NP-MRD: Showing NP-Card for (15r)-3,4,5-trihydroxy-15-(4-hydroxyphenyl)-12-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,16-dioxatetracyclo[8.7.0.0²,⁷.0¹³,¹⁷]heptadeca-1(10),2(7),3,5,11,13(17)-hexaen-8-one (NP0210741)

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Record Information

Version

2.0

Created at

2022-09-05 08:41:30 UTC

Updated at

2022-09-05 08:41:30 UTC

NP-MRD ID

NP0210741

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(15r)-3,4,5-trihydroxy-15-(4-hydroxyphenyl)-12-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,16-dioxatetracyclo[8.7.0.0²,⁷.0¹³,¹⁷]heptadeca-1(10),2(7),3,5,11,13(17)-hexaen-8-one

Description

Polygonumoside B belongs to the class of organic compounds known as 2-arylbenzofuran flavonoids. These are phenylpropanoids containing the 2-phenylbenzofuran moiety. (15r)-3,4,5-trihydroxy-15-(4-hydroxyphenyl)-12-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,16-dioxatetracyclo[8.7.0.0²,⁷.0¹³,¹⁷]heptadeca-1(10),2(7),3,5,11,13(17)-hexaen-8-one is found in Fallopia multiflora. Based on a literature review very few articles have been published on Polygonumoside B.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309052210412D          

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M  END

     RDKit          3D

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M  END


  Mrv1652309052210412D          

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 10 11  1  1  0  0  0
 11 12  1  0  0  0  0
 10 13  1  0  0  0  0
 13 14  1  6  0  0  0
 13 15  1  0  0  0  0
 15 16  1  1  0  0  0
 15 17  1  0  0  0  0
  8 17  1  0  0  0  0
 17 18  1  6  0  0  0
  6 19  2  0  0  0  0
 19 20  1  0  0  0  0
 20 21  2  0  0  0  0
  4 21  1  0  0  0  0
 21 22  1  0  0  0  0
 22 23  2  0  0  0  0
 23 24  1  0  0  0  0
 23 25  1  0  0  0  0
 25 26  1  0  0  0  0
 25 27  2  0  0  0  0
 27 28  1  0  0  0  0
 27 29  1  0  0  0  0
 29 30  2  0  0  0  0
  2 30  1  0  0  0  0
 22 30  1  0  0  0  0
 20 31  1  0  0  0  0
 31 32  1  0  0  0  0
 32 33  1  6  0  0  0
 33 34  2  0  0  0  0
 34 35  1  0  0  0  0
 35 36  2  0  0  0  0
 36 37  1  0  0  0  0
 36 38  1  0  0  0  0
 38 39  2  0  0  0  0
 33 39  1  0  0  0  0
 32 40  1  0  0  0  0
 19 40  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0210741

> <DATABASE_NAME>
NP-MRD

> <SMILES>
OC[C@H]1O[C@@H](OC2=C3C[C@@H](OC3=C3C(OC(=O)C4=CC(O)=C(O)C(O)=C34)=C2)C2=CC=C(O)C=C2)[C@H](O)[C@@H](O)[C@@H]1O

> <INCHI_IDENTIFIER>
InChI=1S/C27H24O13/c28-8-17-21(32)23(34)24(35)27(40-17)39-15-7-16-19(18-12(26(36)38-16)5-13(30)20(31)22(18)33)25-11(15)6-14(37-25)9-1-3-10(29)4-2-9/h1-5,7,14,17,21,23-24,27-35H,6,8H2/t14-,17-,21-,23+,24-,27-/m1/s1

> <INCHI_KEY>
BNHQQRPAHBTLKE-BSGODVDVSA-N

> <FORMULA>
C27H24O13

> <MOLECULAR_WEIGHT>
556.476

> <EXACT_MASS>
556.121690833

> <JCHEM_ACCEPTOR_COUNT>
12

> <JCHEM_ATOM_COUNT>
64

> <JCHEM_AVERAGE_POLARIZABILITY>
54.00099451900583

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
8

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(15R)-3,4,5-trihydroxy-15-(4-hydroxyphenyl)-12-{[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,16-dioxatetracyclo[8.7.0.0^{2,7}.0^{13,17}]heptadeca-1(17),2,4,6,10,12-hexaen-8-one

> <JCHEM_LOGP>
0.805890167666667

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
6

> <JCHEM_PHYSIOLOGICAL_CHARGE>
-1

> <JCHEM_PKA>
8.378050851347078

> <JCHEM_PKA_STRONGEST_ACIDIC>
7.021263202452953

> <JCHEM_PKA_STRONGEST_BASIC>
-2.981092344936174

> <JCHEM_POLAR_SURFACE_AREA>
215.82999999999998

> <JCHEM_REFRACTIVITY>
133.04359999999997

> <JCHEM_ROTATABLE_BOND_COUNT>
4

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(15R)-3,4,5-trihydroxy-15-(4-hydroxyphenyl)-12-{[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,16-dioxatetracyclo[8.7.0.0^{2,7}.0^{13,17}]heptadeca-1(17),2,4,6,10,12-hexaen-8-one

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 05-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   05-SEP-22         0                                  
HETATM    1  O   UNK     0       0.177   4.677   0.000  0.00  0.00           O+0
HETATM    2  C   UNK     0       1.474   3.847   0.000  0.00  0.00           C+0
HETATM    3  O   UNK     0       2.841   4.555   0.000  0.00  0.00           O+0
HETATM    4  C   UNK     0       4.139   3.725   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       5.506   4.434   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       6.803   3.604   0.000  0.00  0.00           C+0
HETATM    7  O   UNK     0       8.171   4.312   0.000  0.00  0.00           O+0
HETATM    8  C   UNK     0       9.468   3.482   0.000  0.00  0.00           C+0
HETATM    9  O   UNK     0       9.398   1.944   0.000  0.00  0.00           O+0
HETATM   10  C   UNK     0      10.695   1.114   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0      10.625  -0.425   0.000  0.00  0.00           C+0
HETATM   12  O   UNK     0      11.922  -1.255   0.000  0.00  0.00           O+0
HETATM   13  C   UNK     0      12.062   1.822   0.000  0.00  0.00           C+0
HETATM   14  O   UNK     0      13.359   0.992   0.000  0.00  0.00           O+0
HETATM   15  C   UNK     0      12.132   3.360   0.000  0.00  0.00           C+0
HETATM   16  O   UNK     0      13.500   4.069   0.000  0.00  0.00           O+0
HETATM   17  C   UNK     0      10.835   4.190   0.000  0.00  0.00           C+0
HETATM   18  O   UNK     0      10.905   5.729   0.000  0.00  0.00           O+0
HETATM   19  C   UNK     0       6.733   2.065   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       5.366   1.357   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       4.068   2.187   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       2.701   1.478   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       2.631  -0.060   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0       3.928  -0.890   0.000  0.00  0.00           O+0
HETATM   25  C   UNK     0       1.263  -0.768   0.000  0.00  0.00           C+0
HETATM   26  O   UNK     0       1.193  -2.307   0.000  0.00  0.00           O+0
HETATM   27  C   UNK     0      -0.034   0.062   0.000  0.00  0.00           C+0
HETATM   28  O   UNK     0      -1.401  -0.647   0.000  0.00  0.00           O+0
HETATM   29  C   UNK     0       0.036   1.600   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       1.404   2.308   0.000  0.00  0.00           C+0
HETATM   31  O   UNK     0       5.617  -0.163   0.000  0.00  0.00           O+0
HETATM   32  C   UNK     0       7.139  -0.393   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0       7.848  -1.761   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0       9.386  -1.831   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0      10.095  -3.198   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0       9.265  -4.495   0.000  0.00  0.00           C+0
HETATM   37  O   UNK     0       9.973  -5.863   0.000  0.00  0.00           O+0
HETATM   38  C   UNK     0       7.726  -4.425   0.000  0.00  0.00           C+0
HETATM   39  C   UNK     0       7.018  -3.058   0.000  0.00  0.00           C+0
HETATM   40  C   UNK     0       7.829   0.984   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3   30                                                  
CONECT    3    2    4                                                       
CONECT    4    3    5   21                                                  
CONECT    5    4    6                                                       
CONECT    6    5    7   19                                                  
CONECT    7    6    8                                                       
CONECT    8    7    9   17                                                  
CONECT    9    8   10                                                       
CONECT   10    9   11   13                                                  
CONECT   11   10   12                                                       
CONECT   12   11                                                            
CONECT   13   10   14   15                                                  
CONECT   14   13                                                            
CONECT   15   13   16   17                                                  
CONECT   16   15                                                            
CONECT   17   15    8   18                                                  
CONECT   18   17                                                            
CONECT   19    6   20   40                                                  
CONECT   20   19   21   31                                                  
CONECT   21   20    4   22                                                  
CONECT   22   21   23   30                                                  
CONECT   23   22   24   25                                                  
CONECT   24   23                                                            
CONECT   25   23   26   27                                                  
CONECT   26   25                                                            
CONECT   27   25   28   29                                                  
CONECT   28   27                                                            
CONECT   29   27   30                                                       
CONECT   30   29    2   22                                                  
CONECT   31   20   32                                                       
CONECT   32   31   33   40                                                  
CONECT   33   32   34   39                                                  
CONECT   34   33   35                                                       
CONECT   35   34   36                                                       
CONECT   36   35   37   38                                                  
CONECT   37   36                                                            
CONECT   38   36   39                                                       
CONECT   39   38   33                                                       
CONECT   40   32   19                                                       
MASTER        0    0    0    0    0    0    0    0   40    0   90    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₇H₂₄O₁₃

Average Mass

556.4760 Da

Monoisotopic Mass

556.12169 Da

IUPAC Name

(15R)-3,4,5-trihydroxy-15-(4-hydroxyphenyl)-12-{[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,16-dioxatetracyclo[8.7.0.0^{2,7}.0^{13,17}]heptadeca-1(17),2,4,6,10,12-hexaen-8-one

Traditional Name

CAS Registry Number

Not Available

SMILES

OC[C@H]1O[C@@H](OC2=C3C[C@@H](OC3=C3C(OC(=O)C4=CC(O)=C(O)C(O)=C34)=C2)C2=CC=C(O)C=C2)[C@H](O)[C@@H](O)[C@@H]1O

InChI Identifier

InChI=1S/C27H24O13/c28-8-17-21(32)23(34)24(35)27(40-17)39-15-7-16-19(18-12(26(36)38-16)5-13(30)20(31)22(18)33)25-11(15)6-14(37-25)9-1-3-10(29)4-2-9/h1-5,7,14,17,21,23-24,27-35H,6,8H2/t14-,17-,21-,23+,24-,27-/m1/s1

InChI Key

BNHQQRPAHBTLKE-BSGODVDVSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Fallopia multiflora	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as 2-arylbenzofuran flavonoids. These are phenylpropanoids containing the 2-phenylbenzofuran moiety.

Kingdom

Organic compounds

Super Class

Phenylpropanoids and polyketides

Class

2-arylbenzofuran flavonoids

Sub Class

Not Available

Direct Parent

2-arylbenzofuran flavonoids

Alternative Parents

Substituents

2-arylbenzofuran flavonoid
Phenolic glycoside
Angular furanocoumarin
Furanocoumarin
Hexose monosaccharide
Isocoumarin
O-glycosyl compound
Glycosyl compound
Coumarin
Benzopyran
2-benzopyran
1-benzopyran
Coumaran
1-hydroxy-4-unsubstituted benzenoid
1-hydroxy-2-unsubstituted benzenoid
Alkyl aryl ether
Phenol
Pyranone
Monocyclic benzene moiety
Oxane
Monosaccharide
Pyran
Benzenoid
Heteroaromatic compound
Lactone
Secondary alcohol
Acetal
Oxacycle
Organoheterocyclic compound
Ether
Polyol
Alcohol
Hydrocarbon derivative
Organic oxygen compound
Organic oxide
Primary alcohol
Organooxygen compound
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	0.81	ChemAxon
pKa (Strongest Acidic)	7.02	ChemAxon
pKa (Strongest Basic)	-3	ChemAxon
Physiological Charge	-1	ChemAxon
Hydrogen Acceptor Count	12	ChemAxon
Hydrogen Donor Count	8	ChemAxon
Polar Surface Area	215.83 Å²	ChemAxon
Rotatable Bond Count	4	ChemAxon
Refractivity	133.04 m³·mol⁻¹	ChemAxon
Polarizability	54 Å³	ChemAxon
Number of Rings	6	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

31130431

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

76328405

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (15r)-3,4,5-trihydroxy-15-(4-hydroxyphenyl)-12-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,16-dioxatetracyclo[8.7.0.0²,⁷.0¹³,¹⁷]heptadeca-1(10),2(7),3,5,11,13(17)-hexaen-8-one (NP0210741)

MOL for NP0210741 ((15r)-3,4,5-trihydroxy-15-(4-hydroxyphenyl)-12-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,16-dioxatetracyclo[8.7.0.0²,⁷.0¹³,¹⁷]heptadeca-1(10),2(7),3,5,11,13(17)-hexaen-8-one)

3D MOL for NP0210741 ((15r)-3,4,5-trihydroxy-15-(4-hydroxyphenyl)-12-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,16-dioxatetracyclo[8.7.0.0²,⁷.0¹³,¹⁷]heptadeca-1(10),2(7),3,5,11,13(17)-hexaen-8-one)

3D SDF for NP0210741 ((15r)-3,4,5-trihydroxy-15-(4-hydroxyphenyl)-12-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,16-dioxatetracyclo[8.7.0.0²,⁷.0¹³,¹⁷]heptadeca-1(10),2(7),3,5,11,13(17)-hexaen-8-one)

3D-SDF for NP0210741 ((15r)-3,4,5-trihydroxy-15-(4-hydroxyphenyl)-12-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,16-dioxatetracyclo[8.7.0.0²,⁷.0¹³,¹⁷]heptadeca-1(10),2(7),3,5,11,13(17)-hexaen-8-one)

PDB for NP0210741 ((15r)-3,4,5-trihydroxy-15-(4-hydroxyphenyl)-12-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,16-dioxatetracyclo[8.7.0.0²,⁷.0¹³,¹⁷]heptadeca-1(10),2(7),3,5,11,13(17)-hexaen-8-one)

3D PDB for NP0210741 ((15r)-3,4,5-trihydroxy-15-(4-hydroxyphenyl)-12-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,16-dioxatetracyclo[8.7.0.0²,⁷.0¹³,¹⁷]heptadeca-1(10),2(7),3,5,11,13(17)-hexaen-8-one)

SMILES for NP0210741 ((15r)-3,4,5-trihydroxy-15-(4-hydroxyphenyl)-12-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,16-dioxatetracyclo[8.7.0.0²,⁷.0¹³,¹⁷]heptadeca-1(10),2(7),3,5,11,13(17)-hexaen-8-one)

INCHI for NP0210741 ((15r)-3,4,5-trihydroxy-15-(4-hydroxyphenyl)-12-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,16-dioxatetracyclo[8.7.0.0²,⁷.0¹³,¹⁷]heptadeca-1(10),2(7),3,5,11,13(17)-hexaen-8-one)

Structure for NP0210741 ((15r)-3,4,5-trihydroxy-15-(4-hydroxyphenyl)-12-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,16-dioxatetracyclo[8.7.0.0²,⁷.0¹³,¹⁷]heptadeca-1(10),2(7),3,5,11,13(17)-hexaen-8-one)

3D Structure for NP0210741 ((15r)-3,4,5-trihydroxy-15-(4-hydroxyphenyl)-12-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-9,16-dioxatetracyclo[8.7.0.0²,⁷.0¹³,¹⁷]heptadeca-1(10),2(7),3,5,11,13(17)-hexaen-8-one)