NP-MRD: Showing NP-Card for (1s,3s,7s,10r,12r,13r,15r,16r,17r,18r,21e,23e,26r,29s)-26-hydroxy-10,17-dimethyl-2,5,11,14,19,28,32-heptaoxaspiro[octacyclo[23.4.3.1¹⁵,¹⁸.0¹,³.0⁷,¹³.0⁷,¹⁷.0¹⁰,¹².0²⁵,²⁹]tritriacontane-16,2'-oxirane]-21,23-diene-4,20,27-trione (NP0207473)

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Record Information

Version

2.0

Created at

2022-09-05 04:06:05 UTC

Updated at

2022-09-05 04:06:06 UTC

NP-MRD ID

NP0207473

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1s,3s,7s,10r,12r,13r,15r,16r,17r,18r,21e,23e,26r,29s)-26-hydroxy-10,17-dimethyl-2,5,11,14,19,28,32-heptaoxaspiro[octacyclo[23.4.3.1¹⁵,¹⁸.0¹,³.0⁷,¹³.0⁷,¹⁷.0¹⁰,¹².0²⁵,²⁹]tritriacontane-16,2'-oxirane]-21,23-diene-4,20,27-trione

Description

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309052206062D          

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M  END

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M  END


  Mrv1652309052206062D          

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    5.5224    2.7934    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.6075    2.8399    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.2297    2.1065    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.8104    1.5205    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.6777    0.7063    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.5472    1.8918    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    4.2805    1.5140    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  2  1  1  1  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  5  4  1  1  0  0  0
  5  6  1  0  0  0  0
  6  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  2  0  0  0  0
  8 10  1  0  0  0  0
 10 11  1  1  0  0  0
 12 11  1  1  0  0  0
 10 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  1  0  0  0  0
 15 16  1  0  0  0  0
 16 17  1  0  0  0  0
 17 18  2  0  0  0  0
 18 19  1  0  0  0  0
 19 20  2  0  0  0  0
 20 21  1  0  0  0  0
 21 22  2  0  0  0  0
 21 23  1  0  0  0  0
 23 24  1  0  0  0  0
 24 25  1  6  0  0  0
 26 25  1  1  0  0  0
 26 27  1  0  0  0  0
 28 27  1  1  0  0  0
  5 28  1  0  0  0  0
 28 29  1  0  0  0  0
  2 29  1  0  0  0  0
 29 30  1  1  0  0  0
  2 30  1  0  0  0  0
 26 31  1  0  0  0  0
 31 32  1  0  0  0  0
 32 33  1  0  0  0  0
 31 33  1  1  0  0  0
 31 34  1  0  0  0  0
 24 34  1  0  0  0  0
  5 34  1  0  0  0  0
 34 35  1  1  0  0  0
 16 36  1  0  0  0  0
 12 36  1  0  0  0  0
 36 37  1  6  0  0  0
 37 38  1  0  0  0  0
 38 39  2  0  0  0  0
 38 40  1  0  0  0  0
 16 40  1  0  0  0  0
 40 41  1  1  0  0  0
M  END
> <DATABASE_ID>
NP0207473

> <DATABASE_NAME>
NP-MRD

> <SMILES>
C[C@@]12CC[C@]34COC(=O)[C@H]5O[C@]55CCOC6(\C=C\C=C/C(=O)O[C@@H]7C[C@@H](O[C@H]3[C@H]1O2)[C@]1(CO1)[C@]47C)[C@@H](O)C(=O)O[C@@H]56

> <INCHI_IDENTIFIER>
InChI=1S/C29H32O12/c1-24-7-8-26-12-34-22(33)20-28(41-20)9-10-35-27(17(31)21(32)39-23(27)28)6-4-3-5-16(30)37-14-11-15(38-19(26)18(24)40-24)29(13-36-29)25(14,26)2/h3-6,14-15,17-20,23,31H,7-13H2,1-2H3/b5-3-,6-4+/t14?,15-,17+,18-,19+,20-,23-,24-,25+,26+,27?,28-,29-/m1/s1

> <INCHI_KEY>
LANVEQVSXWXQLN-UBOVWWEASA-N

> <FORMULA>
C29H32O12

> <MOLECULAR_WEIGHT>
572.563

> <EXACT_MASS>
572.18937647

> <JCHEM_ACCEPTOR_COUNT>
9

> <JCHEM_ATOM_COUNT>
73

> <JCHEM_AVERAGE_POLARIZABILITY>
43.94289458715822

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
1

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(1S,3S,7S,10R,12R,13R,15R,16R,17R,18R,21E,23E,26R,29S)-26-hydroxy-10,17-dimethyl-2,5,11,14,19,28,32-heptaoxaspiro[octacyclo[23.4.3.1^{15,18}.0^{1,3}.0^{7,13}.0^{7,17}.0^{10,12}.0^{25,29}]tritriacontane-16,2'-oxirane]-21,23-diene-4,20,27-trione

> <JCHEM_LOGP>
0.17251758166666709

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
9

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA_STRONGEST_ACIDIC>
11.439886721596045

> <JCHEM_PKA_STRONGEST_BASIC>
-3.547103264709747

> <JCHEM_POLAR_SURFACE_AREA>
155.18

> <JCHEM_REFRACTIVITY>
132.64399999999998

> <JCHEM_ROTATABLE_BOND_COUNT>
0

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(1S,3S,7S,10R,12R,13R,15R,16R,17R,18R,21E,23E,26R,29S)-26-hydroxy-10,17-dimethyl-2,5,11,14,19,28,32-heptaoxaspiro[octacyclo[23.4.3.1^{15,18}.0^{1,3}.0^{7,13}.0^{7,17}.0^{10,12}.0^{25,29}]tritriacontane-16,2'-oxirane]-21,23-diene-4,20,27-trione

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 05-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   05-SEP-22         0                                  
HETATM    1  C   UNK     0      16.489   2.032   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      15.712   3.362   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      14.385   2.574   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      13.051   3.378   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      12.833   4.983   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      11.414   4.221   0.000  0.00  0.00           C+0
HETATM    7  O   UNK     0      10.408   3.040   0.000  0.00  0.00           O+0
HETATM    8  C   UNK     0       8.957   2.549   0.000  0.00  0.00           C+0
HETATM    9  O   UNK     0       8.910   1.010   0.000  0.00  0.00           O+0
HETATM   10  C   UNK     0       7.539   3.128   0.000  0.00  0.00           C+0
HETATM   11  O   UNK     0       7.801   4.620   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0       6.296   4.143   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       4.710   4.081   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       4.673   2.539   0.000  0.00  0.00           C+0
HETATM   15  O   UNK     0       6.181   3.034   0.000  0.00  0.00           O+0
HETATM   16  C   UNK     0       6.387   5.053   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       5.898   6.592   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       4.899   7.802   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       5.669   9.149   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       7.048   9.874   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       8.605   9.954   0.000  0.00  0.00           C+0
HETATM   22  O   UNK     0       9.043  11.431   0.000  0.00  0.00           O+0
HETATM   23  O   UNK     0       9.872   9.035   0.000  0.00  0.00           O+0
HETATM   24  C   UNK     0      10.734   7.683   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0      11.873   8.851   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0      13.292   8.155   0.000  0.00  0.00           C+0
HETATM   27  O   UNK     0      14.556   7.203   0.000  0.00  0.00           O+0
HETATM   28  C   UNK     0      14.341   5.637   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0      15.713   4.902   0.000  0.00  0.00           C+0
HETATM   30  O   UNK     0      17.046   4.130   0.000  0.00  0.00           O+0
HETATM   31  C   UNK     0      12.418   7.053   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0      13.293   5.786   0.000  0.00  0.00           C+0
HETATM   33  O   UNK     0      11.758   5.662   0.000  0.00  0.00           O+0
HETATM   34  C   UNK     0      11.526   6.157   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0      10.308   5.214   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0       4.867   5.301   0.000  0.00  0.00           C+0
HETATM   37  O   UNK     0       4.162   3.932   0.000  0.00  0.00           O+0
HETATM   38  C   UNK     0       5.246   2.838   0.000  0.00  0.00           C+0
HETATM   39  O   UNK     0       4.998   1.318   0.000  0.00  0.00           O+0
HETATM   40  C   UNK     0       6.621   3.531   0.000  0.00  0.00           C+0
HETATM   41  O   UNK     0       7.990   2.826   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3   29   30                                             
CONECT    3    2    4                                                       
CONECT    4    3    5                                                       
CONECT    5    4    6   28   34                                             
CONECT    6    5    7                                                       
CONECT    7    6    8                                                       
CONECT    8    7    9   10                                                  
CONECT    9    8                                                            
CONECT   10    8   11   12                                                  
CONECT   11   10   12                                                       
CONECT   12   11   10   13   36                                             
CONECT   13   12   14                                                       
CONECT   14   13   15                                                       
CONECT   15   14   16                                                       
CONECT   16   15   17   36   40                                             
CONECT   17   16   18                                                       
CONECT   18   17   19                                                       
CONECT   19   18   20                                                       
CONECT   20   19   21                                                       
CONECT   21   20   22   23                                                  
CONECT   22   21                                                            
CONECT   23   21   24                                                       
CONECT   24   23   25   34                                                  
CONECT   25   24   26                                                       
CONECT   26   25   27   31                                                  
CONECT   27   26   28                                                       
CONECT   28   27    5   29                                                  
CONECT   29   28    2   30                                                  
CONECT   30   29    2                                                       
CONECT   31   26   32   33   34                                             
CONECT   32   31   33                                                       
CONECT   33   32   31                                                       
CONECT   34   31   24    5   35                                             
CONECT   35   34                                                            
CONECT   36   16   12   37                                                  
CONECT   37   36   38                                                       
CONECT   38   37   39   40                                                  
CONECT   39   38                                                            
CONECT   40   38   16   41                                                  
CONECT   41   40                                                            
MASTER        0    0    0    0    0    0    0    0   41    0   98    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₉H₃₂O₁₂

Average Mass

572.5630 Da

Monoisotopic Mass

572.18938 Da

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

C[C@@]12CC[C@]34COC(=O)[C@H]5O[C@]55CCOC6(\C=C\C=C/C(=O)O[C@@H]7C[C@@H](O[C@H]3[C@H]1O2)[C@]1(CO1)[C@]47C)[C@@H](O)C(=O)O[C@@H]56

InChI Identifier

InChI=1S/C29H32O12/c1-24-7-8-26-12-34-22(33)20-28(41-20)9-10-35-27(17(31)21(32)39-23(27)28)6-4-3-5-16(30)37-14-11-15(38-19(26)18(24)40-24)29(13-36-29)25(14,26)2/h3-6,14-15,17-20,23,31H,7-13H2,1-2H3/b5-3-,6-4+/t14?,15-,17+,18-,19+,20-,23-,24-,25+,26+,27?,28-,29-/m1/s1

InChI Key

LANVEQVSXWXQLN-UBOVWWEASA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Myrothecium roridum	LOTUS Database	35616633

Chemical Taxonomy

Classification

Not classified

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source

External Links

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (1s,3s,7s,10r,12r,13r,15r,16r,17r,18r,21e,23e,26r,29s)-26-hydroxy-10,17-dimethyl-2,5,11,14,19,28,32-heptaoxaspiro[octacyclo[23.4.3.1¹⁵,¹⁸.0¹,³.0⁷,¹³.0⁷,¹⁷.0¹⁰,¹².0²⁵,²⁹]tritriacontane-16,2'-oxirane]-21,23-diene-4,20,27-trione (NP0207473)

MOL for NP0207473 ((1s,3s,7s,10r,12r,13r,15r,16r,17r,18r,21e,23e,26r,29s)-26-hydroxy-10,17-dimethyl-2,5,11,14,19,28,32-heptaoxaspiro[octacyclo[23.4.3.1¹⁵,¹⁸.0¹,³.0⁷,¹³.0⁷,¹⁷.0¹⁰,¹².0²⁵,²⁹]tritriacontane-16,2'-oxirane]-21,23-diene-4,20,27-trione)

3D MOL for NP0207473 ((1s,3s,7s,10r,12r,13r,15r,16r,17r,18r,21e,23e,26r,29s)-26-hydroxy-10,17-dimethyl-2,5,11,14,19,28,32-heptaoxaspiro[octacyclo[23.4.3.1¹⁵,¹⁸.0¹,³.0⁷,¹³.0⁷,¹⁷.0¹⁰,¹².0²⁵,²⁹]tritriacontane-16,2'-oxirane]-21,23-diene-4,20,27-trione)

3D SDF for NP0207473 ((1s,3s,7s,10r,12r,13r,15r,16r,17r,18r,21e,23e,26r,29s)-26-hydroxy-10,17-dimethyl-2,5,11,14,19,28,32-heptaoxaspiro[octacyclo[23.4.3.1¹⁵,¹⁸.0¹,³.0⁷,¹³.0⁷,¹⁷.0¹⁰,¹².0²⁵,²⁹]tritriacontane-16,2'-oxirane]-21,23-diene-4,20,27-trione)

3D-SDF for NP0207473 ((1s,3s,7s,10r,12r,13r,15r,16r,17r,18r,21e,23e,26r,29s)-26-hydroxy-10,17-dimethyl-2,5,11,14,19,28,32-heptaoxaspiro[octacyclo[23.4.3.1¹⁵,¹⁸.0¹,³.0⁷,¹³.0⁷,¹⁷.0¹⁰,¹².0²⁵,²⁹]tritriacontane-16,2'-oxirane]-21,23-diene-4,20,27-trione)

PDB for NP0207473 ((1s,3s,7s,10r,12r,13r,15r,16r,17r,18r,21e,23e,26r,29s)-26-hydroxy-10,17-dimethyl-2,5,11,14,19,28,32-heptaoxaspiro[octacyclo[23.4.3.1¹⁵,¹⁸.0¹,³.0⁷,¹³.0⁷,¹⁷.0¹⁰,¹².0²⁵,²⁹]tritriacontane-16,2'-oxirane]-21,23-diene-4,20,27-trione)

3D PDB for NP0207473 ((1s,3s,7s,10r,12r,13r,15r,16r,17r,18r,21e,23e,26r,29s)-26-hydroxy-10,17-dimethyl-2,5,11,14,19,28,32-heptaoxaspiro[octacyclo[23.4.3.1¹⁵,¹⁸.0¹,³.0⁷,¹³.0⁷,¹⁷.0¹⁰,¹².0²⁵,²⁹]tritriacontane-16,2'-oxirane]-21,23-diene-4,20,27-trione)

SMILES for NP0207473 ((1s,3s,7s,10r,12r,13r,15r,16r,17r,18r,21e,23e,26r,29s)-26-hydroxy-10,17-dimethyl-2,5,11,14,19,28,32-heptaoxaspiro[octacyclo[23.4.3.1¹⁵,¹⁸.0¹,³.0⁷,¹³.0⁷,¹⁷.0¹⁰,¹².0²⁵,²⁹]tritriacontane-16,2'-oxirane]-21,23-diene-4,20,27-trione)

INCHI for NP0207473 ((1s,3s,7s,10r,12r,13r,15r,16r,17r,18r,21e,23e,26r,29s)-26-hydroxy-10,17-dimethyl-2,5,11,14,19,28,32-heptaoxaspiro[octacyclo[23.4.3.1¹⁵,¹⁸.0¹,³.0⁷,¹³.0⁷,¹⁷.0¹⁰,¹².0²⁵,²⁹]tritriacontane-16,2'-oxirane]-21,23-diene-4,20,27-trione)

Structure for NP0207473 ((1s,3s,7s,10r,12r,13r,15r,16r,17r,18r,21e,23e,26r,29s)-26-hydroxy-10,17-dimethyl-2,5,11,14,19,28,32-heptaoxaspiro[octacyclo[23.4.3.1¹⁵,¹⁸.0¹,³.0⁷,¹³.0⁷,¹⁷.0¹⁰,¹².0²⁵,²⁹]tritriacontane-16,2'-oxirane]-21,23-diene-4,20,27-trione)

3D Structure for NP0207473 ((1s,3s,7s,10r,12r,13r,15r,16r,17r,18r,21e,23e,26r,29s)-26-hydroxy-10,17-dimethyl-2,5,11,14,19,28,32-heptaoxaspiro[octacyclo[23.4.3.1¹⁵,¹⁸.0¹,³.0⁷,¹³.0⁷,¹⁷.0¹⁰,¹².0²⁵,²⁹]tritriacontane-16,2'-oxirane]-21,23-diene-4,20,27-trione)