source
(2R,3S,4R,5R,6S)-4,5-Dihydroxy-2-(hydroxymethyl)-6-{[(2E)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoic acid	Generator

Chemical Formula

C₂₂H₂₂O₁₁

Average Mass

462.4070 Da

Monoisotopic Mass

462.11621 Da

IUPAC Name

(2R,3S,4R,5R,6S)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2E)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate

Traditional Name

(2R,3S,4R,5R,6S)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2E)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate

CAS Registry Number

Not Available

SMILES

OC[C@H]1O[C@@H](OC(=O)\C=C\C2=CC=CC=C2)[C@H](O)[C@@H](O)[C@@H]1OC(=O)C1=CC(O)=C(O)C(O)=C1

InChI Identifier

InChI=1S/C22H22O11/c23-10-15-20(33-21(30)12-8-13(24)17(27)14(25)9-12)18(28)19(29)22(31-15)32-16(26)7-6-11-4-2-1-3-5-11/h1-9,15,18-20,22-25,27-29H,10H2/b7-6+/t15-,18-,19-,20-,22+/m1/s1

InChI Key

BBMUNSXHZJHBFQ-SXFDBIINSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Balanophora fungosa	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as tannins. These are naturally occurring polyphenols which be categorized into four main classes: Hydrolyzable tannin (based on ellagic acid or gallic acid), condensed tannins (made of oligomeric or polymeric proanthocyanidins), complex tannins (made of a catechin bound to a gallotannin or elagitannin), and phlorotannins (oligomers of phloroglucinol).

Kingdom

Organic compounds

Super Class

Phenylpropanoids and polyketides

Class

Tannins

Sub Class

Not Available

Direct Parent

Tannins

Alternative Parents

Substituents

Tannin
O-cinnamoyl glycoside
Galloyl ester
Gallic acid or derivatives
Cinnamic acid or derivatives
Cinnamic acid ester
P-hydroxybenzoic acid alkyl ester
M-hydroxybenzoic acid ester
P-hydroxybenzoic acid ester
Benzoate ester
Pyrogallol derivative
Benzenetriol
Benzoic acid or derivatives
Styrene
Benzoyl
1-hydroxy-4-unsubstituted benzenoid
1-hydroxy-2-unsubstituted benzenoid
Fatty acid ester
Phenol
Fatty acyl
Oxane
Monocyclic benzene moiety
Monosaccharide
Dicarboxylic acid or derivatives
Benzenoid
Enoate ester
Alpha,beta-unsaturated carboxylic ester
Carboxylic acid ester
Secondary alcohol
Acetal
Carboxylic acid derivative
Organoheterocyclic compound
Oxacycle
Polyol
Primary alcohol
Alcohol
Carbonyl group
Hydrocarbon derivative
Organic oxide
Organic oxygen compound
Organooxygen compound
Aromatic heteromonocyclic compound

Molecular Framework

Aromatic heteromonocyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	1.69	ChemAxon
pKa (Strongest Acidic)	8.1	ChemAxon
pKa (Strongest Basic)	-3	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	9	ChemAxon
Hydrogen Donor Count	6	ChemAxon
Polar Surface Area	183.21 Å²	ChemAxon
Rotatable Bond Count	8	ChemAxon
Refractivity	111.26 m³·mol⁻¹	ChemAxon
Polarizability	44.4 Å³	ChemAxon
Number of Rings	3	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	Yes	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

44604129

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (2r,3s,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2e)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate (NP0213352)

MOL for NP0213352 ((2r,3s,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2e)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate)

3D MOL for NP0213352 ((2r,3s,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2e)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate)

3D SDF for NP0213352 ((2r,3s,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2e)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate)

3D-SDF for NP0213352 ((2r,3s,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2e)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate)

PDB for NP0213352 ((2r,3s,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2e)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate)

3D PDB for NP0213352 ((2r,3s,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2e)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate)

SMILES for NP0213352 ((2r,3s,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2e)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate)

INCHI for NP0213352 ((2r,3s,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2e)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate)

Structure for NP0213352 ((2r,3s,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2e)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate)

3D Structure for NP0213352 ((2r,3s,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-{[(2e)-3-phenylprop-2-enoyl]oxy}oxan-3-yl 3,4,5-trihydroxybenzoate)