NP-MRD: Showing NP-Card for 2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2e)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-1h-indol-6-one (NP0209712)

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Record Information

Version

2.0

Created at

2022-09-05 07:13:42 UTC

Updated at

2022-09-05 07:13:42 UTC

NP-MRD ID

NP0209712

Secondary Accession Numbers

None

Natural Product Identification

Common Name

2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2e)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-1h-indol-6-one

Description

Cartormin belongs to the class of organic compounds known as hydroxycinnamic acids and derivatives. Hydroxycinnamic acids and derivatives are compounds containing an cinnamic acid (or a derivative thereof) where the benzene ring is hydroxylated. Cartormin is an extremely weak basic (essentially neutral) compound (based on its pKa). Outside of the human body, Cartormin has been detected, but not quantified in, fats and oils and herbs and spices. 2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2e)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-1h-indol-6-one is found in Carthamus tinctorius. This could make cartormin a potential biomarker for the consumption of these foods.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv0541 05061308182D          

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M  END

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  Mrv0541 05061308182D          

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    0.8142    4.0936    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.5888    2.6368    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434    1.2375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.1018    1.9659    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.5795    1.0799    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4973    1.9947    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  4  1  1  0  0  0  0
  5  2  2  0  0  0  0
  6  3  2  0  0  0  0
 10  1  2  0  0  0  0
 10  2  1  0  0  0  0
 10  3  1  0  0  0  0
 11  4  2  0  0  0  0
 11  5  1  0  0  0  0
 12  7  1  0  0  0  0
 13  7  2  0  0  0  0
 14  6  1  0  0  0  0
 15  9  1  0  0  0  0
 16  8  1  0  0  0  0
 17 14  1  0  0  0  0
 18 12  1  0  0  0  0
 18 17  2  0  0  0  0
 19 15  1  0  0  0  0
 20 16  1  0  0  0  0
 21 20  1  0  0  0  0
 22 21  1  0  0  0  0
 23 13  1  0  0  0  0
 23 19  1  0  0  0  0
 24 12  2  0  0  0  0
 25 17  1  0  0  0  0
 26 22  1  0  0  0  0
 27 24  1  0  0  0  0
 27 25  1  0  0  0  0
 27 26  1  0  0  0  0
 28 13  1  0  0  0  0
 28 24  1  0  0  0  0
 29  8  1  0  0  0  0
 30 11  1  0  0  0  0
 31 14  2  0  0  0  0
 32 15  1  0  0  0  0
 33 18  1  0  0  0  0
 34 19  1  0  0  0  0
 35 20  1  0  0  0  0
 36 21  1  0  0  0  0
 37 22  1  0  0  0  0
 38 25  2  0  0  0  0
 39 27  1  0  0  0  0
 40  9  1  0  0  0  0
 40 23  1  0  0  0  0
 41 16  1  0  0  0  0
 41 26  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0209712

> <DATABASE_NAME>
NP-MRD

> <SMILES>
OCC1OC(C(O)C(O)C1O)C1(O)C2=C(C=C(N2)C2OCC(O)C2O)C(O)=C(C(=O)\C=C\C2=CC=C(O)C=C2)C1=O

> <INCHI_IDENTIFIER>
InChI=1S/C27H29NO13/c29-8-16-20(35)21(36)22(37)26(41-16)27(39)24-12(7-13(28-24)23-19(34)15(32)9-40-23)18(33)17(25(27)38)14(31)6-3-10-1-4-11(30)5-2-10/h1-7,15-16,19-23,26,28-30,32-37,39H,8-9H2/b6-3+

> <INCHI_KEY>
DDYOBOBXPBUGTA-ZZXKWVIFSA-N

> <FORMULA>
C27H29NO13

> <MOLECULAR_WEIGHT>
575.5181

> <EXACT_MASS>
575.163890019

> <JCHEM_ACCEPTOR_COUNT>
13

> <JCHEM_AVERAGE_POLARIZABILITY>
56.740840234969745

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
10

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2E)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-6,7-dihydro-1H-indol-6-one

> <ALOGPS_LOGP>
-0.55

> <JCHEM_LOGP>
-2.3500441890000006

> <ALOGPS_LOGS>
-2.35

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
-1

> <JCHEM_PKA>
8.67107786739996

> <JCHEM_PKA_STRONGEST_ACIDIC>
6.0380046341226885

> <JCHEM_PKA_STRONGEST_BASIC>
-3.527051392619212

> <JCHEM_POLAR_SURFACE_AREA>
250.45999999999992

> <JCHEM_REFRACTIVITY>
138.7944

> <JCHEM_ROTATABLE_BOND_COUNT>
6

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
2.58e+00 g/l

> <JCHEM_TRADITIONAL_IUPAC>
2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2E)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-1H-indol-6-one

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 06-MAY-13   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   06-MAY-13         0                                  
HETATM    1  C   UNK     0       1.334  -5.390   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       4.001  -5.390   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       2.667  -3.080   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       1.334  -6.930   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       4.001  -6.930   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       4.001  -2.310   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0      -1.465  -0.476   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      -3.191   5.137   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0      -6.280   1.540   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       2.667  -4.620   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       2.667  -7.700   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      -2.370   0.770   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       4.001  -0.770   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      -6.280   0.000   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0      -1.651   5.083   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       2.667   0.000   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       1.334  -0.770   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0      -4.815  -0.476   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0      -0.835   6.389   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       0.704   6.335   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       1.427   4.976   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0      -3.910   0.770   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       0.000   1.540   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0       2.667   1.540   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0       0.611   3.670   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       1.334   2.310   0.000  0.00  0.00           C+0
HETATM   28  N   UNK     0      -1.465   2.016   0.000  0.00  0.00           N+0
HETATM   29  O   UNK     0      -4.006   3.831   0.000  0.00  0.00           O+0
HETATM   30  O   UNK     0       2.667  -9.240   0.000  0.00  0.00           O+0
HETATM   31  O   UNK     0       5.335   0.000   0.000  0.00  0.00           O+0
HETATM   32  O   UNK     0      -7.525  -0.905   0.000  0.00  0.00           O+0
HETATM   33  O   UNK     0       1.334  -2.310   0.000  0.00  0.00           O+0
HETATM   34  O   UNK     0      -4.339  -1.941   0.000  0.00  0.00           O+0
HETATM   35  O   UNK     0      -1.558   7.749   0.000  0.00  0.00           O+0
HETATM   36  O   UNK     0       1.520   7.641   0.000  0.00  0.00           O+0
HETATM   37  O   UNK     0       2.966   4.922   0.000  0.00  0.00           O+0
HETATM   38  O   UNK     0       4.001   2.310   0.000  0.00  0.00           O+0
HETATM   39  O   UNK     0       2.057   3.670   0.000  0.00  0.00           O+0
HETATM   40  O   UNK     0      -4.815   2.016   0.000  0.00  0.00           O+0
HETATM   41  O   UNK     0      -0.928   3.723   0.000  0.00  0.00           O+0
CONECT    1    4   10                                                       
CONECT    2    5   10                                                       
CONECT    3    6   10                                                       
CONECT    4    1   11                                                       
CONECT    5    2   11                                                       
CONECT    6    3   14                                                       
CONECT    7   12   13                                                       
CONECT    8   16   29                                                       
CONECT    9   15   40                                                       
CONECT   10    1    2    3                                                  
CONECT   11    4    5   30                                                  
CONECT   12    7   18   24                                                  
CONECT   13    7   23   28                                                  
CONECT   14    6   17   31                                                  
CONECT   15    9   19   32                                                  
CONECT   16    8   20   41                                                  
CONECT   17   14   18   25                                                  
CONECT   18   12   17   33                                                  
CONECT   19   15   23   34                                                  
CONECT   20   16   21   35                                                  
CONECT   21   20   22   36                                                  
CONECT   22   21   26   37                                                  
CONECT   23   13   19   40                                                  
CONECT   24   12   27   28                                                  
CONECT   25   17   27   38                                                  
CONECT   26   22   27   41                                                  
CONECT   27   24   25   26   39                                             
CONECT   28   13   24                                                       
CONECT   29    8                                                            
CONECT   30   11                                                            
CONECT   31   14                                                            
CONECT   32   15                                                            
CONECT   33   18                                                            
CONECT   34   19                                                            
CONECT   35   20                                                            
CONECT   36   21                                                            
CONECT   37   22                                                            
CONECT   38   25                                                            
CONECT   39   27                                                            
CONECT   40    9   23                                                       
CONECT   41   16   26                                                       
MASTER        0    0    0    0    0    0    0    0   41    0   90    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₇H₂₉NO₁₃

Average Mass

575.5181 Da

Monoisotopic Mass

575.16389 Da

IUPAC Name

2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2E)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-6,7-dihydro-1H-indol-6-one

Traditional Name

2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2E)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-1H-indol-6-one

CAS Registry Number

Not Available

SMILES

OCC1OC(C(O)C(O)C1O)C1(O)C2=C(C=C(N2)C2OCC(O)C2O)C(O)=C(C(=O)\C=C\C2=CC=C(O)C=C2)C1=O

InChI Identifier

InChI=1S/C27H29NO13/c29-8-16-20(35)21(36)22(37)26(41-16)27(39)24-12(7-13(28-24)23-19(34)15(32)9-40-23)18(33)17(25(27)38)14(31)6-3-10-1-4-11(30)5-2-10/h1-7,15-16,19-23,26,28-30,32-37,39H,8-9H2/b6-3+

InChI Key

DDYOBOBXPBUGTA-ZZXKWVIFSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Carthamus tinctorius	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as hydroxycinnamic acids and derivatives. Hydroxycinnamic acids and derivatives are compounds containing an cinnamic acid (or a derivative thereof) where the benzene ring is hydroxylated.

Kingdom

Organic compounds

Super Class

Phenylpropanoids and polyketides

Class

Cinnamic acids and derivatives

Sub Class

Hydroxycinnamic acids and derivatives

Direct Parent

Hydroxycinnamic acids and derivatives

Alternative Parents

Substituents

Hydroxycinnamic acid or derivatives
C-glycosyl compound
Glycosyl compound
Indole or derivatives
Styrene
1-hydroxy-2-unsubstituted benzenoid
Phenol
Oxane
Acyloin
Monocyclic benzene moiety
Monosaccharide
Substituted pyrrole
Benzenoid
Acryloyl-group
Enone
Heteroaromatic compound
Tetrahydrofuran
Tertiary alcohol
Alpha,beta-unsaturated ketone
Vinylogous acid
Pyrrole
Ketone
Secondary alcohol
Cyclic ketone
Dialkyl ether
Enol
Ether
Oxacycle
Azacycle
Organoheterocyclic compound
Polyol
Alcohol
Hydrocarbon derivative
Organic oxygen compound
Organic nitrogen compound
Organopnictogen compound
Organic oxide
Primary alcohol
Carbonyl group
Organonitrogen compound
Organooxygen compound
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	-0.55	ALOGPS
logP	-2.4	ChemAxon
logS	-2.4	ALOGPS
pKa (Strongest Acidic)	6.04	ChemAxon
pKa (Strongest Basic)	-3.5	ChemAxon
Physiological Charge	-1	ChemAxon
Hydrogen Acceptor Count	13	ChemAxon
Hydrogen Donor Count	10	ChemAxon
Polar Surface Area	250.46 Å²	ChemAxon
Rotatable Bond Count	6	ChemAxon
Refractivity	138.79 m³·mol⁻¹	ChemAxon
Polarizability	56.74 Å³	ChemAxon
Number of Rings	5	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

HMDB0035209

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

FDB013856

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

131751684

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for 2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2e)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-1h-indol-6-one (NP0209712)

MOL for NP0209712 (2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2e)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-1h-indol-6-one)

3D MOL for NP0209712 (2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2e)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-1h-indol-6-one)

3D SDF for NP0209712 (2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2e)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-1h-indol-6-one)

3D-SDF for NP0209712 (2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2e)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-1h-indol-6-one)

PDB for NP0209712 (2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2e)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-1h-indol-6-one)

3D PDB for NP0209712 (2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2e)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-1h-indol-6-one)

SMILES for NP0209712 (2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2e)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-1h-indol-6-one)

INCHI for NP0209712 (2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2e)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-1h-indol-6-one)

Structure for NP0209712 (2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2e)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-1h-indol-6-one)

3D Structure for NP0209712 (2-(3,4-dihydroxyoxolan-2-yl)-4,7-dihydroxy-5-[(2e)-3-(4-hydroxyphenyl)prop-2-enoyl]-7-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]-1h-indol-6-one)